公开(公告)号：US20160108150A1

公开(公告)日：2016-04-21

申请号：US14981021

申请日：2015-12-28

Applicant: Dow Global Technologies LLC

Inventor： Sylvie Desjardins ,  Mehmet Demirors ,  Ellen Donkers ,  Philip P. Fontaine ,  Cristina Serrat

IPC: C08F110/02 ,  D01F6/04 ,  C08J5/18

CPC classification number: C08F110/02 ,  C08F4/685 ,  C08F10/02 ,  C08F210/16 ,  C08F2410/03 ,  C08J5/18 ,  C08J2323/06 ,  D01F6/04 ,  C08F4/6341 ,  C08F4/6385 ,  C08F4/6374 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/26 ,  C08F4/6357

Abstract: Novel catalyst compositions comprising three or more transition metals are effective in increasing catalyst efficiency, reducing polydispersity, and increasing uniformity in molecular weight distribution when used in olefin, and particularly, linear low density polyethylene (LLDPE), polymerizations. The resulting polymers may be used to form differentiated products including, for example, films that may exhibit improved optical and mechanical properties.

Abstract translation: 包含三种或更多种过渡金属的新型催化剂组合物在用于烯烃，特别是线性低密度聚乙烯（LLDPE））聚合中时，有效地提高催化剂效率，降低多分散性和增加分子量分布的均匀性。 所得聚合物可用于形成分化产物，包括例如可能表现出改善的光学和机械性能的膜。

公开(公告)号：US09115275B2

公开(公告)日：2015-08-25

申请号：US14141835

申请日：2013-12-27

Applicant: Dow Global Technologies LLC

Inventor： Mridula Kupar ,  Mehmet Demirors ,  Pradeep Jain ,  Philip P. Fontaine ,  Douglas S. Ginger ,  David T. Gillespie ,  Mustafa Bilgen

IPC: C08F10/00 ,  C08L23/06 ,  C08L23/08

CPC classification number: C08J5/18 ,  B65D51/26 ,  C07F5/00 ,  C07F7/1804 ,  C08F4/64186 ,  C08F210/14 ,  C08F210/16 ,  C08F2500/03 ,  C08J2323/08 ,  C08J2423/08 ,  C08L23/02 ,  C08L23/06 ,  C08L23/08 ,  C08L23/0815 ,  C08L2203/16 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  Y02P20/582 ,  C08F4/64193 ,  C08F2500/09 ,  C08F2500/12

Abstract: The instant invention provides a polyolefin composition suitable for packaging applications, films, multilayer structures and packaging devices made therefrom. The polyolefin composition according to the present invention comprises: an ethylene/α-olefin interpolymer composition comprising (a) from 50 to 75 percent by weight of a first ethylene/α-olefin copolymer fraction having a density in the range of 0.894 to 0.908 g/cm3, a melt index (I2) in the range of from 0.2 to 1 g/10 minutes, and (b) from 25 to 50 percent by weight of a second ethylene/α-olefin copolymer fraction, and wherein said ethylene/α-olefin interpolymer composition has a density in the range of 0.910 to 0.924 g/cm3, a melt index (I2) in the range of from 0.5 to 2 g/10 minutes, a zero shear viscosity ratio (ZSVR) in the range of from 1.15 to 2.5, a molecular weight distribution, expressed as the ratio of the weight average molecular weight to number average molecular weight (Mw/Mn) in the range of from 2.0 to 4.0, and tan delta at 0.1 radian/second and 190° C. in the range of from 6 to 43.

Abstract translation: 本发明提供一种适用于包装应用，薄膜，多层结构和由其制成的包装装置的聚烯烃组合物。 根据本发明的聚烯烃组合物包含：乙烯/α-烯烃互聚物组合物，其包含（a）50至75重量％的密度在0.894至0.908g范围内的第一乙烯/α-烯烃共聚物部分 / cm 3，熔体指数（I 2）在0.2〜1g / 10分钟的范围内，和（b）25〜50重量％的第二乙烯/α-烯烃共聚物部分，其中所述乙烯/ α-烯烃互聚物组合物的密度范围为0.910〜0.924g / cm3，熔体指数（I2）为0.5〜2g / 10分钟，零剪切粘度比（ZSVR）为 1.15至2.5，分子量分布表示为重均分子量与数均分子量（Mw / Mn）的比值在2.0至4.0的范围内，tanδ在0.1弧度/秒和190℃ 在6到43的范围内。

公开(公告)号：US09102819B2

公开(公告)日：2015-08-11

申请号：US14142014

申请日：2013-12-27

Applicant: Dow Global Technologies LLC

Inventor： Mridula Kapur ,  Mehmet Demirors ,  Philip P. Fontaine ,  Douglas S. Ginger ,  David T. Gillespie

IPC: C08L23/04 ,  C08L23/00 ,  C08L23/08 ,  C08L23/06

CPC classification number: C08J5/18 ,  B65D51/26 ,  C07F5/00 ,  C07F7/1804 ,  C08F4/64186 ,  C08F210/14 ,  C08F210/16 ,  C08F2500/03 ,  C08J2323/08 ,  C08J2423/08 ,  C08L23/02 ,  C08L23/06 ,  C08L23/08 ,  C08L23/0815 ,  C08L2203/16 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  Y02P20/582 ,  C08F4/64193 ,  C08F2500/09 ,  C08F2500/12

Abstract: The instant invention provides a polyolefin composition suitable for injection molding applications, and method of making such injection molded articles. The polyolefin composition suitable for injection molding applications comprises: an ethylene/α-olefin interpolymer composition comprising: (a) from 25 to 50 percent by weight of a first ethylene/α-olefin copolymer fraction having a density in the range of from 0.924 to 0.937 g/cm3, a melt index (I2) in the range of from 0.03 to 0.3 g/10 min, (b) from 50 to 75 percent by weight of a second ethylene homopolymer fraction having a density in the range of from greater than 0.960 g/cm3, a melt index (I2) in the range of from 100 to 180 g/10 minutes, wherein said ethylene/α-olefin interpolymer composition has a density in the range of from 0.950 to 0.958 g/cm3, a melt index (I2) in the range of from 1.0 g/10 min to 3.5 g/10 min, a zero shear viscosity ratio (ZSVR) in the range of from 1.01 to 2.5, a molecular weight distribution (Mw/Mn) in the range of from 2.0 to 4.0, and tan delta at 0.1 radian/second and 190° C. in the range of from 9 to 50.

Abstract translation: 本发明提供了适用于注塑应用的聚烯烃组合物，以及制备这种注模制品的方法。 适用于注塑应用的聚烯烃组合物包括：乙烯/α-烯烃互聚物组合物，其包含：（a）25至50重量％的第一乙烯/α-烯烃共聚物部分，其密度范围为0.924至 0.937g / cm 3，熔体指数（I 2）在0.03至0.3g / 10min的范围内，（b）50至75重量％的第二乙烯均聚物部分，其密度在大于 0.960g / cm 3，熔体指数（I 2）在100至180g / 10分钟的范围内，其中所述乙烯/α-烯烃互聚物组合物的密度范围为0.950至0.958g / cm 3，熔体 指数（I 2）在1.0g / 10min至3.5g / 10min的范围内，零剪切粘度比（ZSVR）在1.01至2.5范围内，分子量分布（Mw / Mn）在该范围内 为2.0〜4.0，tanδ为0.1弧度/秒，190℃为9〜50。

公开(公告)号：US20150148491A1

公开(公告)日：2015-05-28

申请号：US14142014

申请日：2013-12-27

Applicant: Dow Global Technologies LLC

Inventor： Mridula Kapur ,  Mehmet Demirors ,  Philip P. Fontaine ,  Douglas S. Ginger ,  David T. Gillespie

IPC: C08L23/08 ,  C08L23/06

CPC classification number: C08J5/18 ,  B65D51/26 ,  C07F5/00 ,  C07F7/1804 ,  C08F4/64186 ,  C08F210/14 ,  C08F210/16 ,  C08F2500/03 ,  C08J2323/08 ,  C08J2423/08 ,  C08L23/02 ,  C08L23/06 ,  C08L23/08 ,  C08L23/0815 ,  C08L2203/16 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  Y02P20/582 ,  C08F4/64193 ,  C08F2500/09 ,  C08F2500/12

Abstract: The instant invention provides a polyolefin composition suitable for injection molding applications, and method of making such injection molded articles. The polyolefin composition suitable for injection molding applications comprises: an ethylene/α-olefin interpolymer composition comprising: (a) from 25 to 50 percent by weight of a first ethylene/α-olefin copolymer fraction having a density in the range of from 0.924 to 0.937 g/cm3, a melt index (I2) in the range of from 0.03 to 0.3 g/10 min, (b) from 50 to 75 percent by weight of a second ethylene homopolymer fraction having a density in the range of from greater than 0.960 g/cm3, a melt index (I2) in the range of from 100 to 180 g/10 minutes, wherein said ethylene/α-olefin interpolymer composition has a density in the range of from 0.950 to 0.958 g/cm3, a melt index (I2) in the range of from 1.0 g/10 min to 3.5 g/10 min, a zero shear viscosity ratio (ZSVR) in the range of from 1.01 to 2.5, a molecular weight distribution (Mw/Mn) in the range of from 2.0 to 4.0, and tan delta at 0.1 radian/second and 190° C. in the range of from 9 to 50.

Abstract translation: 本发明提供了适用于注塑应用的聚烯烃组合物，以及制备这种注模制品的方法。 适用于注塑应用的聚烯烃组合物包括：乙烯/α-烯烃互聚物组合物，其包含：（a）25至50重量％的第一乙烯/α-烯烃共聚物部分，其密度范围为0.924至 0.937g / cm 3，熔体指数（I 2）在0.03至0.3g / 10min的范围内，（b）50至75重量％的第二乙烯均聚物部分，其密度在大于 0.960g / cm 3，熔体指数（I 2）在100至180g / 10分钟的范围内，其中所述乙烯/α-烯烃互聚物组合物的密度范围为0.950至0.958g / cm 3，熔体 指数（I 2）在1.0g / 10min至3.5g / 10min的范围内，零剪切粘度比（ZSVR）在1.01至2.5范围内，分子量分布（Mw / Mn）在该范围内 为2.0〜4.0，tanδ为0.1弧度/秒，190℃为9〜50。

公开(公告)号：US20250109217A1

公开(公告)日：2025-04-03

申请号：US18725529

申请日：2022-12-29

Applicant: Dow Global Technologies LLC

Inventor： Philip P. Fontaine ,  Edmund M. Carnahan ,  Jerzy Klosin ,  Mari S. Rosen ,  Fawzi G. Hamad

IPC: C08F2/06 ,  C08F2/00 ,  C08F4/64 ,  C08F4/659 ,  C08F210/16

Abstract: Embodiments of this disclosure includes processes of polymerizing a multi-modal polyethylene polymer. The process includes contacting ethylene and optionally one or more α-olefin monomers with at least two catalyst systems in a solution reactor at a reactor temperature of greater than 150° C. The at least two catalyst systems produce a vinyl end group count per 1000 carbon atoms is greater than 0.3. A first catalyst system of the at least two catalyst systems includes a first procatalyst; and a second catalyst system of the at least two catalyst systems comprises a second procatalyst having a reactivity ratio of less than 20, wherein the reactivity ratio of the first procatalyst is measured in a single reactor with only the first catalyst system in the presence of 1250 grams of ISOPAR-E, with a mol fraction of ethylene in solution of 0.709, and at a reactor temperature of at least 150° C.

公开(公告)号：US20250011478A1

公开(公告)日：2025-01-09

申请号：US18710887

申请日：2022-11-21

Applicant: Dow Global Technologies LLC

Inventor： Andrew M. Camelio ,  Rhett A. Baillie ,  Brad C. Bailey ,  Johnathan E. DeLorbe ,  Hien Q. Do ,  David M. Pearson ,  Philip P. Fontaine

IPC: C08F4/659 ,  C08F2/34 ,  C08F210/16

Abstract: Embodiments of the present application are directed to supported catalyst systems that include a metal-ligand complex having the structure of formula (I).

公开(公告)号：US11873393B2

公开(公告)日：2024-01-16

申请号：US16973639

申请日：2019-06-13

Applicant: Dow Global Technologies LLC

Inventor： Kyle E. Hart ,  Mehmet Demirors ,  Timothy W. Gambrel ,  Philip P. Fontaine ,  Pradeep Jain

IPC: C08F210/16 ,  C08L23/12 ,  C08F2/00 ,  C08F2/01 ,  C08F210/14 ,  C08F4/64 ,  C08F4/655 ,  C08F4/659

CPC classification number: C08L23/12 ,  C08F2/001 ,  C08F2/01 ,  C08F210/14 ,  C08F210/16 ,  C08F4/64193 ,  C08F4/6555 ,  C08F4/65904 ,  C08F2500/05 ,  C08F2500/10 ,  C08F2500/12 ,  C08L2203/16 ,  C08L2205/02 ,  C08L2207/062 ,  C08L2207/066

Abstract: A bimodal ethylene-based polymer, including a high density fraction (HDF) from 3.0% to 25.0%, wherein the high density fraction is measured by crystallization elution fractionation (CEF) integration at temperatures from 93° C. to 119° C., an I10/I2 ratio from 5.5 to 7.5, wherein I2 is the melt index when measured according to ASTM D 1238 at a load of 2.16 kg and temperature of 190° C. and I10 is the melt index when measured according to ASTM D 1238 at a load of 10 kg and temperature of 190° C., and a short chain branching distribution (SCBD) less than or equal to 10° C., wherein the short chain branching distribution is measured by CEF full width at half height.

公开(公告)号：US20230322968A1

公开(公告)日：2023-10-12

申请号：US18000036

申请日：2021-05-28

Applicant: Dow Global Technologies LLC

Inventor： Rhett A. Baillie ,  Hien Q. Do ,  Andrew M. Camelio ,  Johnathan E. Delorbe ,  Mari S. Rosen ,  Philip P. Fontaine ,  David M. Pearson

IPC: C08F4/64 ,  C08F210/16 ,  C08F2/01 ,  C08F2/34

CPC classification number: C08F4/64193 ,  C08F2/01 ,  C08F2/34 ,  C08F210/16

Abstract: Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (I): [Formula I]

公开(公告)号：US20230287152A1

公开(公告)日：2023-09-14

申请号：US18005754

申请日：2021-02-05

Applicant: Dow Global Technologies LLC

Inventor： Philip P. Fontaine ,  David M. Pearson ,  Hien Q. Do ,  Johnathan E. Delorbe ,  Rafael Huacuja ,  Rhett A. Baillie

IPC: C08F4/76 ,  C08F4/58 ,  C08F4/52 ,  C08F2/44 ,  C08F210/18

CPC classification number: C08F4/76 ,  C08F2/44 ,  C08F4/52 ,  C08F4/58 ,  C08F210/18 ,  C08F2410/04

Abstract: Processes of polymerizing olefin monomers. The process comprising reacting ethylene and optionally one or more olefin monomers in the presence of a catalyst system, wherein the catalyst system comprises: an activator; hydrocarbyl-modified methylaluminoxane having less than 25 mole percent trihydrocarbyl aluminum compounds AlRA1RB1RC1 based on the total moles of aluminum, where RA1, RB1, and RC1 are independently linear (C1-C40)alkyl, branched (C1-C40)alkyl, or (C6-C40)aryl; and one or more metal-ligand complexes according to formula (1):

公开(公告)号：US20230235099A1

公开(公告)日：2023-07-27

申请号：US18000038

申请日：2021-05-28

Applicant: Dow Global Technologies LLC

Inventor： Rhett A. Baillie ,  Hien Q. Do ,  David M. Pearson ,  Johnathan E. Delorbe ,  Andrew M. Camelio ,  Philip P. Fontaine

IPC: C08F4/646 ,  C08F4/02 ,  C08F210/02 ,  C08F2/34 ,  C08K5/56

CPC classification number: C08F4/6465 ,  C08F2/34 ,  C08F4/02 ,  C08F210/02 ,  C08K5/56 ,  C08F2410/00

Abstract: Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (I):