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    Low-sulfur diesel fuels containing organometallic complexes
    11.
    发明授权
    Low-sulfur diesel fuels containing organometallic complexes 失效
    含有有机金属配合物的低硫柴油燃料

    公开(公告)号：US5376154A

    公开(公告)日：1994-12-27

    申请号：US753517

    申请日：1991-09-03

    Applicant: Daniel T. Daly ,  Paul E. Adams ,  Nai Z. Huang ,  Scott T. Jolley ,  Frederick W. Koch ,  Christopher J. Kolp ,  Stephen H. Stoldt ,  Reed H. Walsh ,  Richard A. Denis ,  Dennis M. Dishong

    Inventor： Daniel T. Daly ,  Paul E. Adams ,  Nai Z. Huang ,  Scott T. Jolley ,  Frederick W. Koch ,  Christopher J. Kolp ,  Stephen H. Stoldt ,  Reed H. Walsh ,  Richard A. Denis ,  Dennis M. Dishong

    IPC: C10L1/14 ,  C10L1/18 ,  C10L1/22 ,  C10L1/30 ,  C10L10/06 ,  F02B3/06 ,  C10L1/26

    CPC classification number: C10L10/06 ,  C10L1/14 ,  C10L1/301 ,  C10L1/183 ,  C10L1/221 ,  C10L1/223 ,  F02B3/06

    Abstract: This invention relates to low-sulfur diesel fuels which are useful with diesel engines equipped with exhaust system particulate traps. These fuels contain an effective amount of an organometallic complex to lower the ignition temperature of exhaust particles collected in the trap. The sulfur content of these diesel fuels is no more than about 0.1% by weight, preferably no more than about 0.05% by weight. The organometallic complex is soluble or stably dispersible in the diesel fuel and is derived from (i) an organic compound containing at least two functional groups attached to a hydrocarbon linkage, and (ii) a metal reactant capable of forming a complex with the organic compound (i), the metal being any metal capable of reducing the ignition temperature of the exhaust particles. The functional groups include .dbd.X, --XR, --NR.sub.2, --NO.sub.2, .dbd.NR, .dbd.NXR, .dbd.N--R*--XR, ##STR1## --CN, --N.dbd.NR and --N.dbd.CR.sub.2 ; wherein X is O or S, R is H or hydrocarbyl, R* is hydrocarbylene or hydrocarbylidene, and a is a number (e.g., zero to about 10). Useful metals include Na, K, Mg, Ca, Sr, Ba, Ti, Zr, V, Cr, Mo, Mn, Fe, Co, Cu, Zn, B, Pb, Sb, and mixtures of two or more thereof. This invention is also directed to methods of operating a diesel engine equipped with an exhaust system particulate trap using the foregoing low-sulfur diesel fuels.

    Abstract translation: 本发明涉及用于配备有排气系统颗粒捕集器的柴油发动机的低硫柴油燃料。 这些燃料含有有效量的有机金属络合物以降低在捕集器中收集的废气颗粒的着火温度。 这些柴油的硫含量不超过约0.1重量％，优选不超过约0.05重量％。 有机金属络合物可溶于或稳定分散于柴油中，并衍生自（i）含有连接至烃键的至少两个官能团的有机化合物，和（ii）能够与有机化合物形成络合物的金属反应物 （i）中，金属是能够降低排气颗粒的着火温度的任何金属。 官能团包括= X，-XR，-NR2，-NO2，= NR，= NXR，= N-R * -XR，图像-CN，-N = NR和-N = CR2; 其中X为O或S，R为H或烃基，R *为亚烃基或亚烃基，a为数（例如0至约10）。 有用的金属包括Na，K，Mg，Ca，Sr，Ba，Ti，Zr，V，Cr，Mo，Mn，Fe，Co，Cu，Zn，B，Pb，Sb及其两种或更多种的混合物。 本发明还涉及使用前述低硫柴油燃料来操作配备有排气系统微粒捕集器的柴油发动机的方法。

    Diesel fuels containing organometallic complexes
    12.
    发明授权
    Diesel fuels containing organometallic complexes 失效
    含有有机金属配合物的柴油

    公开(公告)号：US5340369A

    公开(公告)日：1994-08-23

    申请号：US699409

    申请日：1991-05-13

    Applicant: Frederick W. Koch ,  Daniel T. Daly ,  Nai Z. Huang ,  Scott T. Jolley ,  Christopher J. Kolp ,  Stephen H. Stoldt ,  Richard A. Denis

    Inventor： Frederick W. Koch ,  Daniel T. Daly ,  Nai Z. Huang ,  Scott T. Jolley ,  Christopher J. Kolp ,  Stephen H. Stoldt ,  Richard A. Denis

    IPC: C10L1/14 ,  C10L1/18 ,  C10L1/22 ,  C10L1/24 ,  C10L1/30 ,  C10L10/06 ,  F02B3/06

    CPC classification number: C10L1/301 ,  C10L1/14 ,  C10L10/06 ,  C10L1/183 ,  C10L1/221 ,  C10L1/223 ,  C10L1/232 ,  C10L1/24 ,  F02B3/06

    Abstract: This invention relates to diesel fuels which are useful with diesel engines equipped with exhaust system particulate traps. These fuels contain an effective amount of an organometallic complex to lower the ignition temperature of exhaust particles collected in the trap. The organometallic complex is soluble or stably dispersible in the diesel fuel and is derived from (i) an organic compound containing at least two functional groups attached to a hydrocarbon linkage, and (ii) a metal reactant capable of forming a complex with the organic compound (i), the metal being any metal capable of reducing the ignition temperature of the exhaust particles. The functional groups include .dbd.X, --XR, ##STR1## --CN, --N.dbd.NR and --N.dbd.CR.sub.2 ; wherein X is O or S, R is H or hydrocarbyl, R* is hydrocarbylene or hydrocarbylidene, and a is a number (e.g., zero to about 10). Useful metals include Na, K, Mg, Ca, Sr, Ba, V, Cr, Mo, Fe, Co, Cu, Zn, B, Pb, Sb, and mixtures of two or more thereof. This invention is also directed to methods of operating a diesel engine equipped with an exhaust system particulate trap using the foregoing diesel fuel.

    Abstract translation: 本发明涉及柴油燃料，柴油燃料可用于配备有排气系统颗粒捕集器的柴油发动机。 这些燃料含有有效量的有机金属络合物以降低在捕集器中收集的废气颗粒的着火温度。 有机金属络合物可溶于或稳定分散于柴油中，并衍生自（i）含有连接至烃键的至少两个官能团的有机化合物，和（ii）能够与有机化合物形成络合物的金属反应物 （i）中，金属是能够降低排气颗粒的着火温度的任何金属。 官能团包括= X，-XR，NR2，NO2，NR，NXR，NR * XR，IMA，-CN，-N = NR和-N = CR2; 其中X为O或S，R为H或烃基，R *为亚烃基或亚烃基，a为数（例如0至约10）。 有用的金属包括Na，K，Mg，Ca，Sr，Ba，V，Cr，Mo，Fe，Co，Cu，Zn，B，Pb，Sb及其两种或更多种的混合物。 本发明还涉及使用前述柴油燃料来操作配备有排气系统微粒捕集器的柴油发动机的方法。

    METHODS FOR DISSOLVING POLYMERS USING MIXTURES OF DIFFERENT IONIC LIQUIDS AND COMPOSITIONS COMPRISING THE MIXTURES
    17.
    发明申请
    METHODS FOR DISSOLVING POLYMERS USING MIXTURES OF DIFFERENT IONIC LIQUIDS AND COMPOSITIONS COMPRISING THE MIXTURES 审中-公开
    使用不同离子液体的混合物和包含混合物的组合物溶解聚合物的方法

    公开(公告)号：US20120216705A1

    公开(公告)日：2012-08-30

    申请号：US13505323

    申请日：2010-11-04

    Applicant: Robin D. Rogers ,  Daniel T. Daly ,  Gabriela Gurau

    Inventor： Robin D. Rogers ,  Daniel T. Daly ,  Gabriela Gurau

    IPC: B01F1/00 ,  C08K5/47 ,  C08K5/3415 ,  C08K5/3445 ,  C08K5/3472

    CPC classification number: C08J3/091 ,  C08J2300/16

    Abstract: Disclosed are methods for dissolving biopolymers and synthetic polymers using mixtures of different ionic liquids and compositions comprising the mixture. The methods involve contacting a polymer with a mixture of ionic liquids to provide a composition of polymer and the mixture; the mixture of ionic liquids is prepared by either mixing ionic liquids or by a process comprising reacting ionic liquid precursors in one-pot to form the ionic liquids.

    Abstract translation: 公开了使用不同离子液体和包含该混合物的组合物的混合物溶解生物聚合物和合成聚合物的方法。 所述方法包括使聚合物与离子液体的混合物接触以提供聚合物和混合物的组成; 离子液体的混合物通过混合离子液体或通过包括在一锅中使离子液体前体反应以形成离子液体的方法来制备。

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