Adhesive silicone compositions
    11.
    发明授权
    Adhesive silicone compositions 失效
    粘合硅胶组合物

    公开(公告)号:US5438094A

    公开(公告)日:1995-08-01

    申请号:US266336

    申请日:1994-07-01

    摘要: An adhesive silicone composition comprising (A) an alkenyl group-containing organopolysiloxane, (B) an organohydrogen-polysiloxane having at least three hydrogen atoms each directly bonded to a silicon atom in a molecule, (C) a compound having at least one aliphatic unsaturated group and at least two phenyl skeletons in a molecule, and (D) a platinum catalyst is well adhesive to both metals and reins, and even to difficult-to-adhere resins such as nylon, polycarbonate and acryl resins.

    摘要翻译: 一种粘合性硅氧烷组合物,其包含(A)含链烯基的有机聚硅氧烷,(B)具有至少三个氢原子的有机氢 - 聚硅氧烷,每个氢原子分别直接键合到硅原子上,(C)具有至少一个脂族不饱和基团的化合物 基团和至少两个苯基骨架,以及(D)铂催化剂对金属和筘具有良好的粘合性,并且甚至难以粘附的树脂如尼龙,聚碳酸酯和丙烯酸树脂。

    Silicone composition and a highly damping hardened silicone material
    13.
    发明授权
    Silicone composition and a highly damping hardened silicone material 失效
    有机硅组合物和高阻尼硬化硅酮材料

    公开(公告)号:US5268433A

    公开(公告)日:1993-12-07

    申请号:US964265

    申请日:1992-10-21

    摘要: A silicone composition comprising, as the base component to provide crosslinking points, an organopolysiloxane copolymer comprising diorganosiloxane blocks and trifunctional arylsiloxane blocks and the molecular ends of which are terminated with alkenylsiloxy units. This base component is combined with an organohydrogenpolysiloxane and an addition reaction catalyst. This silicone composition can be hardened to produce a highly elastic and damping material which makes an ideal damping and earthquake-resistant structure.

    摘要翻译: 一种硅氧烷组合物,其包含作为提供交联点的基础组分的包含二有机硅氧烷嵌段和三官能芳基硅氧烷嵌段的有机聚硅氧烷共聚物,其分子末端用烯基甲硅烷氧基单元封端。 该基础组分与有机氢聚硅氧烷和加成反应催化剂组合。 该硅氧烷组合物可以被硬化以产生高弹性和阻尼材料,这使得理想的阻尼和抗震结构。

    Curable organopolysiloxane composition
    14.
    发明授权
    Curable organopolysiloxane composition 失效
    固化有机聚硅氧烷组合物

    公开(公告)号:US4990560A

    公开(公告)日:1991-02-05

    申请号:US394589

    申请日:1989-08-16

    摘要: A curable organopolysiloxane composition comprising a vinyl-containing organopolysiloxane, organohydrogenpolysiloxane and platinum catalyst is proposed which is cured into a gel-like material suitable as a potting and encapsulating agent for protecting, for example, electronic components from mechanical shocks and adverse influence of the ambient atmosphere. Different from conventional similar compositions, the gelled material from the inventive composition little suffers from the problem of bleeding of oily materials contained therein on the surface. This unique advantage is obtained by using, in place of the conventional vinyl-containing organopolysiloxanes in which the vinyl groups are bonded to the silicon atoms at random position in the molecular chain, a combination of two vinyl-containing organopolysiloxanes having a specified viscosity in a limited proportion, of which one has two and only two vinyl groups in a molecular each bonded to one of the silicon atoms at the molecular chain ends and the other has one and only one vinyl group in a molecule bonded to one of the silicon atoms at the molecular chain ends alone. The composition may further contain a low-viscosity dimethylpolysiloxane so that the silicone gel can be imparted with softness and adhesiveness without increasing the amount of bleeding of the oily constituents.

    摘要翻译: 提出了包含含乙烯基的有机聚硅氧烷,有机氢聚硅氧烷和铂催化剂的可固化的有机聚硅氧烷组合物,其被固化成适合作为灌封和封装剂的凝胶状材料,用于保护例如电子部件免受机械冲击和环境的不利影响 大气层。 与传统相似的组合物不同,本发明组合物的胶凝材料很少受到表面上含有的油状物质渗出的问题的困扰。 通过使用代替其中乙烯基键合到分子链中随机位置的硅原子的常规含乙烯基的有机聚硅氧烷来获得这种独特的优点,其中两个含乙烯基的有机聚硅氧烷在 有限的比例,其中一个在分子链末端具有两个且仅两个分子中的一个硅原子的乙烯基,另一个在分子中具有一个且仅一个乙烯基键合到一个硅原子上 分子链单独结束。 该组合物还可以含有低粘度的二甲基聚硅氧烷,使硅酮凝胶具有柔软性和粘合性,而不增加油性成分的渗出量。

    Curable silicone composition and cured product thereof
    15.
    发明授权
    Curable silicone composition and cured product thereof 失效
    可固化硅酮组合物及其固化产物

    公开(公告)号:US5276087A

    公开(公告)日:1994-01-04

    申请号:US824304

    申请日:1992-01-23

    摘要: A curable silicone composition which can cure using hydrosilylation, comprising an aluminum oxide powder and/or silica powder, the powders each consisting of substantially spherical particles with an average particle diameter of 50 .mu.m or below and an elongation of from 1.0 to 1.4 and being such that the respective amounts of alkali metal ions and halogen ions are extracted with 50 ml of water from 5 g of the powder at 121.degree. C. for 20 hours are not more than 10 ppm, wherein the amount of the component (D) is from 25 to 90% by weight based on the composition, and the ratio of the amount of hydrosilyl groups contained in the components (A) and (B) to the amount of alkenyl groups contained in the components (A) and (B) is in the range from 0.5/1 to 1.5/1. When the composition is used as a protective material or encapsulating material for devices such as ICs, generated heat can be dissipated efficiently and the devices are not be broken by abrasion. There are no fears of causing corrosion of the devices.

    摘要翻译: 一种可固化的硅氧烷组合物,其可以使用氢化硅烷化固化,其包含氧化铝粉末和/或二氧化硅粉末,所述粉末各自由平均粒径为50(my)m或更小的基本上球形的颗粒和1.0至1.4的伸长率组成 并且使得在121℃下从5g粉末中用50ml水萃取碱金属离子和卤素离子的相应量不超过10ppm,其中组分(D )为25〜90重量%,组分(A)和(B)中所含的氢化甲硅烷基的量与组分(A)和(B)中所含的烯基的量的比率为25至90重量% )在0.5 / 1至1.5 / 1的范围内。 当组合物用作诸如IC之类的装置的保护材料或封装材料时,可以有效地消散所产生的热量,并且不会由于磨损而破坏装置。 没有担心会导致器件腐蚀。

    Organopolysiloxane composition
    16.
    发明授权
    Organopolysiloxane composition 失效
    有机聚硅氧烷组合物

    公开(公告)号:US4886865A

    公开(公告)日:1989-12-12

    申请号:US169849

    申请日:1988-03-18

    CPC分类号: C08G77/50 C08L83/14

    摘要: The organopolysiloxane composition is useful as a potting or encapsulating material having a gel-like consistency for protecting electronic components even at an extremely low temperature as is encountered in the space industry. The composition is basically of the type in which crosslinks are formed by the addition reaction between silicon-bonded vinyl groups in an organopolysiloxane and silicon-bonded hydrogen atoms in an organohydrogenpolysiloxane but the outstanding cold resistance of the gel-like material obtained from the composition is imparted by incorporating specific silethylene-containing units of the unit formula OSiMe--CH.sub.2 CH.sub.2 --SiMe.sub.2 O.sub.0.5 into the organopolysiloxane in a specified molar content.

    摘要翻译: 有机聚硅氧烷组合物可用作具有凝胶状稠度的灌封或封装材料,即使在空间工业中遇到的极低温下也能保护电子元件。 组合物基本上是通过有机聚硅氧烷中与硅键合的乙烯基与有机氢聚硅氧烷中与硅键合的氢原子之间的加成反应形成交联的类型,但由组合物获得的凝胶状材料的出色的耐寒性为 通过将单元式OSiMe-CH 2 CH 2 -SiMe 2 O 0.5的特定的含有亚乙烯基的单元以特定的摩尔含量加入有机聚硅氧烷中。

    Vulcanizable fluorinated silicone compositions
    17.
    发明授权
    Vulcanizable fluorinated silicone compositions 失效
    可硫化的氟化硅氧烷组合物

    公开(公告)号:US4818805A

    公开(公告)日:1989-04-04

    申请号:US157939

    申请日:1988-02-19

    IPC分类号: C08L83/07 C08L83/08 C08G77/06

    CPC分类号: C08L83/08

    摘要: Curable or vulcanizable fluorinated silicone compositions which comprise a uniform mixture of predetermined amounts of an organopolysiloxane of the following average unit formula ##STR1## in which R.sup.1 represents a monovalent hydrocarbon group having from 1 to 8 carbon atoms, and a and b are, respectively, a defined value; an organohydrogenpolysiloxane having at least three SiH groups in one molecule and consisting of the several siloxane units; and a catalytic amount of a platinum compound. If necessary, another type of polysiloxane may be added to the above composition in order to further improve physical properties. The composition is rapidly vulcanized to give a cured product having stable physical properties within a short time.

    Organopolysiloxane composition for molding
    18.
    发明授权
    Organopolysiloxane composition for molding 失效
    用于成型的有机聚硅氧烷组合物

    公开(公告)号:US06780919B2

    公开(公告)日:2004-08-24

    申请号:US10020219

    申请日:2001-12-18

    IPC分类号: C08L8305

    摘要: An organopolysiloxane composition for molding purposes is provided which includes: (A) an organopolysiloxane with at least two alkenyl groups bonded to silicon atoms, (B) a straight chain organopolysiloxane with a hydrogen atom bonded to a silicon atom at both terminals, (C) an organohydrogenpolysiloxane with at least three hydrogen atoms bonded to silicon atoms within a single molecule and including a RHSiO unit and a R2XSiO1/2 unit (wherein R is an unsubstituted or a substituted monovalent hydrocarbon group with no alkenyl groups, and X represents either a hydrogen atom or a group represented by R as defined above) within the molecule, (D) a hydrosilylation reaction catalyst, and (E) finely powdered silica, wherein the total number of hydrogen atoms bonded to silicon atoms within the constituent (B) and the constituent (C) ranges from 1 to 5 per alkenyl group within the constituent (A), and the number of hydrogen atoms bonded to silicon atoms within the constituent (B) accounts for 20 to 70 mol % of the combined number of hydrogen atoms bonded to silicon atoms within the constituent (B) and the constituent (C). This composition displays superior mold releasability relative to materials such as urethane resins, epoxy resins, dicyclopentadiene resins and polyester resins, and moreover also displays superior elongation at shearing and tear strength, and can be suitably used as a highly durable mold composition.

    摘要翻译: 提供了用于成型目的的有机基聚硅氧烷组合物,其包括:(A)具有至少两个与硅原子键合的烯基的有机聚硅氧烷,(B)具有与两个末端的硅原子键合的氢原子的直链有机聚硅氧烷,(C) 具有至少三个与单个分子中的硅原子键合的氢原子的有机氢聚硅氧烷,并且包括RHSiO单元和R2XSiO1 / 2单元(其中R是未被取代的或没有烯基的取代的单价烃基,X表示氢 (D)氢化硅烷化反应催化剂和(E)二氧化硅细粉,其中与组分(B)中的硅原子键合的氢原子总数和 组分(C)在组分(A)中每个烯基的1至5个范围内,并且与组分(B)中的硅原子键合的氢原子数为2 组分(B)和组分(C)中与硅原子键合的氢原子的总数为0至70摩尔%。 该组合物相对于诸如聚氨酯树脂,环氧树脂,二环戊二烯树脂和聚酯树脂的材料显示优异的脱模性,并且还显示出优异的剪切和撕裂强度伸长率,并且可以适合用作高度耐用的模具组合物。