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公开(公告)号：US20200299450A1
公开(公告)日：2020-09-24
申请号：US16894290
申请日：2020-06-05
Applicant: Henkel AG & Co. KGaA
Inventor： Jan-Erik Damke , Johann Klein , Rok Brisar , Esteban Mejia
Abstract: The invention relates to a silylated polyurethane obtainable by reacting: d) at least one polyol having a number average molecular weight of from 1000 to 50,000 g/mol; e) at least one polyisocyanate, preferably diisocyanate; and f) at least one tertiary hydroxyl functional alkoxysilane of the general formula (I) wherein R1 is selected from the group consisting of hydrogen and a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; R2 and R3 are same or different and are, independent from one another, selected from a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; R4 is selected from a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; R5 is selected from a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; R6 and R7 are same or different and are, independent from one another, selected from a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; and n is 1, 2 or 3, a method for preparing thereof, a curable composition comprising the thereby obtained silylated polyurethane, and its use.
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公开(公告)号：US20190100618A1
公开(公告)日：2019-04-04
申请号：US16207447
申请日：2018-12-03
Applicant: Henkel AG & Co. KGaA
Inventor： Christina Despotopoulou , Jan-Erik Damke , Markus Bonigut , Johann Klein
IPC: C08G65/336 , C08G65/08 , C08J3/24 , C09K3/10 , C09J171/02 , C09D171/02
Abstract: The invention relates to a curable composition comprising a) at least one polymer having at least one terminal group of the general formula (I) -An-R-SiXYZ (I), wherein A is a divalent bonding group containing at least one heteroatom, R is selected from divalent hydrocarbon residues having 1 to 12 carbon atoms, X, Y, Z are, independently of one another, selected from the group consisting of a hydroxyl group and C1 to C8 alkyl, C1 to C8 alkoxy, and C1 to C8 acyloxy groups, wherein X, Y, Z are substituents directly bound with the Si atom or the two of the substituents X, Y, Z form a ring together with the Si atom to which they are bound, and at least one of the substituents X, Y, Z is selected from the group consisting of a hydroxyl group, C1 to C8 alkoxy or C1 to C8 acyloxy groups, and n is 0 or 1; and b) at least one compound of the general formula (II) wherein R′ is same or different and is, independently from one another, selected from the group consisting of a hydrogen atom and hydrocarbon residues having 1 to 12 carbon atoms, and Ar is selected from aryl groups, and adhesive, sealant, or coating materials comprising the composition and use thereof.
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公开(公告)号：US10118984B2
公开(公告)日：2018-11-06
申请号：US15697499
申请日：2017-09-07
Applicant: Henkel AG & Co. KGaA
Inventor： Ralf Bätzgen , Jan-Erik Damke , David Briers , Johann Klein
Abstract: A silylated polyurethane obtainable by a process comprising the following steps: (a) reacting at least one polyol with at least one triisocyanate to form a hydroxyl-terminated polyurethane prepolymer, and (b) reacting said polyurethane prepolymer with at least one isocyanatosilane of the formula (1): OCN—R—Si—(X)m(R1)3−m, wherein m is 0, 1 or 2, each R1 is independently from each other a hydroxyl group, an alkoxy group having 1 to 10 carbon atoms, an acyloxy group having 1 to 10 carbon atoms, or —OCH(R2)COOR3, wherein R2 is hydrogen or an alkyl group having 1 to 4 carbon atoms and R3 is a straight-chain or branched alkyl group having 1 to 8 carbon atoms, each X is independently from each other and optionally substituted hydrocarbon group having 1 to 10 carbon atoms, which can be interrupted by at least one heteroatom, and R is a difunctional organic group, to endcap the hydroxyl groups on said prepolymer with said isocyanatosilane. The silylated polyurethanes are suitable for use in a preparation as an adhesive, sealant, or coating agent.
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公开(公告)号：US20170362371A1
公开(公告)日：2017-12-21
申请号：US15697499
申请日：2017-09-07
Applicant: Henkel AG & Co. KGaA
Inventor： Ralf Bätzgen , Jan-Erik Damke , David Briers , Johann Klein
CPC classification number: C08G18/10 , C08G18/227 , C08G18/4825 , C08G18/718 , C08G18/792
Abstract: A silylated polyurethane obtainable by a process comprising the following steps: (a) reacting at least one polyol with at least one triisocyanate to form a hydroxyl-terminated polyurethane prepolymer, and (b) reacting said polyurethane prepolymer with at least one isocyanatosilane of the formula (1): OCN—R—Si—(X)m(R1)3-m, wherein m is 0, 1 or 2, each R1 is independently from each other a hydroxyl group, an alkoxy group having 1 to 10 carbon atoms, an acyloxy group having 1 to 10 carbon atoms, or —OCH(R2)COOR3, wherein R2 is hydrogen or an alkyl group having 1 to 4 carbon atoms and R3 is a straight-chain or branched alkyl group having 1 to 8 carbon atoms, each X is independently from each other and optionally substituted hydrocarbon group having 1 to 10 carbon atoms, which can be interrupted by at least one heteroatom, and R is a difunctional organic group, to endcap the hydroxyl groups on said prepolymer with said isocyanatosilane. The silylated polyurethanes are suitable for use in a preparation as an adhesive, sealant, or coating agent.
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公开(公告)号：US20220363699A1
公开(公告)日：2022-11-17
申请号：US17813687
申请日：2022-07-20
Applicant: Henkel AG & Co. KGaA
Inventor： Jan-Erik Damke , Johann Klein , Rok Brisar , Esteban Mejia
IPC: C07F7/18 , C08L101/02
Abstract: Disclosed is a tertiary hydroxyl functional alkoxysilane of the general formula (I) wherein R1 is selected from the group consisting of hydrogen and a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; R2 and R3 are same or different and are, independent from one another, selected from a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; R4 is selected from a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; R5 is selected from a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; R6 and R7 are same or different and are, independent from one another, selected from a linear or branched, substituted or unsubstituted hydrocarbon residue having 1 to 20 carbon atoms; and n is 1, 2 or 3, a method for preparing thereof, and the use of the tertiary hydroxyl functional alkoxysilane of the general formula (I).
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Patent Agency Ranking
公开(公告)号：US10961393B2
公开(公告)日：2021-03-30
申请号：US16443957
申请日：2019-06-18
Applicant: Henkel AG & Co. KGaA
Inventor： Jan-Erik Damke , Christina Despotopoulou , Ralf Baetzgen , Johann Klein
IPC: C08G77/18 , C08L83/06 , C08L71/02 , C09D171/02 , C09D183/06 , C09J171/02 , C09J183/06 , C09K3/10 , C08G77/00 , C09D183/04 , C08L83/04 , C08G65/336
Abstract: The invention relates to a curable composition comprising a) at least one polymer having at least one terminal group of the general formula (I) -An-R—SiXYZ (I), wherein A is a divalent or trivalent bonding group containing at least one heteroatom, R is selected from divalent hydrocarbon residues having 1 to 12 carbon atoms, X, Y, Z are, independently of one another, selected from the group consisting of a hydroxyl group and C1 to C8 alkyl, C1 to C8 alkoxy, C1 to C8 acyloxy groups and —CH2—N—R′ wherein N is oxygen, nitrogen or sulfur, preferably oxygen, and R′ is selected from C1 to C8 alkyl groups, preferably a methyl group, wherein X, Y, Z are substituents directly bound with the Si atom or the two of the substituents X, Y, Z form a ring together with the Si atom to which they are bound, and at least one of the substituents X, Y, Z is selected from the group consisting of a hydroxyl group, C1 to C8 alkoxy or C1 to C8 acyloxy groups, and n is 0 or 1; and b) at least one compound of the general formula (II) wherein R1 is same or different and is, independently from one another, selected from the group consisting of a hydrogen atom and hydrocarbon residues having 1 to 12 carbon atoms, R2 is same or different and is, independently from one another, selected from hydrocarbon residues having 1 to 12 carbon atoms, Ar is selected from aryl groups, and n is an integer selected from 3 to 9; and adhesive, sealant, or coating materials comprising the composition and use thereof.
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17.发明申请公开(公告)号：US20210040269A1
公开(公告)日：2021-02-11
申请号：US17075482
申请日：2020-10-20
Applicant: Henkel AG & Co. KGaA
Inventor： Marta Woznicka , Swarup Ghosh , Marion Marquardt , Esteban Mejia , Udo Kragl , Christina Despotopoulou , Jan-Erik Damke , Johann Klein
Abstract: The present invention is directed to a hydroxyl-functionalized polyether-polysiloxane block copolymer of the structure A(-X—B)n wherein: A represents said polysiloxane block; B represents said polyether block; X is a linker group characterized by including the moiety Si—C—C— of which said Si is the terminal silicon atom of the polysiloxane block A; and, n is an integer of from 2 to 4, said block copolymer being further characterized by a terminal unsaturation of less than 0.04 meq/g, preferably less than 0.03 meq/g and more preferably less than 0.025 meq/g and the method for producing thereof.
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公开(公告)号：US10889682B2
公开(公告)日：2021-01-12
申请号：US16742988
申请日：2020-01-15
Applicant: Henkel AG & Co. KGaA
Inventor： Jan-Erik Damke , Johann Klein , Esteban Mejia , Rok Brisar
IPC: C08G18/28 , C08G18/10 , C08G18/24 , C08G18/48 , C08G18/75 , C09D175/04 , C09J175/04
Abstract: The present invention discloses silylated polyurethanes obtainable by reacting at least one polyols, at least one polyisocyanates, at least one silicon-containing heterocycle of the general formula (I): wherein R1 is hydrogen; R2 and R3 are same or different and are, independently from one another, selected from a linear or branched, substituted or unsubstituted C1-C20 alkyl or C6-C18 aryl residue which may be interrupted by at least one heteroatom; R4 is selected from a linear or branched, substituted or unsubstituted C1-C20 alkylene residue which may be interrupted by at least one heteroatom; R5 and R6 are same or different and are, independently from one another, selected from the group consisting of hydrogen, a linear or branched, substituted or unsubstituted C1-C20 alkyl or C6-C18 aryl which may be interrupted by at least one heteroatom, and a C4-C8 cycloalkyl, or R5 and R6 may form a ring, preferably a 4- to 8-membered alkyl ring; and n is 0, 1 or 2, their preparation methods, curable compositions comprising the silylated polyurethanes, and their use as adhesive, sealant, spray foam and/or coating.
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公开(公告)号：US20200291186A1
公开(公告)日：2020-09-17
申请号：US16890994
申请日：2020-06-02
Applicant: Henkel AG & Co. KGaA
Inventor： Andrea Gutacker , Jan-Erik Damke , Johann Klein , Esteban Mejia
Abstract: The invention relates to a curable composition comprising a) at least one polymer having at least one silicon-containing group of formula (1) —Si(R1)k(Y)3-k (1), wherein each R1 is independently selected from a hydrocarbon radical containing 1 to 20 C atoms or a triorganosiloxane group of formula —O—Si(R2)3, wherein each R2 is independently selected from a hydrocarbon radical containing 1 to 20 C atoms; each Y is independently selected from a hydroxy group or a hydrolysable group; and k is 0, 1, or 2; b) at least one mixture of paramagnetic titanium complexes, characterized by a Landé g-factor of less than 2 detected by Electron Paramagnetic Resonance Spectroscopy; c) optionally, at least one compound which has a hydrolysable silicon-containing group and a molecular weight in the range of 100 to 1000 g/mol, an aminosilane preparations containing these compositions thereof.
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公开(公告)号：US20200148708A1
公开(公告)日：2020-05-14
申请号：US16745609
申请日：2020-01-17
Applicant: Henkel AG & Co. KGaA
Inventor： Jan-Erik Damke , Johann Klein , Esteban Mejia , Rok Brisar
IPC: C07F7/18
Abstract: The present invention relates to a method for preparing silicon-containing heterocycles of the general formula (I) wherein R1 is hydrogen; R2 and R3 are same or different and are, independently from one another, selected from a linear or branched, substituted or unsubstituted C1-C20 alkyl or C6-C18 aryl residue which may be interrupted by at least one heteroatom; R4 is selected from a linear or branched C1-C20 alkylene residue which may be interrupted by at least one heteroatom; R5 and R6 are same or different and are, independently from one another, selected from the group consisting of hydrogen, a linear or branched, substituted or unsubstituted C1-C20 alkyl or C6-C18 aryl which may be interrupted by at least one heteroatom, and a C4-C8 cycloalkyl, or R5 and R6 may form a ring, a 4- to 8-membered alkyl ring; and n is 0, 1 or 2, 2, said method comprising a one-step reaction of at least one epoxide compound of the general formula (II) and at least one aminoalkoxysilane having a primary amino group in the presence of a catalyst wherein R5 and R6 are the same as defined for the general formula (I) above; as well as the use of the silicon-containing heterocycles of the general formula (I).
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