摘要:
The present invention relates to flame-retarded flexible thermoplastic compositions of high thermomechanical strength, containing no halogen compound, comprising a graft copolymer containing polyamide blocks and composed of a polyolefin backbone and on average at least one polyamide graft, in which the grafts are attached to the backbone by the radicals of an unsaturated monomer (X) having a function capable of reacting with an amine-terminal polyamide, the radicals of the unsaturated monomer (X) being fixed to the backbone by grafting or copolymerization from its double bond, wherein said composition comprises, in a mixture: 50% to 70% by weight of the graft copolymer containing polyamide blocks, 25% to 35% by weight of a flame retardant selected from ammonium phosphates, phosphinates, pyrophosphates, and polyphosphates, approximately 2% by weight of molecular sieve, such as a zeolite, or of hydrotalcite(s). These compositions find favored application for the manufacture of electrical cables, electrical components, for molding cases in electrical engineering, or for producing protective layers or thermal protection sleeves for automotive fluid transfer lines.
摘要:
The invention relates to compositions containing a polyamide matrix (A) and a polyolefin dispersed phase (B), in which compositions the polyamide has a melting point below that of PA-6 and the dispersed phase consists of at least one polyolefin (B) chosen from functionalized polyolefins (B1) and non-functionalized polyolefins (B2). Advantageously, (A) is PA-6/12 or PA-6/6,6. These compositions are useful for making monolayer or multilayer films by extrusion with EVA or PE.
摘要:
A flame-retarded thermoplastic composition including a graft copolymer containing polyamide blocks and composed of a polyolefin backbone and on average at least one polyamide graft, in which the grafts are attached to the backbone by the residues of an unsaturated monomer (X) having a function capable of reacting with a polyamide, the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from its double bond, wherein the composition includes: —between 60% and 70% by weight of the graft copolymer containing polyamide blocks, —between 22% and 28% by weight of poly(pentabromobenzyl acrylate), —between 4% and 8% by weight of a synergistic flame retardant chosen from antimony trioxide, derivatives of tin, of molybdenum and/or bismuth and also boron and zinc oxides, calcium borates, calcium sulphate and/or zinc stannate, between 0.5% and 5% by weight of organophilic treated clay.
摘要:
The invention relates to a flexible thermoplastic composition resistant to the ageing effects of oil, said composition comprising a grafted copolymer containing polyamide blocks and consisting of a polyolefin backbone and at least one polyamide graft. According to the invention, the grafts are attached to the core by the residues of an unsaturated monomer (X) having a function that can react with a polyamide comprising an amine end or a carboxylic acid end; the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerisation from the double bond thereof; and the composition comprises between 40 to 90 wt % of the polyolefin core comprising the unsaturated monomer (X); between 5 to 40 wt % of polyamide grafts; and between 5 to 40% of at least one polymer selected from a saponified ethylene/vinyl acetate copolymer and a polyamide.
摘要:
The invention relates to a method for converting a polycondensed elastomeric thermoplastic polymer, including a step of extruding the polycondensed elastomeric thermoplastic polymer in the presence of water. The polycondensed elastomeric thermoplastic polymer is in particular chosen from copolymer block amides, copolyethers or copolyester block urethanes, copolyether block esters and the mixtures thereof, and is preferably a copolyether block amide.
摘要:
The invention relates to a flexible thermoplastic composition resistant to the ageing effects of oil, said composition comprising a grafted copolymer containing polyamide blocks and consisting of a polyolefin backbone and at least one polyamide graft. According to the invention, the grafts are attached to the core by the residues of an unsaturated monomer (X) having a function that can react with a polyamide comprising an amine end or a carboxylic acid end; the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from the double bond thereof; and the composition comprises between 40 to 90 wt % of the polyolefin core comprising the unsaturated monomer (X); between 5 to 40 wt % of polyamide grafts; and between 5 to 40% of at least one polymer selected from a saponified ethylene/vinyl acetate copolymer and a polyamide.
摘要:
Compositions, which are stable on storage, which make it possible to obtain elastomer coatings. The compositions are obtained from a hydroxylated urethane prepolymer and from a mixture of acrylate monomer and oligomers, capable of giving an elastomer by thermal or photochemical radical polymerization; the urethane prepolymer being obtained by condensation of a conjugated diene oligomer comprising hydroxylated endings, optionally mixed with a chain extender, with a polyisocyanate compound. These compositions can be used in the protection of electrical and/or electronic components and generally as coatings for metal surfaces or for plastic surfaces.
摘要:
The invention relates to a polyol-based plasticized composition which includes a sufficient quantity of a thickening additive to obtain a viscosity at 20.degree. C. of at least 4 Pa.cndot.s. This plasticized composition can be employed for obtaining a polyurethane gel.
摘要:
A transparent, fireproof thermoplastic composition which is free from halogen compounds and includes a polyamide-block graft copolymer formed by a polyolefin backbone and, on average, at least one polyamide graft. The grafts are attached to the backbone by the radicals of an unsaturated monomer (X) that has a function capable of reacting with a polyamide, and the radicals of the unsaturated monomer (X) are attached to the backbone by grafting or co-polymerisation from the double bond thereof. The composition includes, as a weight percentage of the total composition: 90 to 99 wt % of the polyamide-block graft copolymer, and 1 to 10 wt % of metal salts of phosphoric acid.
摘要:
A flame-retarded thermoplastic composition including a graft copolymer containing polyamide blocks and composed of a polyolefin backbone and on average at least one polyamide graft, in which the grafts are attached to the backbone by the residues of an unsaturated monomer (X) having a function capable of reacting with a polyamide, the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from its double bond, wherein the composition includes: —between 60% and 70% by weight of the graft copolymer containing polyamide blocks, —between 22% and 28% by weight of poly(pentabromobenzyl acrylate), —between 4% and 8% by weight of a synergistic flame retardant chosen from antimony trioxide, derivatives of tin, of molybdenum and/or bismuth and also boron and zinc oxides, calcium borates, calcium sulphate and/or zinc stannate, between 0.5% and 5% by weight of organophilic treated clay.