公开(公告)号：US08883899B2

公开(公告)日：2014-11-11

申请号：US13881491

申请日：2011-10-18

Applicant: Dominique Jousset ,  Jean-Jacques Flat ,  Pierre Georlette

Inventor： Dominique Jousset ,  Jean-Jacques Flat ,  Pierre Georlette

IPC: H01B3/44 ,  F16L57/04 ,  C08L53/00 ,  C08G81/02 ,  C08L87/00 ,  C08L33/16

CPC classification number: H01B3/447 ,  C08G81/028 ,  C08L33/16 ,  C08L53/00 ,  C08L87/005 ,  F16L57/04

Abstract: A flame-retarded thermoplastic composition including a graft copolymer containing polyamide blocks and composed of a polyolefin backbone and on average at least one polyamide graft, in which the grafts are attached to the backbone by the residues of an unsaturated monomer (X) having a function capable of reacting with a polyamide, the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from its double bond, wherein the composition includes: —between 60% and 70% by weight of the graft copolymer containing polyamide blocks, —between 22% and 28% by weight of poly(pentabromobenzyl acrylate), —between 4% and 8% by weight of a synergistic flame retardant chosen from antimony trioxide, derivatives of tin, of molybdenum and/or bismuth and also boron and zinc oxides, calcium borates, calcium sulphate and/or zinc stannate, between 0.5% and 5% by weight of organophilic treated clay.

Abstract translation: 一种阻燃热塑性组合物，其包含含有聚酰胺嵌段的接枝共聚物，由聚烯烃骨架和平均至少一个聚酰胺接枝物组成，其中移植物通过具有功能的不饱和单体（X）的残基连接到主链上 能够与聚酰胺反应，不饱和单体（X）的残基通过从其双键接枝或共聚而连接到主链上，其中组合物包括：含有聚酰胺的接枝共聚物的60重量％至70重量％ （聚丙烯酸五溴苄酯）的22重量％至28重量％，4重量％至8重量％的协同阻燃剂，其选自三氧化锑，锡，钼和/或铋的衍生物，以及硼 和氧化锌，硼酸钙，硫酸钙和/或锡酸锌，占亲水处理粘土的0.5重量％至5重量％。

公开(公告)号：US08841542B2

公开(公告)日：2014-09-23

申请号：US13500648

申请日：2010-10-07

Applicant: Pierre Gerard ,  Stephane Bizet ,  Dominique Jousset

Inventor： Pierre Gerard ,  Stephane Bizet ,  Dominique Jousset

IPC: H01L31/048 ,  C08F293/00 ,  C08L53/00 ,  B32B17/10

CPC classification number: C08L53/00 ,  B32B17/10743 ,  C08F293/005 ,  H01L31/048 ,  H01L31/0481 ,  Y02E10/50

Abstract: The present invention relates to a photovoltaic module comprising as an encapsulant a composition comprising at least one polyacrylate- or polymethacrylate-type block copolymer with the general formula B-(A)n, n being a natural integer no lower than one, preferably 1 to 8, the block A being selected from among methacrylates having a Tg higher than 0° C., the block B being a polyacrylate or a polymethacrylate having a Tg lower than 0° C., the block B being at least 50 wt % of the total weight of the block copolymer.

Abstract translation: 本发明涉及一种光伏组件，其包含作为密封剂的组合物，该组合物包含至少一种具有通式B-（A）n的聚丙烯酸酯或聚甲基丙烯酸酯型嵌段共聚物，n为不低于1的自然整数，优选1至 如图8所示，嵌段A选自Tg高于0℃的甲基丙烯酸酯，嵌段B为Tg低于0℃的聚丙烯酸酯或聚甲基丙烯酸酯，嵌段B为至少50重量％ 嵌段共聚物的总重量。

公开(公告)号：US08779060B2

公开(公告)日：2014-07-15

申请号：US12667265

申请日：2008-07-01

Applicant: Marius Hert ,  Dominique Jousset

Inventor： Marius Hert ,  Dominique Jousset

IPC: C08L23/08 ,  C08L23/10 ,  C08L77/00 ,  C08F255/00 ,  C08L51/06 ,  C08F255/02 ,  C09D151/06 ,  C08L23/06 ,  C08L53/00 ,  C08L23/16 ,  C08L23/12 ,  C09J151/06 ,  C08L23/22 ,  C08L23/36

CPC classification number: C08L51/06 ,  C08F255/00 ,  C08F255/02 ,  C08F255/026 ,  C08L23/06 ,  C08L23/0853 ,  C08L23/0869 ,  C08L23/10 ,  C08L23/12 ,  C08L23/16 ,  C08L23/22 ,  C08L23/36 ,  C08L53/00 ,  C08L2205/03 ,  C08L2666/02 ,  C09D151/06 ,  C09J151/06 ,  C08L2666/24 ,  C08L2666/06

Abstract: The mixture of the invention contains, for 100 parts in weight of (A)+(B): (A) 10 to 90 parts in weight of at least one non-nanostructured olefinic thermoplastic polymer; (B) 90 to 10 parts in weight of a formulation of at least one elastomer having unsaturated double bonds and capable of reacting with a cross-linking or vulcanization agent, said formulation containing a crosslinking or vulcanization system of said elastomer(s), at least one plasticizer, and the standard additives present in elastomer formulations; (C) up to 100 parts in weight, relative to (A)+(B), of at least one copolymer grafted with polyamide blocks, said copolymer comprising a polyolefin trunk and at least 1.3 polyamide grafts on said trunk in average, and having a nanostructured organization, wherein said grafts are attached to the trunk by the rest of an unsaturated monomer (X) having a function capable of reacting with a polyamide with an amine end; and rest of said unsaturated monomer (X) being attached on the trunk by grafting or copolymerization from its double bond thereof, and wherein (A) and (B) in the mixture can already have been combined together by the crosslinking or vulcanization dynamic method in order to provide a crosslinked or vulcanized thermoplastic composition.

Abstract translation: 对于100重量份的（A）+（B）：（A）10重量份的至少一种非纳米结构的烯属热塑性聚合物，本发明的混合物包含： （B）90至10份重量的至少一种具有不饱和双键且能够与交联或硫化剂反应的弹性体的制剂，所述制剂含有所述弹性体的交联或硫化体系， 至少一种增塑剂和弹性体配方中存在的标准添加剂; （C）至少一种接枝有聚酰胺嵌段共聚物的（A）+（B）至多100重量份，所述共聚物平均包含聚烯烃树干和至少1.3个聚酰胺接枝物，并且具有 纳米结构组织，其中所述移植物通过剩余的具有能够与聚酰胺与胺末端反应的功能的不饱和单体（X）连接到树干上; 并且其余所述不饱和单体（X）通过其双键接枝或共聚而附着在树干上，并且其中混合物中的（A）和（B）可以已经通过交联或硫化动力学方法组合在一起 以提供交联或硫化的热塑性组合物。

公开(公告)号：US20130247983A1

公开(公告)日：2013-09-26

申请号：US13879959

申请日：2011-10-18

Applicant: Dominique Jousset ,  Jean-Jacques Flat ,  Pierre Georlette

Inventor： Dominique Jousset ,  Jean-Jacques Flat ,  Pierre Georlette

IPC: H01L31/0203

CPC classification number: H01L31/0203 ,  C08G81/028 ,  C09K21/12 ,  H01L31/0481 ,  Y02E10/50

Abstract: A transparent, fireproof thermoplastic composition which is free from halogen compounds and includes a polyamide-block graft copolymer formed by a polyolefin backbone and, on average, at least one polyamide graft. The grafts are attached to the backbone by the radicals of an unsaturated monomer (X) that has a function capable of reacting with a polyamide, and the radicals of the unsaturated monomer (X) are attached to the backbone by grafting or co-polymerisation from the double bond thereof. The composition includes, as a weight percentage of the total composition: 90 to 99 wt % of the polyamide-block graft copolymer, and 1 to 10 wt % of metal salts of phosphoric acid.

Abstract translation: 一种不含卤素化合物的透明耐火热塑性组合物，包括由聚烯烃主链和平均至少一个聚酰胺接枝物形成的聚酰胺嵌段接枝共聚物。 移植物通过具有能够与聚酰胺反应的功能的不饱和单体（X）的基团连接到主链上，并且不饱和单体（X）的基团通过接枝或共聚从 其双键。 该组合物包含总组合物的重量百分数：聚酰胺 - 嵌段共聚物的90-99重量％和磷酸金属盐的1-10重量％。

公开(公告)号：US20100256276A1

公开(公告)日：2010-10-07

申请号：US12667259

申请日：2008-07-01

Applicant: Marius Hert ,  Dominique Jousset

Inventor： Marius Hert ,  Dominique Jousset

IPC: C08K5/12 ,  C08L51/00 ,  C08K5/01 ,  C08K3/22 ,  C08K3/34 ,  C08K5/101

CPC classification number: C08F255/02 ,  C08F255/00 ,  C08L51/06 ,  C08L2666/04 ,  C08L2666/02

Abstract: The mixture of the invention contains, for 100 parts by weight: (A) 10 to 90 parts in weight of at least one copolymer grafted to polyamide blocks, said copolymer comprising a polyolefin trunk and at least 1.3 polyamide grafts on said trunk in average, and having a nanostructured organization, wherein said grafts are attached to the trunk by the rest of an unsaturated monomer (X) having a function capable of reacting with a polyamide with an amine end; the rest of said monomer (X) being attached on the trunk by grafting or copolymerization from its double bond thereof, (A) optionally including at least one non-grafted polyolefin in a proportion such that the nano-structured organization of the compound (A) is preserved; and (B) 90 to 10 parts in weight of a formulation of at least one elastomer having unsaturated double bonds and capable of reacting with a cross-linking or vulcanization agent, said formulation containing a crosslinking or vulcanization system of said elastomer(s), at least one plasticizer and the standard additives present in elastomer formulations.

Abstract translation: 对于100重量份，本发明的混合物包含：（A）10至90重量份的至少一种接枝到聚酰胺嵌段的共聚物，所述共聚物平均包含聚烯烃树干和所述树干上至少1.3个聚酰胺接枝物， 并且具有纳米结构组织，其中所述移植物通过剩余的具有能够与聚酰胺与胺末端反应的功能的不饱和单体（X）连接到树干上; 所述单体（X）的其余部分通过从其双键接枝或共聚而附着在树干上，（A）任选地包括至少一种非接枝聚烯烃，使得化合物（A ）保存; 和（B）90至10重量份的至少一种具有不饱和双键且能与交联或硫化剂反应的弹性体的制剂，所述制剂含有所述弹性体的交联或硫化体系， 至少一种增塑剂和弹性体配方中存在的标准添加剂。

公开(公告)号：US20120298195A1

公开(公告)日：2012-11-29

申请号：US13522054

申请日：2011-01-07

Applicant: Dominique Plee ,  Dominique Jousset ,  Francois Beaume ,  Anthony Bonnet

Inventor： Dominique Plee ,  Dominique Jousset ,  Francois Beaume ,  Anthony Bonnet

IPC: H01L31/02 ,  B32B27/08 ,  B32B27/20

CPC classification number: H01L51/448 ,  H01L31/0481 ,  H01L51/5253 ,  Y02E10/549 ,  Y10T428/24975 ,  Y10T428/256

Abstract: The invention relates to a multilayer structure that includes: a layer of a composition including a fluorinated polymer and a zinc oxide (ZnO), said ZnO being present in said composition in the form of particles having a weight proportion of less than 1%, said ZnO particles having a size between 10 to 100 nm, and an adhesion promoter present in the body and/or surface of said layer; and at least one oxide layer (MOx) selected from among silicon oxide and aluminum oxide, and having a thickness of from 20 to 200 nm. Aid structure has excellent properties of transparency within the visible range, excellent properties of opacity to UV rays, as well as good mechanical resistance and aging resistance while having excellent moisture barrier properties. Said structure can thus be advantageously used in the front surface of photovoltaic panels or fro protecting organic light-emitting diodes.

Abstract translation: 本发明涉及一种多层结构，其包括：包含氟化聚合物和氧化锌（ZnO）的组合物层，所述ZnO在所述组合物中以重量比例小于1％的颗粒形式存在，所述 尺寸在10至100nm之间的ZnO颗粒和存在于所述层的主体和/或表面中的粘合促进剂; 和选自氧化硅和氧化铝中的至少一种氧化物层（MOx），其厚度为20〜200nm。 辅助结构在可见光范围内具有优异的透明性，优异的紫外线不透明性以及良好的机械阻力和耐老化性，同时具有优异的防潮性能。 因此，所述结构可有利地用于光伏面板的前表面或保护有机发光二极管。

公开(公告)号：US08236412B2

公开(公告)日：2012-08-07

申请号：US12990030

申请日：2009-04-27

Applicant: Dominique Jousset ,  Stephane Bizet ,  Laurent B. Cartier

Inventor： Dominique Jousset ,  Stephane Bizet ,  Laurent B. Cartier

IPC: C08L77/00 ,  C08G61/00 ,  B29C45/00 ,  B29C51/36

CPC classification number: H01L31/0504 ,  B32B3/08 ,  B32B7/12 ,  B32B15/08 ,  B32B27/08 ,  B32B27/18 ,  B32B27/22 ,  B32B27/28 ,  B32B27/304 ,  B32B27/306 ,  B32B27/308 ,  B32B27/32 ,  B32B27/322 ,  B32B27/34 ,  B32B27/36 ,  B32B2307/30 ,  B32B2307/40 ,  B32B2307/412 ,  B32B2307/50 ,  B32B2307/554 ,  B32B2307/7242 ,  B32B2307/7244 ,  B32B2307/7246 ,  B32B2307/7265 ,  B32B2457/12 ,  C08G81/028 ,  H01L31/0481 ,  Y02E10/50 ,  Y10T428/31623 ,  Y10T428/31681 ,  Y10T428/31725

Abstract: The present invention relates to a thermoplastic composition including a polyamide graft polymer including a polyolefin backbone containing a residue of at least one unsaturated monomer having reacted with at least one polyamide graft. The invention also relates to structures, particularly multilayer structures, including said composition. One of the preferred structures of the present invention is a photovoltaic module including said composition. The composition according to the invention can advantageously be used as a binder or encapsulant. It is also used in solar panels and laminated glass.

Abstract translation: 本发明涉及包含聚酰胺接枝聚合物的热塑性组合物，该聚酰胺接枝聚合物包括聚烯烃主链，其含有至少一种与至少一种聚酰胺接枝物反应的不饱和单体的残基。 本发明还涉及包括所述组合物的结构，特别是多层结构。 本发明的优选结构之一是包括所述组合物的光伏组件。 根据本发明的组合物可有利地用作粘合剂或密封剂。 它也用于太阳能电池板和夹层玻璃。

公开(公告)号：US20140026960A1

公开(公告)日：2014-01-30

申请号：US13984468

申请日：2012-01-12

Applicant: Stéphane Bizet ,  Samuel Devisme ,  Thomas Fine ,  Dominique Jousset

Inventor： Stéphane Bizet ,  Samuel Devisme ,  Thomas Fine ,  Dominique Jousset

IPC: H01L31/048

CPC classification number: H01L31/0481 ,  B32B27/08 ,  B32B27/32 ,  B32B2457/12 ,  C08G81/028 ,  Y02E10/50 ,  Y10T428/31928

Abstract: An encapsulant for a photovoltaic module, intended to coat a photovoltaic cell, including at least two adjacent thermoplastic layers together forming a core-skin assembly: the skin layer is a polyamide graft polymer including a polyolefin backbone representing 50 wt % to 95 wt % of the polyamide graft polymer, containing a residue of at least one unsaturated monomer (X) and at least one polyamide graft, representing 5 wt % to 50 wt % of said polyamide graft polymer; the polyolefin backbone and the polyamide graft of the skin layer are chosen so that the polyamide graft polymer has a flow temperature greater than or equal to 75° C. and less than or equal to 160° C., this flow temperature being defined as the highest temperature out of the melting temperature and the glass transition temperature of the polyamide graft and of the polyolefin backbone.

Abstract translation: 一种用于光伏组件的密封剂，其旨在将包括至少两个相邻的热塑性层的光伏电池包覆在一起形成芯 - 皮组件：表层是聚酰胺接枝聚合物，其包含聚烯烃主链，占50重量％至95重量％ 所述聚酰胺接枝聚合物含有至少一种不饱和单体（X）的残余物和至少一种聚酰胺接枝物，占所述聚酰胺接枝聚合物的5重量％至50重量％ 选择表面层的聚烯烃骨架和聚酰胺接枝物，使得聚酰胺接枝聚合物的流动温度大于或等于75℃且小于或等于160℃，该流动温度定义为 聚酰胺接枝物和聚烯烃主链的熔融温度和玻璃化转变温度以外的最高温度。

公开(公告)号：US20140000707A1

公开(公告)日：2014-01-02

申请号：US13984549

申请日：2012-01-12

Applicant: Stephane Bizet ,  Samuel Devisme ,  Thomas Fine ,  Dominique Jousset ,  Gregory O'Brien ,  Amy Lefebvre

Inventor： Stephane Bizet ,  Samuel Devisme ,  Thomas Fine ,  Dominique Jousset ,  Gregory O'Brien ,  Amy Lefebvre

IPC: H01L31/0203

CPC classification number: H01L31/0203 ,  B32B27/08 ,  B32B27/32 ,  B32B2250/02 ,  B32B2250/24 ,  B32B2457/12 ,  C08G81/028 ,  H01L31/0481 ,  H01L31/049 ,  Y02E10/50 ,  Y10T428/3154 ,  Y10T428/31728

Abstract: A double-layer thermoplastic film of a photovoltaic module, including two layers, one forms the encapsulator and the other forms the backsheet, wherein: a) the encapsulator is a layer including at least one polyolefin containing a polyethylene selected from a homopolymer of ethylene or a copolymer comprising at least 50 mol % of ethylene and at least one comonomer and between 0% and 100% of a polyamide grafted polymer comprising a polyolefin trunk that represents between 50 mass % and 95 mass % of the polyamide grafted polymer containing a radical of at least one unsaturated monomer (X) and at least one polyamide graft that represents between 5 mass % and 50 mass % of said polyamide grafted polymer; and b) the backsheet comprises a layer formed from a polyamide grafted polymer that is identical to that of the encapsulator except that it has a flow temperature higher than 160° C.

Abstract translation: 包括两层的光伏模块的双层热塑性膜形成封装体，另一层形成底片，其中：a）封装剂是包含至少一种含有聚乙烯的层，所述聚烯烃选自乙烯的均聚物或 包含至少50摩尔％乙烯和至少一种共聚单体和0％至100％的聚酰胺接枝聚合物的共聚物，所述聚酰胺接枝聚合物包含聚烯烃树脂，所述聚烯烃树脂占聚合物接枝聚合物的50质量％至95质量％ 至少一种不饱和单体（X）和至少一种代表所述聚酰胺接枝聚合物的5质量％至50质量％的聚酰胺接枝物; 和b）底片包括由与聚合物接枝的聚合物形成的层，其与除了具有高于160℃的流动温度之外的封装剂相同。

公开(公告)号：US20120260975A1

公开(公告)日：2012-10-18

申请号：US13500648

申请日：2010-10-07

Applicant: Pierre Gerard ,  Stephane Bizet ,  Dominique Jousset

Inventor： Pierre Gerard ,  Stephane Bizet ,  Dominique Jousset

IPC: H01L31/048

CPC classification number: C08L53/00 ,  B32B17/10743 ,  C08F293/005 ,  H01L31/048 ,  H01L31/0481 ,  Y02E10/50

Abstract: The present invention relates to a photovoltaic module comprising as an encapsulant a composition comprising at least one polyacrylate- or polymethacrylate-type block copolymer with the general formula B-(A)n, n being a natural integer no lower than one, preferably 1 to 8, the block A being selected from among methacrylates having a Tg higher than 0° C., the block B being a polyacrylate or a polymethacrylate having a Tg lower than 0° C., the block B being at least 50 wt % of the total weight of the block copolymer.

Abstract translation: 本发明涉及一种光伏组件，其包含作为密封剂的组合物，该组合物包含至少一种具有通式B-（A）n的聚丙烯酸酯或聚甲基丙烯酸酯型嵌段共聚物，n为不低于1的自然整数，优选1至 如图8所示，嵌段A选自Tg高于0℃的甲基丙烯酸酯，嵌段B为Tg低于0℃的聚丙烯酸酯或聚甲基丙烯酸酯，嵌段B为至少50重量％ 嵌段共聚物的总重量。