Crosslinkable copolymers obtained by polycondensation and ionically
conductive material containing the same
    16.
    发明授权
    Crosslinkable copolymers obtained by polycondensation and ionically conductive material containing the same 失效
    通过缩聚获得的可交联共聚物和含有它们的离子导电材料

    公开(公告)号:US5521019A

    公开(公告)日:1996-05-28

    申请号:US344643

    申请日:1994-11-18

    摘要: The invention relates to copolymers, a process for preparing them and their use for the production of ionically conductive materials. The copolymers consist of identical or different organic blocks A which cannot be crosslinked by a radical route or by a Diels-Alder reaction, each of which has a valency i such that 1.ltoreq.i.ltoreq.6, and identical or different blocks Z(CH.sub.2).sub.j, in each of which Z denotes an organic radical which has a valency j such that 1.ltoreq.j.ltoreq.6, the radicals Z additionally containing at least one functional group permitting crosslinking by a radical route or by a Diels-Alder reaction; each block being joined to at least one other block by a functional group Y, the functional group Y being an ether functional group or a secondary or tertiary amine functional group. They are obtained by polycondensation of A(YH); monomers and Z(CH.sub.2 X).sub.j monomers, wherein Y is a leaving group. They are useful in the production of ionically conductive materials.

    摘要翻译: 本发明涉及共聚物,其制备方法及其用于制备离子导电材料的用途。 共聚物由相同或不同的有机嵌段A组成,其不能通过自由基途径或Diels-Alder反应进行交联,每个反应的价态i使得1〜6个相同或不同的嵌段 Z(CH 2)j,其中Z表示有价基团j的有机基团,使得基团Z另外含有至少一个允许通过基团路线交联的官能团或由 狄尔斯 - 阿尔德反应 每个嵌段通过官能团Y连接至至少一个其它嵌段,官能团Y是醚官能团或仲胺或叔胺官能团。 它们通过A(YH)的缩聚获得; 单体和Z(CH 2 X)j单体,其中Y是离去基团。 它们可用于生产离子导电材料。

    Crosslinkable copolymers obtained by polycondensation and ionically
conductive material containing the same
    17.
    发明授权
    Crosslinkable copolymers obtained by polycondensation and ionically conductive material containing the same 失效
    通过缩聚获得的可交联共聚物和含有它们的离子导电材料

    公开(公告)号:US5393847A

    公开(公告)日:1995-02-28

    申请号:US105807

    申请日:1993-08-13

    摘要: The invention relates to copolymers, a process for preparing them and their use for the production of ionically conductive materials.The copolymers consist of identical or different organic blocks A which cannot be crosslinked by a radical route or by a Diels-Alder reaction, each of which has a valency i such that 1.ltoreq.i.ltoreq.6, and identical or different blocks Z(CH.sub.2).sub.j, in each of which Z denotes an organic radical which has a valency j such that 1.ltoreq.j.ltoreq.6, the radicals Z additionally containing at least one functional group permitting crosslinking by a radical route or by a Diels-Alder reaction; each block being joined to at least one other block by a functional group Y, the functional group Y being an ether functional group or a secondary or tertiary amine functional group.They are obtained by polycondensation of HYAYH monomers and Z(CH.sub.2 X).sub.j monomers, wherein Y is a leaving group.They are useful in the production of ionically conductive materials.

    摘要翻译: 本发明涉及共聚物,其制备方法及其用于制备离子导电材料的用途。 共聚物由相同或不同的有机嵌段A组成,其不能通过自由基途径或Diels-Alder反应进行交联,每个反应的价态i使得1〜6个相同或不同的嵌段 Z(CH 2)j,其中Z表示有价基团j的有机基团,使得基团Z另外含有至少一个允许通过基团路线交联的官能团或由 狄尔斯 - 阿尔德反应 每个嵌段通过官能团Y连接至至少一个其它嵌段,官能团Y是醚官能团或仲胺或叔胺官能团。 它们通过HYAYH单体和Z(CH 2 X)j单体的缩聚获得,其中Y是离去基团。 它们可用于生产离子导电材料。

    Copolymer of propylene or ethylene oxide and of an oxirane bearing an ionic group
    18.
    发明授权
    Copolymer of propylene or ethylene oxide and of an oxirane bearing an ionic group 有权
    丙烯或环氧乙烷和带有离子基团的环氧乙烷的共聚物

    公开(公告)号:US08216487B2

    公开(公告)日:2012-07-10

    申请号:US11884476

    申请日:2006-02-09

    IPC分类号: H01G9/02

    摘要: The invention relates to a copolymer of ethylene oxide or propylene oxide and at least one substituted oxirane bearing an ionic group.The copolymer is characterized in that its chain comprises repeat units —O—CH2—CH(—CH2—O—SO3−Li+)—, repeat units —O—CH2—CHR— in which R is H or CH3, optionally, repeat units —O—CH2—CH(—CH2R′)— in which R′ is a functional group. x Uses: electrolyte in electrochemical, selective-membrane and reference-membrane devices.

    摘要翻译: 本发明涉及环氧乙烷或环氧丙烷与至少一个带有离子基团的取代的环氧乙烷的共聚物。 共聚物的特征在于其链包含重复单元-O-CH 2 -CH(-CH 2 -O-SO 3 -Li +) - ,其中R是H或CH 3的重复单元-O-CH 2 -CHR-,任选地,重复单元 -O-CH 2 -CH(-CH 2 R') - 其中R'是官能团。 x用途:电化学,选择膜和参比膜装置中的电解质。

    Ionic conducting material containing an oligoether sulphate
    19.
    发明申请
    Ionic conducting material containing an oligoether sulphate 有权
    含有低聚醚硫酸盐的离子导电材料

    公开(公告)号:US20070190428A1

    公开(公告)日:2007-08-16

    申请号:US11630745

    申请日:2005-06-27

    IPC分类号: H01M10/40 G02F1/15

    摘要: Ion-conducting material containing an oligoether sulfate The invention relates to an ion-conducting material containing an oligoether sulfate. The material comprises an ionic compound dissolved in a solvating polymer. The ionic compound is a mixture of a lithium bis(trifluoromethanesulfonyl)imide and of at least one lithium oligoether sulfate chosen from the lithium oligoether monosulfates corresponding to the formula R—[O—CH2—CH2)]n—O—SO3−Li+(I) in which R is a group CmH2m+1 with 1≦m≦4 and 2≦n≦17, and the lithium oligoether disulfates corresponding to the formula Li+O−SO2—O—CH2—[CH2—O—CH2]p—CH2—O—SO2—O−Li+(II) in which 3≦p≦45; the overall ratio Ot/Lit is less than or equal to 40, Ot representing the total number of O atoms provided by the solvating polymer and by the oligoether; the content of LiTFSI is such that the Ot/LiTFSI ratio is greater than or equal to 20.

    摘要翻译: 含有低聚醚硫酸盐的离子导电材料本发明涉及含有低聚醚硫酸盐的离子导电材料。 该材料包含溶解在溶剂化聚合物中的离子化合物。 离子化合物是双(三氟甲磺酰基)亚胺锂和至少一种锂低聚醚硫酸盐的混合物,其选自对应于式R- [O- CH 2 -CH = SUB的锂低聚醚单硫酸盐 (2)]其中-O-SO 3 - ( - )其中, R 1是具有1≤m≤4和2≤n≤17的基团C m 2 H 2 m + 1,并且对应于式(I)的锂低聚醚二硫酸盐 - - - - (CH 2) - - - - (CH 2) -O-CH 2 - - - - CH 2 -O-SO 2 -O -O - (II)其中3 <= p <= 45; 总比例O t小于或等于40,表示由溶剂化物提供的O原子的总数,O

    Copolymer of ethylene oxide and at least one substituted oxirane carrying a cross-linkable function, process for preparation thereof, and use thereof for producing ionically conductive materials
    20.
    发明申请
    Copolymer of ethylene oxide and at least one substituted oxirane carrying a cross-linkable function, process for preparation thereof, and use thereof for producing ionically conductive materials 审中-公开
    环氧乙烷和至少一个具有可交联功能的取代环氧乙烷的共聚物,其制备方法及其用于制备离子导电材料的用途

    公开(公告)号:US20050159561A1

    公开(公告)日:2005-07-21

    申请号:US11037475

    申请日:2005-01-19

    摘要: The invention concerns a copolymer of ethylene oxide and at least one substituted oxirane carrying a cross-linkable function. The copolymer comprises ethylene oxide, —O—CH2—CHR— units in which R is a substituent containing a reactive function which is cross-linkable by free radical process, and possibly —O—CH2—CHR′— units in which R′ is a substituent containing no reactive function which is cross-linkable by means of a free radical process, It is characterized by an excellent polydispersity index I=MW/Mn and a random distribution of the different monomer units. The copolymer is prepared by an anionic copolymerization process. The copolymer is useful for preparing a solid electrolyte having good mechanical properties, a good cationic conductivity and a good chemical compatibility with the electrodes of a generator operating with alkali metals such as lithium and sodium.

    摘要翻译: 本发明涉及环氧乙烷和至少一个带有可交联功能的取代环氧乙烷的共聚物。 该共聚物包含环氧乙烷,-O-CH 2 -CH-单元,其中R是含有可通过自由基过程交联的反应性官能团的取代基,以及可能的-O-CH 2个-CHR'-单元,其中R'是不含可通过自由基方法交联的反应性官能团的取代基,其特征在于优异的多分散指数I = M W Mn和不同单体单元的随机分布。 共聚物通过阴离子共聚方法制备。 该共聚物可用于制备具有良好的机械性能,良好的阳离子导电性和与用碱金属如锂和钠操作的发电机的电极的良好的化学相容性的固体电解质。