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11.发明授权Production of grafted polyethylene from renewable materials, the obtained polyethylene and uses thereof 有权从可再生材料生产接枝聚乙烯，获得的聚乙烯及其用途公开(公告)号：US09045577B2
公开(公告)日：2015-06-02
申请号：US13055857
申请日：2009-07-27
IPC分类号： C08F8/46 , C08F255/02 , C08F10/02 , C08F110/02 , B32B27/32 , C08F210/16 , C08L51/06
CPC分类号： C08F255/02 , B32B7/12 , B32B15/08 , B32B27/08 , B32B27/18 , B32B27/30 , B32B27/32 , B32B27/327 , B32B27/34 , B32B27/36 , B32B2270/00 , B32B2307/558 , C08F8/46 , C08F10/02 , C08F110/02 , C08F210/16 , C08L51/06 , C08F2/00 , C08L2666/02 , C08F210/06 , C08F2500/12 , C08F2500/08 , C08F210/14
摘要： The invention relates to a method for production of grafted polyethylene comprising the following steps: a) fermentation of primary renewable material with optional purification to give at least one alcohol chosen from ethanol or a mixture of alcohols comprising ethanol; b) dehydration of the alcohol obtained to give in a first reactor at least one alkene selected from ethylene and mixtures of alkenes containing ethylene and optional purification of the alkene to give ethylene; c) polymerization, in a second reactor, of the ethylene to give polyethylene; d) isolation of the polyethylene obtained in step c); e) grafting the polyethylene with at least one grafting monomer selected from the unsaturated carboxylic acids or theifunctional derivatives thereof, the unsaturated dicarboxylic acids having 4-10 carbon atoms and the functional derivatives thereof being C1-C8 alkyl esters or glycidyl ester derivatives of the unsaturated carboxylic acids and the metal salts of the unsaturated carboxylic acids. The invention further relates to the grafted polyethylene obtained by said method, the copolymers and compositions comprising said polyethylene and the use of said polyethylene.
摘要翻译： 本发明涉及生产接枝聚乙烯的方法，包括以下步骤：a）可任选地纯化初级可再生材料发酵，得到至少一种选自乙醇或包含乙醇的醇的混合物的醇; b）在第一反应器中获得的醇的脱水得到至少一种选自乙烯的烯烃和含乙烯的烯烃的混合物和任选的烯烃纯化以得到乙烯; c）在第二反应器中聚合乙烯，得到聚乙烯; d）分离步骤c）中获得的聚乙烯; e）用至少一种选自不饱和羧酸或其官能衍生物的接枝单体，具有4-10个碳原子的不饱和二羧酸接枝聚乙烯，其官能衍生物是不饱和羧酸或其不饱和羧酸的缩水甘油酯衍生物 羧酸和不饱和羧酸的金属盐。 本发明还涉及通过所述方法获得的接枝聚乙烯，所述共聚物和组合物包含所述聚乙烯和所述聚乙烯的用途。
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12.发明授权Coextrusion binder of co-grafted polyethylene and polypropylene diluted in a non-grafted polyethylene 失效在非接枝聚乙烯中稀释的共接枝聚乙烯和聚丙烯的共挤出粘合剂公开(公告)号：US08007919B2
公开(公告)日：2011-08-30
申请号：US11915450
申请日：2006-05-23
CPC分类号： B32B27/32 , C08L23/10 , C08L51/06 , C08L2666/06 , C09J123/0815 , Y10T428/31522 , Y10T428/31757 , Y10T428/31855
摘要： The invention concerns a coextrusion binder comprising a mixture of at least one ethylene homo- or copolymer (A1) of density ranging between 0.940 and 0.980 g/cm3 with at least one propylene homo- or copolymer (B), said mixture being grafted by at least one functional monomer and optionally diluted in at least one non-grafted ethylene homo- or copolymer (A2) of density ranging between 0.940 and 0.980 g/cm3; the grafting rate of said coextrusion binder being less than 0.5% wt. % based on the total weight of said binder; the density of said tie ranging between 0.940 and 0.980 g/cm3. The invention also concerns a structure comprising said type of binder as well as its use.
摘要翻译： 本发明涉及一种共挤出粘合剂，其包含至少一种密度为0.940至0.980g / cm3的乙烯均聚物或共聚物（A1）与至少一种丙烯均聚物或共聚物（B）的混合物，所述混合物通过在 至少一种官能单体，并任选地在至少一种密度在0.940至0.980g / cm3之间的非接枝乙烯均聚物或共聚物（A2）中稀释; 所述共挤出粘合剂的接枝速率小于0.5重量％。 基于所述粘合剂的总重量的％; 所述粘合剂的密度在0.940至0.980g / cm3之间。 本发明还涉及包括所述类型的粘合剂以及其用途的结构。
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13.发明授权Composition based on isotactic polypropylene obtained by metallocene catalysis and on grafted isotactic polypropylene obtained by Ziegler-Natta catalysis 失效基于通过茂金属催化得到的全同立构聚丙烯和通过齐格勒 - 纳塔催化得到的接枝全同立构聚丙烯的组合物公开(公告)号：US06884846B2
公开(公告)日：2005-04-26
申请号：US10268916
申请日：2002-10-11
申请人： Jean-Laurent Pradel
发明人： Jean-Laurent Pradel
IPC分类号： B32B27/32 , C08F255/00 , C08L23/02 , C08L23/08 , C08L23/10 , C08L23/14 , C08L23/16 , C08L51/00 , C08L51/06 , C09J123/10
CPC分类号： C09J123/10 , C08L23/02 , C08L23/0815 , C08L23/16 , C08L51/06 , C08L2666/24 , Y10T428/31692 , Y10T428/31696 , Y10T428/3175 , Y10T428/31786
摘要： The present invention relates to a composition comprising isotactic polypropylene homo- or copolymer obtained by metallocene catalysis (A), abbreviated to miPP, and isotactic polypropylene homo- or copolymer obtained by Ziegler-Natta catalysis (B), abbreviated to zniPP, and grafted. It also relates to a coextrusion tie comprising such a composition.It also relates to a multilayer structure comprising a layer (L) comprising the preceding tie and, directly attached to this layer:a nitrogen-comprising or oxygen-comprising polar layer (J), such as a layer of polyamide resin, of saponified ethylene/vinyl acetate copolymer (EVOH) or of polyester;a layer (J) of an inorganic oxide deposited on a polymer, such as polyethylene (PE), poly(ethylene terephthalate) (PET) or EVOH; ora metal or metalloplastic layer (J).
摘要翻译： 本发明涉及包含通过茂金属催化（A）缩写为miPP获得的全同立构聚丙烯均聚物或共聚物和通过齐格勒 - 纳塔催化（B），缩写为zniPP获得的全同立构聚丙烯均聚物或共聚物，并接枝。 它还涉及包含这种组合物的共挤出粘合剂。 它还涉及一种多层结构，其包含一层（L），该层包括前述的连接并且直接附着在该层上：含氮或含氧的极性层（J），例如聚酰胺树脂层，皂化的乙烯 /乙酸乙烯酯共聚物（EVOH）或聚酯; 沉积在聚合物如聚乙烯（PE），聚（对苯二甲酸乙二醇酯）（PET）或EVOH）上的无机氧化物层（J） 或金属或金属塑料层（J）。
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公开(公告)号：US06750288B2
公开(公告)日：2004-06-15
申请号：US10208192
申请日：2002-07-31
申请人： Jean-Laurent Pradel
发明人： Jean-Laurent Pradel
IPC分类号： C08L2300
CPC分类号： B32B27/08 , B32B27/306 , B32B27/32 , B32B27/327 , B32B27/34 , B32B27/36 , B32B2323/043 , B32B2323/046 , B32B2367/00 , B32B2377/00 , C08F255/00 , C08F255/02 , C08L51/04 , Y10T428/1352 , Y10T428/31692 , Y10T428/31909 , C08L2666/04
摘要： The present invention relates to an isotactic polypropylene obtained by metallocene catalysis, onto which is grafted a functional monomer. The invention also relates to a composition which may form part of the composition of a coextrusion binder. This composition according to the invention comprises isotactic polypropylene obtained by metallocene catalysis, grafted and then optionally diluted with at least one polyolefin (C1) and/or in at least one polymer of elastomeric nature (D). The invention also relates to a multilayer structure comprising a layer (L) comprising the above binder, and, directly attached thereto, a layer (E): which is polar, nitrogenous or oxygenated, such as a layer of polyamide resin, of ethylene/saponified vinyl acetate copolymer (EVOH) or of polyester; or of a mineral oxide deposited on a polymer such as polyethylene (PE), polyethylene terephthalate (PET) or EVOH; or which is metallic or metalloplastic.
摘要翻译： 本发明涉及通过金属茂催化获得的全同立构聚丙烯，其上接枝有官能单体。本发明还涉及可形成共挤出粘合剂组合物的一部分的组合物。 根据本发明的组合物包含通过茂金属催化获得的全同立构聚丙烯，接枝并随后用至少一种聚烯烃（C1）和/或至少一种弹性体聚合物（D）稀释。本发明还涉及一种多层结构 包括上述粘合剂的层（L），并且直接附着有乙烯/皂化乙酸乙烯酯共聚物（EVOH）或聚乙烯乙酸乙烯酯共聚物（EVOH）的极性，含氮或氧化的层（E），例如聚酰胺树脂层 的聚酯; 沉积在诸如聚乙烯（PE），聚对苯二甲酸乙二醇酯（PET）或EVOH的聚合物上的无机氧化物; 或者是金属或金属塑料。
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15.发明授权公开(公告)号：US08338549B2
公开(公告)日：2012-12-25
申请号：US13119863
申请日：2009-09-22
CPC分类号： C11C3/12 , C08F210/16 , C08K5/092 , C08L23/02 , C08L23/04 , C08L23/20 , C11C3/00 , C11C3/003 , C08F2/00 , C08L2666/04 , C08F210/14
摘要： The invention relates to a polymer obtained by polymerizing olefins having 6 to 9 carbon atoms and partially derived from renewable resources. In particular, the polymer according to the invention can be derived from vegetable oil or animal fat. The invention also relates to the method for producing the polymer.
摘要翻译： 本发明涉及通过聚合具有6至9个碳原子且部分衍生自可再生资源的烯烃获得的聚合物。 特别地，根据本发明的聚合物可以衍生自植物油或动物脂肪。 本发明还涉及聚合物的制造方法。
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16.发明申请COMPOSITION CONTAINING POLYPROPYLENE AND/OR A PROPYLENE COPOLYMER OBTAINED FROM RENEWABLE MATERIALS, AND USES THEREOF 审中-公开含有聚丙烯和/或由可再生材料获得的丙烯共聚物的组合物及其用途公开(公告)号：US20110305900A1
公开(公告)日：2011-12-15
申请号：US13131347
申请日：2009-12-02
申请人： Samuel Devisme , Fabrice R. Chop , Jean-Laurent Pradel , Guillaume Le , Thomas Roussel , Jean-Luc Dubois
发明人： Samuel Devisme , Fabrice R. Chop , Jean-Laurent Pradel , Guillaume Le , Thomas Roussel , Jean-Luc Dubois
IPC分类号： B32B7/12 , B32B27/08 , C09J151/06 , B32B15/08 , C08F255/02 , C08L51/06
CPC分类号： C08F255/04 , B32B7/12 , B32B27/08 , C08F255/02 , C08L51/06 , C08L2666/02 , C09J151/06 , Y10T428/2804 , Y10T428/2891 , Y10T428/31511 , Y10T428/31522 , Y10T428/31678 , Y10T428/31725 , Y10T428/31855 , Y10T428/31859
摘要： The present application relates to a method for manufacturing a propylene polymer, including: a) fermenting and optionally purifying first renewable materials to produce an alcohol or an alcohol mixture, the alcohol or alcohol mixture including at least isopropanol and/or at least a mixture of ethanol and 1-butanol; b) dehydrating the resulting alcohol or the alcohol mixture to produce an alkene or alkene mixture in a first series of reactors, the alkene or alkene mixture containing at least propylene; c) polymerizing the propylene in a second reactor, optionally in the presence of a comonomer, so as to produce a propylene polymer; d) isolating the propylene polymer obtained in step c); and e) grafting the propylene polymer obtained from step d). The invention also relates to the grafted propylene polymer capable of being obtained by the method, to the compositions containing the polymer, as well as to the uses of the polymer.
摘要翻译： 本申请涉及一种用于制备丙烯聚合物的方法，包括：a）发酵和任选地净化第一可再生材料以产生醇或醇混合物，所述醇或醇混合物至少包括异丙醇和/或至少一种 乙醇和1-丁醇; b）使所得醇或醇混合物脱水以在第一系列反应器中产生烯烃或烯烃混合物，所述烯烃或烯烃混合物至少含有丙烯; c）任选地在共聚单体存在下，在第二反应器中聚合丙烯，以产生丙烯聚合物; d）分离步骤c）中获得的丙烯聚合物; 和e）接枝由步骤d）得到的丙烯聚合物。 本发明还涉及能够通过该方法获得的接枝丙烯聚合物，含有聚合物的组合物以及聚合物的用途。
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17.发明授权Composition based on isotactic polypropylene obtained by metallocene catalysis and on grafted isotactic polypropylene obtained by ziegler-natta catalysis 失效基于通过金属茂催化得到的全同立构聚丙烯和通过齐格勒 - 纳塔催化得到的接枝全同立构聚丙烯的组合物公开(公告)号：US07510775B2
公开(公告)日：2009-03-31
申请号：US11113187
申请日：2005-04-25
申请人： Jean-Laurent Pradel
发明人： Jean-Laurent Pradel
CPC分类号： C09J123/10 , C08L23/02 , C08L23/0815 , C08L23/16 , C08L51/06 , C08L2666/24 , Y10T428/31692 , Y10T428/31696 , Y10T428/3175 , Y10T428/31786
摘要： The present invention relates to a composition comprising isotactic polypropylene homo- or copolymer obtained by metallocene catalysis (A), abbreviated to miPP, and isotactic polypropylene homo- or copolymer obtained by Ziegler-Natta catalysis (B), abbreviated to zniPP, and grafted. It also relates to a coextrusion tie comprising such a composition.It also relates to a multilayer structure comprising a layer (L) comprising the preceding tie and, directly attached to this layer: a nitrogen-comprising or oxygen-comprising polar layer (J), such as a layer of polyamide resin, of saponified ethylene/vinyl acetate copolymer (EVOH) or of polyester; a layer (J) of an inorganic oxide deposited on a polymer, such as polyethylene (PE), poly(ethylene terephthalate) (PET) or EVOH; or a metal or metalloplastic layer (J).
摘要翻译： 本发明涉及包含通过茂金属催化（A）缩写为miPP获得的全同立构聚丙烯均聚物或共聚物和通过齐格勒 - 纳塔催化（B），缩写为zniPP获得的全同立构聚丙烯均聚物或共聚物，并接枝。 它还涉及包含这种组合物的共挤出粘合剂。 它还涉及一种多层结构，其包含一层（L），该层包括前述的连接并且直接附着在该层上：含氮或含氧的极性层（J），例如聚酰胺树脂层，皂化的乙烯 /乙酸乙烯酯共聚物（EVOH）或聚酯; 沉积在聚合物如聚乙烯（PE），聚（对苯二甲酸乙二醇酯）（PET）或EVOH）上的无机氧化物层（J） 或金属或金属塑料层（J）。
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18.发明授权Coextrusion tie based on cografted metallacene polyethylene and LLDPE on SBS and on PE 有权基于共同移植的金属茂聚乙烯和LLDPE在SBS和PE上的共挤出粘合公开(公告)号：US07074492B2
公开(公告)日：2006-07-11
申请号：US10662146
申请日：2003-09-12
IPC分类号： B32B15/085 , B32B27/08
CPC分类号： C08L23/0815 , B32B7/12 , B32B27/322 , C08F210/16 , C08F255/00 , C08F255/02 , C08L23/06 , C08L51/06 , C08L53/02 , C08L2205/02 , C08L2314/06 , C08L2666/02 , C09J151/06 , C09J153/02 , Y10T428/31678 , Y10T428/31692 , Y10T428/31696 , Y10T428/31725 , Y10T428/3175 , Y10T428/31786 , Y10T428/31797 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , Y10T428/31917 , Y10T428/31924 , C08L2666/24 , C08L2666/06 , C08L2666/04 , C08F210/08 , C08F2500/12 , C08F210/14
摘要： The present invention relates to a coextrusion tie comprising 10 to 35 weight % of a polymer (A) itself composed of a blend of 80 to 20 weight % of a metallocene polyethylene (A1) with a density of between 0.865 and 0.915 and of 20 to 80 weight % of a non-metallocene LLDPE polyethylene (A2), the blend of polymers (A1) and (A2) being cografted by an unsaturated carboxylic acid or its derivative, the content of which in the said blend is between 30 and 100 000 ppm; 40 to 60 weight % of a styrene/butadiene/styrene block copolymer (B) with 50 to 90 mol % of styrene; and 20 to 35 weight % of PE (C); the total making 100%, the blend of (A), (B) and (C) being such that the MFI or melt flow index (ASTM D 1238, 190° C., 2.16 kg) is between 0.1 and 10 g/10 min. The present invention also relates to a multilayer structure comprising a layer of tie according to the invention and to the objects comprising such a structure.
摘要翻译： 本发明涉及包含10至35重量％的本身由80至20重量％的密度为0.865至0.915和20至20重量％的茂金属聚乙烯（A1）的共混物的聚合物（A） 80重量％的非茂金属LLDPE聚乙烯（A2），聚合物（A1）和（A2）的共混物由不饱和羧酸或其衍生物共同接枝，其中所述共混物的含量为30-100,000 ppm; 40〜60重量％的具有50〜90摩尔％苯乙烯的苯乙烯/丁二烯/苯乙烯嵌段共聚物（B） 和20〜35重量％的PE（C）; 共计100％，（A），（B）和（C）的共混物使得MFI或熔体流动指数（ASTM D 1238,190℃，2.16kg）为0.1至10g / 10 分钟 本发明还涉及包括根据本发明的连接层和包括这种结构的物体的多层结构。
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公开(公告)号：US20050261445A1
公开(公告)日：2005-11-24
申请号：US10510830
申请日：2002-04-11
摘要： The invention concerns a method for hydrogenation of unsaturated polymers in dispersed medium based on an oxidation-reduction system containing hydrazine, an oxidant such as a peroxide and optionally a carboxylic acid. The hydrogenation rate can reach 100% in certain conditions.
摘要翻译： 本发明涉及一种基于含有肼的氧化还原体系，氧化剂如过氧化物和任选的羧酸在分散介质中氢化不饱和聚合物的方法。 在某些条件下，氢化率可以达到100％。
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20.发明申请Coextrusion tie for polyester based on cografted metallocene polyethylene and LLDPE and on metallocene polyethylene 有权基于共同移植的茂金属聚乙烯和LLDPE和茂金属聚乙烯的聚酯的共挤出粘合公开(公告)号：US20050019516A1
公开(公告)日：2005-01-27
申请号：US10671758
申请日：2003-09-26
CPC分类号： C08L23/0815 , C08L51/06 , C08L2205/02 , C08L2314/06 , Y10T428/13 , Y10T428/1303 , Y10T428/1352 , Y10T428/1359 , Y10T428/139 , Y10T428/31909 , Y10T428/31913 , C08L2666/24
摘要： A subject matter of the invention is a coextrusion tie, which comprises: 5 to 35% by weight of a polymer (A) itself composed of a blend of 80 to 20% by weight of a metallocene polyethylene (A1) with a density of between 0.863 and 0.915 and of 20 to 80% by weight of a non-metallocene LLDPE polyethylene (A2) with a density of between 0.900 and 0.950, the blend of polymers (A1) and (A2) being cografted; 95 to 65% by weight of metallocene polyethylene (B) homo- or copolymer, the comonomer of which comprises 3 to 20 carbon atoms, preferably 4 to 8 carbon atoms, the density of which is between 0.863 and 0.915 and the MFI of which is between 0.5 and 30, preferably between 3 and 15, g/10 min; the total forming 100%, the blend of (A) and (B) being such that its MFI is between 0.1 and 15, preferably between 1 and 13, g/10 min.
摘要翻译： 本发明的主题是共挤出粘合剂，其包括：5至35重量％的本身由80至20重量％的茂金属聚乙烯（A1）的共混物构成的聚合物（A），其密度介于 0.863和0.915，以及20-80重量％的密度为0.900-0.950的非茂金属LLDPE聚乙烯（A2），聚合物（A1）和（A2）的共混物被共同接枝; 95至65重量％的茂金属聚乙烯（B）均聚物或共聚物，其共聚单体包含3至20个碳原子，优选4至8个碳原子，其密度为0.863至0.915，MFI为 在0.5和30之间，优选在3和15之间，g / 10分钟; 总成型100％，（A）和（B）的共混物使得其MFI为0.1至15，优选1至13g / 10min。
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