公开(公告)号：US20170101366A1

公开(公告)日：2017-04-13

申请号：US15387977

申请日：2016-12-22

Applicant: ExxonMobil Research and Engineering Company

Inventor： Kun Wang

IPC: C07C253/30 ,  C07C407/00 ,  C07C17/281 ,  C07C51/353 ,  C07C209/68 ,  C07C201/12 ,  C07C29/32 ,  C07C29/48

CPC classification number: C07C253/30 ,  C07C17/269 ,  C07C29/132 ,  C07C29/32 ,  C07C29/50 ,  C07C51/353 ,  C07C201/12 ,  C07C209/68 ,  C07C407/00 ,  C10G50/02 ,  C10G69/126 ,  C10G2300/1025 ,  C10G2300/1081 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P20/125 ,  C07C409/04 ,  C07C409/16 ,  C07C211/10 ,  C07C205/02 ,  C07C255/04 ,  C07C31/12 ,  C07C31/202 ,  C07C55/10 ,  C07C19/045

Abstract: An integrated process for making di-functional or multi-functional molecules with concurrent light paraffin upgrading is disclosed. The process involves three primary steps: (1) oxidation of an iso-paraffin to alkyl hydroperoxide and alcohol; (2) converting the alkyl hydroperoxide and alcohol to dialkyl peroxide; and (3) coupling functional molecules into di-functional or multi-functional molecules using the dialkyl peroxide as a radical initiator, while the dialkyl peroxide is converted to a tertiary alcohol. The functional molecules include any functional molecule R—X, where R is a hydrocarbyl group and X is a functional group such as —OH, —CN, —C(O)OH, —NH—, or the like.

公开(公告)号：US20170101355A1

公开(公告)日：2017-04-13

申请号：US15387996

申请日：2016-12-22

Applicant: ExxonMobil Research and Engineering Company

Inventor： Kun Wang

IPC: C07C2/86 ,  C07C29/48 ,  C07C407/00

CPC classification number: C07C407/00 ,  C07C2/862 ,  C07C29/132 ,  C07C29/50 ,  C10G45/02 ,  C10G50/02 ,  C10G69/126 ,  C10G2300/1025 ,  C10G2300/1081 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/06 ,  C10L2290/543 ,  C07C409/04 ,  C07C409/16 ,  C07C31/12 ,  C07C9/21 ,  C07C9/16

Abstract: A process for converting light paraffins to heavier paraffinic hydrocarbon fluids is disclosed. The process involves: (1) oxidation of iso-paraffins to alkyl hydroperoxides and alcohols; (2) conversion of the alkyl hydroperoxides and alcohols to dialkyl peroxides; and (3) radical-initiated coupling of paraffins and/or iso-paraffins using the dialkyl peroxides as radical initiators, thereby forming heavier hydrocarbon products. Fractionation of the heavy hydrocarbon products can then be used to isolate fractions for use as hydrocarbon fluids.

公开(公告)号：US09587180B2

公开(公告)日：2017-03-07

申请号：US14096295

申请日：2013-12-04

Applicant: ExxonMobil Research and Engineering Company

Inventor： Virginia M. Roberts ,  Suzzy Chen Hsi Ho ,  Paul D. Oldenburg ,  Michel Daage ,  Kun Wang ,  Bradley R. Fingland ,  Patrick Loring Hanks

IPC: C10G3/00 ,  C10G45/58 ,  C10G65/04 ,  C10G65/12 ,  C10L1/04 ,  C10L1/08 ,  C10M109/02 ,  C10M177/00

CPC classification number: C10G3/50 ,  C10G3/42 ,  C10G3/46 ,  C10G3/47 ,  C10G3/49 ,  C10G45/58 ,  C10G65/043 ,  C10G65/12 ,  C10G2300/1011 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  C10L1/08 ,  C10L2200/0469 ,  C10L2270/04 ,  C10M109/02 ,  C10M177/00 ,  C10N2220/022 ,  C10N2270/00 ,  Y02E50/13 ,  Y02P30/20

Abstract: Provided are processes for making hydrocarbons from renewable feed sources. In an embodiment, there is provided a method for co-producing lube basestock and transportation fuel from a feedstock of biological origin, the method including: a) converting a feedstock of biological origin to a ketone or a dimer acid in the presence of a first catalyst; and b) hydrogenating the ketone or the dimer acid to produce a hydrocarbon in the presence of a second catalyst comprising a hydrogenation catalyst and a hydrothermally stable binder.

Abstract translation: 提供从可再生饲料来源制造碳氢化合物的方法。 在一个实施方案中，提供了一种用于从生物来源的原料共同生产润滑油基础油和运输燃料的方法，所述方法包括：a）在第一次存在下将生物来源的原料转化为酮或二聚酸 催化剂; 和b）在包含氢化催化剂和水热稳定的粘合剂的第二催化剂的存在下，使酮或二聚酸氢化以制备烃。

公开(公告)号：US09422206B2

公开(公告)日：2016-08-23

申请号：US14096322

申请日：2013-12-04

Applicant: ExxonMobil Research and Engineering Company

Inventor： Kun Wang ,  Randall D. Partridge ,  Himanshu Gupta

IPC: C10G45/58 ,  C10G45/48 ,  C10M105/02 ,  C10M101/00 ,  C07C1/22 ,  C07C45/48 ,  C10G3/00 ,  C07C1/207

CPC classification number: C07C1/22 ,  C07C1/2072 ,  C07C1/2076 ,  C07C1/2078 ,  C07C45/48 ,  C10G3/42 ,  C10G3/46 ,  C10G3/47 ,  C10G3/49 ,  C10G3/50 ,  C10G45/58 ,  C10G2300/1011 ,  C10M101/00 ,  C10M105/02 ,  C10N2230/64 ,  C10N2270/00 ,  Y02P30/20 ,  C07C49/788 ,  C07C49/17

Abstract: Provided are processes for making hydrocarbons from renewable feed sources. In an embodiment, there is provided a method for producing a lube basestock including: contacting a compound of Formula (I) and a feedstock of biological origin with a catalyst component including a basic material: wherein R1 is selected from acyclic hydrocarbyl, cyclic hydrocarbyl, and aryl, wherein R1 has one or more optional substitutions selected from the group consisting of —Ra, —ORa, —C(O)Ra, and —C(O)ORa, wherein Ra is H or C1-C6 alkyl group; and n is 1, 2, 3, 4 or 5; and hydrogenating a ketone to a hydrocarbon with a catalyst including a hydrogenation catalyst and a hydrothermally stable binder.

Abstract translation: 提供从可再生饲料来源制造碳氢化合物的方法。 在一个实施方案中，提供了一种制备润滑油基础油料的方法，包括：使式（I）化合物和生物来源的原料与包含碱性物质的催化剂组分接触：其中R 1选自无环烃基，环状烃基， 和芳基，其中R 1具有一个或多个选自-R a，-OR，-C（O）R a和-C（O）OR a的任选取代基，其中R a是H或C 1 -C 6烷基; n为1,2,3,4或5; 并用含有氢化催化剂和水热稳定的粘合剂的催化剂将酮氢化成烃。

公开(公告)号：US20130324777A1

公开(公告)日：2013-12-05

申请号：US13851293

申请日：2013-03-27

Applicant: ExxonMobil Research and Engineering Company

Inventor： Patrick Loring Hanks ,  Bradley R. Fingland ,  Suzzy Chen Hsi Ho ,  Kun Wang

IPC: C10G3/00

CPC classification number: C10G3/50 ,  C10G3/44 ,  C10G3/45 ,  C10G69/126 ,  C10G2300/1014 ,  C10G2400/04 ,  C10G2400/10 ,  C10G2400/20 ,  C10L1/08 ,  Y02E50/13 ,  Y02P30/20

Abstract: Feeds containing triglycerides are processed to produce an olefinic diesel fuel product and propylene. The olefinic diesel can optionally be oligomerized to form a lubricant base oil product. The olefinic diesel and propylene are generated by deoxygenating the triglyceride-containing feed using processing conditions that enhance preservation of olefins that are present in the triglycerides. The triglyceride-containing feed is processed in the presence of a catalyst containing a Group VI metal or a Group VIII metal and optionally a physical promoter metal.

Abstract translation: 加工含有甘油三酯的饲料以生产烯烃柴油燃料产物和丙烯。 烯烃柴油可以任选地低聚以形成润滑剂基础油产品。 烯烃柴油和丙烯是通过使用增强甘油三酯中存在的烯烃保存的加工条件对含甘油三酯的进料进行脱氧而产生的。 含有甘油三酯的进料在含有VI族金属或VIII族金属和任选的物理助催化剂金属的催化剂存在下进行处理。

公开(公告)号：US20210189276A1

公开(公告)日：2021-06-24

申请号：US17119096

申请日：2020-12-11

Applicant: ExxonMobil Research and Engineering Company

Inventor： Deyaa I. AbuSalim ,  Eugine Choi ,  Kun Wang ,  Himanshu Gupta ,  Dongil Kang ,  Jung Park ,  Jonathan E. Mitchell

IPC: C10L10/10 ,  C07C407/00 ,  C10L1/04 ,  C07C29/48 ,  C07C2/86

Abstract: A process for converting light paraffins and/or light hydrocarbons to a high octane gasoline composition is disclosed. The process involves: (1) oxidation of iso-paraffins to alkyl hydroperoxides and alcohol; (2) conversion of the alkyl hydroperoxides and alcohol to dialkyl peroxides; and (3) radical coupling of one or more iso-paraffins and/or iso-hydrocarbons using the dialkyl peroxides as radical initiators, thereby forming a gasoline composition comprising gasoline-range molecules including a C7 enriched gasoline composition having a road octane number (RON) greater than 100.

公开(公告)号：US20210179511A1

公开(公告)日：2021-06-17

申请号：US17077059

申请日：2020-10-22

Applicant: ExxonMobil Research and Engineering Company

Inventor： Kun Wang ,  Jihad M. Dakka

IPC: C07C1/22 ,  C07C45/27 ,  C07C45/68 ,  C07C29/38 ,  B01J19/24

Abstract: A method may include reacting at least a naphtha range alkane with oxygen and to produce oxygenate products; reacting at least a portion of the oxygenate products to produce condensed products; and reacting at least a portion of the condensed products with at least hydrogen to produce a distillate range product.

公开(公告)号：US20200255357A1

公开(公告)日：2020-08-13

申请号：US16743181

申请日：2020-01-15

Applicant: ExxonMobil Research and Engineering Company

Inventor： Kun Wang

IPC: C07C2/86 ,  C07C51/377 ,  C07C253/30 ,  C07C407/00 ,  C07C1/24

Abstract: Provided are processes for preparing alpha, beta-unsaturated functional compounds using four major reaction steps: 1) air oxidation of an iso-paraffin to a mixture of alkyl hydroperoxide and alcohol; 2) converting the alkyl hydroperoxide and alcohol to dialkyl peroxide; 3) oxidative cross-coupling between a primary or secondary alcohol and a compound comprising at least one R3CH2- (R3=hydrogen or an optionally substituted hydrocarbyl) moiety to afford a coupled product using the dialkyl peroxide as a radical initiator, while the dialkyl peroxide is converted to a tertiary alcohol; 4) dehydration of the coupled product to yield an alpha, beta-unsaturated functional compound.

公开(公告)号：US09574138B2

公开(公告)日：2017-02-21

申请号：US14096277

申请日：2013-12-04

Applicant: ExxonMobil Research and Engineering Company

Inventor： Kun Wang ,  Virginia M. Roberts ,  Paul D. Oldenburg ,  Suzzy Chen Hsi Ho ,  Michel Daage ,  Frank Cheng-Yu Wang

IPC: C10G3/00 ,  C10M105/04

CPC classification number: C10G3/50 ,  C10G3/44 ,  C10M105/04 ,  Y02E50/13 ,  Y02P30/20

Abstract: Provided are processes for making saturated hydrocarbons from renewable feed sources. In an embodiment, a process for producing a lube basestock and/or a diesel fuel from a feedstock of biological origin includes: contacting the feedstock in a single reactor in the presence of hydrogen with catalyst components including a first catalyst and a second catalyst, wherein the first catalyst comprises an acidic material, a basic material, or a combination of both, and wherein the second catalyst is a hydrogenation catalyst including a hydrothermally stable binder.

Abstract translation: 提供了从可再生饲料源制备饱和烃的方法。 在一个实施方案中，用于从生物来源的原料生产润滑油基础油料和/或柴油燃料的方法包括：在氢存在下在单个反应器中使原料与包含第一催化剂和第二催化剂的催化剂组分接触，其中 第一催化剂包括酸性物质，碱性物质或两者的组合，其中第二催化剂是包含水热稳定粘合剂的氢化催化剂。

公开(公告)号：US20140171699A1

公开(公告)日：2014-06-19

申请号：US14096277

申请日：2013-12-04

Applicant: ExxonMobil Research and Engineering Company

Inventor： Kun Wang ,  Virginia M. Roberts ,  Paul D. Oldenburg ,  Suzzy Chen Hsi Ho ,  Michel Daage ,  Frank Cheng-Yu Wang

IPC: C10G3/00 ,  C10M105/04

CPC classification number: C10G3/50 ,  C10G3/44 ,  C10M105/04 ,  Y02E50/13 ,  Y02P30/20

Abstract: Provided are processes for making saturated hydrocarbons from renewable feed sources. In an embodiment, a process for producing a lube basestock and/or a diesel fuel from a feedstock of biological origin includes: contacting the feedstock in a single reactor in the presence of hydrogen with catalyst components including a first catalyst and a second catalyst, wherein the first catalyst comprises an acidic material, a basic material, or a combination of both, and wherein the second catalyst is a hydrogenation catalyst including a hydrothermally stable binder.

Abstract translation: 提供了从可再生饲料源制备饱和烃的方法。 在一个实施方案中，用于从生物来源的原料生产润滑油基础油料和/或柴油燃料的方法包括：在氢存在下在单个反应器中将原料与包含第一催化剂和第二催化剂的催化剂组分接触，其中 第一催化剂包括酸性物质，碱性物质或两者的组合，其中第二催化剂是包含水热稳定粘合剂的氢化催化剂。