Selective aromatics disproportionation process
    11.
    发明授权
    Selective aromatics disproportionation process 失效
    选择性芳烃歧化过程

    公开(公告)号:US6114592A

    公开(公告)日:2000-09-05

    申请号:US213957

    申请日:1998-12-17

    摘要: An improved process combination is disclosed for the selective disproportionation of toluene. The combination comprises selective hydrogenation of a toluene feedstock followed by disproportionation using a zeolitic catalyst which is oil-dropped in an aluminum phosphate binder to achieve a high yield of paraxylene. Optionally, the catalyst is selectively precoked prior to toluene disproportionation. The catalyst and process provide improved selectivity for the production of paraxylene.

    摘要翻译: 公开了改进的方法组合用于甲苯的选择性歧化。 该组合包括甲苯原料的选择性氢化,然后使用沸石催化剂进行歧化,该沸石催化剂油滴在磷酸铝粘合剂中以实现高产率的对二甲苯。 任选地,在甲苯歧化之前选择性地预先催化剂。 催化剂和方法为对二甲苯的生产提供了改进的选择性。

    XYLENE PRODUCTION PROCESSES WITH INTEGRATED FEEDSTOCK TREATMENT
    13.
    发明申请
    XYLENE PRODUCTION PROCESSES WITH INTEGRATED FEEDSTOCK TREATMENT 有权
    具有集成进料处理的XYLENE生产工艺

    公开(公告)号:US20110046427A1

    公开(公告)日:2011-02-24

    申请号:US12917045

    申请日:2010-11-01

    IPC分类号: C07C15/08

    CPC分类号: C07C6/123 C07C15/08

    摘要: A process for aromatic transalkylation and olefin reduction of a feed stream is disclosed. Transalkylation conditions provide a product having increased xylene concentration and reduced olefin concentration relative to the feed. The process may be used in a xylene production facility to minimize or avoid the necessity of feedstock pretreatment such as hydrotreating, hydrogenation, or treating with clay and/or molecular sieves.

    摘要翻译: 公开了一种进料流的芳族烷基转移和烯烃还原方法。 烷基转移条件提供了相对于进料的二甲苯浓度增加和烯烃浓度降低的产物。 该方法可用于二甲苯生产设备中以最小化或避免原料预处理(如加氢处理,氢化或用粘土和/或分子筛处理)的必要性。

    Xylene production processes with integrated feedstock treatment
    14.
    发明授权
    Xylene production processes with integrated feedstock treatment 有权
    二甲苯生产工艺采用综合原料处理

    公开(公告)号:US07847137B2

    公开(公告)日:2010-12-07

    申请号:US11830424

    申请日:2007-07-30

    IPC分类号: C07C6/12 C07C5/27

    CPC分类号: C07C6/123 C07C15/08

    摘要: A process for aromatic transalkylation and olefin reduction of a feed stream is disclosed. Transalkylation conditions provide a product having increased xylene concentration and reduced olefin concentration relative to the feed. The process may be used in a xylene production facility to minimize or avoid the necessity of feedstock pretreatment such as hydrotreating, hydrogenation, or treating with clay and/or molecular sieves.

    摘要翻译: 公开了一种进料流的芳族烷基转移和烯烃还原方法。 烷基转移条件提供了相对于进料的二甲苯浓度增加和烯烃浓度降低的产物。 该方法可用于二甲苯生产设备中以最小化或避免原料预处理(如加氢处理,氢化或用粘土和/或分子筛处理)的必要性。

    Xylene Production Apparatus With Integrated Feedstock Treatment
    17.
    发明申请
    Xylene Production Apparatus With Integrated Feedstock Treatment 有权
    具有一体化原料处理的二甲苯生产设备

    公开(公告)号:US20090032386A1

    公开(公告)日:2009-02-05

    申请号:US11830460

    申请日:2007-07-30

    IPC分类号: B01D3/14

    CPC分类号: C10G29/205

    摘要: An apparatus for producing a xylene isomer, which integrates the removal of olefins into a reaction zone of the apparatus is disclosed. Apparatus of this invention enable the use of aromatic feedstocks containing olefins and reduce or eliminate the need for feed pretreatment by olefin removal assemblies or zones such as hydrotreating, hydrogenation, and clay and/or molecular sieve treating, thereby reducing capital and operating costs.

    摘要翻译: 公开了一种用于生产二甲苯异构体的装置,其将烯烃的除去整合到装置的反应区中。 本发明的装置能够使用含有烯烃的芳族原料,并减少或消除了通过烯烃去除组件或诸如加氢处理,氢化和粘土和/或分子筛处理的区域的进料预处理的需要,从而降低了资金和运行成本。

    Alumina guard bed for aromatics transalkylation process
    18.
    发明授权
    Alumina guard bed for aromatics transalkylation process 失效
    氧化铝保护床用于芳烃烷基转移工艺

    公开(公告)号:US07307034B2

    公开(公告)日:2007-12-11

    申请号:US11550823

    申请日:2006-10-19

    摘要: A transalkylation process for reacting carbon number nine aromatics with toluene to form carbon number eight aromatics such as para-xylene is herein disclosed. The process is based on the discovery that deactivating contaminants present in typical hydrocarbon feeds, such as chlorides, can be removed with an alumina guard bed prior to contacting with a transalkylation catalyst. Effective transalkylation catalysts have a solid-acid component such as mordenite, and a metal component such as rhenium. The invention is embodied in a process, a catalyst system, and an apparatus. The invention provides for longer catalyst cycle life when processing aromatics under commercial transalkylation conditions.

    摘要翻译: 本文公开了用于使碳数为9的芳族化合物与甲苯反应以形成碳数为8的芳族化合物如对二甲苯的烷基转移方法。 该方法基于以下发现:在与烷基转移催化剂接触之前,可以用氧化铝保护床除去存在于典型烃进料(例如氯化物)中的污染物。 有效的烷基转移催化剂具有固体酸组分如丝光沸石和金属组分如铼。 本发明体现在工艺,催化剂系统和装置中。 本发明提供了在商业烷基转移条件下处理芳族化合物时更长的催化剂循环寿命。

    Selective aromatics disproportionation process
    19.
    发明授权
    Selective aromatics disproportionation process 失效
    选择性芳烃歧化过程

    公开(公告)号:US06429347B1

    公开(公告)日:2002-08-06

    申请号:US09844227

    申请日:2001-04-27

    申请人: Edwin P. Boldingh

    发明人: Edwin P. Boldingh

    IPC分类号: C07C500

    摘要: An improved process is disclosed for the selective disproportionation of toluene. The process preferably uses a disproportionation catalyst comprising MFI bound with alumina phosphate. Running the process at a hydrogen to hydrocarbon ratio between 0.2 to 0.5 improves the yield of para-xylene. Optional periodic rejuvenation by increasing the hydrogen to hydrocarbon ratio removes some carbon deposits and restores catalyst activity.

    摘要翻译: 公开了用于甲苯选择性歧化的改进方法。 该方法优选使用包含与磷酸铝的结合的MFI的歧化催化剂。 以0.2至0.5的氢与烃的比例运行该方法可提高对二甲苯的产率。 通过增加氢气与烃的比例来选择性地定期复原除去一些碳沉积物并恢复催化剂活性。