Abstract:
A laminate, including a fluororesin sheet; and a base material. The fluororesin sheet including a fluororesin composition containing: a melt moldable fluororesin; and a silica. The fluororesin is a tetrafluoroethylene-perfluoro(alkyl vinyl ether) copolymer and/or a tetrafluoroethylene-hexafluoropropylene copolymer having 25 or more carbonyl group-containing functional groups per 106 main-chain carbon atoms; the silica is a spherical silica; a blending ratio of the spherical silica to a total amount of the fluororesin and the silica is 50% by mass or higher and 70% by mass or lower; the fluororesin composition has a linear expansion coefficient of 100 ppm/° C. or lower and a melt flow rate (MFR) of 1.0 g/10 min or higher and 30 g/10 min or lower. Also disclosed is a substrate for circuits including the fluororesin sheet used as a part in a multilayer structure.
Abstract:
An all-solid-state secondary battery mixture, a secondary battery electrode mixture sheet containing the all-solid-state secondary battery mixture, and a secondary battery including the all-solid-state secondary battery sheet. Also provided is a method for producing an all-solid-state secondary battery sheet containing a polytetrafluoroethylene resin having a fine fiber structure. The all-solid-state secondary battery mixture includes a solid-state electrolyte and a binder. The binder is a polytetrafluoroethylene resin, and the polytetrafluoroethylene resin has a fibrous structure with a fibril diameter (median value) of 70 nm or less. In addition, the all-solid-state secondary battery mixture sheet contains the all-solid-state secondary battery mixture.
Abstract:
A composite containing a fluorine-containing copolymer, an alkali metal salt, and an ionic liquid. The fluorine-containing copolymer essentially contains: a structural unit represented by formula (1): —[CR1R2—CR3R4]— wherein R1 to R4 are each independently H, F, Cl, CF3, or OR10, where R10 is an organic group having 1 to 8 carbon atoms, provided that at least one of R1 to R4 is F; and a structural unit represented by formula (2): —[CR5R6—CR7R8]— wherein R5 to R8 are each independently H, F, an alkyl group having 1 to 3 carbon atoms, a functional group containing a heteroatom other than the fluorine atom, or a group containing the functional group. At least one of R5 to R8 is a functional group containing a heteroatom other than the fluorine atom or a group containing the functional group, and the composite has a volatile content of 0.1 mass % or less.
Abstract:
A binder and a slurry suitable for use in the production of an electrode in a sulfide-based solid-state battery. The binder contains sulfide-based solid electrolyte particles, and is a fluorine-containing elastomer in which resin end functional groups satisfy: 0.01≤([—CH2OH]+[—COOH])/([—CH3]+[—CF2H]+[—CH2OH]+[—CH2I]+[—OC(O)RH]+[—COOH]≤0.25 where R represents an alkyl group with 1 to 20 carbon atoms. Also disclosed is an electrode including an electrode active material layer formed using the slurry and a lithium-ion secondary solid state battery including the electrode.
Abstract:
The present invention aims to provide a laminate in which a fluororesin layer and a fluororubber layer are firmly bonded even when the fluororesin layer contains a fluororesin having excellently low fuel permeability. The present invention relates to a laminate including a fluororubber layer (A) and a fluororesin layer (B) stacked on the fluororubber layer (A). The fluororubber layer (A) is a layer formed from a fluororubber composition. The fluororubber composition contains a fluororubber (a1) and a basic multifunctional compound having at least two nitrogen atoms in the molecule with a distance between the nitrogen atoms in the molecule of 5.70 Å or greater. The fluororubber (a1) has an absorption coefficient at 1720 cm−1, determined after being brought into contact with triethyl amine, of 0.35 or lower. The fluororesin layer (B) is formed from a fluororesin (b1) having a fuel permeability coefficient of 2.0 g·mm/m2/day or lower.
Abstract:
A binder and a slurry suitable for use in the production of an electrode in a sulfide-based solid-state battery. The binder contains sulfide-based solid electrolyte particles, and is a fluorine-containing elastomer in which resin end functional groups satisfy: 0.01≤([—CH2OH]+[—COOH])/([—CH3]+[—CF2H]+[—CH2OH]+[—CH2I]+[—OC(O)RH]+[—COOH]≤0.25 wherein R represents an alkyl group with 1 to 20 carbon atoms. Also disclosed is an electrode including an electrode active material layer formed using the slurry and a lithium-ion secondary solid state battery including the electrode.
Abstract:
The present disclosure provides a secondary battery mixture that has good properties, a secondary battery mixture sheet containing the mixture, and a secondary battery using the secondary battery mixture sheet. The secondary battery mixture contains a solid-state electrolyte and/or electrode active material, and a binder, wherein the binder is a fibrillatable resin having a fibrous structure with a fibril diameter (median value) of 100 nm or less, and is contained in the secondary battery mixture in an amount of 0.3% by mass or more and 8% by mass or less.
Abstract:
The present disclosure provides a secondary battery mixture containing an oxide-based electrolyte that has good properties, a secondary battery mixture sheet containing the mixture, and a solid-state secondary battery using the secondary battery mixture sheet. In addition, the present disclosure provides a method for producing a secondary battery mixture sheet that contains a binder having a fine fiber structure. The secondary battery mixture contains an oxide-based solid-state electrolyte and a binder, wherein the binder is a fibrillatable resin. The fibrillatable resin preferably has a fibrous structure with a fibril diameter (median value) of 100 nm or less.
Abstract:
The disclosure aims to provide a polytetrafluoroethylene powder for an electrode binder which can not only reduce or prevent gas generation inside a battery cell and deterioration of battery characteristics but also improve the electrode strength, an electrode binder, an electrode mixture, an electrode, and a secondary battery. Provided is a polytetrafluoroethylene powder for use as an electrode binder, the polytetrafluoroethylene having a standard specific gravity of 2.200 or less and being substantially free from water.
Abstract:
Provided is a composition for electrode formation comprising a copolymer comprising vinylidene fluoride unit and a unit of an other monomer other than vinylidene fluoride, and a solvent represented by a general formula (1): NR1R2R3 wherein R1, R2, and R3 are each independently H or a monovalent substituent, provided that the total number of carbon atoms of R1, R2, and R3 is 6 or more, and at least one of R1, R2, and R3 is an organic group having carbonyl group; and any two of R1, R2, and R3 optionally bond to each other to form a ring.