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公开(公告)号：US09034969B2
公开(公告)日：2015-05-19
申请号：US13501071
申请日：2010-10-08
CPC分类号： C08K5/46 , B60C1/0016 , C07D277/16 , C08K5/0025 , C08K5/23 , C08L7/00 , C08L9/00 , C08L9/06 , C08L21/00 , C08L2666/08
摘要： A rubber composition for the manufacture of tires, based on a blend of at least one diene elastomer chosen from natural rubber and synthetic polyisoprene and of one or more diene elastomers chosen from the group consisting of polybutadienes, butadiene copolymers and isoprene copolymers, on one or more reinforcing fillers and on a vulcanization system, the said vulcanization system comprising one or more thiazoline compounds of formula:
摘要翻译： 一种用于制造轮胎的橡胶组合物，其基于选自天然橡胶和合成聚异戊二烯的至少一种二烯弹性体和一种或多种选自聚丁二烯，丁二烯共聚物和异戊二烯共聚物的二烯弹性体的共混物， 更多的增强填料，并且在硫化体系上，所述硫化体系包含一种或多种下式的噻唑啉化合物：
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公开(公告)号：US08957155B2
公开(公告)日：2015-02-17
申请号：US13141511
申请日：2009-12-18
CPC分类号： C07F7/1804
摘要： The invention relates to a blocked mercaptosilane of general formula I below: (HO)2R1—Si—Z—S—C(═O)-A in which: R1 represents a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms; A represents hydrogen or a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms; Z represents a divalent bonding group comprising from 1 to 18 carbon atoms.
摘要翻译： 本发明涉及以下通式I的封端巯基硅烷：（HO）2R1-Si-Z-S-C（= O）-A，其中：R1表示选自烷基的一价烃基，其为直链或 具有1至18个碳原子的支链，环烷基或芳基; A表示氢或选自具有1至18个碳原子的直链或支链，环烷基或芳基的烷基的一价烃基; Z表示包含1至18个碳原子的二价键合基团。
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公开(公告)号：US20130085223A1
公开(公告)日：2013-04-04
申请号：US13501093
申请日：2010-10-08
IPC分类号： C07D277/36 , C08L7/00
CPC分类号： C07D277/36 , B60C1/00 , B60C1/0016 , C08K3/04 , C08K3/36 , C08K5/0025 , C08K5/47 , C08L7/00 , C08L9/00 , C08L9/06 , C08L21/00 , C08L2666/08
摘要： A rubber composition for the manufacture of tires, based on one or more diene elastomers, on one or more reinforcing fillers and on a vulcanization system, the vulcanization system comprising one or more thiazole compounds of formula:
摘要翻译： 一种用于制造基于一种或多种二烯弹性体在一种或多种增强填料和硫化体系上的轮胎的橡胶组合物，所述硫化体系包含一种或多种下式的噻唑化合物：
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公开(公告)号：US20130053504A1
公开(公告)日：2013-02-28
申请号：US13501071
申请日：2010-10-08
IPC分类号： C08L9/00
CPC分类号： C08K5/46 , B60C1/0016 , C07D277/16 , C08K5/0025 , C08K5/23 , C08L7/00 , C08L9/00 , C08L9/06 , C08L21/00 , C08L2666/08
摘要： A rubber composition for the manufacture of tires, based on a blend of at least one diene elastomer chosen from natural rubber and synthetic polyisoprene and of one or more diene elastomers chosen from the group consisting of polybutadienes, butadiene copolymers and isoprene copolymers, on one or more reinforcing fillers and on a vulcanization system, the said vulcanization system comprising one or more thiazoline compounds of formula:
摘要翻译： 一种用于制造轮胎的橡胶组合物，其基于选自天然橡胶和合成聚异戊二烯的至少一种二烯烃弹性体的共混物和选自聚丁二烯，丁二烯共聚物和异戊二烯共聚物的一种或多种二烯弹性体， 更多的增强填料，并且在硫化体系上，所述硫化体系包含一种或多种下式的噻唑啉化合物：
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15.发明申请Elastomer Mixture Mainly Comprising a Diene Elastomer Coupled by an Aminoalkoxysilane Group, Rubber Composition Including the Same and Methods for Obtaining Same 有权主要包含由氨基烷氧基硅烷基团连接的二烯弹性体的弹性体混合物，包括其的橡胶组合物及其获得方法公开(公告)号：US20110178233A1
公开(公告)日：2011-07-21
申请号：US12990212
申请日：2009-04-27
申请人： Philippe Chaboche , Jean-Michel Favrot , Nicolas Seeboth , Fanny Barbotin , Stéphanie De Landtsheer
发明人： Philippe Chaboche , Jean-Michel Favrot , Nicolas Seeboth , Fanny Barbotin , Stéphanie De Landtsheer
CPC分类号： C08F297/04 , B60C1/0016 , C08C19/22 , C08C19/25 , C08C19/44 , C08F8/32 , C08F8/42 , C08F297/044 , C08L15/00 , C08L53/025 , C08L2666/02
摘要： The present invention relates to an elastomer mixture resulting from the modification of a diene elastomer by a coupling agent that introduces, into the elastomer chain, an alkoxysilane group bearing a tertiary or secondary amine functional group. This mixture predominantly comprises the diene elastomer coupled by the alkoxysilane group bearing a tertiary or secondary amine functional group which is bonded to the diene elastomer through the silicon atom. The invention also relates to a reinforced rubber composition, in particular that can be used for the manufacture of tyres, which comprises a reinforcing filler and an elastomer matrix comprising at least this elastomer mixture, and to its preparation process. This composition has improved hysteresis and mechanical properties in the vulcanized state, and also improved processing in the uncured state.
摘要翻译： 本发明涉及通过偶联剂改性二烯弹性体而得到的弹性体混合物，该偶联剂将具有叔胺或仲胺官能团的烷氧基硅烷基引入到弹性体链中。 该混合物主要包含通过具有通过硅原子键合到二烯弹性体上的叔胺官能团的烷氧基硅烷基团偶联的二烯弹性体。 本发明还涉及一种增强橡胶组合物，特别是可用于制造轮胎的增强橡胶组合物，其包括增强填料和至少包含该弹性体混合物的弹性体基质及其制备方法。 该组合物在硫化状态下具有改善的滞后和机械性能，并且还改善了未固化状态下的加工。
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16.发明申请Process for Preparing a Diene Copolymer Comprising a Polyether Block, Diene Copolymer Comprising a Polyether Block, Reinforced Rubber Composition and Tire 有权制备包含聚醚嵌段的二烯共聚物，包含聚醚嵌段的二烯共聚物，增强橡胶组合物和轮胎的方法公开(公告)号：US20100249270A1
公开(公告)日：2010-09-30
申请号：US12666962
申请日：2008-06-19
IPC分类号： C08G81/02 , C08G65/336 , C08K3/36 , C08K3/04
CPC分类号： C08F297/02 , B60C1/0016 , C08C19/44 , C08F297/04 , C08F297/044 , C08G65/336 , C08G65/337 , C08G81/025 , C08K3/013 , C08L53/00 , C08L53/005 , C08L53/02 , C08L53/025 , C08L71/02 , C08L2205/05 , C08L2666/02 , C08L2666/04 , C08L2666/24 , C08L15/00
摘要： A process for preparing a functionalized or unfunctionalized diene block copolymer comprising at least one polyether block of number-average molecular weight approximately from 150 to 5000 g/mol linked to at least one block constituted of a diene elastomer via at least one silicon atom. The process allows a high degree of grafting of the polyether to the polymer chains. Also disclosed is a reinforced rubber composition, especially intended for the manufacture of tires, comprising such a diene block copolymer which is intended to interact with the reinforcing filler. Such a rubber composition has improved hysteresis properties in the vulcanized state, while retaining satisfactory processing properties in the non-vulcanized state.
摘要翻译： 一种制备官能化或未官能化二烯嵌段共聚物的方法，其包含至少一个数均分子量为约150至5000g / mol的聚醚嵌段，其通过至少一个硅原子与至少一个二烯弹性体构成的嵌段连接。 该方法允许聚醚向聚合物链的高度接枝。 还公开了一种增强橡胶组合物，特别是用于制造轮胎的增强橡胶组合物，其包含这种旨在与增强填料相互作用的二烯嵌段共聚物。 这种橡胶组合物在硫化状态下具有改善的滞后性能，同时在非硫化状态下保持令人满意的加工性能。
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17.发明授权Elastomer mixture mainly comprising a diene elastomer coupled by an aminoalkoxysilane group, rubber composition including the same and methods for obtaining same 有权主要由通过氨基烷氧基硅烷基团偶合的二烯弹性体的弹性体混合物，包含该二烯弹性体的橡胶组合物及其获得方法公开(公告)号：US09175124B2
公开(公告)日：2015-11-03
申请号：US12990212
申请日：2009-04-27
申请人： Philippe Chaboche , Jean-Michel Favrot , Nicolas Seeboth , Fanny Barbotin , Stéphanie De Landtsheer
发明人： Philippe Chaboche , Jean-Michel Favrot , Nicolas Seeboth , Fanny Barbotin , Stéphanie De Landtsheer
IPC分类号： C08F8/00 , C08F297/04 , C08C19/25 , C08C19/22 , C08F8/32 , B60C1/00 , C08C19/44 , C08F8/42 , C08L15/00 , C08L53/02
CPC分类号： C08F297/04 , B60C1/0016 , C08C19/22 , C08C19/25 , C08C19/44 , C08F8/32 , C08F8/42 , C08F297/044 , C08L15/00 , C08L53/025 , C08L2666/02
摘要： The present invention relates to an elastomer mixture resulting from the modification of a diene elastomer by a coupling agent that introduces, into the elastomer chain, an alkoxysilane group bearing a tertiary or secondary amine functional group. This mixture predominantly comprises the diene elastomer coupled by the alkoxysilane group bearing a tertiary or secondary amine functional group which is bonded to the diene elastomer through the silicon atom. The invention also relates to a reinforced rubber composition, in particular that can be used for the manufacture of tires, which comprises a reinforcing filler and an elastomer matrix comprising at least this elastomer mixture, and to its preparation process. This composition has improved hysteresis and mechanical properties in the vulcanized state, and also improved processing in the uncured state.
摘要翻译： 本发明涉及通过偶联剂改性二烯弹性体而得到的弹性体混合物，该偶联剂将具有叔胺或仲胺官能团的烷氧基硅烷基引入到弹性体链中。 该混合物主要包含通过具有通过硅原子键合到二烯弹性体上的叔胺官能团的烷氧基硅烷基团偶联的二烯弹性体。 本发明还涉及一种增强橡胶组合物，特别是可用于制造轮胎的增强橡胶组合物，其包括增强填料和至少包含该弹性体混合物的弹性体基质及其制备方法。 该组合物在硫化状态下具有改善的滞后和机械性能，并且还改善了未固化状态下的加工。
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18.发明授权Process for preparing a diene copolymer comprising a polyether block, diene copolymer comprising a polyether block, reinforced rubber composition and tire 有权制备包含聚醚嵌段，包含聚醚嵌段，增强橡胶组合物和轮胎的二烯共聚物的二烯共聚物的方法公开(公告)号：US08492479B2
公开(公告)日：2013-07-23
申请号：US12666962
申请日：2008-06-19
CPC分类号： C08F297/02 , B60C1/0016 , C08C19/44 , C08F297/04 , C08F297/044 , C08G65/336 , C08G65/337 , C08G81/025 , C08K3/013 , C08L53/00 , C08L53/005 , C08L53/02 , C08L53/025 , C08L71/02 , C08L2205/05 , C08L2666/02 , C08L2666/04 , C08L2666/24 , C08L15/00
摘要： A process for preparing a functionalized or unfunctionalized diene block copolymer comprising at least one polyether block of number-average molecular weight approximately from 150 to 5000 g/mol linked to at least one block constituted of a diene elastomer via at least one silicon atom. The process allows a high degree of grafting of the polyether to the polymer chains. Also disclosed is a reinforced rubber composition, especially intended for the manufacture of tires, comprising such a diene block copolymer which is intended to interact with the reinforcing filler. Such a rubber composition has improved hysteresis properties in the vulcanized state, while retaining satisfactory processing properties in the non-vulcanized state.
摘要翻译： 一种制备官能化或未官能化二烯嵌段共聚物的方法，其包含至少一个数均分子量为约150至5000g / mol的聚醚嵌段，其通过至少一个硅原子与至少一个由二烯弹性体构成的嵌段连接。 该方法允许聚醚向聚合物链的高度接枝。 还公开了一种增强橡胶组合物，特别是用于制造轮胎的增强橡胶组合物，其包含这种旨在与增强填料相互作用的二烯嵌段共聚物。 这种橡胶组合物在硫化状态下具有改善的滞后性能，同时在非硫化状态下保持令人满意的加工性能。
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公开(公告)号：US20130053510A1
公开(公告)日：2013-02-28
申请号：US13501090
申请日：2010-10-08
IPC分类号： C08L7/00
CPC分类号： C08K5/46 , B60C1/00 , C07D285/125 , C08K5/0025 , C08K5/47 , C08L9/06 , C08L21/00
摘要： A rubber composition for the manufacture of tires, based on one or more diene elastomers, on one or more reinforcing fillers and on a vulcanization system, characterized in that the said vulcanization system comprises one or more thiadiazole compounds of formula:
摘要翻译： 一种用于在一种或多种增强填料上和硫化体系上制造基于一种或多种二烯弹性体的轮胎的橡胶组合物，其特征在于所述硫化体系包含一种或多种下式的噻二唑化合物：
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公开(公告)号：US09045432B2
公开(公告)日：2015-06-02
申请号：US13809795
申请日：2011-07-12
IPC分类号： C07D233/34 , C07D233/36
CPC分类号： C07D233/34 , C07D233/36
摘要： A compound includes at least one group Q and at least one group A linked together by at least one “spacer” group Sp, in which: group Q includes a dipole containing at least one nitrogen atom, preferably a nitrile oxide, nitrone, or nitrile imine function; group A contains at least one nitrogen atom, and is preferably an imidazolidinyl, ureyl, bis-ureyl, ureido-pyrimidyl, and triazolyl group; and Sp is an atom or a group of atoms forming a link between Q and A, preferably, a linear, branched or cyclic hydrocarbon-based optionally substituted chain, and may contain one or more aromatic radicals and/or heteroatoms. The compound may react with an unsaturated polymer forming a covalent bond with the polymer. The compound is useful for providing good interaction between fillers and polymers by establishing labile, non-covalent bonds between the polymer chains and the filler, thereby limiting processing problems.
摘要翻译： 化合物包括至少一个基团Q和至少一个通过至少一个“间隔基”基团Sp连接在一起的基团A，其中：基团Q包括含有至少一个氮原子的偶极子，优选氧化腈，硝酮或腈 亚胺功能; A组含有至少一个氮原子，优选为咪唑烷基，脲基，双ureyl，脲基 - 嘧啶基和三唑基; 并且Sp是在Q和A之间形成连接的原子或一组原子，优选直链，支链或环状烃基任选取代的链，并且可以含有一个或多个芳族基团和/或杂原子。 该化合物可与与聚合物形成共价键的不饱和聚合物反应。 该化合物可用于通过在聚合物链和填料之间建立不稳定的非共价键来提供填料和聚合物之间的良好相互作用，从而限制了加工问题。
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