Repellent fluorochemical compositions
    11.
    发明授权
    Repellent fluorochemical compositions 失效
    排斥含氟组成

    公开(公告)号:US07078454B2

    公开(公告)日:2006-07-18

    申请号:US10124523

    申请日:2002-04-17

    摘要: This invention provides compositions for treating fibrous substrates to render those substrates durably repellent to water and oil and durably resistant to dry soil comprising a 1) fluorochemical urethane formed by reacting a tri- or higher order isocyanate with a fluorochemical monofunctional compound and optionally a non-fluorinated aliphatic monofunctional compound; and 2) a fluorochemical polymeric surfactant.The present invention also provides a method of treating fibrous substrates to render those substrates durably repellent to water and oil and durably resistant to dry soil comprising application of the aforementioned composition to a fibrous substrate with optionally one or more stainblocker compounds such as acrylic and methacrylic acid polymers and copolymers, sulfonated phenol-formaldehyde resins, and styrene-maleic anhydride polymers and copolymers, said application of the composition taking place either coincident with or following application of the hydrophilic anti-staining compound or compounds to the substrate. Fibrous substrates treated according to this method and fibrous substrates treated with the aforementioned compositions are also disclosed.

    摘要翻译: 本发明提供了用于处理纤维基材以使这些基材耐久地驱除水和油并且耐受干土的耐久性的组合物,其包含1)通过使三价或更高级异氰酸酯与含氟单官能化合物和任选的非官能化合物反应形成的含氟氨基甲酸酯, 氟化脂肪族单官能化合物; 和2)含氟聚合物表面活性剂。 本发明还提供了一种处理纤维基材以使这些基材耐久地驱除水和油并且耐久干燥的土壤的方法,其包括将上述组合物施用到纤维基材中,任选地包含一种或多种着色剂化合物如丙烯酸和甲基丙烯酸 聚合物和共聚物,磺化酚醛树脂和苯乙烯 - 马来酸酐聚合物和共聚物,所述组合物的应用与亲水性抗染色化合物或化合物一起施加或者应用于底物。 还公开了根据该方法处理的纤维基材和用上述组合物处理的纤维基材。

    Compositions and methods for modifying a surface suited for semiconductor fabrication
    14.
    发明授权
    Compositions and methods for modifying a surface suited for semiconductor fabrication 有权
    用于修改适合于半导体制造的表面的组合物和方法

    公开(公告)号:US08092707B2

    公开(公告)日:2012-01-10

    申请号:US11839329

    申请日:2007-08-15

    IPC分类号: C09K13/00

    摘要: The disclosure pertains to compositions and methods for modifying or refining the surface of a wafer suited for semiconductor fabrication. The compositions include working liquids useful in modifying a surface of a wafer suited for fabrication of a semiconductor device. In some embodiments, the working liquids are aqueous solutions of initial components substantially free of loose abrasive particles, the components including water, a surfactant, and a pH buffer exhibiting at least one pKa greater than 7. In certain embodiments, the pH buffer includes a basic pH adjusting agent and an acidic complexing agent, and the working liquid exhibits a pH from about 7 to about 12. In further embodiments, the disclosure provides a fixed abrasive article comprising a surfactant suitable for modifying the surface of a wafer, and a method of making the fixed abrasive article. Additional embodiments describe methods that may be used to modify a wafer surface.

    摘要翻译: 本公开涉及用于改性或精制适于半导体制造的晶片表面的组合物和方法。 组合物包括可用于改性适于制造半导体器件的晶片表面的工作液体。 在一些实施方案中,工作液体是基本上不含松散磨料颗粒的初始组分的水溶液,组分包括水,表面活性剂和显示出至少一个pKa大于7的pH缓冲液。在某些实施方案中,pH缓冲剂包括 碱性pH调节剂和酸性络合剂,并且工作液体的pH为约7至约12.在另外的实施方案中,本公开提供了包含适于改性晶片表面的表面活性剂的固定磨料制品,以及方法 制造固定的磨料制品。 另外的实施例描述了可用于修改晶片表面的方法。

    Process for preparing fluorochemical monoisocyanates
    15.
    发明授权
    Process for preparing fluorochemical monoisocyanates 失效
    氟化物单异氰酸酯的制备方法

    公开(公告)号:US07081545B2

    公开(公告)日:2006-07-25

    申请号:US10751142

    申请日:2003-12-31

    IPC分类号: C07C269/02

    CPC分类号: C07C303/40 C07C311/09

    摘要: A process for preparing fluorochemical monoisocyanates comprises reacting at least one fluorochemical alcohol represented by the formula CnF2n+1SO2NCH3(CH2)mOH, wherein n=2 to 5, and m=2 to 4, with 4,4′-diphenylmethane diisocyanate (MDI) in a solvent in which the resulting fluorochemical monoisocyanate is not soluble; wherein the molar ratio of fluorochemical alcohol:MDI is from about 1:1 to about 1:2.5.

    摘要翻译: 一种制备含氟化合物单异氰酸酯的方法包括使至少一种由式C n 2 N 2n + 1 SO 2 NCH 3表示的含氟化合物醇反应, 其中n = 2〜5,m = 2〜4,与4,4'-二苯基甲烷二异氰酸酯(MDI)反应,得到(CH 2 CH 2)m OH )在其中所得氟化异氰酸酯不溶于其中的溶剂中; 其中含氟醇:MDI的摩尔比为约1:1至约1:2.5。

    Thermally compensated x-ray tube bearings
    19.
    发明授权
    Thermally compensated x-ray tube bearings 失效
    热补偿x射线管轴承

    公开(公告)号:US4569070A

    公开(公告)日:1986-02-04

    申请号:US533769

    申请日:1983-09-19

    CPC分类号: H01J35/101

    摘要: The rotor that carries the target in a rotating anode x-ray tube is carried on a shaft that is journaled in axially spaced apart ball bearings. The outer and inner races of the bearings have curved grooves presented toward each other and there are a plurality of balls in the grooves. A preloaded spring is interposed between corresponding races of the bearings for applying oppositely directed axial forces to them. The grooves are so shaped and the clearance between the balls and groove surfaces is such that when the axial force is applied, one race shifts axially relative to the other in which case each ball has two points of contact, one point at which the ball contacts the surface of the groove in the outer race on one side of a plane transverse to the shaft axis and another point where the ball contacts the surface of the groove in the inner race on the other side of the plane. The chosen axial preload force is in a range of forces that compels many balls to share the radial load of the rotor and target to minimize contact stress on each ball and the races and the preload spring force range begins just above the force that would result in one or a few of the balls carrying the radial load.

    摘要翻译: 在旋转的阳极x射线管中承载目标的转子被承载在轴向间隔开的球轴承中的轴上。 轴承的外圈和内圈具有朝向彼此呈现的弯曲槽,并且在凹槽中存在多个滚珠。 预先加载的弹簧介于相应的轴承座之间,以向它们施加相反的轴向力。 凹槽是这样的形状,并且球和凹槽表面之间的间隙使得当施加轴向力时,一个圆圈相对于另一个轴向轴向移动,在这种情况下,每个球具有两个接触点,球接触的一个点 外圈中的槽的表面在横向于轴线的一个平面的一侧上,另一个点与球体在该平面的另一侧的内圈中的表面接触。 所选择的轴向预紧力是在一定范围内的力,其强制许多球共享转子和目标的径向载荷,以使每个球和座圈上的接触应力最小化,并且预载弹簧力范围刚刚高于将产生的力 一个或几个承载径向载荷的球。

    Fluoroacrylate-mercaptofunctional copolymers
    20.
    发明授权
    Fluoroacrylate-mercaptofunctional copolymers 有权
    氟丙烯酸酯 - 巯基官能共聚物

    公开(公告)号:US07666964B2

    公开(公告)日:2010-02-23

    申请号:US11859295

    申请日:2007-09-21

    CPC分类号: C08F220/38

    摘要: A copolymer comprises repeating units derived from at least one co-reactant comprising two or more mercapto functional groups, and repeating units derived from a fluoroacrylate comprising the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: C4F9—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, n=1 to 5, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoroacrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.

    摘要翻译: 共聚物包含衍生自至少一种包含两个或多个巯基官能团的共反应物的重复单元和衍生自氟代丙烯酸酯的重复单元,其包含以下反应产物:(a)至少一种由式C4F9-X表示的含氟醇 -OH其中:R =氢或1至4个碳原子的烷基,m = 2至8,R f = C n F 2n + 1,n = 1至5,y = 0至6,q = 1至8; (b)至少一种非支化对称二异氰酸酯; 和(c)至少一种羟基封端的(甲基)丙烯酸烷基酯或其亚烷基部分具有2至约30个碳原子的2-氟丙烯酸酯单体。