Abstract:
A barrier film comprising a polyester-based polymer with (a) an O2 gas permeability of 0.25 cc-mil/100 in.2 24 hrs atm (5 cc 20 μm/m2 24 hrs atm) at 80% relative humidity (ASTM D-3985) or less, (b) a moisture permeability of 0.5 g-mil/100 in.2 24 hrs atm (9.8 g 20 μm/m2 24 hrs atm) at 38° C. (ASTM F-1249) or less, (c) haze of 1% or less (ASTM D1003), and (d) a glass transition temperature of 100° C. or higher. The polyester-based polymer may comprise reaction product of (a) one or more diacid or diester thereof, and (b) one or more polyol, wherein component (a) comprises 5 to 100 mole %, based on the total amount of component (a), of 2,5-furan dicarboxylic acid, or one or more C1 to C10 alkyl diester thereof, and component (b) comprises ethylene glycol, a mixture of 1,3-cyclohexanedimethanol and 1,4-cyclohexanedimethanol, or 2,2,4,4-tetramethyl-1,3-cyclobutanediol, or combinations thereof.
Abstract translation:包含聚酯基聚合物的隔离膜,其具有(a)在80%相对湿度下的氧气渗透率为0.25cc密尔/ 100in.2,24小时atm(5cc20μm/ m 2 24小时atm)(ASTM D- 3985)或更小,(b)在38℃下24小时大气压(9.8g20μm/ m 2 24小时atm)下的透湿度为0.5g密耳/ 100(ASTM F-1249)或更低,( c)雾度为1%以下(ASTM D1003),(d)玻璃化转变温度为100℃以上。 基于聚酯的聚合物可以包含(a)一种或多种二酸或二酯的反应产物和(b)一种或多种多元醇,其中组分(a)占组分总量的5-100摩尔% a),2,5-呋喃二羧酸或其一个或多个C1至C10烷基二酯,组分(b)包括乙二醇,1,3-环己烷二甲醇和1,4-环己烷二甲醇的混合物,或2, 2,4,4-四甲基-1,3-环丁二醇或其组合。
Abstract:
A process to prepare a vinylidene chloride heteropolymer comprising copolymerizing vinylidene chloride with at least one comonomer selected from the group consisting of alkyl acrylates, non-vinylidene chloride vinyl monomers and combinations thereof in the presence of an indicator, wherein the indicator is soluble in vinylidene chloride, the at least one comonomer, or a mixture of the vinylidene chloride and the at least one comonomer is provided.
Abstract:
The present disclosure provides a coextruded multi layer film. The coextruded multilayer film includes a core component having from 15 to 1000 alternating layers of layer A and layer B. Layer A has a thickness from 30 nm to 1000 nm and includes a propylene-based polymer having a crystallization temperature (T1c). Layer B includes a second polymer having a glass transition temperature (T2g), wherein l\ c
Abstract translation:本公开提供了共挤出的多层膜。 共挤出多层膜包括具有15至1000层交替层A和B层的芯组分。层A具有30nm至1000nm的厚度,并且包括具有结晶温度(T1c)的丙烯类聚合物。 层B包括具有玻璃化转变温度(T2g)的第二聚合物,其中l 1 c
Abstract:
The disclosure provides a coextruded multilayer film. The coextruded multilayer film includes a core component having from 15 to 1000 alternating layers of layer A and layer B. Layer A has a thickness from 100 nm to 500 nm and includes an ethylene-based polymer. Layer B has a thickness from 100 nm to 500 nm and includes a cyclic olefin polymer (“COP”). Layer A has an effective moisture permeability less than 0.20 g-mil/100 in2/day and an effective oxygen permeability less than 150 cc-mil/100 in2/day/atm. In an embodiment, the multilayer film includes skin layers.
Abstract translation:本公开提供了共挤出的多层膜。 共挤出的多层膜包括具有层A和层B的15至1000个交替层的芯部件。层A具有100nm至500nm的厚度,并且包括乙烯类聚合物。 层B具有100nm至500nm的厚度,并且包括环烯烃聚合物(“COP”)。 层A的有效透湿度小于0.20g / mil / 100in2 /天,有效透氧度小于150cc / mil / 100in2 /天/ atm。 在一个实施例中,多层膜包括表皮层。
Abstract:
A multilayer film comprising (a) a biaxially-oriented polyethylene furanoate (BO-PEF) polymer layer, (b) an optional ink layer, (c) a bonding layer, and (d) a sealant layer, wherein the BO-PEF polymer has an 02 gas permeability of less than 0.25 cc-mil/100 in.2 24 hrs atm at 80% relative humidity, or a moisture permeability of less than 0.5 g-mil/ 100 in.2 24 hrs atm at 38° C., or both. The film may be formed from microlayers of BO-PEF -based polymer and polymer with a melting point of at least 5° C. greater than the melting point of the BO-PEF-based polymer.
Abstract:
A microlayer component having improved oxygen and water vapor barrier properties (i.e., decreased permeabilities) comprises a barrier microlayer of a semi-crystalline barrier polymer in direct contact with a confining microlayer to promote in-plane crystalline lamellae formation. A microlayer component having a significant amount of in-plane crystalline lamellae may be characterized by at least 1.5× oxygen permeability improvement and at least 1.5× water vapor permeability improvement. A microlayer component having at least 1.5× improvement in oxygen and water vapor permeability may be coextruded and subjected to post extrusion stretching or heat treating.
Abstract:
A polymer blend including a vinylidene chloride interpolymer; an ethylene-acrylate interpolymer; and optionally one or more additives selected from the group consisting of stabilizers, plasticizers, and processing aids is provided. Also provided is an extruded film and a packaging or container which includes the film.
Abstract:
A multilayer film comprising (a) a biaxially-oriented polyethylene furanoate (BO-PEF) polymer layer, (b) an optional ink layer, (c) a bonding layer, and (d) a sealant layer, wherein the BO-PEF polymer has an O2 gas permeability of less than 0.25 cc-mil/100 in.2 24 hrs atm at 80% relative humidity, or a moisture permeability of less than 0.5 g-mil/100 in.2 24 hrs atm at 38° C., or both. The film may be formed from microlayers of BO-PEF-based polymer and polymer with a melting point of at least 5° C. greater than the melting point of the BO-PEF-based polymer.
Abstract:
Disclosed herein is a barrier film comprising at least two substrates each comprising a first surface and a second surface; where the first surface and the second surface are opposedly disposed to each other; the second surfaces of each substrates being in direct contact with each other; where the second surfaces do not contact a barrier coating; and a barrier coating comprising alternating layers of cationic material and anionic material; where the barrier coating is adhesively bonded with the first surfaces of each substrate.
Abstract:
A microlayer component having improved oxygen and water vapor barrier properties (i.e., decreased permeabilities) comprises a barrier microlayer of a semi-crystalline barrier polymer in direct contact with a confining microlayer to promote in-plane crystalline lamellae formation. A microlayer component having a significant amount of in-plane crystalline lamellae may be characterized by at least 1.5× oxygen permeability improvement and at least 1.5× water vapor permeability improvement. A microlayer component having at least 1.5× improvement in oxygen and water vapor permeability may be coextruded and subjected to post extrusion stretching or heat treating.