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11.发明授权Multipodal tethers for high-density attachment of redox-active moieties to substrates 有权用于将氧化还原活性部分高密度连接到底物的多峰系链公开(公告)号：US08173630B2
公开(公告)日：2012-05-08
申请号：US11446586
申请日：2006-06-01
申请人： Jonathan S. Lindsey , David F. Bocian , Robert Loewe , Ignacio Sanchez , Werner G. Kuhr , Kisari Padmaja , Lingyun Wei
发明人： Jonathan S. Lindsey , David F. Bocian , Robert Loewe , Ignacio Sanchez , Werner G. Kuhr , Kisari Padmaja , Lingyun Wei
IPC分类号： A01N55/02 , C07B47/00 , C07D487/22
CPC分类号： C07D207/335 , B82Y10/00 , B82Y30/00 , C07C17/093 , C07C21/17 , C07C25/24 , C07C45/44 , C07C45/58 , C07C47/548 , C07C255/50 , H01L51/0077 , H01L51/0595 , C07C47/24 , C07C25/22
摘要： This invention provides redox-active molecules attached to polypodal (e.g., bipodal, tripodal, quadrapodal, pentapodal, etc.) tethers that can be used for attachment of the redox-active molecules to a substrate (e.g., an electrode). The tethered redox-active molecules are useful for the fabrication of memory devices.
摘要翻译： 本发明提供连接到可以用于将氧化还原活性分子连接到底物（例如电极）上的多峰（例如，双峰，三峰，四峰，五峰等）系链的氧化还原活性分子。 系留的氧化还原活性分子可用于制造存储器件。
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公开(公告)号：US06657884B2
公开(公告)日：2003-12-02
申请号：US10053814
申请日：2002-01-18
IPC分类号： G11C1100
CPC分类号： H01L51/0078 , B82Y10/00 , C07D487/22 , C07D519/00 , C07F17/02 , G11B9/14 , G11B9/149 , G11C11/5664 , G11C13/0009 , G11C13/0014 , G11C13/0016 , G11C2213/15 , G11C2213/77 , H01L27/28 , H01L51/0077 , H01L51/0084 , H01L51/009 , H01L51/0595 , Y10S977/943
摘要： This invention provides novel high density memory devices that are electrically addressable permitting effective reading and writing, that provide a high memory density (e.g., 1015 bits/cm3), that provide a high degree of fault tolerance, and that are amenable to efficient chemical synthesis and chip fabrication. The devices are intrinsically latchable, defect tolerant, and support destructive or non-destructive read cycles. In a preferred embodiment, the device comprises a fixed electrode electrically coupled to a storage medium having a multiplicity of different and distinguishable oxidation states wherein data is stored in said oxidation states by the addition or withdrawal of one or more electrons from said storage medium via the electrically coupled electrode.
摘要翻译： 本发明提供了可提供高存储密度（例如，10,15bit / cm 3）的电位置可允许有效读/写的新型高密度存储器件，其提供高度的容错能力，并且 适合有效的化学合成和芯片制造。 器件本质上可锁定，缺陷容忍，并支持破坏性或非破坏性的读取周期。 在优选实施例中，该装置包括电耦合到存储介质的固定电极，该存储介质具有多种不同且可区分的氧化态，其中通过经由该存储介质从所述存储介质中添加或撤出一个或多个电子而将数据存储在所述氧化态中 电耦合电极。
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公开(公告)号：US07061791B2
公开(公告)日：2006-06-13
申请号：US10723315
申请日：2003-11-25
IPC分类号： G11C11/00
CPC分类号： H01L51/0078 , B82Y10/00 , C07D487/22 , C07D519/00 , C07F17/02 , G11B9/14 , G11B9/149 , G11C11/5664 , G11C13/0009 , G11C13/0014 , G11C13/0016 , G11C2213/15 , G11C2213/77 , H01L27/28 , H01L51/0077 , H01L51/0084 , H01L51/009 , H01L51/0595 , Y10S977/943
摘要： This invention provides novel high density memory devices that are electrically addressable permitting effective reading and writing, that provide a high memory density (e.g., 1015 bits/cm3), that provide a high degree of fault tolerance, and that are amenable to efficient chemical synthesis and chip fabrication. The devices are intrinsically latchable, defect tolerant, and support destructive or non-destructive read cycles. In a preferred embodiment, the device comprises a fixed electrode electrically coupled to a storage medium having a multiplicity of different and distinguishable oxidation states wherein data is stored in said oxidation states by the addition or withdrawal of one or more electrons from said storage medium via the electrically coupled electrode.
摘要翻译： 本发明提供了可提供高存储密度（例如，10位/ cm 3以上）的可电寻址以允许有效读取和写入的新型高密度存储器件，该 提供高度的容错性，并且适合高效的化学合成和芯片制造。 器件本质上可锁定，缺陷容忍，并支持破坏性或非破坏性的读取周期。 在优选实施例中，该装置包括电耦合到存储介质的固定电极，该存储介质具有多种不同且可区分的氧化态，其中通过经由该存储介质从所述存储介质中添加或撤出一个或多个电子而将数据存储在所述氧化态中 电耦合电极。
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14.发明授权公开(公告)号：US07074519B2
公开(公告)日：2006-07-11
申请号：US10046499
申请日：2001-10-26
申请人： Werner G. Kuhr , David F. Bocian , Zhiming Liu , Amir Yasseri
发明人： Werner G. Kuhr , David F. Bocian , Zhiming Liu , Amir Yasseri
CPC分类号： H01L29/82 , B82Y10/00 , G01N27/3278 , G01N33/5438 , G11C11/5664 , G11C13/0009 , G11C13/0014 , G11C13/0016 , G11C2213/77 , H01M2/02 , H01M4/38 , H01M4/602 , H01M6/40 , H01M10/0436
摘要： This invention provides a new design and fabrication for a three-dimensional crossbar architecture embedding a sub-micron or nanometer sized hole (called a molehole) in each cross-region. Each molehole is an electrochemical cell consisting of two or more sectional surfaces separated by a non-conductor (e.g. a dialectric layer and solid electrolyte). When used in electrochemical molecular memory device (EMMD), the architecture provides unique features such as a nano-scale electroactive surface, no interaction between memory elements, and easier miniaturization and integration.
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公开(公告)号：US08231941B2
公开(公告)日：2012-07-31
申请号：US12265990
申请日：2008-11-06
CPC分类号： H01L51/0089 , B82Y10/00 , H01L51/0003 , H01L51/0595
摘要： This invention provides novel methods for the formation of redox-active polymers attached to surfaces. In certain embodiments, the methods involve providing redox-active molecules bearing at least a first reactive site or group and a second reactive site or group; and contacting the surface with the redox-active molecules where the contacting is under conditions that result in attachment of said redox-active molecules to said surface via the first reactive site or group and attachment of redox-active molecules via the second reactive site or group, to the redox-active molecules attached to the surface thereby forming a polymer attached to said surface where the polymers comprise at least two of said redox-active molecules.
摘要翻译： 本发明提供了形成附着于表面的氧化还原活性聚合物的新方法。 在某些实施方案中，所述方法包括提供至少具有第一反应位点或基团和第二反应位点或基团的氧化还原活性分子; 以及使所述表面与所述氧化还原活性分子接触，其中所述接触在导致所述氧化还原活性分子经由所述第一反应位点或基团连接到所述表面的条件下，并且经由所述第二反应性位点或基团连接氧化还原活性分子 附着于表面的氧化还原活性分子，从而形成连接到所述表面的聚合物，其中聚合物包含至少两种所述氧化还原活性分子。
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公开(公告)号：US06943054B2
公开(公告)日：2005-09-13
申请号：US10628868
申请日：2003-07-28
CPC分类号： H01M4/60 , B82Y10/00 , G11C13/0014 , G11C13/0016 , H01L51/0002 , H01L51/0003 , H01L51/0008 , H01L51/0026 , H01L51/0075 , H01L51/0077 , H01L51/0595 , H01L51/4213 , H01M14/005 , Y02E10/549
摘要： This invention provides a new procedure for attaching molecules to semiconductor surfaces, in particular silicon. The molecules, which include, but are not limited to porphyrins and ferrocenes, have been previously shown to be attractive candidates for molecular-based information storage. The new attachment procedure is simple, can be completed in short times, requires minimal amounts of material, is compatible with diverse molecular functional groups, and in some instances affords unprecedented attachment motifs. These features greatly enhance the integration of the molecular materials into the processing steps that are needed to create hybrid molecular/semiconductor information storage devices.
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公开(公告)号：US08529996B2
公开(公告)日：2013-09-10
申请号：US11688194
申请日：2007-03-19
申请人： David F. Bocian , Jonathan S. Lindsey , Zhiming Liu , Amir A. Yasseri , Veena Misra , Qian Zhao , Qiliang Li , Shyam Surthi , Robert S. Loewe
发明人： David F. Bocian , Jonathan S. Lindsey , Zhiming Liu , Amir A. Yasseri , Veena Misra , Qian Zhao , Qiliang Li , Shyam Surthi , Robert S. Loewe
IPC分类号： C23C16/00
CPC分类号： H01L51/0002 , B82Y10/00 , G11B9/14 , G11B9/149 , G11C13/0014 , G11C13/0016 , H01L51/0008 , H01L51/001 , H01L51/0026 , H01L51/0075 , H01L51/0077 , H01L51/0595 , H01L51/4213 , H01M4/60 , H01M14/005 , Y02E10/549
摘要： This invention provides a new procedure for attaching molecules to semiconductor surfaces, in particular silicon. The molecules, which include, but are not limited to porphyrins and ferrocenes, have been previously shown to be attractive candidates for molecular-based information storage. The new attachment procedure is simple, can be completed in short times, requires minimal amounts of material, is compatible with diverse molecular functional groups, and in some instances affords unprecedented attachment motifs. These features greatly enhance the integration of the molecular materials into the processing steps that are needed to create hybrid molecular/semiconductor information storage devices.
摘要翻译： 本发明提供了一种将分子连接到半导体表面，特别是硅的新方法。 以前已经显示出包括但不限于卟啉和二茂铁的分子是用于基于分子的信息存储的有吸引力的候选物。 新的附件程序简单，可以在短时间内完成，需要最少量的材料，与不同的分子官能团相容，并在某些情况下提供前所未有的附着图案。 这些特征大大增强了分子材料与创建混合分子/半导体信息存储设备所需的处理步骤的集成。
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18.发明授权Stepwise growth of oligomeric redox-active molecules on a surface without the use of protecting groups 有权在不使用保护基团的情况下，在表面上逐步生长低聚氧化还原活性分子公开(公告)号：US08062756B2
公开(公告)日：2011-11-22
申请号：US11509319
申请日：2006-08-23
IPC分类号： B32B15/04
CPC分类号： H01L51/0077 , B05D1/34 , B05D7/24 , B82Y10/00 , G01N27/305 , G11C13/0009 , G11C13/0014 , G11C13/0016 , H01L51/0053 , H01L51/0591 , H01L51/0595 , H01L51/4206 , Y02E10/549 , Y10T428/31678 , Y10T428/8305
摘要： This invention provides a procedure for growing oligomers via a stepwise process. The oligomers can include porphyrins, which have been previously shown to be attractive candidates for molecular-based information storage. The stepwise synthesis procedure requires no protecting groups, thus eliminating protection/deprotection reactions that add complexity to the process.
摘要翻译： 本发明提供了通过逐步方法生长低聚物的方法。 低聚物可以包括卟啉，其先前已经被证明是用于基于分子的信息存储的有吸引力的候选物。 逐步合成方法不需要保护基团，因此消除了加工过程复杂性的保护/去保护反应。
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公开(公告)号：US20100330284A1
公开(公告)日：2010-12-30
申请号：US12265990
申请日：2008-11-06
IPC分类号： B05D3/10
CPC分类号： H01L51/0089 , B82Y10/00 , H01L51/0003 , H01L51/0595
摘要： This invention provides novel methods for the formation of redox-active polymers attached to surfaces. In certain embodiments, the methods involve providing redox-active molecules bearing at least a first reactive site or group and a second reactive site or group; and contacting the surface with the redox-active molecules where the contacting is under conditions that result in attachment of said redox-active molecules to said surface via the first reactive site or group and attachment of redox-active molecules via the second reactive site or group, to the redox-active molecules attached to the surface thereby forming a polymer attached to said surface where the polymers comprise at least two of said redox-active molecules.
摘要翻译： 本发明提供了形成附着于表面的氧化还原活性聚合物的新方法。 在某些实施方案中，所述方法包括提供至少具有第一反应位点或基团和第二反应位点或基团的氧化还原活性分子; 以及使所述表面与所述氧化还原活性分子接触，其中所述接触在导致所述氧化还原活性分子经由所述第一反应位点或基团连接到所述表面的条件下，并且经由所述第二反应性位点或基团连接氧化还原活性分子 附着于表面的氧化还原活性分子，从而形成连接到所述表面的聚合物，其中聚合物包含至少两种所述氧化还原活性分子。
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公开(公告)号：US07452572B1
公开(公告)日：2008-11-18
申请号：US10800147
申请日：2004-03-11
CPC分类号： H01L51/0089 , B82Y10/00 , H01L51/0003 , H01L51/0595
摘要： This invention provides novel methods for the formation of redox-active polymers attached to surfaces. In certain embodiments, the methods involve providing redox-active molecules bearing at least a first reactive site or group and a second reactive site or group; and contacting the surface with the redox-active molecules where the contacting is under conditions that result in attachment of said redox-active molecules to said surface via the first reactive site or group and attachment of redox-active molecules via the second reactive site or group, to the redox-active molecules attached to the surface thereby forming a polymer attached to said surface where the polymers comprise at least two of said redox-active molecules.
摘要翻译： 本发明提供了形成附着于表面的氧化还原活性聚合物的新方法。 在某些实施方案中，所述方法包括提供至少具有第一反应位点或基团和第二反应位点或基团的氧化还原活性分子; 以及使所述表面与所述氧化还原活性分子接触，其中所述接触在导致所述氧化还原活性分子经由所述第一反应位点或基团连接到所述表面的条件下，并且经由所述第二反应性位点或基团连接氧化还原活性分子 附着于表面的氧化还原活性分子，从而形成连接到所述表面的聚合物，其中聚合物包含至少两种所述氧化还原活性分子。
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