公开(公告)号：US07435310B2

公开(公告)日：2008-10-14

申请号：US11452564

申请日：2006-06-07

申请人： M. Joseph Roberts ,  Scott K. Johnson ,  Richard A. Hollins ,  Curtis E. Johnson ,  Thomas J. Groshens ,  David J. Irvin

发明人： M. Joseph Roberts ,  Scott K. Johnson ,  Richard A. Hollins ,  Curtis E. Johnson ,  Thomas J. Groshens ,  David J. Irvin

IPC分类号： B29C39/12

CPC分类号： H01L27/14601 ,  B82Y10/00 ,  H01L27/14665 ,  H01L51/0004 ,  H01L51/0036 ,  H01L51/0048 ,  H01L51/422 ,  H01L51/424 ,  H01L51/426 ,  H01L2251/105 ,  Y02E10/549 ,  Y10S977/773 ,  Y10S977/778 ,  Y10S977/842 ,  Y10T156/1023 ,  Y10T156/1039 ,  Y10T156/1041 ,  Y10T156/1044

摘要： A method of making films surface imprinted with nanometer-sized particles to produce micro- and/or nano-structured electron and hole collecting interfaces, include providing at least one transparent substrate, providing at least one photoabsorbing conjugated polymer, providing a sufficient amount of nanometer-sized particles to produce a charge separation interface, providing at least one transparent polymerizable layer, embedding the nanometer-sized particles in the conjugated polymer, applying the polymerizable layer and the conjugated polymer/nanometer-sized particle mixture on separate substrates where the nanometer-sized particles form a stamp surface, imprinting the stamp surface into the surface of the polymerizable film layer to produce micro- and/or nano-structured electron and hole collecting interfaces, polymerizing the polymerizable film layer to form a conformal gap, and filling the gap with at least one photoabsorbing material to promote the generation of photoexcited electrons and transport to the charge separation interface.

摘要翻译： 制备表面印有纳米尺寸颗粒以产生微观和/或纳米结构的电子和空穴收集界面的膜的方法包括提供至少一个透明基底，提供至少一种光吸收共轭聚合物，提供足够量的纳米 提供至少一个透明可聚合层，将纳米尺寸的颗粒嵌入到共轭聚合物中，将可聚合层和共轭聚合物/纳米尺寸的颗粒混合物施加在分开的基底上， 大小的颗粒形成印模表面，将印模表面印刷到可聚合膜层的表面中以产生微观和/或纳米结构的电子和空穴收集界面，聚合可聚合膜层以形成共形间隙，并填充间隙 具有至少一种光吸收材料以促进产生光激发的电子 电解质和运输到电荷分离界面。

公开(公告)号：US07632943B1

公开(公告)日：2009-12-15

申请号：US11010059

申请日：2004-12-10

申请人： Robert D. Chapman ,  Thomas J. Groshens

发明人： Robert D. Chapman ,  Thomas J. Groshens

IPC分类号： C07D245/00

CPC分类号： C07D245/02 ,  Y02P20/55

摘要： A novel reaction scheme is presented for making a 3,3,7,7-tetrakis(difluoramino)octahydro-1,5-diazocinium salt, such as HNFX, from a tetrahydro-1,5-diazocine-3,7(2H,6H)-dione that does not employ N-nitrolysis,—but that instead requires protolytic N-deprotection, or protolytic denosylation, (i.e., the nosyl N-protecting group is replaced with protons, forming the corresponding protonated amine or ammonium derivative). In summary, the present method subjects a suitably N-protected dione to difluoramination followed by protolytic N-deprotection by addition of a superacid and subsequent nitration utilizing an electrophilic nitrating agent to yield the diazocinium salt.

摘要翻译： 提出了一种新的反应方案，用于制备3,3,7,7-四（二氟氨基）八氢-1,5-二氮杂盐如HNFX，由四氢-1,5-二氮辛-3,7（2H， 6H） - 二酮，但不是使用N-脱水解，而是需要原位N-脱保护，或者是原酸去甲硅烷基化（即，用质子取代nosyl N-保护基团，形成相应的质子化胺或铵衍生物）。 总之，本发明方法使合适的N-保护的二酮进行二氟化，随后通过加入超酸进行原位N-脱保护，然后利用亲电硝化剂进行硝化，得到二重氮杂鎓盐。

公开(公告)号：US08708276B1

公开(公告)日：2014-04-29

申请号：US13552259

申请日：2012-07-18

申请人： Michael L. Petersen ,  Thomas J. Groshens ,  Elsa J. Hennings

发明人： Michael L. Petersen ,  Thomas J. Groshens ,  Elsa J. Hennings

IPC分类号： B64B1/58

CPC分类号： B64B1/50 ,  B64B1/58 ,  G08B25/002

摘要： A lighter than air emergency beacon platform as part of a hydrogen generation and filtration apparatus includes at least one power source having at least one activation switch. At least one reaction chamber is electrically connected to the at least one reaction chamber by at least one low-resistance electrical conductor. The reaction chamber is configured to house a hydrogen generating material. At least one flow disruption chamber is in fluid communication with the reaction chamber. The flow disruption chamber(s) are configured to provide fluid communication with the next flow disruption chamber in the direction of fluid flow. At least one inflatable housing is configured to carry payload and is in fluid communication with the flow disruption chambers. The inflatable housing is detached from a fill tube to lift the payload above terrain blocking line-of-sight signal communication.

摘要翻译： 作为氢生成和过滤装置的一部分的比空气应急信标平台更轻，包括至少一个具有至少一个激活开关的电源。 至少一个反应室通过至少一个低电阻电导体与至少一个反应室电连接。 反应室被构造成容纳氢气产生材料。 至少一个流动破裂室与反应室流体连通。 流动破坏室被配置成在流体流动的方向上提供与下一个流动破裂室的流体连通。 至少一个可充气壳体构造成承载有效载荷并且与流动破裂室流体连通。 可充气壳体与填充管分离，以将有效载荷提升到地形上以阻挡视线信号通信。

公开(公告)号：US08444783B1

公开(公告)日：2013-05-21

申请号：US12479278

申请日：2009-06-05

申请人： Robert D. Chapman ,  Thomas J. Groshens

发明人： Robert D. Chapman ,  Thomas J. Groshens

IPC分类号： C06B45/00 ,  D03D23/00 ,  D03D43/00

CPC分类号： C07D245/02

摘要： 3,3,7,7-Tetrakis(difluoramino)octahydro-1,5-diazocinium intermediate salts through difluoramination followed by N-denosylation or N-deprotection, which are valuable for use as precursor(s) to HNFX as well as to other members of the rare class of 3,3,7,7-tetrakis(difluoramino)octahydro-1,5-diazocines.

摘要翻译： 3,3,7,7-四（二氟氨基）八氢-1,5-二氮杂鎓中间体盐，通过二氟化，然后进行N-去甲硅烷基化或N-去保护，这对HNFX以及其他 稀有类3,3,7,7-四（二氟氨基）八氢-1,5-二氮杂辛的成员。

公开(公告)号：US6060119A

公开(公告)日：2000-05-09

申请号：US803208

申请日：1997-02-10

申请人： Robert W. Gedridge, Jr. ,  Thomas J. Groshens ,  Kelvin T. Higa

发明人： Robert W. Gedridge, Jr. ,  Thomas J. Groshens ,  Kelvin T. Higa

IPC分类号： C23C16/30 ,  C30B25/02 ,  H01L21/205 ,  H01L21/316 ,  H01L21/365 ,  C23C16/00

CPC分类号： C30B25/02 ,  C23C16/301 ,  C30B29/38 ,  C30B29/40 ,  H01L21/02524 ,  H01L21/02543 ,  H01L21/02551 ,  H01L21/02576 ,  H01L21/0262 ,  H01L21/31625

摘要： A new compound tertiarybutylbis-(dimethylamino)phosphine and a process for preparing the compound, which has the formula ((CH.sub.3).sub.3 C) ((CH.sub.3).sub.2 N).sub.2 P. The process has the steps of: (1) reacting phosphorus trihalide, PX.sub.3, with tertiarybutyl Grignard reagent, ((CH.sub.3).sub.3 C)MgX, where X is a halide; (2) treating the resulting product with lithium dimethylamide, LiN(CH.sub.3).sub.2 to form a reaction mixture; and (3) recovering ((CH.sub.3).sub.3 C) ((CH.sub.3).sub.2 N).sub.2 P from the reaction mixture.

摘要翻译： 一种新的化合物叔丁基双（二甲基氨基）膦及其制备方法，其具有式（（CH3）3C）（（CH3）2N）2P。 该方法具有以下步骤：（1）使三卤化磷PX3与叔丁基格氏试剂（（CH3）3C）MgX反应，其中X为卤化物; （2）用二甲基氨基锂LiN（CH 3）2处理所得产物以形成反应混合物; 和（3）从反应混合物中回收（（CH3）3C）（（CH3）2N）2P。

公开(公告)号：US08029602B1

公开(公告)日：2011-10-04

申请号：US12398249

申请日：2009-03-05

申请人： Thomas J. Groshens

发明人： Thomas J. Groshens

IPC分类号： H01M8/06 ,  C07F5/02

CPC分类号： H01M8/04216 ,  C01B3/065 ,  H01M8/065 ,  Y02E60/362

摘要： A fuel cell and a method for chemically storing hydrogen. Embodiments of the fuel cell include a mixture having at least one boron-nitrogen-hydrogen compound and a reactive hydride where the mixture has more than about 10 wt % hydrogen density and a hydrogen storage density of about 0.1 kg H21−1.

摘要翻译： 一种燃料电池和用于化学储存氢的方法。 燃料电池的实施方案包括具有至少一种硼 - 氢 - 氢化合物和反应性氢化物的混合物，其中混合物具有大于约10重量％的氢密度和约0.1kg H21-1的储氢密度。

公开(公告)号：US07119028B1

公开(公告)日：2006-10-10

申请号：US10699440

申请日：2003-10-29

申请人： M. Joseph Roberts ,  Scott K. Johnson ,  Richard A. Hollins ,  Curtis E. Johnson ,  Thomas J. Groshens ,  David J. Irvin

发明人： M. Joseph Roberts ,  Scott K. Johnson ,  Richard A. Hollins ,  Curtis E. Johnson ,  Thomas J. Groshens ,  David J. Irvin

IPC分类号： H01L21/302

CPC分类号： H01L51/426 ,  B82Y10/00 ,  C08G2261/1412 ,  C08G2261/3223 ,  C08K3/041 ,  H01L27/14601 ,  H01L27/14665 ,  H01L51/0004 ,  H01L51/0036 ,  H01L51/0048 ,  H01L51/422 ,  H01L51/424 ,  H01L2251/105 ,  Y02E10/549 ,  Y10S977/742 ,  Y10S977/842 ,  Y10S977/845 ,  C08L65/00

摘要： A film surface imprinted with nanometer-sized particles to produce micro- and/or nano-structured electron and hole collecting interfaces, including: at least one substrate; at least one photoabsorbing conjugated polymer (including polybutylthiophene (pbT)) applied on a substrate, nanometer-sized particles including multiwalled carbon nanotubes (MWNT) to produce a charge separation interface; at least one transparent polymerizable layer, wherein the MWNT are embedded in the conjugated polymer to produce mixture and applied on a substrate to form a MWNT bearing surface film layer to form a stamp surface which is imprinted into the surface of the polymerizable film layer to produce micro- and/or nano-structured electron and hole collecting interfaces; polymerizing the polymerizable film layer to form a conformal gap between the MWNT stamp surface and the surface of the polymerizable film layer, and filling the gap with a photoabsorbing material to promote the generation of photoexcited electrons and transport to the charge separation interface.

摘要翻译： 印有纳米尺寸颗粒以产生微观和/或纳米结构的电子和空穴收集界面的薄膜表面，包括：至少一个基底; 施加在基材上的至少一种光吸收共轭聚合物（包括聚丁基噻吩（pbT）），包括多壁碳纳米管（MWNT）的纳米尺寸颗粒以产生电荷分离界面; 至少一个透明可聚合层，其中将MWNT嵌入共轭聚合物中以产生混合物并施加在基底上以形成MWNT承载表面膜层，以形成印模到可聚合膜层的表面中的印模表面，以产生 微和/或纳米结构的电子和空穴收集界面; 聚合可聚合膜层以在MWNT印模表面和可聚合膜层的表面之间形成共形间隙，并用光吸收材料填充间隙以促进产生光激发电子并传输到电荷分离界面。

公开(公告)号：US07563889B1

公开(公告)日：2009-07-21

申请号：US11010058

申请日：2004-12-10

申请人： Robert D. Chapman ,  Thomas J. Groshens

发明人： Robert D. Chapman ,  Thomas J. Groshens

IPC分类号： C07D245/00

CPC分类号： C07D245/02

摘要： 3,3,7,7-Tetrakis(difluoramino)octahydro-1,5-diazocinium intermediate salts and method for making the salts, through difluoramination followed by N-denosylation or N-deprotection, which are valuable for use as precursor(s) to HNFX as well as to other members of the rare class of 3,3,7,7-tetrakis(difluoramino)octahydro-1,5-diazocines.

摘要翻译： 3,3,7,7-四（二氟氨基）八氢-1,5-二氮杂鎓中间体盐和通过二氟化，然后进行N-去甲硅烷基化或N-去保护制备盐的方法，其对于用作前体是有价值的， 到HNFX以及稀有类别的3,3,7,7-四（二氟氨基）八氢-1,5-二氮杂环辛烷的其它成员。

公开(公告)号：US06020253A

公开(公告)日：2000-02-01

申请号：US267911

申请日：1999-03-05

申请人： Robert W. Gedridge, Jr. ,  Thomas J. Groshens ,  Kelvin T. Higa

发明人： Robert W. Gedridge, Jr. ,  Thomas J. Groshens ,  Kelvin T. Higa

IPC分类号： C23C16/30 ,  C30B25/02 ,  H01L21/205 ,  H01L21/316 ,  H01L21/365 ,  H01L21/20

CPC分类号： C30B25/02 ,  C23C16/301 ,  C30B29/38 ,  C30B29/40 ,  H01L21/02524 ,  H01L21/02543 ,  H01L21/02551 ,  H01L21/02576 ,  H01L21/0262 ,  H01L21/31625

摘要： A new compound, tertiarybutylbis-(dimethylamino)phosphine, ((CH.sub.3).sub.3 C)((CH.sub.3).sub.2 N).sub.2 P, is used as a precursor in forming phosphorus-containing semiconductor material by chemical vapor deposition. Tertiarybutylbis-(dimethylamino)phosphine is prepared by reacting a phosphorus trihalide, PX.sub.3, with the tertiarybutyl Grignard reagent ((CH.sub.3).sub.3 C)MgX. The resultant product is treated with lithium dimethylamide reagent LiN(CH.sub.3).sub.2. Tertiarybutylbis-(dimethylamino)phosphine is then recovered from the reaction mixture. Phosphorus-containing semiconductor materials are formed by chemical vapor deposition by means of bubbling a carrier gas through the new compound and then transporting the ((CH.sub.3).sub.3 C)((CH.sub.3).sub.2 N).sub.2 P with the carrier gas to a heated substrate. Additional elements from groups II, III, V, and VI of the periodic table are then deposited on the substrate to form the Phosphorus-containing semiconductor materials.

摘要翻译： 使用新的化合物叔丁基二（二甲基氨基）膦，（（CH3）3C）（（CH3）2N）2P作为通过化学气相沉积形成含磷半导体材料的前体。 通过三氯化磷PX3与叔丁基格氏试剂（（CH3）3C）MgX反应制备叔丁基双（二甲基氨基）膦。 所得产物用二甲基酰胺试剂LiN（CH 3）2处理。 然后从反应混合物中回收叔丁基双（二甲氨基）膦。 含磷的半导体材料通过化学气相沉积形成，通过使载气鼓泡通过新化合物，然后将（（CH 3）3 C）（（CH 3）2 N）2 P与载气输送到加热的基底。 然后将周期表第II，III，V和VI族的附加元素沉积在衬底上以形成含磷的半导体材料。