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156 条记录 (耗时 0.032 秒)

    Method to alter coke morphology using metal salts of aromatic sulfonic acids and/or polysulfonic acids
    11.
    发明申请
    Method to alter coke morphology using metal salts of aromatic sulfonic acids and/or polysulfonic acids 有权
    使用芳族磺酸和/或多磺酸的金属盐改变焦炭形态的方法

    公开(公告)号：US20090184029A1

    公开(公告)日：2009-07-23

    申请号：US12010145

    申请日：2008-01-22

    申请人： Ramesh Varadaraj ,  Michael Siskin ,  Leo D. Brown ,  Cornelius H. Brons

    发明人： Ramesh Varadaraj ,  Michael Siskin ,  Leo D. Brown ,  Cornelius H. Brons

    IPC分类号： C10G9/14

    CPC分类号： C10B55/00 ,  C10B57/06

    摘要： A method for altering coke morphology in a delayed coking process of heavy oil is provided. An effective amount of oil dispersible or oil soluble metal salts of aromatic sulfonic acids and/or polysulfonic acids is added or contacted with the resid or heavy oil at a point before or after the step of heating the heavy oil to coking temperatures. The addition of additives facilitates the formation of shot coke and inhibits the formation of sponge coke.

    摘要翻译： 提供了一种在重油延迟焦化过程中改变焦炭形态的方法。 在将重油加热至焦化温度的步骤之前或之后的一点加入芳族磺酸和/或多磺酸的有效量的油分散性或油溶性金属盐与残油或重油接触。 添加添加剂促进了焦炭的形成并抑制海绵焦炭的形成。

    Chemical structural and compositional yields model for predicting hydrocarbon thermolysis products
    13.
    发明授权
    Chemical structural and compositional yields model for predicting hydrocarbon thermolysis products 有权
    用于预测碳氢化合物热解产物的化学结构和组成产量模型

    公开(公告)号：US07344889B2

    公开(公告)日：2008-03-18

    申请号：US10426356

    申请日：2003-04-30

    申请人： Simon R. Kelemen ,  Howard Freund ,  Michael Siskin ,  David J. Curry ,  Yitian Xiao ,  William N. Olmstead ,  Martin L. Gorbaty ,  A. E. Bence

    发明人： Simon R. Kelemen ,  Howard Freund ,  Michael Siskin ,  David J. Curry ,  Yitian Xiao ,  William N. Olmstead ,  Martin L. Gorbaty ,  A. E. Bence

    IPC分类号： G01N33/24

    CPC分类号： G01N33/241 ,  G01N33/2823 ,  G06F19/702 ,  G06F19/703

    摘要： A method of predicting the composition of hydrocarbon products of a complex carbonaceous material when exposed to specific time and temperature conditions is disclosed. In one embodiment, the material is characterized to obtain elemental, chemical and structural parameters. A representative chemical structure of the material is constructed based on the characterization information. The representative chemical structure is then stochastically expanded to a molecular ensemble chemical structural model that includes heteroatoms. The chemical structural model is coupled to a compositional yield model and the composition of the material products is determined using kinetic modeling. Methods are provided of constructing a chemical structural model of complex carbonaceous material, of coupling a molecular ensemble of chemical structures to a thermal chemical mechanism, of updating an ensemble of chemical structures during the kinetic modeling to reflect chemical reaction products and of eliminating molecules from the system.

    摘要翻译： 公开了当暴露于特定的时间和温度条件时预测复合碳质材料的烃产物的组成的方法。 在一个实施方案中，该材料的特征在于获得元素，化学和结构参数。 基于特征信息构建材料的代表性化学结构。 然后将代表性的化学结构随机扩展到包括杂原子的分子整体化学结构模型。 化学结构模型与组合产量模型耦合，并且使用动力学模型确定材料产物的组成。 提供了构建复杂碳质材料的化学结构模型的方法，将化学结构的分子组合耦合到热化学机制，在动力学建模期间更新化学结构的集合以反映化学反应产物并从中消除分子 系统。

    Residuum conversion process
    16.
    发明授权
    Residuum conversion process 失效
    残留转化过程

    公开(公告)号：US07033486B2

    公开(公告)日：2006-04-25

    申请号：US10368186

    申请日：2003-02-18

    申请人： Martin L. Gorbaty ,  Michael Siskin ,  Mitchell Jacobson

    发明人： Martin L. Gorbaty ,  Michael Siskin ,  Mitchell Jacobson

    IPC分类号： C10G11/14

    CPC分类号： C10G9/32 ,  C10G2300/107

    摘要： The present invention relates to a process for increasing the capacity for processing residua and obtaining higher yields of liquids having an average boiling point equal to or less than about 510° C. A residual feedstock is introduced with recycled product asphaltenes into a short vapor contact time thermal process unit wherein the vaporized product is sent to a fractionator zone to produce a 510° C.− fraction and a 510° C.+ fraction. The 510° C.+ fraction is sent to a solvent extraction zone to produce an asphaltene-rich fraction that is recycled to the short vapor contact time thermal process unit.

    摘要翻译： 本发明涉及一种增加处理残留物的能力并获得更高产量的平均沸点等于或小于约510℃的液体的方法。将残余原料与再循环产物沥青质引入短时间的蒸气接触时间 热处理单元，其中蒸发的产物被送到分馏器区域以产生510℃的馏分和510℃的+馏分。 将510℃的馏分送入溶剂萃取区，以产生富含沥青质的馏分，再循环到短蒸汽接触时间热处理装置。

    Delayed coking process for producing free-flowing coke using an overbased metal detergent additive
    17.
    发明申请
    Delayed coking process for producing free-flowing coke using an overbased metal detergent additive 审中-公开
    使用高碱性金属洗涤剂添加剂生产自由流动焦炭的延迟焦化工艺

    公开(公告)号：US20050279673A1

    公开(公告)日：2005-12-22

    申请号：US11127823

    申请日：2005-05-12

    申请人： Christopher Eppig ,  Michael Siskin ,  Daniel Leta

    发明人： Christopher Eppig ,  Michael Siskin ,  Daniel Leta

    IPC分类号： C10B55/00 ,  C10B57/06 ,  C10G9/14

    CPC分类号： C10B55/00 ,  C10B57/06 ,  C10G2300/107 ,  C10G2300/1077

    摘要： A delayed coking process for making substantially free-flowing coke, preferably shot coke. A coker feedstock, such as a vacuum residuum, is heated in a heating zone to coking temperatures then conducted to a coking zone wherein volatiles are collected overhead and coke is formed. An overbased alkaline earth metal detergent additive is added to the feedstock prior to it being heated in the heating zone, prior to its being conducted to the coking zone, or both.

    摘要翻译： 一种延迟焦化工艺，用于制造基本上自由流动的焦炭，优选喷射焦炭。 焦化原料如真空残渣在加热区被加热至焦化温度，然后进入焦化区，其中挥发物在塔顶馏出并形成焦炭。 将高碱性碱土金属洗涤剂添加剂在其被加热到加热区之前，在其被引导到焦化区之前或两者的同时，被加入到原料中。

    Direct synthesis of di-heteroatom containing cyclic organic compounds
    18.
    发明申请
    Direct synthesis of di-heteroatom containing cyclic organic compounds 审中-公开
    直接合成含二杂原子的环状有机化合物

    公开(公告)号：US20050043532A1

    公开(公告)日：2005-02-24

    申请号：US10894804

    申请日：2004-07-20

    申请人： Michael Siskin ,  Edmund Mozeleski

    发明人： Michael Siskin ,  Edmund Mozeleski

    IPC分类号： C07D295/02 ,  C07D295/027 ,  C07D319/12 ,  C07D279/12 ,  C07D265/30 ,  C07D339/02

    CPC分类号： C07D295/027 ,  C07D319/12

    摘要： The present invention provides for the simplified, direct synthesis of di-heteroatom containing cyclic organic compounds by forming an aqueous mixture of material of the formula 1 wherein X and Y are heteroatoms which may be the same or different and X is selected from the group consisting of O, S and N, and both Y's are the same and are selected from the group consisting of O, S and N, and R1 through R8 are the same or different and are selected from the group consisting of H, C1 to C10 alkyl radicals, C1 to C10 aryl radicals, C1 to C10 alkyl aryl radicals, and z is zero when X and Y are O or S, and z is 1 when X and Y are N, and water at a mole ratio of water to material of formula I in the range of about 10:1 to about 0.001:1 and heating the mixture to a temperature in the range of about 250° C. to about 350° C. under autogeneous pressure for a time of from about 0.5 to 10 hours. Trace amounts of liquid, solid or gaseous acid can be present to further accelerate dehydration, dehydrosulfurization or deamination and cyclization.

    摘要翻译： 本发明通过形成式1的材料的水性混合物来简化，直接合成含二杂原子的环状有机化合物，其中X和Y是可以相同或不同的杂原子，X选自 的O，S和N，并且两个Y都相同并且选自O，S和N，并且R 1至R 8相同或不同，并且选自由以下组成的组： H，C1至C10烷基，C1至C10芳基，C1至C10烷基芳基，当X和Y为O或S时z为零，当X和Y为N时z为1， 水与式I物质的比例在约10:1至约0.001:1的范围内，并将混合物在自压下加热至约250℃至约350℃的温度，持续一段时间 约0.5至10小时。 可以存在微量的液体，固态或气态酸，以进一步加速脱水，脱硫脱硫或脱氨和环化。

    Process for removal of heteroatoms under reducing conditions in supercritical water
    19.
    发明授权
    Process for removal of heteroatoms under reducing conditions in supercritical water 失效
    在超临界水中还原条件下去除杂原子的方法

    公开(公告)号：US5611915A

    公开(公告)日：1997-03-18

    申请号：US583692

    申请日：1996-01-05

    申请人： Michael Siskin ,  David T. Ferrughelli ,  Alan R. Katritzky ,  William N. Olmstead

    发明人： Michael Siskin ,  David T. Ferrughelli ,  Alan R. Katritzky ,  William N. Olmstead

    IPC分类号： C07B37/00 ,  C07C1/00 ,  C07C1/32 ,  C07C15/02 ,  C10G1/00 ,  C10G1/04 ,  C10G1/06

    CPC分类号： C07C1/322 ,  C07C1/323 ,  C10G1/00 ,  Y02P20/544 ,  Y10S208/952

    摘要： A process for heteroatom removal-enhancing hydrogenation of highly refractory aromatic ring structures that involves contacting a highly refractory structure having at least one aryl linkage connecting a first heteroaryl moiety and a moiety selected from the group consisting of an aryl moiety and a second heteroaryl moiety with supercritical water having a temperature of from about 400.degree. C. to about 600.degree. C. in the presence of from about 3.4 MPa to about 18.6 MPa of CO to produce lower molecular weight products having decreased aromatic and heteroatom content. The process has utility for producing more valuable lower molecular weight products having a reduced aromatic heteroatom content from starting materials that are highly refractory and widely considered to be difficult to upgrade such as coals and asphaltenes, and model compounds containing the biaryl linkages.

    摘要翻译： 使高难度芳族环结构的杂原子去除增强氢化的方法包括将具有至少一个连接第一杂芳基部分的芳基与选自芳基部分和第二杂芳基部分的部分的至少一个芳基键接触的高度耐火结构与 在约3.4MPa至约18.6MPa的CO存在下，温度为约400℃至约600℃的超临界水，以产生具有降低的芳族和杂原子含量的较低分子量产物。 该方法可用于生产具有降低的芳族杂原子含量的低价分子量产物，所述低分子量产物具有高度耐火且被广泛认为难以升级的起始材料，例如煤和沥青质，以及含有联芳基键的模型化合物。