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    Modified Polyethylene Compositions with Enhanced Melt Strength
    11.
    发明申请
    Modified Polyethylene Compositions with Enhanced Melt Strength 审中-公开
    改进的聚乙烯组合物，具有增强的熔体强度

    公开(公告)号：US20130216812A1

    公开(公告)日：2013-08-22

    申请号：US13800098

    申请日：2013-03-13

    Applicant: ExxonMobil Chemical Patents Inc.

    Inventor： Jianya Cheng ,  Pradeep P. Shirodkar ,  Jiang Pejiun ,  Johannes M. Soulages

    IPC: C08L9/00 ,  C08F236/20

    CPC classification number: C08L23/06 ,  C08F210/18 ,  C08F236/20 ,  C08J5/18 ,  C08J2323/06 ,  C08J2323/08 ,  C08J2423/08 ,  C08L9/00 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2207/07 ,  C08F210/14 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/19 ,  C08L23/083

    Abstract: The present invention relates to a branched modifier and a composition comprising more than 25 wt % (based on the weight of the composition) of one or more linear ethylene polymers having a g′vis of 0.97 or more and an Mw of 20,000 g/mol or more and at least 0.1 wt % of a branched modifier where the modifier has a) a g′vis of 0.70 or less; b) an Mw of 100,000 g/mol or more; c) an Mw/Mn of 4.0 or more; d) a shear thinning ratio of 110 or more, e) a melt strength of 10 cN or more; f) a complex viscosity at 0.1 rad/sec at 190° C. of at least 130,000 Pa·s; and g) a phase angle of Z° or less where Z=138.3G*(−0.142), where G* is the complex modulus reported in Pascals measured at 190° C. and the phase angle units are reported in degrees, wherein the G* is from 1,000 to 1,000,000 Pa.

    Abstract translation: 本发明涉及一种支化改性剂和一种组合物，其包含超过25重量％（基于组合物的重量）的一种或多种线性乙烯聚合物，其g'vis为0.97以上，Mw为20,000g / mol 或更多和至少0.1重量％的支化改性剂，其中改性剂具有a）g'vis为0.70以下; b）Mw为100,000g / mol以上; c）Mw / Mn为4.0以上; d）剪切稀化比为110或更大，e）熔体强度为10cN以上; f）在190℃下0.1rad / sec下的复数粘度至少为130,000Pa·s; 和g）Z°或更小的相位角，其中Z = 138.3G *（ - 0.142），其中G *是在190℃下测量的帕斯卡报告的复数模量，并且以角度报告相位角单位，其中 G *为1,000至1,000,000Pa。

    Modified Polyethylene Compositions with Enhanced Melt Strength
    13.
    发明申请
    Modified Polyethylene Compositions with Enhanced Melt Strength 审中-公开

    公开(公告)号：US20190322848A1

    公开(公告)日：2019-10-24

    申请号：US16502256

    申请日：2019-07-03

    Applicant: ExxonMobil Chemical Patents Inc

    Inventor： Jianya Cheng ,  Pradeep P. Shirodkar ,  Peijun Jiang ,  Johannes M. Soulages

    IPC: C08L23/06 ,  C08F236/20 ,  C08L23/08 ,  C08F210/18 ,  C08J5/18 ,  C08L9/00

    Abstract: The present invention relates to a branched modifier and a composition comprising more than 25 wt % (based on the weight of the composition) of one or more linear ethylene polymers having a g′vis of 0.97 or more and an Mw of 20,000 g/mol or more and at least 0.1 wt % of a branched modifier where the modifier has a) a g′vis of 0.70 or less; b) an Mw of 100,000 g/mol or more; c) an Mw/Mn of 4.0 or more; d) a shear thinning ratio of 110 or more, e) a melt strength of 10 cN or more; f) a complex viscosity at 0.1 rad/sec at 190° C. of at least 130,000 Pa·s; and g) a phase angle of Z° or less where Z=138.3G*(−0.142), where G* is the complex modulus reported in Pascals measured at 190° C. and the phase angle units are reported in degrees, wherein the G* is from 1,000 to 1,000,000 Pa.

    Modified Polyethylene Compositions with Enhanced Melt Strength
    15.
    发明申请
    Modified Polyethylene Compositions with Enhanced Melt Strength 审中-公开
    改进的聚乙烯组合物，具有增强的熔体强度

    公开(公告)号：US20160272798A1

    公开(公告)日：2016-09-22

    申请号：US15080000

    申请日：2016-03-24

    Applicant: ExxonMobil Chemical Patents Inc.

    Inventor： Jianya Cheng ,  Pradeep P. Shirodkar ,  Peijun Jiang ,  Johannes M. Soulages

    IPC: C08L23/06 ,  C08J5/18

    CPC classification number: C08L23/06 ,  C08F210/18 ,  C08F236/20 ,  C08J5/18 ,  C08J2323/06 ,  C08J2323/08 ,  C08J2423/08 ,  C08L9/00 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2207/07 ,  C08F210/14 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/19 ,  C08L23/083

    Abstract: The present invention relates to a branched modifier and a composition comprising more than 25 wt % (based on the weight of the composition) of one or more linear ethylene polymers having a g′vis of 0.97 or more and an Mw of 20,000 g/mol or more and at least 0.1 wt % of a branched modifier where the modifier has a) a g′vis of 0.70 or less; b) an Mw of 100,000 g/mol or more; c) an Mw/Mn of 4.0 or more; d) a shear thinning ratio of 110 or more, e) a melt strength of 10 cN or more; f) a complex viscosity at 0.1 rad/sec at 190° C. of at least 130,000 Pa·s; and g) a phase angle of Z° or less where Z=138.3 G*(−0.142), where G* is the complex modulus reported in Pascals measured at 190° C. and the phase angle units are reported in degrees, wherein the G* is from 1,000 to 1,000,000 Pa.

    Abstract translation: 支链改性剂和组合物，其包含超过25重量％（基于组合物的重量）的一种或多种线性乙烯聚合物，其具有0.97以上的Mw和20,000g / mol的Mw， 更多且至少0.1重量％的支化改性剂，其中改性剂具有0.70以下的a）ag'vis; b）Mw为100,000g / mol以上; c）Mw / Mn为4.0以上; d）剪切稀化比为110或更大，e）熔体强度为10cN以上; f）在190℃下0.1rad / sec下的复数粘度至少为130,000Pa·s; 并且g）Z°或更小的相位角，其中Z = 138.3G *（ - 0.142），其中G *是在190℃下测量的帕斯卡报告的复数模量，并且以角度报告相位角单位，其中 G *为1,000至1,000,000Pa。

    Vulcanized Polymer Blends
    17.
    发明申请
    Vulcanized Polymer Blends 有权
    硫化聚合物共混物

    公开(公告)号：US20140309358A1

    公开(公告)日：2014-10-16

    申请号：US14315425

    申请日：2014-06-26

    Applicant: ExxonMobil Chemical Patents Inc.

    Inventor： Sunny Jacob ,  Peijun Jiang ,  Aspy K. Mehta ,  Pradeep P. Shirodkar ,  Armenag H. Dekmezian

    IPC: C08L47/00 ,  C08L23/12

    CPC classification number: C08L47/00 ,  C08L23/10 ,  C08L23/12 ,  C08L23/145 ,  C08L23/16 ,  C08L2312/00 ,  C08L2314/06 ,  C08L2666/06

    Abstract: A heterogeneous vulcanized polymer blend comprising a continuous phase comprising a thermoplastic polypropylene having a crystallinity of at least 30% and a dispersed phase comprising particles of an elastomeric copolymer dispersed in the continuous phase and having an average particle size of less than 5 micron. The elastomeric copolymer has a crystallinity of less than 20% and is at least partially cross-linked such that no more than about 80 wt % of the elastomeric copolymer is extractable in cyclohexane at 23° C.

    Abstract translation: 一种异相硫化聚合物共混物，其包含连续相，其包含具有至少30％的结晶度的热塑性聚丙烯和包含分散在连续相中的平均粒度小于5微米的弹性共聚物颗粒的分散相。 弹性体共聚物的结晶度小于20％并且至少部分交联，使得不超过约80重量％的弹性体共聚物可在23℃的环己烷中提取。

    Foamed Polyethylene Compositions
    19.
    发明申请
    Foamed Polyethylene Compositions 审中-公开
    发泡聚乙烯组合物

    公开(公告)号：US20150126634A1

    公开(公告)日：2015-05-07

    申请号：US14596516

    申请日：2015-01-14

    Applicant: ExxonMobil Chemical Patents Inc.

    Inventor： Pradeep P. Shirodkar ,  Jianya Cheng ,  Joseph M. Tomei ,  Peijun Jiang ,  Arturo Leyva

    IPC: C08J9/00 ,  C08J9/06

    Abstract: A foamable or foamed article comprising a diene terpolymer, the diene terpolymer comprising (or consisting essentially of) from 0.01 wt % to 10.0 wt % diene derived units, and 1.0 wt % to 20 wt % of C4 to C10 α-olefin derived units based on the weight of the diene terpolymer, wherein the diene terpolymer: a) has a g′vis of less than 0.90; b) has an Mw within a range of from 100,000 g/mol to 500,000 g/mol; c) has an Mw/Mn within the range of from 3.5 to 12.0; and d) an Mz/Mn of greater than 7.0. Inventive articles comprise a blend of a relatively high density linear polyethylene and the diene terpolymer.

    Abstract translation: 包含二烯三元共聚物的可发泡或发泡制品，所述二烯三元共聚物包含（或基本上由0.01重量％至10.0重量％的二烯衍生单元）和1.0重量％至20重量％的C 4至C 10α-烯烃衍生的单元基 关于二烯三元共聚物的重量，其中二烯三元共聚物：a）具有小于0.90的ag'vis; b）具有在100,000g / mol至500,000g / mol范围内的Mw; c）具有在3.5至12.0范围内的Mw / Mn; 和d）大于7.0的Mz / Mn。 本发明的制品包括相对高密度的线性聚乙烯和二烯三元共聚物的共混物。

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