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公开(公告)号:US20190135996A1
公开(公告)日:2019-05-09
申请号:US16054827
申请日:2018-08-03
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Jianya Cheng , Adriana S. Silva , Peijun Jiang , Wen Li , Alexander I. Norman
IPC: C08J5/18 , C08L23/08 , C08L23/06 , C08F210/18
CPC classification number: B29C48/022 , B29C48/10 , B29C48/913 , B29K2009/00 , B29K2023/06 , B29K2409/00 , C08F4/65908 , C08F4/65927 , C08F210/18 , C08J5/18 , C08J2323/06 , C08J2447/00 , C08L23/06 , C08L23/0815 , C08L2203/16 , C08L2205/025 , C08F210/14 , C08F236/20 , C08F2500/12 , C08F2500/17 , C08F2500/26
Abstract: A method of forming a finished film comprising extruding a molten polyethylene comprising a diene terpolymer modifier through a die opening to form a film, wherein the diene-terpolymer modifier is a terpolymer comprising ethylene-derived units, C3 to C10 α-olefin derived units, and diene-derived units; causing the film to progress in a direction away from the die opening; cooling the film at a distance from the die opening, the distance adjusted to allow relaxation of the molten polyethylene prior to solidification and/or crystallization upon cooling; and isolating a finished film therefrom. Desirably, the polyethylene is a linear low density polyethylene, and the die and cooling is suitable for forming a blown film.
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12.
公开(公告)号:US20190134876A1
公开(公告)日:2019-05-09
申请号:US16112321
申请日:2018-08-24
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Periagaram S. Ravishankar , Jianya Cheng , Adriana S. Silva , Wen Li , Abelhadi Sahnoune , Arturo Leyva , Alexander I. Norman
CPC classification number: B29C48/10 , B29C48/9125 , B29C48/913 , B29C55/28 , B29K2023/06 , B29K2023/38 , B29K2105/0085 , B29K2105/0088 , B29K2995/0063 , B29K2995/0077 , B29L2007/00 , C08J5/18 , C08J9/00 , C08J2323/08 , C08J2423/08 , C08F210/18 , C08F210/06 , C08F236/20 , C08F2500/25 , C08F2500/26 , C08F210/16 , C08F210/08 , C08F2500/12 , C08F2500/08 , C08F210/14
Abstract: A method of forming a blown film comprising extruding a molten composition through a die opening to form a film; wherein the molten composition comprises at least one polyethylene and within the range from 0.10 wt % to 10 wt % of a cyclic-diene terpolymer by weight of the composition; causing the film to progress in a direction away from the die opening; cooling the film at a distance from the die opening, the distance adjusted to effect the properties of the film; and isolating a blown film therefrom.
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公开(公告)号:US09580533B2
公开(公告)日:2017-02-28
申请号:US13623242
申请日:2012-09-20
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Peijun Jiang , Kevin R. Squire , Jianya Cheng , Pradeep P. Shirodkar , Johannes M. Soulages , Keith E. Jolibois , Ronald R. Thackston , Andrew G. Narvaez, Jr.
IPC: C08F210/18 , C08F236/20 , C08J5/18 , C08L23/08 , C08F210/02
CPC classification number: C08F236/20 , C08F210/02 , C08F210/18 , C08F2500/09 , C08J5/18 , C08L23/0815 , C08L23/083 , C08L2203/16 , C08L2205/025 , C08L2207/07 , C08L2314/06 , C08F210/14 , C08F2500/12 , C08F2500/17 , C08F2500/19
Abstract: The present invention relates to a branched modifier and a composition comprising more than 25 wt % (based on the weight of the composition) of one or more linear ethylene polymers having a g′vis of 0.97 or more and an Mw of 20,000 g/mol or more and at least 0.1 wt % of a branched modifier where the modifier has a g′vis of less than 0.97, wherein the ethylene polymer has a g′vis of at least 0.01 units higher than the g′vis of the branched modifier.
Abstract translation: 支链改性剂和组合物,其包含超过25重量%(基于组合物的重量)的一种或多种线性乙烯聚合物,其具有0.97以上的Mw和20,000g / mol的Mw, 更多且至少0.1重量%的支化改性剂,其中改性剂的含量小于0.97,其中乙烯聚合物具有比分支改性剂的g'vis高至少0.01单位的氨基酸。
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公开(公告)号:US20150225521A1
公开(公告)日:2015-08-13
申请号:US14423042
申请日:2013-09-30
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Zhenyu Zhu , Jianya Cheng
IPC: C08J5/18
CPC classification number: C08J5/18 , C08J2323/06 , C08J2323/08 , C08J2423/06 , C08J2423/08 , C08L23/0815 , C08L2203/16 , C08L2205/025 , C08L2207/07
Abstract: Polymer compositions including (A) 15.0 to 90.0 wt % of a heterogeneously branched ethylene polymer having polymer units derived from at least one C3-C20 alpha-olefin and having a CBDI
Abstract translation: 聚合物组合物,包括(A)15.0至90.0重量%的具有衍生自至少一种C 3 -C 20α-烯烃并具有CBDI <50.0%的聚合物单元的非均匀支化的乙烯聚合物; 和(B)85.0〜10.0重量% 公开了乙烯类聚合物的%和由其制成的薄膜。
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公开(公告)号:US20150126634A1
公开(公告)日:2015-05-07
申请号:US14596516
申请日:2015-01-14
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Pradeep P. Shirodkar , Jianya Cheng , Joseph M. Tomei , Peijun Jiang , Arturo Leyva
Abstract: A foamable or foamed article comprising a diene terpolymer, the diene terpolymer comprising (or consisting essentially of) from 0.01 wt % to 10.0 wt % diene derived units, and 1.0 wt % to 20 wt % of C4 to C10 α-olefin derived units based on the weight of the diene terpolymer, wherein the diene terpolymer: a) has a g′vis of less than 0.90; b) has an Mw within a range of from 100,000 g/mol to 500,000 g/mol; c) has an Mw/Mn within the range of from 3.5 to 12.0; and d) an Mz/Mn of greater than 7.0. Inventive articles comprise a blend of a relatively high density linear polyethylene and the diene terpolymer.
Abstract translation: 包含二烯三元共聚物的可发泡或发泡制品,所述二烯三元共聚物包含(或基本上由0.01重量%至10.0重量%的二烯衍生单元)和1.0重量%至20重量%的C 4至C 10α-烯烃衍生的单元基 关于二烯三元共聚物的重量,其中二烯三元共聚物:a)具有小于0.90的ag'vis; b)具有在100,000g / mol至500,000g / mol范围内的Mw; c)具有在3.5至12.0范围内的Mw / Mn; 和d)大于7.0的Mz / Mn。 本发明的制品包括相对高密度的线性聚乙烯和二烯三元共聚物的共混物。
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公开(公告)号:US20220153940A1
公开(公告)日:2022-05-19
申请号:US17455579
申请日:2021-11-18
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Zhenyu ZHU , Jianya Cheng
Abstract: Polymer compositions and films are provided. The polymer compositions include (A) 10-50 wt % heterogeneously branched Ziegler-Natta-catalyzed LLDPE polymer having a composition distribution breadth index (CBDI)
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公开(公告)号:US10822479B2
公开(公告)日:2020-11-03
申请号:US14596516
申请日:2015-01-14
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Pradeep P. Shirodkar , Jianya Cheng , Joseph M. Tomei , Peijun Jiang , Arturo Leyva
IPC: C08L23/08 , C08J9/00 , C08F210/18 , C08J5/18 , C08J9/06
Abstract: A foamable or foamed article comprising a diene terpolymer, the diene terpolymer comprising (or consisting essentially of) from 0.01 wt % to 10.0 wt % diene derived units, and 1.0 wt % to 20 wt % of C4 to C10 α-olefin derived units based on the weight of the diene terpolymer, wherein the diene terpolymer: a) has a g′vis of less than 0.90; b) has an Mw within a range of from 100,000 g/mol to 500,000 g/mol; c) has an Mw/Mn within the range of from 3.5 to 12.0; and d) an Mz/Mn of greater than 7.0. Inventive articles comprise a blend of a relatively high density linear polyethylene and the diene terpolymer.
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18.
公开(公告)号:US10562219B2
公开(公告)日:2020-02-18
申请号:US16112321
申请日:2018-08-24
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Periagaram S. Ravishankar , Jianya Cheng , Adriana S. Silva , Wen Li , Abdelhadi Sahnoune , Arturo Leyva , Alexander I. Norman
Abstract: A method of forming a blown film comprising extruding a molten composition through a die opening to form a film; wherein the molten composition comprises at least one polyethylene and within the range from 0.10 wt % to 10 wt % of a cyclic-diene terpolymer by weight of the composition; causing the film to progress in a direction away from the die opening; cooling the film at a distance from the die opening, the distance adjusted to effect the properties of the film; and isolating a blown film therefrom.
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公开(公告)号:US20190322848A1
公开(公告)日:2019-10-24
申请号:US16502256
申请日:2019-07-03
Applicant: ExxonMobil Chemical Patents Inc
Inventor: Jianya Cheng , Pradeep P. Shirodkar , Peijun Jiang , Johannes M. Soulages
IPC: C08L23/06 , C08F236/20 , C08L23/08 , C08F210/18 , C08J5/18 , C08L9/00
Abstract: The present invention relates to a branched modifier and a composition comprising more than 25 wt % (based on the weight of the composition) of one or more linear ethylene polymers having a g′vis of 0.97 or more and an Mw of 20,000 g/mol or more and at least 0.1 wt % of a branched modifier where the modifier has a) a g′vis of 0.70 or less; b) an Mw of 100,000 g/mol or more; c) an Mw/Mn of 4.0 or more; d) a shear thinning ratio of 110 or more, e) a melt strength of 10 cN or more; f) a complex viscosity at 0.1 rad/sec at 190° C. of at least 130,000 Pa·s; and g) a phase angle of Z° or less where Z=138.3G*(−0.142), where G* is the complex modulus reported in Pascals measured at 190° C. and the phase angle units are reported in degrees, wherein the G* is from 1,000 to 1,000,000 Pa.
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公开(公告)号:US20170305124A1
公开(公告)日:2017-10-26
申请号:US15518269
申请日:2015-09-25
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Paul M. German, JR. , Wen Li , Jianya Cheng
CPC classification number: B32B27/08 , B32B27/32 , B32B2250/03 , B32B2250/242 , B32B2250/40 , B32B2270/00 , B32B2307/51 , B32B2307/54 , B32B2553/00 , C08F10/02 , C08F10/06
Abstract: This disclosure relates to films particularly suitable for stretch hood applications. More particularly, this disclosure relates to multi-layer films particularly suitable for stretch hood applications comprising an inner layer that includes a blend of a propylene-based elastomer and a polyethylene having long-chain branching.
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