摘要:
The present invention relates to a method for preparing a catalyst, and in particular provides a method for preparing a catalyst suitable for the polymerisation of ethylene and/or propylene, said catalyst comprising a compound of yttrium, neodymium or scandium supported on a silica support, and wherein the method comprises: a) Treating a silica support by heating at a temperature of at least 550° C., b) Contacting the treated silica support with a complex of the following formula: DmMX1X2R wherein M is selected from Y, Sc and Nd, R is a hydrocarbyl group, X1 and X2 are anionic groups, D is a neutral donor group, and m is 0 or greater.
摘要:
The present invention provides a polyolefin polymer having a bimodal composition with a reduced higher molecular weight component prepared using a self-supported phosphinimine single site catalyst. The catalyst is prepared by precipitating an emulsion of the activated catalyst from a perfluoroalkane continuous phase resulting in spherical catalyst particles having a diameter typically from 5 to 200 μm.
摘要:
The present invention relates to an olefm polymerization process, wherein propylene and 1-butene and optionally ethylene are reacted in the presence of a Ziegler-Natta catalyst system so as to obtain a polypropylene, wherein the polypropylene comprises 1-butene-derived comonomer units in an amount of from 5 to 20 wt % and optionally ethylene-derived comonomer units in an amount of up to 3 wt %, and the Ziegler-Natta catalyst system comprises an external donor of the following formula (I): (R3)z(R2O)ySi(R1)x.
摘要:
Provided are methods of preparing polymers, such as polyisoprene, polybutadiene, polypiperylene, polycyclohexadiene, poly-β-farnesene, or poly-β-myrcene, using iron complexes. Also provided are novel iron complexes, pre-catalysts, intermediates, and ligands useful in the inventive polymerization system.
摘要:
Provided are methods of preparing polymers, such as polyisoprene, polybutadiene, polypiperylene, polycyclohexadiene, poly-β-farnesene, or poly-β-myrcene, using iron complexes. Also provided are novel iron complexes, pre-catalysts, intermediates, and ligands useful in the inventive polymerization system.
摘要:
An object of the present invention is to provide a curing accelerator for an oxidative polymerization-type unsaturated resin which can decrease the amount of use of a cobalt metal soap and which has curing performance equal to or higher than the excellent curing performance of a cobalt metal soap, and also provide a printing ink and a coating material using the curing accelerator. The present invention provides a curing accelerator, and a printing ink and a coating material containing the curing accelerator, the curing accelerator including a fatty acid manganese salt (A), an aminoalcohol (B) represented by general formula (1) below, and at least one fatty acid metal salt (C) selected from the group consisting of a fatty acid bismuth salt, a fatty acid zirconium salt, a fatty acid barium salt, and a fatty acid iron salt.
摘要:
The invention relates to free-radical polymerization and free-radical cross-linking and more particularly provides a process of free-radical polymerization or cross-linking wherein at least one polymerizable monomer or at least one compound to be cross-linked is contacted in the presence of at least one selected organic peroxides, characterized in that the organic peroxide is prepared continuously by an ex situ process with the aid of a closed plate exchanger. In the process according to the invention, it's possible to introduce the above selected organic peroxide continuously during the polymerization or cross-linking reaction.
摘要:
Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (I):
摘要:
A catalyst system including a procatalyst, a co-catalyst and an external electron donor of Formula I′: Si(L)n(OR11)4-n-m(R12)m Formula I′ wherein, Si has a valency 4+; O has a valency 2− and O is bonded to Si via a silicon-oxygen bond; n is 1-4; m is 0-3; n+m≦4; each R11 and R12 group is independently an alkyl or aromatic substituted or unsubstituted hydrocarbyl; each L group is independently of Formula II: wherein, L is bonded to the silicon atom via the nitrogen-silicon bond; L has a single substituent on the nitrogen atom, where this single substituent is an imine carbon atom; and X and Y are independently a hydrogen atom; a heteroatom of Groups 13-17; an alkyl, optionally containing a heteroatom of Groups 13-17 or an aromatic substituted and unsubstituted hydrocarbyl, optionally containing a heteroatom of Groups 13-17.
摘要:
A catalyst system including a procatalyst, a co-catalyst and an external electron donor of Formula I′: Si(L)n(OR11)4-n-m(R12)m Formula I′ wherein, Si has a valency 4+; O has a valency 2− and O is bonded to Si via a silicon-oxygen bond; n is 1-4; m is 0-3; n+m≦4; each R11 and R12 group is independently an alkyl or aromatic substituted or unsubstituted hydrocarbyl; each L group is independently of Formula II: wherein, L is bonded to the silicon atom via the nitrogen-silicon bond; L has a single substituent on the nitrogen atom, where this single substituent is an imine carbon atom; and X and Y are independently a hydrogen atom; a heteroatom of Groups 13-17; an alkyl, optionally containing a heteroatom of Groups 13-17 or an aromatic substituted and unsubstituted hydrocarbyl, optionally containing a heteroatom of Groups 13-17.