FLEXIBLE HIGH THERMOMECHANICAL STRESS-RESISTANT AND FIREPROOF HALOGEN-FREE THERMOPLASTIC COMPOSITIONS
    11.
    发明申请
    FLEXIBLE HIGH THERMOMECHANICAL STRESS-RESISTANT AND FIREPROOF HALOGEN-FREE THERMOPLASTIC COMPOSITIONS 有权
    柔性高温耐热耐火材料和无机无卤素热塑性组合物

    公开(公告)号:US20090253836A1

    公开(公告)日:2009-10-08

    申请号:US12303174

    申请日:2007-06-01

    摘要: The present invention relates to flame-retarded flexible thermoplastic compositions of high thermomechanical strength, containing no halogen compound, comprising a graft copolymer containing polyamide blocks and composed of a polyolefin backbone and on average at least one polyamide graft, in which the grafts are attached to the backbone by the radicals of an unsaturated monomer (X) having a function capable of reacting with an amine-terminal polyamide, the radicals of the unsaturated monomer (X) being fixed to the backbone by grafting or copolymerization from its double bond, wherein said composition comprises, in a mixture: 50% to 70% by weight of the graft copolymer containing polyamide blocks, 25% to 35% by weight of a flame retardant selected from ammonium phosphates, phosphinates, pyrophosphates, and polyphosphates, approximately 2% by weight of molecular sieve, such as a zeolite, or of hydrotalcite(s). These compositions find favored application for the manufacture of electrical cables, electrical components, for molding cases in electrical engineering, or for producing protective layers or thermal protection sleeves for automotive fluid transfer lines.

    摘要翻译: 本发明涉及不含卤素化合物的具有高热机械强度的阻燃柔性热塑性组合物,其包含含有聚酰胺嵌段的接枝共聚物,由聚烯烃骨架和平均至少一个聚酰胺接枝物组成,其中移植物附着于 具有能够与胺末端聚酰胺反应的功能的不饱和单体(X)的基团的主链,不饱和单体(X)的基团通过从其双键接枝或共聚而固定在主链上,其中所述 组合物包含:含有50重量%至70重量%的含有聚酰胺嵌段的接枝共聚物,25重量%至35重量%的选自磷酸铵,次膦酸盐,焦磷酸盐和多磷酸盐的阻燃剂,约2重量% 的分子筛,如沸石,或水滑石。 这些组合物可用于制造电缆,电气部件,用于电气工程中的成型箱,或用于生产用于汽车流体输送管线的保护层或热保护套管。

    Flame-retarded thermoplastic compositions of high thermomechanical strength, in particular for electric cables
    13.
    发明授权
    Flame-retarded thermoplastic compositions of high thermomechanical strength, in particular for electric cables 有权
    具有高热机械强度的阻燃热塑性组合物,特别是电缆

    公开(公告)号:US08883899B2

    公开(公告)日:2014-11-11

    申请号:US13881491

    申请日:2011-10-18

    摘要: A flame-retarded thermoplastic composition including a graft copolymer containing polyamide blocks and composed of a polyolefin backbone and on average at least one polyamide graft, in which the grafts are attached to the backbone by the residues of an unsaturated monomer (X) having a function capable of reacting with a polyamide, the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from its double bond, wherein the composition includes: —between 60% and 70% by weight of the graft copolymer containing polyamide blocks, —between 22% and 28% by weight of poly(pentabromobenzyl acrylate), —between 4% and 8% by weight of a synergistic flame retardant chosen from antimony trioxide, derivatives of tin, of molybdenum and/or bismuth and also boron and zinc oxides, calcium borates, calcium sulphate and/or zinc stannate, between 0.5% and 5% by weight of organophilic treated clay.

    摘要翻译: 一种阻燃热塑性组合物,其包含含有聚酰胺嵌段的接枝共聚物,由聚烯烃骨架和平均至少一个聚酰胺接枝物组成,其中移植物通过具有功能的不饱和单体(X)的残基连接到主链上 能够与聚酰胺反应,不饱和单体(X)的残基通过从其双键接枝或共聚而连接到主链上,其中组合物包括:含有聚酰胺的接枝共聚物的60重量%至70重量% (聚丙烯酸五溴苄酯)的22重量%至28重量%,4重量%至8重量%的协同阻燃剂,其选自三氧化锑,锡,钼和/或铋的衍生物,以及硼 和氧化锌,硼酸钙,硫酸钙和/或锡酸锌,占亲水处理粘土的0.5重量%至5重量%。

    FLEXIBLE THERMOPLASTIC COMPOSITION WITH IMPROVED RESISTANCE TO THE EFFECT OF OILS, AND USE OF SUCH A COMPOSITION
    14.
    发明申请
    FLEXIBLE THERMOPLASTIC COMPOSITION WITH IMPROVED RESISTANCE TO THE EFFECT OF OILS, AND USE OF SUCH A COMPOSITION 有权
    具有改善耐油性的柔性热塑性组合物,以及这些组合物的使用

    公开(公告)号:US20100099817A1

    公开(公告)日:2010-04-22

    申请号:US12526097

    申请日:2008-02-06

    IPC分类号: C08L77/00 C08F287/00

    摘要: The invention relates to a flexible thermoplastic composition resistant to the ageing effects of oil, said composition comprising a grafted copolymer containing polyamide blocks and consisting of a polyolefin backbone and at least one polyamide graft. According to the invention, the grafts are attached to the core by the residues of an unsaturated monomer (X) having a function that can react with a polyamide comprising an amine end or a carboxylic acid end; the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerisation from the double bond thereof; and the composition comprises between 40 to 90 wt % of the polyolefin core comprising the unsaturated monomer (X); between 5 to 40 wt % of polyamide grafts; and between 5 to 40% of at least one polymer selected from a saponified ethylene/vinyl acetate copolymer and a polyamide.

    摘要翻译: 本发明涉及耐油性的老化作用的柔性热塑性组合物,所述组合物包含含聚酰胺嵌段的接枝共聚物,由聚烯烃骨架和至少一种聚酰胺接枝物组成。 根据本发明,移植物通过具有可与包含胺末端或羧酸端的聚酰胺反应的功能的不饱和单体(X)的残基连接到芯上; 不饱和单体(X)的残基通过从其双键接枝或共聚而连接到主链上; 并且所述组合物包含40-90重量%的包含不饱和单体(X)的聚烯烃芯; 5〜40重量%的聚酰胺接枝物; 和5至40%的至少一种选自皂化乙烯/乙酸乙烯酯共聚物和聚酰胺的聚合物。

    Flexible thermoplastic composition with improved resistance to the effect of oils, and use of such a composition
    16.
    发明授权
    Flexible thermoplastic composition with improved resistance to the effect of oils, and use of such a composition 有权
    柔性热塑性组合物具有改善的耐油性能,以及使用这种组合物

    公开(公告)号:US08227543B2

    公开(公告)日:2012-07-24

    申请号:US12526097

    申请日:2008-02-06

    IPC分类号: C08G63/48

    摘要: The invention relates to a flexible thermoplastic composition resistant to the ageing effects of oil, said composition comprising a grafted copolymer containing polyamide blocks and consisting of a polyolefin backbone and at least one polyamide graft. According to the invention, the grafts are attached to the core by the residues of an unsaturated monomer (X) having a function that can react with a polyamide comprising an amine end or a carboxylic acid end; the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from the double bond thereof; and the composition comprises between 40 to 90 wt % of the polyolefin core comprising the unsaturated monomer (X); between 5 to 40 wt % of polyamide grafts; and between 5 to 40% of at least one polymer selected from a saponified ethylene/vinyl acetate copolymer and a polyamide.

    摘要翻译: 本发明涉及耐油性的老化作用的柔性热塑性组合物,所述组合物包含含聚酰胺嵌段的接枝共聚物,由聚烯烃骨架和至少一种聚酰胺接枝物组成。 根据本发明,移植物通过具有可与包含胺末端或羧酸端的聚酰胺反应的功能的不饱和单体(X)的残基连接到芯上; 不饱和单体(X)的残基通过从其双键接枝或共聚而连接到主链上; 并且所述组合物包含40-90重量%的包含不饱和单体(X)的聚烯烃芯; 5〜40重量%的聚酰胺接枝物; 和5至40%的至少一种选自皂化乙烯/乙酸乙烯酯共聚物和聚酰胺的聚合物。

    Storage stable compositions for obtaining elastomer coatings
    17.
    发明授权
    Storage stable compositions for obtaining elastomer coatings 失效
    用于获得弹性体涂层的储存稳定的组合物

    公开(公告)号:US06387976B1

    公开(公告)日:2002-05-14

    申请号:US09445479

    申请日:1999-05-11

    申请人: Jean-Jacques Flat

    发明人: Jean-Jacques Flat

    IPC分类号: C08F250

    摘要: Compositions, which are stable on storage, which make it possible to obtain elastomer coatings. The compositions are obtained from a hydroxylated urethane prepolymer and from a mixture of acrylate monomer and oligomers, capable of giving an elastomer by thermal or photochemical radical polymerization; the urethane prepolymer being obtained by condensation of a conjugated diene oligomer comprising hydroxylated endings, optionally mixed with a chain extender, with a polyisocyanate compound. These compositions can be used in the protection of electrical and/or electronic components and generally as coatings for metal surfaces or for plastic surfaces.

    摘要翻译: 组合物在储存时稳定,可以获得弹性体涂层。 该组合物由羟基化氨基甲酸酯预聚物和丙烯酸酯单体和低聚物的混合物获得,能够通过热或光化学自由基聚合提供弹性体; 氨基甲酸酯预聚物通过包含羟基化末端的任选与扩链剂混合的共轭二烯低聚物与多异氰酸酯化合物缩合而获得。 这些组合物可用于保护电气和/或电子部件,通常用作金属表面或塑料表面的涂层。

    Halogen-free, fireproof, transparent thermoplastic compositions having high thermomechanical strength, in particular for encapsulation in photovoltaic modules
    19.
    发明授权
    Halogen-free, fireproof, transparent thermoplastic compositions having high thermomechanical strength, in particular for encapsulation in photovoltaic modules 有权
    具有高热机械强度的无卤素,防火,透明的热塑性组合物,特别用于光伏模块中的封装

    公开(公告)号:US09331215B2

    公开(公告)日:2016-05-03

    申请号:US13879959

    申请日:2011-10-18

    摘要: A transparent, fireproof thermoplastic composition which is free from halogen compounds and includes a polyamide-block graft copolymer formed by a polyolefin backbone and, on average, at least one polyamide graft. The grafts are attached to the backbone by the radicals of an unsaturated monomer (X) that has a function capable of reacting with a polyamide, and the radicals of the unsaturated monomer (X) are attached to the backbone by grafting or co-polymerisation from the double bond thereof. The composition includes, as a weight percentage of the total composition: 90 to 99 wt % of the polyamide-block graft copolymer, and 1 to 10 wt % of metal salts of phosphoric acid.

    摘要翻译: 一种不含卤素化合物的透明耐火热塑性组合物,包括由聚烯烃骨架和平均至少一种聚酰胺接枝物形成的聚酰胺嵌段接枝共聚物。 移植物通过具有能够与聚酰胺反应的功能的不饱和单体(X)的基团连接到主链上,并且不饱和单体(X)的基团通过接枝或共聚从 其双键。 该组合物包含总组合物的重量百分数:聚酰胺 - 嵌段共聚物的90-99重量%和磷酸金属盐的1-10重量%。

    FLAME-RETARDED THERMOPLASTIC COMPOSITIONS OF HIGH THERMOMECHANICAL STRENGTH, IN PARTICULAR FOR ELECTRIC CABLES
    20.
    发明申请
    FLAME-RETARDED THERMOPLASTIC COMPOSITIONS OF HIGH THERMOMECHANICAL STRENGTH, IN PARTICULAR FOR ELECTRIC CABLES 有权
    高温度机械强度的阻燃热塑性组合物,特别是电缆

    公开(公告)号:US20130261244A1

    公开(公告)日:2013-10-03

    申请号:US13881491

    申请日:2011-10-18

    IPC分类号: H01B3/44 F16L57/04

    摘要: A flame-retarded thermoplastic composition including a graft copolymer containing polyamide blocks and composed of a polyolefin backbone and on average at least one polyamide graft, in which the grafts are attached to the backbone by the residues of an unsaturated monomer (X) having a function capable of reacting with a polyamide, the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from its double bond, wherein the composition includes: —between 60% and 70% by weight of the graft copolymer containing polyamide blocks, —between 22% and 28% by weight of poly(pentabromobenzyl acrylate), —between 4% and 8% by weight of a synergistic flame retardant chosen from antimony trioxide, derivatives of tin, of molybdenum and/or bismuth and also boron and zinc oxides, calcium borates, calcium sulphate and/or zinc stannate, between 0.5% and 5% by weight of organophilic treated clay.

    摘要翻译: 一种阻燃热塑性组合物,其包含含有聚酰胺嵌段的接枝共聚物,由聚烯烃骨架和平均至少一个聚酰胺接枝物组成,其中移植物通过具有功能的不饱和单体(X)的残基连接到主链上 能够与聚酰胺反应,不饱和单体(X)的残基通过从其双键接枝或共聚而连接到主链上,其中组合物包括:含有聚酰胺的接枝共聚物的60重量%至70重量% (聚丙烯酸五溴苄酯)的22重量%至28重量%,4重量%至8重量%的协同阻燃剂,其选自三氧化锑,锡,钼和/或铋的衍生物,以及硼 和氧化锌,硼酸钙,硫酸钙和/或锡酸锌,占亲水处理粘土的0.5重量%至5重量%。