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111 条记录 (耗时 0.031 秒)

    Double-metal cyanide catalysts for producing polyether polyols
    11.
    发明授权
    Double-metal cyanide catalysts for producing polyether polyols 失效
    用于生产聚醚多元醇的双金属氰化物催化剂

    公开(公告)号：US06608231B1

    公开(公告)日：2003-08-19

    申请号：US09787130

    申请日：2001-03-13

    申请人： Pieter Ooms ,  Jörg Hofmann ,  Pramod Gupta

    发明人： Pieter Ooms ,  Jörg Hofmann ,  Pramod Gupta

    IPC分类号： C07C4311

    CPC分类号： C08G65/2663 ,  B01J27/26 ,  B01J31/2213 ,  B01J2231/14 ,  B01J2531/26 ,  B01J2531/845 ,  C08G65/2642

    摘要： The invention relates to novel double metal cyanide (DMC) catalysts for the preparation of polyether polyols by polyaddition of alkylene oxides to starter compounds containing active hydrogen atoms, wherein the catalyst contains a) double metal cyanide compounds, b) organic complex ligands other than c), and c) carboxylic acid ester of polyhydric alcohols. The catalysts according to the invention have greatly increased activity in the preparation of polyether polyols.

    摘要翻译： 本发明涉及用于制备聚醚多元醇的新型双金属氰化物（DMC）催化剂，其通过将环氧烷加成到含有活性氢原子的起始化合物中，其中催化剂含有a）双金属氰化物化合物，b）除c以外的有机络合物配体 ）和c）多元醇的羧酸酯。 根据本发明的催化剂在制备聚醚多元醇中的活性大大增加。

    Double metal cyanide catalysts for the preparation of polyether polyols
    12.
    发明授权
    Double metal cyanide catalysts for the preparation of polyether polyols 有权
    用于制备聚醚多元醇的双金属氰化物催化剂

    公开(公告)号：US06468939B1

    公开(公告)日：2002-10-22

    申请号：US09525882

    申请日：2000-03-15

    申请人： Pieter Ooms ,  Jörg Hofmann ,  Pramod Gupta

    发明人： Pieter Ooms ,  Jörg Hofmann ,  Pramod Gupta

    IPC分类号： B01J2726

    CPC分类号： C08G65/2663 ,  B01J31/0212 ,  B01J31/0235 ,  B01J31/0259 ,  B01J31/0261 ,  B01J31/185 ,  B01J31/1865 ,  B01J31/1875 ,  B01J31/24 ,  B01J2231/34 ,  B01J2531/26 ,  B01J2531/845

    摘要： This invention relates to new double metal cyanide (DMC) catalysts, a process for the preparation of these DMC catalysts, and to a process for the production of polyether polyols by the polyaddition of alkylene oxides to starter compounds which comprise active hydrogen atoms, wherein the catalyst comprises a) one or more double metal cyanide compounds, b) one or more organic complexing ligands, and c) one or more organic phosphates, organic phosphites, organic phosphonates, organic phosphonites, organic phosphinates or organic phosphinites. The catalysts according to the invention exhibit a considerably increased activity for polyether polyol production.

    摘要翻译： 本发明涉及新的双金属氰化物（DMC）催化剂，制备这些DMC催化剂的方法，以及通过将环氧烷烃加成到起始化合物（其包含活性氢原子）中加成聚醚多元醇的方法，其中 催化剂包括a）一种或多种双金属氰化物，b）一种或多种有机络合配体，和c）一种或多种有机磷酸盐，有机亚磷酸盐，有机膦酸盐，有机亚膦酸盐，有机次膦酸盐或有机亚磷酸盐。 根据本发明的催化剂对于聚醚多元醇的生产显示出显着提高的活性。

    Double metal cyanide catalysts for preparing poly-etherpolyols
    13.
    发明授权
    Double metal cyanide catalysts for preparing poly-etherpolyols 失效
    用于制备聚醚多元醇的双金属氰化物催化剂

    公开(公告)号：US06204357B1

    公开(公告)日：2001-03-20

    申请号：US09500840

    申请日：2000-02-10

    申请人： Pieter Ooms ,  Jörg Hofmann ,  Pramod Gupta ,  Lambertus Groenendaal

    发明人： Pieter Ooms ,  Jörg Hofmann ,  Pramod Gupta ,  Lambertus Groenendaal

    IPC分类号： C08G6500

    CPC分类号： C08G65/2663 ,  B01J27/26 ,  C08B37/0015

    摘要： The invention is directed to new double metal cyanide (DMC) catalysts, a process for the preparation of these catalysts, and to a process for the preparation of polyetherpolyols by the polyaddition of alkylene oxides to starter compounds which contain active hydrogen atoms, wherein the catalyst comprises the novel double metal cyanide (DMC) catalyst of the present invention. These new double metal cyanide (DMC) catalysts comprise a) one or more double metal cyanide compounds, b) one or more organic complex ligands, and c) one or more cyclodextrins, with the proviso that b) and c) are different compounds. The catalysts of this invention exhibit greatly increased activity during preparation of a polyetherpolyol.

    摘要翻译： 本发明涉及新的双金属氰化物（DMC）催化剂，这些催化剂的制备方法，以及通过将烯化氧加成含有活性氢原子的起始化合物来制备聚醚多元醇的方法，其中催化剂 包括本发明的新型双金属氰化物（DMC）催化剂。 这些新的双金属氰化物（DMC）催化剂包括a）一种或多种双金属氰化物化合物，b）一种或多种有机络合物配体，和c）一种或多种环糊精，条件是b）和c）是不同的化合物。 本发明的催化剂在制备聚醚多元醇过程中表现出极大的增加的活性。

    Method for preparing polyether polyols
    19.
    发明授权
    Method for preparing polyether polyols 失效
    制备聚醚多元醇的方法

    公开(公告)号：US06350920B1

    公开(公告)日：2002-02-26

    申请号：US09485507

    申请日：2000-03-20

    申请人： Hans-Josef Buysch ,  Manfred Dietrich ,  Pramod Gupta ,  Pieter Ooms

    发明人： Hans-Josef Buysch ,  Manfred Dietrich ,  Pramod Gupta ,  Pieter Ooms

    IPC分类号： C07C4311

    CPC分类号： B01J31/0202 ,  B01J31/068 ,  C08G65/2648 ,  C08G65/2651 ,  C08G65/30

    摘要： Polyether polyols can be prepared by reacting polyols with epoxides in the presence of basic catalysts, by treating the polyether polyols containing the basic catalysts with OH-functional solid compounds of metals of groups III to VIII of the periodic system of the elements (Mendeleyev), the compounds being insoluble in the polyether polyols and having BET surface areas of from 10 to 1000 m2/g, isolating the solid inorganic compounds laden with the basic catalysts from the polyether polyol and using them in the reaction of polyols with epoxides, or bringing the isolated inorganic compounds laden with the basic catalysts into contact with the polyols that are to be used in the reaction with epoxides, separating those polyols from the inorganic compounds and delivering them to the reaction with epoxides.

    摘要翻译： 聚醚多元醇可以通过在碱性催化剂的存在下使多元醇与环氧化物反应来制备，通过用含有元素（Mendeleyev）的周期体系的III-VIII族金属的OH-官能固体化合物处理含有碱性催化剂的聚醚多元醇， 所述化合物不溶于所述聚醚多元醇并具有10至1000m 2 / g的BET表面积，从所述聚醚多元醇中分离含有碱性催化剂的固体无机化合物，并将其用于多元醇与环氧化物的反应，或将 分离的无机化合物与碱性催化剂接触，与用于与环氧化物的反应中使用的多元醇接触，将这些多元醇与无机化合物分离并将其输送到与环氧化物反应。

    Zinc/metal hexacyanocobaltate complex compounds, a process for their preparation, and their use in a process for the production of polyether polyols
    20.
    发明授权
    Zinc/metal hexacyanocobaltate complex compounds, a process for their preparation, and their use in a process for the production of polyether polyols 失效
    锌/金属六氰合钴酸盐络合物，其制备方法及其在制备聚醚多元醇的方法中的用途

    公开(公告)号：US5998327A

    公开(公告)日：1999-12-07

    申请号：US114359

    申请日：1998-07-13

    申请人： Jorg Hofmann ,  Pramod Gupta ,  Harald Pielartzik ,  Pieter Ooms ,  Walter Schafer

    发明人： Jorg Hofmann ,  Pramod Gupta ,  Harald Pielartzik ,  Pieter Ooms ,  Walter Schafer

    IPC分类号： B01J31/22 ,  B01J27/16 ,  B01J27/26 ,  B01J37/04 ,  C07C41/02 ,  C07F19/00 ,  C08G65/10 ,  C08G65/26 ,  C08G65/28

    CPC分类号： B01J27/26 ,  C08G65/2663

    摘要： The invention relates to novel zinc/metal hexacyanocobaltate complex compounds corresponding to the formula:Zn.sub.3-v M.sub.v [Co(CN).sub.6 ].sub.2.w(H.sub.2 O).x(L).y[Zn(X).sub.n ].z[M(Y).sub.m)].These complex compounds are suitable catalysts. This invention also relates to a process for the production of the compounds, and to the use of the compounds in a process for the production of polyether polyols.These novel zinc/metal hexacyanocobaltate complex compounds when used as catalysts in a process for the production of polyether polyols substantially reduce the induction period of the polyaddition reaction of alkylene oxides to starter compounds containing hydrogen atoms. Furthermore, the resultant polyether polyols have a significantly narrower molecular weight distribution.

    摘要翻译： 本发明涉及对应于式Zn3-vMv [Co（CN）6] 2.w（H2O）.x（L）.y [Zn（X）n] .z [M]的新型锌/金属六氰合钴酸盐络合物 （Y）m）]。 这些络合物是合适的催化剂。 本发明还涉及一种生产该化合物的方法，以及该化合物在制备聚醚多元醇的方法中的用途。 当在制备聚醚多元醇的方法中用作催化剂时，这些新型的锌/金属六氰合钴酸盐络合物基本上降低了环氧烷烃与起始化合物含氢原子的加成反应的诱导期。 此外，所得聚醚多元醇具有明显较窄的分子量分布。