摘要:
This invention provides compositions for treating fibrous substrates to render those substrates durably repellent to water and oil and durably resistant to dry soil comprising a 1) fluorochemical urethane formed by reacting a tri- or higher order isocyanate with a fluorochemical monofunctional compound and optionally a non-fluorinated aliphatic monofunctional compound; and 2) a fluorochemical polymeric surfactant.The present invention also provides a method of treating fibrous substrates to render those substrates durably repellent to water and oil and durably resistant to dry soil comprising application of the aforementioned composition to a fibrous substrate with optionally one or more stainblocker compounds such as acrylic and methacrylic acid polymers and copolymers, sulfonated phenol-formaldehyde resins, and styrene-maleic anhydride polymers and copolymers, said application of the composition taking place either coincident with or following application of the hydrophilic anti-staining compound or compounds to the substrate. Fibrous substrates treated according to this method and fibrous substrates treated with the aforementioned compositions are also disclosed.
摘要:
Fluorinated arylene-containing compounds and fluorinated polymers formed from fluorinated arylene-containing compounds, and methods are described. Fluorinated polymers formed from fluorinated arylene-containing compound can be used to provide a low energy surface.
摘要:
A fishing line comprises an outer surface having at least one array of shaped features therein and having an advancing contact angle with deionized water of at least about 115°. The array comprises a plurality of discrete shaped features spaced equidistantly along a longitudinal axis of the fishing line. The shaped features are from about 0.005 to about 0.02 inches across in their broadest dimension.
摘要:
The disclosure pertains to compositions and methods for modifying or refining the surface of a wafer suited for semiconductor fabrication. The compositions include working liquids useful in modifying a surface of a wafer suited for fabrication of a semiconductor device. In some embodiments, the working liquids are aqueous solutions of initial components substantially free of loose abrasive particles, the components including water, a surfactant, and a pH buffer exhibiting at least one pKa greater than 7. In certain embodiments, the pH buffer includes a basic pH adjusting agent and an acidic complexing agent, and the working liquid exhibits a pH from about 7 to about 12. In further embodiments, the disclosure provides a fixed abrasive article comprising a surfactant suitable for modifying the surface of a wafer, and a method of making the fixed abrasive article. Additional embodiments describe methods that may be used to modify a wafer surface.
摘要:
A process for preparing fluorochemical monoisocyanates comprises reacting at least one fluorochemical alcohol represented by the formula CnF2n+1SO2NCH3(CH2)mOH, wherein n=2 to 5, and m=2 to 4, with 4,4′-diphenylmethane diisocyanate (MDI) in a solvent in which the resulting fluorochemical monoisocyanate is not soluble; wherein the molar ratio of fluorochemical alcohol:MDI is from about 1:1 to about 1:2.5.
摘要翻译:一种制备含氟化合物单异氰酸酯的方法包括使至少一种由式C n 2 N 2n + 1 SO 2 NCH 3表示的含氟化合物醇反应, 其中n = 2〜5,m = 2〜4,与4,4'-二苯基甲烷二异氰酸酯(MDI)反应,得到(CH 2 CH 2)m OH )在其中所得氟化异氰酸酯不溶于其中的溶剂中; 其中含氟醇:MDI的摩尔比为约1:1至约1:2.5。
摘要:
A process is described which imparts exceptional antisoiling, anti-staining and repellent properties to carpets. The process makes use of a water-based exhaustion process wherein the water-based treating solution contains (1) glassy fluorochemical material, glassy hydrocarbon material, or combinations thereof; (2) a stainblocking material; (3) a polyvalent metal salt, acid, or combinations thereof; and (4) water. Subsequent to exhaustion, the wet treated carpet is heated, usually in a steaming step, rinsed, and dried in a dry heat oven.
摘要:
A process is described which imparts exceptional antisoiling, anti-staining and repellent properties to carpets. The process makes use of a water-based exhaustion process wherein the water-based treating solution contains (1) glassy fluorochemical material, glassy hydrocarbon material, or combinations thereof; (2) a stainblocking material; (3) a polyvalent metal salt, acid, or combinations thereof; and (4) water. Subsequent to exhaustion, the wet treated carpet is heated, usually in a steaming step, rinsed, and dried in a dry heat oven.
摘要:
Low energy surfaces based on nanostructured films exhibit advancing and receding contact angles for liquids such that (1) the difference between the advancing and receding contact angles approaches zero and (2) the advancing and receding contact angles approach 180.degree.. The low energy surface of the present invention comprises a nanostructured film coated with an organized molecular assembly (OMA). Advantageously, the chemical and wetting characteristics of the surface can be altered by changing the functionality of the OMA end groups exposed to the environment in contact with the surface of the nanostructured film.
摘要:
The rotor that carries the target in a rotating anode x-ray tube is carried on a shaft that is journaled in axially spaced apart ball bearings. The outer and inner races of the bearings have curved grooves presented toward each other and there are a plurality of balls in the grooves. A preloaded spring is interposed between corresponding races of the bearings for applying oppositely directed axial forces to them. The grooves are so shaped and the clearance between the balls and groove surfaces is such that when the axial force is applied, one race shifts axially relative to the other in which case each ball has two points of contact, one point at which the ball contacts the surface of the groove in the outer race on one side of a plane transverse to the shaft axis and another point where the ball contacts the surface of the groove in the inner race on the other side of the plane. The chosen axial preload force is in a range of forces that compels many balls to share the radial load of the rotor and target to minimize contact stress on each ball and the races and the preload spring force range begins just above the force that would result in one or a few of the balls carrying the radial load.
摘要:
A copolymer comprises repeating units derived from at least one co-reactant comprising two or more mercapto functional groups, and repeating units derived from a fluoroacrylate comprising the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: C4F9—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, n=1 to 5, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoroacrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.
摘要翻译:共聚物包含衍生自至少一种包含两个或多个巯基官能团的共反应物的重复单元和衍生自氟代丙烯酸酯的重复单元,其包含以下反应产物:(a)至少一种由式C4F9-X表示的含氟醇 -OH其中:R =氢或1至4个碳原子的烷基,m = 2至8,R f = C n F 2n + 1,n = 1至5,y = 0至6,q = 1至8; (b)至少一种非支化对称二异氰酸酯; 和(c)至少一种羟基封端的(甲基)丙烯酸烷基酯或其亚烷基部分具有2至约30个碳原子的2-氟丙烯酸酯单体。