公开(公告)号：US10551739B2

公开(公告)日：2020-02-04

申请号：US15925779

申请日：2018-03-20

Applicant: FUJIFILM Corporation

Inventor： Akira Takada ,  Shuji Hirano ,  Naoya Shimoju ,  Toshiya Takahashi ,  Hidehiro Mochizuki

IPC: G03F7/075 ,  G03F7/038 ,  G03F7/039 ,  G03F7/16 ,  G03F7/20 ,  G03F7/32 ,  G03F7/38 ,  G03F7/40

Abstract: Provided are a resist composition capable of forming a pattern having excellent pattern collapse performance, particularly in the formation of an ultrafine pattern (for example, a pattern with a line width 50 nm or less) using the resist composition containing a resin (A) having a repeating unit (a) having an aromatic ring group and a repeating unit (b) having a silicon atom in a side chain, as well as a resist film, a pattern forming method, and a method for manufacturing an electronic device, each using the resist composition.

公开(公告)号：US09368144B2

公开(公告)日：2016-06-14

申请号：US14670066

申请日：2015-03-26

Applicant: FUJIFILM Corporation

Inventor： Hidehiro Mochizuki ,  Toshio Sasaki ,  Tetsuya Watanabe ,  Tatsuo Mikami

IPC: G11B7/24 ,  G11B7/24035 ,  G11B7/245 ,  G11B7/246 ,  G11B7/24038 ,  G11B7/256 ,  G11B7/26

CPC classification number: G11B7/24035 ,  G11B7/24038 ,  G11B7/245 ,  G11B7/246 ,  G11B7/256 ,  G11B7/26

Abstract: The object of the invention is to provide an optical information recording medium which excels in stability e.g., for preserving the properties during a long-term storage and which enables recording using a laser having a small peak power, and a method for manufacturing such an optical information recording medium. An optical information recording medium 10 includes a recording layer 14, and intermediate layers (adhesive agent layer 15A and recording layer support layer 15B) adjacent to the recording layer 14, and the recording layer 14 includes a recording material comprising a one-photon absorption dye bound to a polymer binder (polymer compound).

Abstract translation: 本发明的目的是提供一种光稳定性优良的光学信息记录介质，例如用于在长期存储期间保持特性，并且能够使用具有小峰值功率的激光进​​行记录，以及用于制造这种光学 信息记录介质。 光学信息记录介质10包括记录层14和与记录层14相邻的中间层（粘合剂层15A和记录层支撑层15B），并且记录层14包括包含单光子吸收染料 与聚合物粘合剂（高分子化合物）结合。

公开(公告)号：US08670296B2

公开(公告)日：2014-03-11

申请号：US13714645

申请日：2012-12-14

Applicant: Fujifilm Corporation

Inventor： Hidehiro Mochizuki ,  Toshio Sasaki ,  Toshiyuki Kitahara

IPC: G11B7/24035 ,  G11B7/0055

CPC classification number: G11B7/24035 ,  B82Y10/00 ,  G11B7/00451 ,  G11B7/00452 ,  G11B7/0055 ,  G11B7/245 ,  G11B7/246 ,  G11B7/2467 ,  G11B7/2495 ,  Y10T428/265 ,  Y10T428/31504

Abstract: An optical information recording medium includes: a recording layer 12 comprising a multi-photon absorption compound and a one-photon absorption compound; and a supporting member (base layer 11) configured to support the recording layer 12. In this optical information recording medium, absorption of multiple photons by the multi-photon absorption compound and absorption of one photon by the one-photon absorption compound cause a void to be generated in the recording layer, whereby information is recordable by modulation based on a presence or absence of a void.

Abstract translation: 光信息记录介质包括：包含多光子吸收化合物和单光子吸收化合物的记录层12; 以及被配置为支撑记录层12的支撑构件（基底层11）。在该光学信息记录介质中，多光子吸收化合物吸收多个光子并且通过单光子吸收化合物吸收一个光子导致空隙 在记录层中产生，由此基于空隙的存在或不存在可以通过调制记录信息。

公开(公告)号：US10120281B2

公开(公告)日：2018-11-06

申请号：US15176345

申请日：2016-06-08

Applicant: FUJIFILM Corporation

Inventor： Koutarou Takahashi ,  Tomotaka Tsuchimura ,  Shuhei Yamaguchi ,  Natsumi Yokokawa ,  Hidehiro Mochizuki

IPC: G03F7/20 ,  G03F7/24 ,  G03F7/038 ,  G03F7/32 ,  G03F1/24 ,  G03F1/50 ,  G03F1/78

Abstract: An actinic ray-sensitive or radiation-sensitive resin composition includes an alkali-soluble resin (A) having a phenolic hydroxyl group, and a crosslinking agent (C) having two or more hydroxymethyl groups or alkoxymethyl groups in total within the molecule, wherein the composition contains a crosslinking agent (C1) having a molecular weight of 420 or more and also having two to four hydroxymethyl groups or alkoxymethyl groups in total within the molecule in a proportion of 60 mol % to 100 mol % based on the total amount of the crosslinking agent (C) including the crosslinking agent (C1), and in which the total concentration of the hydroxymethyl groups or the alkoxymethyl groups of the crosslinking agent (C) relative to 1 g of the solid content in the actinic ray-sensitive or radiation-sensitive resin composition is 0.30 mmol/g or more.

公开(公告)号：US10011576B2

公开(公告)日：2018-07-03

申请号：US15176810

申请日：2016-06-08

Applicant: FUJIFILM Corporation

Inventor： Shuhei Yamaguchi ,  Koutarou Takahashi ,  Tomotaka Tsuchimura ,  Natsumi Yokokawa ,  Hidehiro Mochizuki

IPC: G03F7/039 ,  G03F7/004 ,  G03F7/20 ,  G03F7/32 ,  C07D307/33 ,  C08F12/24 ,  C08F112/14 ,  C08F212/32 ,  G03F7/038 ,  C08F212/14 ,  C09D125/18 ,  G03F1/50 ,  C08F12/22

CPC classification number: C07D307/33 ,  C08F12/22 ,  C08F12/24 ,  C08F112/14 ,  C08F212/14 ,  C09D125/18 ,  G03F1/50 ,  G03F7/004 ,  G03F7/038 ,  G03F7/0382 ,  G03F7/2004 ,  G03F7/2059 ,  G03F7/322 ,  C08F212/32 ,  C08F212/08

Abstract: The actinic ray-sensitive or radiation-sensitive resin composition includes a crosslinking agent having a polarity converting group and an alkali-soluble resin, in which the polarity converting group is a group capable of decomposing by the action of an alkaline aqueous solution to generate a carboxylic acid or sulfonic acid on the side having a crosslinking group.

公开(公告)号：US09406332B2

公开(公告)日：2016-08-02

申请号：US14845492

申请日：2015-09-04

Applicant: FUJIFILM CORPORATION

Inventor： Hidehiro Mochizuki ,  Tetsuya Watanabe ,  Toshio Sasaki ,  Tatsuo Mikami ,  Takumi Nakamura

IPC: G11B7/24 ,  G11B7/246 ,  G11B7/24038 ,  G11B7/245 ,  C08F220/18 ,  C08F226/06 ,  G11B7/2405 ,  G11B7/256

CPC classification number: G11B7/246 ,  C08F220/18 ,  C08F226/06 ,  C09D4/00 ,  G11B7/24038 ,  G11B7/2405 ,  G11B7/245 ,  G11B7/256 ,  C08F2220/185 ,  C08F220/34

Abstract: An optical information recording medium includes at least one recording layer. The recording layer includes a recording material comprising a polymer compound to which a one-photon absorption dye is bonded, and a coupling strength Δ2 between the one-photon absorption dye and the polymer compound in the recording material is higher than a coupling strength estimated to be exerted between the same one-photon absorption dye and the same polymer compound if the one-photon absorption dye is dispersed in the polymer compound in the recording material.

Abstract translation: 光学信息记录介质包括至少一个记录层。 记录层包括记录材料，该记录材料包含结合有单光子吸收染料的高分子化合物，记录材料中单光子吸收染料与高分子化合物之间的耦合强度Δ2高于估计为 如果单光子吸收染料分散在记录材料中的高分子化合物中，则施加在相同的单光子吸收染料和相同的聚合物化合物之间。

公开(公告)号：US08526291B2

公开(公告)日：2013-09-03

申请号：US13739668

申请日：2013-01-11

Applicant: FUJIFILM Corporation

Inventor： Hidehiro Mochizuki ,  Tatsuo Mikami ,  Shunichi Hoshino

IPC: G11B7/00

CPC classification number: G11B7/24035 ,  B82Y10/00 ,  G11B7/00455 ,  G11B7/0055 ,  G11B7/24038 ,  G11B7/245 ,  G11B7/246 ,  G11B7/248

Abstract: Optical information recording medium comprises: a plurality of recording layers 14, each of which undergoes a change in refractive index by irradiation with recording beam; and an intermediate layer 15 provided between recording layers 14. The recording layer 14 contains polymer binder and dye dispersed in the polymer binder, and at least in proximity to an interface (far-side interface 18) between the intermediate layer 15 and a recording layer 14 disposed adjacent to incident side of the intermediate layer 15 from which the recording beam enters the intermediate layer, the intermediate layer 15 has refractive index different from that of the recording layer 14. Glass transition temperature of the polymer binder is lower than melting point and decomposition point of the dye, and refractive index of the polymer binder changes by receiving heat generated when the dye absorbs the recording beam, whereby information is recordable in the recording layer.

Abstract translation: 光信息记录介质包括：多个记录层14，每个通过记录光束的照射而经历折射率的变化; 以及设置在记录层14之间的中间层15.记录层14包含分散在聚合物粘合剂中的聚合物粘合剂和染料，并且至少在中间层15与记录层之间的界面（远侧界面18）附近 14与中间层15的入射侧相邻设置，记录光从该入射侧入射到中间层，中间层15的折射率与记录层14的折射率不同。聚合物粘合剂的玻璃化转变温度低于熔点， 染料的分解点和聚合物粘合剂的折射率通过接收当染料吸收记录光束时产生的热量而改变，由此信息可记录在记录层中。

公开(公告)号：US08477577B2

公开(公告)日：2013-07-02

申请号：US13713888

申请日：2012-12-13

Applicant: Fujifilm Corporation

Inventor： Toshio Sasaki ,  Hidehiro Mochizuki ,  Toshiyuki Kitahara

IPC: G11B7/00

CPC classification number: G11B7/0932 ,  B82Y10/00 ,  G11B7/00455 ,  G11B2007/0013 ,  G11B2007/00457

Abstract: Recording and reading method for optical information recording medium comprising: recording layer having thickness not less than 2λ/n, where λ is wavelength of recording beam and n is refractive index of the recording layer, and configured to undergo a change in the refractive index by irradiation with the recording beam; and adjacent layer adjacent to the recording layer at a side opposite to an incident side, comprises the steps of: recording a recording spot by irradiating with the recording beam, while shifting focal position by offset amount d, which satisfies ω0d3ω0, where ω0 is radius of the recording spot, from interface between recording layer and adjacent layer toward the incident side at a time of recording, whereby the refractive index of recording layer changes at a recording position to record recording spot; and reading out the information by irradiating with reading beam, while bringing it into focus on the interface.

Abstract translation: 用于光信息记录介质的记录和读取方法，包括：具有不小于2λ/ n的厚度的记录层，其中λ是记录光束的波长，n是记录层的折射率，并且被配置为经历折射率的变化 用记录光束照射; 以及在与入射侧相对的一侧与记录层相邻的相邻层包括以下步骤：通过照射记录光束来记录记录点，同时将焦点位置移动偏移量d，该偏移量d满足omega0d3omega0，其中ω=半径 在记录时从记录层和相邻层之间的界面向入射侧记录记录点，由此记录层的折射率在记录位置改变以记录记录点; 并通过用读取光束照射来读出信息，同时将其重点放在界面上。