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公开(公告)号：US20220025277A1
公开(公告)日：2022-01-27
申请号：US17495948
申请日：2021-10-07
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Kapil Kandel , Glenn A. Heeter , Teng Xu , Giovanni S. Contello , Krystle J. Emanuele
Abstract: This invention relates to a process for determining the suitability of pyrolysis tar, such as steam cracker tar, for upgrading using hydroprocessing without excessive fouling of the hydroprocessing reactor. A pyrolysis tar is sampled, the sample is analyzed to determine one or more characteristics of the tar related to tar reactivity, and the analysis is used to determine conditions under which the tar can be blended, pre-treated, and/or hydroprocessed.
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公开(公告)号：US10968404B2
公开(公告)日：2021-04-06
申请号：US16467749
申请日：2017-12-01
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Teng Xu , Kapil Kandel , Glenn A. Heeter , David T. Ferrughelli , John S. Coleman , Michael J. Clemmons , Jesse R. McManus
Abstract: A process id disclosed for upgrading tars, typically those resulting from hydrocarbon refining processes, to products suitable for other uses, such as blending with other hydrocarbons to provide low-sulfur fuel oils or Emission Control Area-acceptable fuels. A low-sulfur hydrocarbon product obtained from the process is also disclosed.
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公开(公告)号：US10894924B2
公开(公告)日：2021-01-19
申请号：US16025622
申请日：2018-07-02
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： John S. Coleman , Kapil Kandel , Subramanya V. Nayak , Teng Xu
IPC: C10G69/06 , C10G65/02 , C10G65/10 , C10G65/12 , C10G67/02 , B01J23/28 , B01J23/44 , B01J23/745 , B01J23/75 , B01J23/755
Abstract: A multi-stage process is described for upgrading pyrolysis tar, such as steam cracker tar, by hydroprocessing in at least two stages. Hydroprocessing in a first stage is performed in the presence of a utility fluid. The utility fluid has a boiling point distribution from about 120° C. to about 480° C. and is separated from the first stage product.
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公开(公告)号：US20210009545A1
公开(公告)日：2021-01-14
申请号：US16978496
申请日：2019-02-11
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Kapil Kandel , Stephen T. Cohn , Michael Salciccioli , Crisita Carmen H. Atienza , Alan A. Galuska
IPC: C07D307/36 , C08G63/185 , C07D307/54
Abstract: A 5,5′-Di-(protected)-2,2′-bifuran: wherein each R1 is independently an unsubstituted or substituted 5- or 6-member 1,3-dioxo-2-yl ring radical. Processes for making the bifuran include coupling 2-(protected)-furfural. Processes for using the bifuran include deprotection, functionalization, and/or polymerization to form a polyester. The polyester can be a renewable, high-performing polyester offering a combination of low cost of production, high sustainability, and excellent performance
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15.发明申请公开(公告)号：US20200071626A1
公开(公告)日：2020-03-05
申请号：US16545976
申请日：2019-08-20
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Kapil Kandel , Teng Xu , Glenn A. Heeter , Frank Cheng-Yu Wang , Anthony S. Mennito , David T. Ferrughelli , Krystle J. Emanuele
IPC: C10G47/24
Abstract: Processes for improving hydrocarbon feedstock compatibility are provided. More specifically, a process for preparing a liquid hydrocarbon product includes heat soaking a tar stream to produce a reduced reactivity tar and blending the reduced reactivity tar with a utility fluid comprising recycle solvent to produce a lower viscosity, reduced reactivity tar. The process also includes hydroprocessing the lower viscosity, reduced reactivity tar at a temperature of greater than 350° C. to produce a total liquids product containing the liquid hydrocarbon product and the recycle solvent. The process further includes separating the recycle solvent from the total liquids product, where the recycle solvent has the SBN of greater than 110, and flowing the recycle solvent to the reduced reactivity tar for blending to produce the lower viscosity, reduced reactivity tar.
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Patent Agency Ranking
公开(公告)号：US20180178199A1
公开(公告)日：2018-06-28
申请号：US15905282
申请日：2018-02-26
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Kapil Kandel , Paul F. Keusenkothen , Jeevan S. Abichandani
IPC: B01J23/745 , C07C29/50 , B01J37/06 , B01J37/16 , B01J37/08 , B01J35/10 , C07C29/153 , B01J37/02 , B01J37/00
CPC classification number: B01J23/745 , B01J21/08 , B01J23/002 , B01J23/72 , B01J23/80 , B01J23/8892 , B01J23/89 , B01J29/0333 , B01J35/1014 , B01J35/1019 , B01J35/1061 , B01J37/0018 , B01J37/0203 , B01J37/0205 , B01J37/0215 , B01J37/06 , B01J37/08 , B01J37/086 , B01J37/16 , B01J2229/18 , B01J2229/38 , C07C29/153 , C07C29/50 , C10G2/332
Abstract: The invention relates to templated active material, including those deriving order from organic and/or inorganic templating agents. The invention also relates to methods for producing templated active material, and to active material produced by such methods, and the use of such templated active material for producing oxygenate.
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公开(公告)号：US09931621B2
公开(公告)日：2018-04-03
申请号：US15146468
申请日：2016-05-04
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Kapil Kandel , Paul F. Keusenkothen , Jeevan S. Abichandani
IPC: C07C29/156 , C07C31/125 , B01J35/10 , B01J8/02 , B01J23/745
CPC classification number: B01J35/1019 , B01J8/02 , B01J23/72 , B01J23/745 , B01J35/1014 , B01J35/1061 , B01J37/0201 , B01J2208/027 , C07C29/156 , C07C31/125
Abstract: The invention relates to long chain alcohol, to processes for catalytically producing long chain alcohol from carbon monoxide and molecular hydrogen, to equipment useful in such processes, and to the use of long chain alcohol, e.g., for producing fuel, lubricating oil, detergent, and plasticizer. The catalyst is mesoporous and comprises iron and copper.
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公开(公告)号：US20210355271A1
公开(公告)日：2021-11-18
申请号：US17284717
申请日：2019-11-13
Inventor： Monica Lotz , Kapil Kandel , Michael Salciccioli , Stephen Cohn , Alan A. Galuska , Javier Guzman , S. Richard Turner , Hans Eliot Edling , Edward E. Paschke
IPC: C08G63/185 , C08G63/199 , C08G63/85 , C08G63/80
Abstract: Semicrystalline bifuran polyesters wherein the diacid and/or diol components include bifuran units such as those derived from 2,2′-bifuran-5,5′-dicarboxylic acid (BFA), dimethyl-2,2′-bifuran-5,5′-dicarboxylate (BFE), and/or bis(hydroxyethyl) bifuranoate (BHEB) Polyethylene-BFE (PEBF) having a high ΔHf and high Tg determined by DSC on the second heating ramp is described. Polybutylene-BFE (PBBF), polyhexylene-BFE (PHBF), polypropylene-BFE (PPBF), etc., are also described. Method for making bifuran polyesters includes melt esterification or transesterification and polycondensation of one or more monomers comprising a diacid component and a diol component, wherein the one or more monomers include a bifuran monomer, such as BFA, BFE, BHEB or BFD. Also described is a method of forming a bifuran polyester prepolymer in the melt, pelletization, crystallization, and solid state polymerization.
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公开(公告)号：US20210348064A1
公开(公告)日：2021-11-11
申请号：US17278547
申请日：2019-10-18
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Kapil Kandel , Teng Xu , John S. Coleman , Krystle J. Emanuele , Frank Cheng-Yu Wang , Anthony S. Mennito
Abstract: Processes for preparing a low particulate liquid hydrocarbon product are provided and include blending a tar stream containing particles with a fluid and heating to a temperature of 250° C. or greater to produce a fluid-feed mixture that contains tar, the particles, and the fluid. The fluid-feed mixture contains about 20 wt % or greater of the fluid, based on a combined weight of the tar stream and the fluid. Also, about 25 wt % to about 99 wt % of the particles in the tar stream are dissolved or decomposed when producing the fluid-feed mixture.
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公开(公告)号：US20210230490A1
公开(公告)日：2021-07-29
申请号：US16972363
申请日：2019-05-24
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Teng Xu , Kapil Kandel , Krystle J. Emanuele , Jeffrey C. Yeh , Glovanni S. Contello
Abstract: Systems and methods are provided for co-processing of pyrolysis tar with pre-pyrolysis flash bottoms. In some aspects, the co-processing can correspond to solvent-assisted hydroprocessing. By combining pyrolysis tar and flash bottoms with a solvent, various difficulties associated with hydroprocessing of the fractions can be reduced or minimized, such as difficulties associated with hydroprocessing of high viscosity feeds and/or high sulfur feeds. Optionally, separate solvents and/or fluxes can be used for the pyrolysis tar and the flash bottoms. The resulting upgraded products can be suitable, for example, for inclusion in low sulfur fuel oils (LSFO).
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