摘要:
A process for producing a clearcoat and a multi-component composition. The process comprises applying the multi-component composition to a primed substrate, an unprimed substrate, or a coated substrate. The multi-component composition comprises (A) a binder containing on average at least one isocyanate-reactive functional group, (B) an adduct prepared from (b1) a diisocyanate and (b2) a compound of the general formula I containing an isocyanate-reactive group: and (C) at least one cross-linking agent containing on average at least one isocyanate group and at least one functional group which may be activated by actinic reaction.
摘要:
Compounds which can be activated by actinic radiation, contain at least one urethane group, and have the general formula I: X[N(R)—C(O)—O—C(R1R2)—C(R3R4)—Y-Z]n (I), in which the index and the variables have the following meanings: n is an integer from 1 to 5; X is an at least n-valent, substituted or unsubstituted organic radical; R is a hydrogen atom or a monovalent substituted or unsubstituted organic radical; R1-R4 independently of one another are a hydrogen atom, halogen atom or monovalent, substituted or unsubstituted organic radical, it being possible for at least two radicals to be cyclically linked to one another; Y is a divalent, linking functional group containing at least one oxygen atom; and Z is an organic radical containing at least one group which can be activated by actinic radiation; with the proviso that at least for n=1 the radical R and/or the radical X are/is substituted by at least one substituent of the general formula II: Z—Y— (II), in which the variables Z and Y are as defined above; processes for preparing them, and their use.
摘要:
An aqueous primary dispersion curable with actinic radiation and comprising liquid and/or solid, emulsified and/or dispersed polymer particles with a z-average diameter ≦500 nm, preparable by polyaddition in a microemulsion and/or miniemulsion of at least (A) at least one polyisocyanate, (B) at least one polyol and (C) at least one compound containing at least one isocyanate-reactive functional group and at least one reactive functional group containing at least one bond which can be activated with actinic radiation; process for preparing it, and its use.
摘要:
Disclosed is an aqueous clearcoat material for producing a waterborne urethane-based two-coat coating system, comprising at least one secondary polyacrylate dispersion having a polyacrylate glass transition temperature Tg≧20° C. and at least one hybrid polyacrylate-polyurethane dispersion with a weight ratio of the polyacrylate fraction of the secondary dispersion to the polyacrylate-polyurethane fraction of the hybrid dispersion of 1:1 to 4:1, and as curing agent at least one low-viscosity aminosulfonic polyisocyanate and an aqueous basecoat material for producing a waterborne two-coat coating system comprising at least one polyurethane dispersion, at least one hybrid polyacrylate-polyurethane dispersion, and at least one melamine resin. Also disclosed are a waterborne two-coat coating system comprising the clearcoat material and the basecoat material, a process for producing it, its use to coat a substrate, and substrates coated with it.
摘要:
An oligomeric urethane acrylate composition is disclosed. The composition comprises, on average per molecule, at least two structural units of the general formula I: R{—X—CH2—CH(—CH2—O—(O)—CR1═CH2)[—O—C(O)—NH—]}n (I), where n is a number from 1 to 6, R is a monovalent to hexavalent organic radical, X is oxygen atom or —C(O)—O— radical linked by the carbon atom to the radical R, and R1 is hydrogen atom, halogen atom, nitrile group, substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, substituted or unsubstituted cycloalkyl group having 3 to 6 carbon atoms, or substituted or unsubstituted aryl group having 6 to 10 carbon atoms. Also disclosed are processes for preparing and using the compositions.
摘要:
Novel polyurethanes containing sulfide groups which comprise at least one group of the general formula I in the polymer main chain and/or at least one group of the general formula II incorporated at the chain end: —X—A—S—B—Y— (I) —X—A—S—B—YH (II) in which the variables have the following definitions: S is the sulfur atom; X and Y independently of one another are oxygen atoms, sulfur atoms or groups —NZ where Z is the hydrogen atom or an alkyl radical of 1 to 10 carbon atoms; and A and B independently of one another are divalent organic radicals; novel polymer mixtures based thereon, and the use of the novel polyurethanes and polymer mixtures and dispersions thereof for the preparation of coating materials, adhesives and sealing compounds.
摘要:
Powder coating materials prepared by (1) mixing at least two liquid components comprising in each case at least one liquid starting product in a static mixer, to give a molecularly disperse and/or finely dispersed liquid mixture, (2) emulsifying the liquid mixture (1) in an aqueous medium in a dispersing unit, to give an aqueous emulsion of liquid particals, (3) cooling the emulsion (2) so that a suspension of dimensionally stable particles is formed, (4) isolating the dimensionally stable particles from the suspension (3) or alternatively (3) isolating the dimensionally stable particles directly from the emulsion (2); and also processes for preparing them and their use as coating materials, adhesives, and sealing compounds or to prepare such compositions.
摘要:
Liquid compositions and homopolymers or copolymers of olefinically unsaturated compounds, preparable by (co)polymerizing olefinically unsaturated compounds and reactive diluents for thermally curable multisubstance mixtures as reaction medium, and their use to prepare coating compositions, adhesives and sealing compounds.
摘要:
Multicomponent coating materials, adhesives and sealing compounds comprising a (meth)acrylate (A) containing, based on (A), up to 90% by weight of hydroxyl-containing monomers in copolymerized form, of which (a1) from 20-90% by weight, based on (A), are 4-hydroxybutyl (meth)acrylate and/or 2-alkylpropane-1,3-diol mono(meth)acrylate, and (a2) from 0-40% by weight based on (A), are other hydroxyl-containing monomers; and (B) an adduct preparable from (b1) a diisocyanate, and (b2) a compound of the general formula I having an isocyanate-reactive group: wherein R1 and R2 are hydrogen or alkyl radicals, X and Y are oxygen, sulfur or >N—R6 where R6 is alkyl radical or aryl radical, R3 is alkylene radical and R4 and R5 are hydrogen, isocyanate-reactive groups or radicals R6; where R4, R5 or R6 contains an isocyanate-reactive group or R4 or R5 is an isocyanate-reactive functional group, and where R4, R5 or R6, where present, contain no isocyanate-reactive groups and the molar ratio of isocyanate groups in (b1) to the isocyanate-reactive groups in the compound I is 1.0.