公开(公告)号：US07456295B1

公开(公告)日：2008-11-25

申请号：US11645257

申请日：2006-11-25

申请人： David J. Irvin ,  David L. Witker ,  John D. Stenger-Smith ,  Jennifer A. Irvin

发明人： David J. Irvin ,  David L. Witker ,  John D. Stenger-Smith ,  Jennifer A. Irvin

IPC分类号： C07D231/10 ,  C07D409/06

CPC分类号： C07D409/04 ,  C07D333/22

摘要： The present invention demonstrates the synthesis of a new pyrazole-containing monomer by means of an easily implemented two-step process. This monomer can be electropolymerized to yield a stable n-doping polymer that may easily be electrochemically characterized. It is demonstrated that the electrochemical behavior of the polymer films produced is dependent upon the conditions applied during electrodeposition. Films deposited by cycling only at relatively positive potentials (0 to 2000 mV) show less intense n-doping responses than those films obtained by scanning the applied potential throughout a wider range (−2000 mV to 2000 mV). It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope of the claims.

摘要翻译： 本发明通过易于实施的两步方法证明了新的含吡唑单体的合成。 该单体可以电聚合以产生可以容易地电化学表征的稳定的n掺杂聚合物。 证明所生产的聚合物膜的电化学行为取决于电沉积期间的应用条件。 通过仅在相对正电位（0至2000mV）下循环沉积的膜显示比通过在更宽范围（-2000mV至2000mV）范围内扫描施加电位获得的那些薄膜更强烈的n掺杂响应。 要强调的是，该摘要被提供以符合要求抽象的规则，允许搜索者或其他读者快速确定技术公开的主题。 提交它的理解是，它不会用于解释或限制权利要求的范围。

公开(公告)号：US08183390B1

公开(公告)日：2012-05-22

申请号：US12858993

申请日：2010-08-18

申请人： David J. Irvin ,  David L. Witker ,  John D. Stenger-Smith ,  Jennifer A. Irvin

发明人： David J. Irvin ,  David L. Witker ,  John D. Stenger-Smith ,  Jennifer A. Irvin

IPC分类号： C07D409/06

CPC分类号： C08F128/06 ,  C07D333/22 ,  C07D409/06 ,  C08G61/123 ,  C08G61/126 ,  C08G73/0616 ,  C08G2261/3221 ,  C08G2261/3223 ,  C08G2261/364 ,  C08G2261/44

摘要： The invention demonstrates the synthesis of a new pyrazole-containing monomer by means of an easily implemented two-step process. This monomer can be electropolymerized to yield a stable n-doping polymer that may easily be electrochemically characterized. It is demonstrated that the electrochemical behavior of the polymer films produced is dependent upon the conditions applied during electrodeposition. Films deposited by cycling only at relatively positive potentials (0 to 2000 mV) show less intense n-doping responses than those films obtained by scanning the applied potential throughout a wider range (−2000 mV to 2000 mV).

摘要翻译： 本发明通过易于实施的两步法合成了含吡唑的单体。 该单体可以电聚合以产生可以容易地电化学表征的稳定的n掺杂聚合物。 证明所生产的聚合物膜的电化学行为取决于电沉积期间的应用条件。 通过仅在相对正电位（0至2000mV）下循环沉积的膜比通过在更宽范围（-2000mV至2000mV）范围内扫描施加电位而获得的膜显示出更少的强度n掺杂响应。

公开(公告)号：US07462681B1

公开(公告)日：2008-12-09

申请号：US11239443

申请日：2005-09-19

申请人： Andrew J. Guenthner ,  Gregory R. Yandek ,  David J. Irvin

发明人： Andrew J. Guenthner ,  Gregory R. Yandek ,  David J. Irvin

IPC分类号： C08G64/00 ,  C08G63/02

CPC分类号： C08L69/00 ,  C08L79/04 ,  C08L2666/20 ,  C08L2666/18

摘要： A polycyanurate composition (I), wherein “n” is a positive integer of about 1 to about 10, and wherein R, R′, and R″ comprising at least one of C, H, N, O, F, Si, P, S, Cl, Br, I, and any combination thereof. A method of making a polycyanurate composition (I) including, providing at least one semi-aliphatic polycarbonate (V), wherein R comprises at least one of C, H, N, O, F, Si, P, S, Cl, Br, I, providing at least one uncured reactive thermoset monomer, dissolving the polycarbonate in a solvent with a high vapor pressure or suspending the polycarbonate directly into the reactive monomer, mixing the liquefied polycarbonate with the uncured reactive thermoset monomer into a homogeneous liquid component, curing the liquid component into a viscous component, and exposing the cured component to temperatures of about 50° C. to about 400° C. forming tricyanurate linkages in the polycyanurate composition (I).

摘要翻译： 一种聚氰尿酸酯组合物（I），其中“n”为约1至约10的正整数，并且其中R，R'和R“包含C，H，N，O，F，Si， P，S，Cl，Br，I及其任何组合。 一种制备聚氰脲酸盐组合物（I）的方法，包括提供至少一种半脂族聚碳酸酯（V），其中R包含C，H，N，O，F，Si，P，S，Cl，Br I提供至少一种未固化的反应性热固性单体，将聚碳酸酯溶解在具有高蒸气压的溶剂中或将聚碳酸酯直接悬浮于反应性单体中，将液化的聚碳酸酯与未固化的反应性热固性单体混合成均匀的液体组分，固化 将液体组分变成粘性组分，并将固化的组分暴露于约50℃至约400℃的温度，在聚氰化脲组合物（I）中形成三氰脲酸酯键。

公开(公告)号：US08737038B1

公开(公告)日：2014-05-27

申请号：US12878744

申请日：2010-09-09

申请人： David J. Irvin ,  Jennifer A. Irvin ,  John D. Stenger-Smith

发明人： David J. Irvin ,  Jennifer A. Irvin ,  John D. Stenger-Smith

IPC分类号： H01G9/00

CPC分类号： C07D409/04 ,  C07D333/22

摘要： An electroactive polymer based super capacitor capable of operation at MILSPEC temperatures, with electroactive polymers acting as the charge storage layers, and a mixture of electrolytes enabling operation down to −60° C.

摘要翻译： 一种基于电活性聚合物的超级电容器，能够以MILSPEC的温度运行，电活性聚合物充当电荷存储层，以及电解质的混合使其能够运行到-60℃。

公开(公告)号：US07608179B1

公开(公告)日：2009-10-27

申请号：US12178947

申请日：2008-07-24

申请人： David J. Irvin ,  David L. Witker ,  John D. Stenger-Smith ,  Jennifer A. Irvin

发明人： David J. Irvin ,  David L. Witker ,  John D. Stenger-Smith ,  Jennifer A. Irvin

IPC分类号： C25B3/00

CPC分类号： C07D409/04 ,  C07D333/22

摘要： The present invention demonstrates the synthesis of a new pyrazole-containing monomer by an easily implemented two-step process. This monomer can be electropolymerized to yield a stable n-doping polymer that may easily be electrochemically characterized. It is demonstrated that the electrochemical behavior of the polymer films produced is dependent upon the conditions applied during electrodeposition. Films deposited by cycling only at relatively positive potentials (0 to 2000 mV) show less intense n-doping responses than those films obtained by scanning the applied potential throughout a wider range (−2000 mV to 2000 mV).

摘要翻译： 本发明通过易于实施的两步法合成了含吡唑的单体。 该单体可以电聚合以产生可以容易地电化学表征的稳定的n掺杂聚合物。 证明所生产的聚合物膜的电化学行为取决于电沉积期间的应用条件。 通过仅在相对正电位（0至2000mV）下循环沉积的膜比通过在更宽范围（-2000mV至2000mV）范围内扫描施加电位而获得的膜显示出更少的强度n掺杂响应。

公开(公告)号：US08680292B1

公开(公告)日：2014-03-25

申请号：US13412789

申请日：2012-03-06

申请人： David J. Irvin ,  David L. Witker ,  John D. Stenger-Smith ,  Jennifer A. Irvin

发明人： David J. Irvin ,  David L. Witker ,  John D. Stenger-Smith ,  Jennifer A. Irvin

IPC分类号： C07D231/10

CPC分类号： C08F128/06 ,  C07D333/22 ,  C07D409/06 ,  C08G61/123 ,  C08G61/126 ,  C08G73/0616 ,  C08G2261/3221 ,  C08G2261/3223 ,  C08G2261/364 ,  C08G2261/44

摘要： The invention demonstrates the synthesis of a new pyrazole-containing monomer by means of an easily implemented two-step process. This monomer can be electropolymerized to yield a stable n-doping polymer that may easily be electrochemically characterized. It is demonstrated that the electrochemical behavior of the polymer films produced is dependent upon the conditions applied during electrodeposition. Films deposited by cycling only at relatively positive potentials (0 to 2000 mV) show less intense n-doping responses than those films obtained by scanning the applied potential throughout a wider range (−2000 mV to 2000 mV).

摘要翻译： 本发明通过易于实施的两步法合成了含吡唑的单体。 该单体可以电聚合以产生可以容易地电化学表征的稳定的n掺杂聚合物。 证明所生产的聚合物膜的电化学行为取决于电沉积期间的应用条件。 通过仅在相对正电位（0至2000mV）下循环沉积的膜比通过在更宽范围（-2000mV至2000mV）范围内扫描施加电位而获得的膜显示出更少的强度n掺杂响应。

公开(公告)号：US07829660B1

公开(公告)日：2010-11-09

申请号：US12178972

申请日：2008-07-24

申请人： David J. Irvin ,  David L. Witker ,  John D. Stenger-Smith ,  Jennifer A. Irvin

发明人： David J. Irvin ,  David L. Witker ,  John D. Stenger-Smith ,  Jennifer A. Irvin

IPC分类号： C08G73/06 ,  C08K5/3445 ,  C07D231/10

CPC分类号： C07D409/04 ,  C07D333/22

摘要： The present invention demonstrates the synthesis of a new pyrazole-containing monomer by means of an easily implemented two-step process. This monomer can be electropolymerized to yield a stable n-doping polymer that may easily be electrochemically characterized. It is demonstrated that the electrochemical behavior of the polymer films produced is dependent upon the conditions applied during electrodeposition. Films deposited by cycling only at relatively positive potentials (0 to 2000 mV) show less intense n-doping responses than those films obtained by scanning the applied potential throughout a wider range (−2000 mV to 2000 mV).

摘要翻译： 本发明通过易于实施的两步方法证明了新的含吡唑单体的合成。 该单体可以电聚合以产生可以容易地电化学表征的稳定的n掺杂聚合物。 证明所生产的聚合物膜的电化学行为取决于电沉积期间的应用条件。 通过仅在相对正电位（0至2000mV）下循环沉积的膜比通过在更宽范围（-2000mV至2000mV）范围内扫描施加电位而获得的膜显示出更少的强度n掺杂响应。

公开(公告)号：US07435310B2

公开(公告)日：2008-10-14

申请号：US11452564

申请日：2006-06-07

申请人： M. Joseph Roberts ,  Scott K. Johnson ,  Richard A. Hollins ,  Curtis E. Johnson ,  Thomas J. Groshens ,  David J. Irvin

发明人： M. Joseph Roberts ,  Scott K. Johnson ,  Richard A. Hollins ,  Curtis E. Johnson ,  Thomas J. Groshens ,  David J. Irvin

IPC分类号： B29C39/12

CPC分类号： H01L27/14601 ,  B82Y10/00 ,  H01L27/14665 ,  H01L51/0004 ,  H01L51/0036 ,  H01L51/0048 ,  H01L51/422 ,  H01L51/424 ,  H01L51/426 ,  H01L2251/105 ,  Y02E10/549 ,  Y10S977/773 ,  Y10S977/778 ,  Y10S977/842 ,  Y10T156/1023 ,  Y10T156/1039 ,  Y10T156/1041 ,  Y10T156/1044

摘要： A method of making films surface imprinted with nanometer-sized particles to produce micro- and/or nano-structured electron and hole collecting interfaces, include providing at least one transparent substrate, providing at least one photoabsorbing conjugated polymer, providing a sufficient amount of nanometer-sized particles to produce a charge separation interface, providing at least one transparent polymerizable layer, embedding the nanometer-sized particles in the conjugated polymer, applying the polymerizable layer and the conjugated polymer/nanometer-sized particle mixture on separate substrates where the nanometer-sized particles form a stamp surface, imprinting the stamp surface into the surface of the polymerizable film layer to produce micro- and/or nano-structured electron and hole collecting interfaces, polymerizing the polymerizable film layer to form a conformal gap, and filling the gap with at least one photoabsorbing material to promote the generation of photoexcited electrons and transport to the charge separation interface.

摘要翻译： 制备表面印有纳米尺寸颗粒以产生微观和/或纳米结构的电子和空穴收集界面的膜的方法包括提供至少一个透明基底，提供至少一种光吸收共轭聚合物，提供足够量的纳米 提供至少一个透明可聚合层，将纳米尺寸的颗粒嵌入到共轭聚合物中，将可聚合层和共轭聚合物/纳米尺寸的颗粒混合物施加在分开的基底上， 大小的颗粒形成印模表面，将印模表面印刷到可聚合膜层的表面中以产生微观和/或纳米结构的电子和空穴收集界面，聚合可聚合膜层以形成共形间隙，并填充间隙 具有至少一种光吸收材料以促进产生光激发的电子 电解质和运输到电荷分离界面。

公开(公告)号：US07351448B1

公开(公告)日：2008-04-01

申请号：US10911750

申请日：2004-07-27

申请人： David J. Irvin ,  Andrew Guenthner ,  Nicholas Prokopuk

发明人： David J. Irvin ,  Andrew Guenthner ,  Nicholas Prokopuk

IPC分类号： B05D5/06

CPC分类号： C25D7/00 ,  C25D3/12 ,  C25D3/50 ,  C25D5/02 ,  G02B5/003 ,  G02B5/02

摘要： An apparatus and process for coating surfaces of metal or metallic components including providing at least one metal having a patterned outer surface exhibiting an optical reflection greater than about 40%, providing at least one anti-reflective coating material, the anti-reflective coating material(s) including effective amount of electrically conductive light scattering and/or wavelength absorbent properties, and depositing the anti-reflective coating material(s) onto the patterned outer surface(s) of each metal, wherein the anti-reflective coating material(s) conforms to the desired patterned outer surface(s) of each metal. In another embodiment, a coated metal component includes at least one metal having a patterned outer surface(s); and, a coating of at least one antireflective material deposited on the metal patterned outer surface by deposition, wherein the antireflective coating material(s) including effective amount of electrically conductive light scattering and/or wavelength absorbent properties.

摘要翻译： 一种用于涂覆金属或金属部件的表面的装置和方法，包括提供至少一种具有显示大于约40％的光学反射的图案化外表面的金属，提供至少一种抗反射涂层材料，抗反射涂层材料 包括有效量的导电光散射和/或波长吸收性能，以及将抗反射涂层材料沉积到每种金属的图案化外表面上，其中抗反射涂层材料 符合每种金属的期望的图案化外表面。 在另一个实施方案中，涂覆的金属组分包括至少一种具有图案化外表面的金属; 以及通过沉积沉积在金属图案化外表面上的至少一种抗反射材料的涂层，其中所述抗反射涂层材料包括有效量的导电光散射和/或波长吸收性质。

公开(公告)号：US06685442B2

公开(公告)日：2004-02-03

申请号：US10081286

申请日：2002-02-20

申请人： Douglas A. Chinn ,  David J. Irvin

发明人： Douglas A. Chinn ,  David J. Irvin

IPC分类号： F04B3500

CPC分类号： F16K99/0001 ,  B01L3/5027 ,  F04B17/00 ,  F04B19/24 ,  F04B43/043 ,  F15C5/00 ,  F16K99/0007 ,  F16K99/0015 ,  F16K99/0025 ,  F16K99/0042 ,  F16K99/0059 ,  F16K2099/0076 ,  F16K2099/0078 ,  F16K2099/0094 ,  G01N2035/00247

摘要： A valve actuator based on a conductive polymer gel is disclosed. A nonconductive housing is provided having two separate chambers separated by a porous frit. The conductive polymer is held in one chamber and an electrolyte solution, used as a source of charged ions, is held in the second chamber. The ends of the housing a sealed with a flexible elastomer. The polymer gel is further provide with electrodes with which to apply an electrical potential across the gel in order to initiate an oxidation reaction which in turn drives anions across the porous frit and into the polymer gel, swelling the volume of the gel and simultaneously contracting the volume of the electrolyte solution. Because the two end chambers are sealed the flexible elastomer expands or contracts with the chamber volume change. By manipulating the potential across the gel the motion of the elastomer can be controlled to act as a “gate” to open or close a fluid channel and thereby control flow through that channel.

摘要翻译： 公开了一种基于导电聚合物凝胶的阀致动器。 提供具有由多孔玻璃料分隔开的两个分开的室的非导电外壳。 导电聚合物保持在一个室中，并且用作带电离子源的电解质溶液被保持在第二室中。 壳体的端部用柔性弹性体密封。 聚合物凝胶进一步提供电极，以在凝胶上施加电势，以便引发氧化反应，其反过来驱使跨过多孔玻璃料的阴离子并进入聚合物凝胶，使凝胶的体积膨胀并同时收缩 电解液体积。 因为两个端部腔被密封，所以柔性弹性体膨胀或收缩室容积变化。 通过操纵穿过凝胶的电势，可以控制弹性体的运动以充当打开或关闭流体通道的“门”，从而控制通过该通道的流动。