公开(公告)号：US20090017378A1

公开(公告)日：2009-01-15

申请号：US12162095

申请日：2007-01-24

申请人： Patrick Charest ,  Michel Perrier ,  Martin Dontigny ,  Michel Petitclerc ,  Abdelbast Guerfi ,  Karim Zaghib

发明人： Patrick Charest ,  Michel Perrier ,  Martin Dontigny ,  Michel Petitclerc ,  Abdelbast Guerfi ,  Karim Zaghib

IPC分类号： H01M4/60 ,  H01B1/12 ,  H01M4/88 ,  B05D5/12 ,  H01M6/00

CPC分类号： H01M4/621 ,  H01M4/131 ,  H01M4/136 ,  H01M4/139 ,  H01M4/366 ,  H01M4/485 ,  H01M4/5825 ,  H01M4/625 ,  H01M10/052 ,  H01M10/0565 ,  Y10T29/49108

摘要： Particles comprising a core and a coat covering at least part of the core surface. The core has more than 50% of an acidic metal oxide and the core coating is based on a polymer, preferably based on a soiled polymer with high electrochemical stability. The particle has a solubility rate (ts), in fixed time, of the metal oxide migrating towards the electrolyte, per cycle, which is less than 5 per 10000. The particles are obtained by mixing the polymer and a metal oxide, via dry process with addition of solvent. The electrodes constituting an electrode substrate at least partly coated with a mixture consisting of at least 40 of those particles have remarkable electrochemical properties, in particular regarding the lifetime of batteries in which they are incorporated.

摘要翻译： 颗粒包括芯和覆盖芯表面的至少一部分的涂层。 核心具有超过50％的酸性金属氧化物，核心涂层基于聚合物，优选基于具有高电化学稳定性的污染聚合物。 颗粒在固定时间内的溶解速率（ts）在金属氧化物向电解质迁移的循环中，每周期小于5。通过干法将该聚合物与金属氧化物混合得到颗粒 加入溶剂。 构成至少部分地涂覆有由这些颗粒中的至少40个的混合物组成的电极基底的电极具有显着的电化学特性，特别是关于它们掺入的电池的寿命。

公开(公告)号：US20060166093A1

公开(公告)日：2006-07-27

申请号：US10534697

申请日：2003-11-13

申请人： Karim Zaghib ,  Michel Armand ,  Abdelbast Guerfi ,  Michel Perrier ,  Elisabeth Dupuis ,  Patrick Charest

发明人： Karim Zaghib ,  Michel Armand ,  Abdelbast Guerfi ,  Michel Perrier ,  Elisabeth Dupuis ,  Patrick Charest

IPC分类号： H01M4/62 ,  B05D5/12 ,  H01M4/74 ,  H01M4/66

CPC分类号： H01M4/0404 ,  H01G11/06 ,  H01G11/24 ,  H01G11/28 ,  H01G11/30 ,  H01G11/32 ,  H01G11/42 ,  H01G11/46 ,  H01G11/86 ,  H01M2/145 ,  H01M2/1653 ,  H01M4/04 ,  H01M4/0409 ,  H01M4/0471 ,  H01M4/133 ,  H01M4/136 ,  H01M4/139 ,  H01M4/1391 ,  H01M4/1393 ,  H01M4/1397 ,  H01M4/366 ,  H01M4/5825 ,  H01M4/587 ,  H01M4/621 ,  H01M4/622 ,  H01M4/623 ,  H01M4/625 ,  H01M4/66 ,  H01M4/661 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2004/027 ,  H01M2004/028 ,  H01M2300/0028 ,  H01M2300/0037 ,  H01M2300/004 ,  H01M2300/0042 ,  H01M2300/0082 ,  Y02E60/122 ,  Y02E60/13 ,  Y02P70/54

摘要： The invention relates to a method of preparing an electrochemical electrode which is partially or totally covered with a film that is obtained by spreading an aqueous solution comprising a water-soluble binder over the electrode and subsequently drying same. The production cost of the electrodes thus obtained is reduced and the surface porosity thereof is associated with desirable resistance values.

摘要翻译： 本发明涉及一种制备电化学电极的方法，其部分或全部被膜覆盖，所述膜通过在电极上铺展包含水溶性粘合剂的水溶液并随后干燥而获得。 由此获得的电极的生产成本降低，并且其表面孔隙率与期望的电阻值相关联。

公开(公告)号：US09972865B2

公开(公告)日：2018-05-15

申请号：US10543885

申请日：2004-01-29

申请人： Karim Zaghib ,  Michel Perrier ,  Abdelbast Guerfi ,  Elizabeth Dupuis ,  Patrick Charest

发明人： Karim Zaghib ,  Michel Perrier ,  Abdelbast Guerfi ,  Elizabeth Dupuis ,  Patrick Charest

IPC分类号： H01M10/00 ,  H01M10/0566 ,  H01M6/16 ,  H01M10/04 ,  H01M10/0567 ,  H01M10/42 ,  H01M2/16 ,  H01M4/134 ,  H01M10/052

CPC分类号： H01M10/0566 ,  H01M2/1653 ,  H01M4/134 ,  H01M6/168 ,  H01M10/0436 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/4235 ,  H01M2300/0037 ,  H01M2300/0042 ,  H01M2300/0085 ,  Y02E60/122 ,  Y02P70/54

摘要： The invention relates to a metallic lithium rechargeable electrochemical accumulator, comprising at least one lithium metal electrode and at least one polymeric electrolyte gel. Said accumulator is capable of operating at temperatures from −20 to 60° C., essentially without formation of lithium dendrites on the whole surface of the metallic lithium electrode. The above is also wherein a particularly long life, even with intensive use at low temperature. Said inventive rechargeable accumulator can be produced by use of a production method with particular application of temperature control during the specific production stages. As a result of the extremely high electrochemical performance of said accumulator, in particular the remarkable stability thereof, said accumulator can be used in new application fields such as hybrid vehicles, electric vehicles and emergency supply systems such as those of the UPS type.

公开(公告)号：US20070111105A1

公开(公告)日：2007-05-17

申请号：US10543885

申请日：2004-01-29

申请人： Karim Zaghib ,  Michel Perrier ,  Abdelbast Guerfi ,  Elizabeth Dupuis ,  Patrick Charest

发明人： Karim Zaghib ,  Michel Perrier ,  Abdelbast Guerfi ,  Elizabeth Dupuis ,  Patrick Charest

IPC分类号： H01M6/18

CPC分类号： H01M10/0566 ,  H01M2/1653 ,  H01M4/134 ,  H01M6/168 ,  H01M10/0436 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/4235 ,  H01M2300/0037 ,  H01M2300/0042 ,  H01M2300/0085 ,  Y02E60/122 ,  Y02P70/54

摘要： The invention relates to a metallic lithium rechargeable electrochemical accumulator, comprising at least one lithium metal electrode and at least one polymeric electrolyte gel. Said accumulator is capable of operating at temperatures from −20 to 60° C., essentially without formation of lithium dendrites on the whole surface of the metallic lithium electrode. The above is also wherein a particularly long life, even with intensive use at low temperature. Said inventive rechargeable accumulator can be produced by use of a production method with particular application of temperature control during the specific production stages. As a result of the extremely high electrochemical performance of said accumulator, in particular the remarkable stability thereof, said accumulator can be used in new application fields such as hybrid vehicles, electric vehicles and emergency supply systems such as those of the UPS type.

摘要翻译： 本发明涉及一种金属锂可再充电电化学蓄电池，其包含至少一种锂金属电极和至少一种聚合物电解质凝胶。 所述蓄能器能够在-20至60℃的温度下操作，基本上在金属锂电极的整个表面上不形成锂枝晶。 上述还具有特别长的使用寿命，即使在低温下也是密集使用的。 所述本发明的可再充电蓄电池可以通过使用在特定生产阶段中特别应用温度控制的生产方法来生产。 由于所述蓄电池的电化学性能极高，特别是其显着的稳定性，所述蓄电池可用于诸如混合动力车辆，电动车辆和UPS型应急供电系统等新的应用领域。

公开(公告)号：US20060115732A1

公开(公告)日：2006-06-01

申请号：US10521365

申请日：2003-07-10

申请人： Karim Zaghib ,  Patrick Charest ,  Abdelbast Guerfi ,  Michael Perrier ,  Kimio Kinoshita

发明人： Karim Zaghib ,  Patrick Charest ,  Abdelbast Guerfi ,  Michael Perrier ,  Kimio Kinoshita

IPC分类号： H01M4/48 ,  H01B1/00 ,  H01B1/06 ,  H01B1/12 ,  H01B1/02

摘要： Mixture of particles comprising a non-conducting or semi-conducting nucleus covered with a hybrid conductor coating and hybrid conductor chains located between the particles of the mixture to constitute a conductivity network, that is prepared by mechanical crushing. Due to a very good conductivity of the network, a low resistivity, a very good capacity under elevated current and/or a good density of energy, these mixtures of particles are advantageously incorporated in anodes and cathodes of electrochemical generators, resulting in highly performing electrochemical systems.

摘要翻译： 包含非导电或半导体核的混合物，其覆盖有混合导体涂层和位于混合物颗粒之间的混合导体链，以构成通过机械破碎制备的导电网络。 由于网络的非常好的导电性，低电阻率，在升高的电流和/或良好的能量密度下具有非常好的容量，这些颗粒混合物有利地结合到电化学发生器的阳极和阴极中，导致高度电化学 系统。

公开(公告)号：US08435671B2

公开(公告)日：2013-05-07

申请号：US12162933

申请日：2007-01-31

申请人： Karim Zaghib ,  Michel Petitclerc ,  Patrick Charest ,  Abdelbast Guerfi ,  Martin Dontigny

发明人： Karim Zaghib ,  Michel Petitclerc ,  Patrick Charest ,  Abdelbast Guerfi ,  Martin Dontigny

IPC分类号： B23H3/04 ,  B05D5/12 ,  C25B9/00

CPC分类号： H01M4/485 ,  H01M4/0404 ,  H01M4/0421 ,  H01M4/0426 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/136 ,  H01M4/1391 ,  H01M4/1393 ,  H01M4/1395 ,  H01M4/1397 ,  H01M4/366 ,  H01M4/5805 ,  H01M4/5825 ,  H01M4/621 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0085 ,  H01M2300/0091 ,  Y02E60/122 ,  Y02P70/54

摘要： A multilayer material includes a solid substrate and at least two superimposed solid layers containing particles of an electrochemically active material, the first solid layer adhering to the solid substrate and the second solid layer adhering to the first solid layer. The multilayer material has a constant thickness of upper layer not less than 95% and a depth of penetration of the second layer into the first layer which is less than 10% of the thickness of the first layer, and enables as electrode constituent, generators having a low risk of overload degradation to be prepared.

摘要翻译： 多层材料包括固体基质和包含电化学活性材料的颗粒的至少两个叠加的固体层，第一固体层粘附到固体基底和粘附到第一固体层的第二固体层。 多层材料具有上层的恒定厚度不小于95％，第二层进入第一层的深度小于第一层的厚度的10％，并且能够作为电极组分，具有 低准备过载降解的风险。

公开(公告)号：US20090123845A1

公开(公告)日：2009-05-14

申请号：US11991270

申请日：2006-07-28

申请人： Karim Zaghib ,  Jocelyn Jalbert ,  Abdelbast Guerfi ,  Christophe Michot ,  Michel Gauthier ,  Martin Dontigny ,  Patrick Charest

发明人： Karim Zaghib ,  Jocelyn Jalbert ,  Abdelbast Guerfi ,  Christophe Michot ,  Michel Gauthier ,  Martin Dontigny ,  Patrick Charest

IPC分类号： B01D15/00 ,  H01M10/26 ,  H01M4/36 ,  B01J20/04 ,  C01D15/00 ,  H01M4/40

CPC分类号： H01M10/4242 ,  B01D15/00 ,  H01M10/0565 ,  H01M10/0566 ,  H01M2300/0085

摘要： Process for the purification of an ionic electrolyte comprising at least one alkali metal salt, the process having at least one stage in which particles of at least one calcium salt are brought into contact. The process makes it possible to obtain electrolytes characterized in particular by a particularly low water content. The corresponding electrochemical generators which incorporate the electrolyte as constituent component are characterized by a noteworthy stability and are particularly safe.

摘要翻译： 用于纯化包含至少一种碱金属盐的离子电解质的方法，该方法具有至少一个阶段，其中使至少一种钙盐的颗粒接触。 该方法可以获得特别特别是特别低含水量的电解质。 结合电解质作为组成成分的相应的电化学发生器的特征在于值得注意的稳定性并且特别安全。

公开(公告)号：US10147978B2

公开(公告)日：2018-12-04

申请号：US11991270

申请日：2006-07-28

申请人： Karim Zaghib ,  Jocelyn Jalbert ,  Abdelbast Guerfi ,  Christophe Michot ,  Michel Gauthier ,  Martin Dontigny ,  Patrick Charest

发明人： Karim Zaghib ,  Jocelyn Jalbert ,  Abdelbast Guerfi ,  Christophe Michot ,  Michel Gauthier ,  Martin Dontigny ,  Patrick Charest

IPC分类号： H01M10/42 ,  H01M10/0566 ,  B01D15/00 ,  H01M10/0565

摘要： Process for the purification of an ionic electrolyte comprising at least one alkali metal salt, the process having at least one stage in which particles of at least one calcium salt are brought into contact. The process makes it possible to obtain electrolytes characterized in particular by a particularly low water content. The corresponding electrochemical generators which incorporate the electrolyte as constituent component are characterized by a noteworthy stability and are particularly safe.

公开(公告)号：US20100327223A1

公开(公告)日：2010-12-30

申请号：US12827565

申请日：2010-06-30

申请人： Karim ZAGHIB ,  Patrick Charest ,  Abdelbast Guerfi ,  Guoxian Liang

发明人： Karim ZAGHIB ,  Patrick Charest ,  Abdelbast Guerfi ,  Guoxian Liang

IPC分类号： H01M4/90 ,  B05D5/00

CPC分类号： H01M4/5825 ,  H01M4/364 ,  H01M4/366 ,  H01M4/625 ,  H01M10/0525

摘要： The invention is related to a cathode material comprising particles having a lithium metal phosphate core and a pyrolytic carbon deposit, said particles having a synthetic multimodal particle size distribution comprising at least one fraction of micron size particles and one fraction of submicron size particles, said lithium metal phosphate having formula LiMPO4 wherein M is at least Fe or Mn.Said material is prepared by method comprising the steps of providing starting micron sized particles and starting submicron sized particles of at least one lithium metal phosphate or of precursors of a lithium metal phosphate; mixing by mechanical means said starting particles; making a pyrolytic carbon deposit on the lithium metal phosphate starting particles before or after the mixing step, and on their metal precursor before or after mixing the particles; optionally adding carbon black, graphite powder or fibers to the said lithium metal phosphate particles before the mechanical mixing.

摘要翻译： 本发明涉及包含具有锂金属磷酸盐芯和热解碳沉积物的颗粒的阴极材料，所述颗粒具有包含至少一部分微米级颗粒和一部分亚微米尺寸颗粒的合成多峰粒度分布，所述锂 具有式LiMPO 4的金属磷酸盐，其中M至少为Fe或Mn。 所述材料通过包括以下步骤的方法制备：包括提供起始微米尺寸的颗粒和开始至少一种锂金属磷酸盐或锂金属磷酸盐前体的亚微米尺寸的颗粒; 通过机械装置混合所述起始颗粒; 在混合步骤之前或之后在锂金属磷酸盐起始颗粒上制备热解碳沉积物，以及在混合颗粒之前或之后对其金属前体; 在机械混合之前，任选地将碳黑，石墨粉或纤维加入到所述锂金属磷酸盐颗粒中。

公开(公告)号：US20090155689A1

公开(公告)日：2009-06-18

申请号：US12000625

申请日：2007-12-14

申请人： Karim Zaghib ,  Patrick Charest ,  Abdelbast Guerfi ,  Guoxian Liang

发明人： Karim Zaghib ,  Patrick Charest ,  Abdelbast Guerfi ,  Guoxian Liang

IPC分类号： H01M4/40 ,  H01M4/48 ,  C01B25/30

CPC分类号： H01M4/5825 ,  H01M4/364 ,  H01M4/366 ,  H01M4/625 ,  H01M10/0525

摘要： The invention is related to a cathode material comprising particles having a lithium metal phosphate core and a pyrolytic carbon deposit, said particles having a synthetic multimodal particle size distribution comprising at least one fraction of micron size particles and one fraction of submicron size particles, said lithium metal phosphate having formula LiMPO4 wherein M is at least Fe or Mn.Said material is prepared by method comprising the steps of providing starting micron sized particles and starting submicron sized particles of at least one lithium metal phosphate or of precursors of a lithium metal phosphate; mixing by mechanical means said starting particles; making a pyrolytic carbon deposit on the lithium metal phosphate starting particles before or after the mixing step, and on their metal precursor before or after mixing the particles; optionally adding carbon black, graphite powder or fibers to the said lithium metal phosphate particles before the mechanical mixing.

摘要翻译： 本发明涉及包含具有锂金属磷酸盐芯和热解碳沉积物的颗粒的阴极材料，所述颗粒具有合成多峰粒度分布，其包含至少一部分微米级颗粒和一部分亚微米级颗粒，所述锂 具有式LiMPO 4的金属磷酸盐，其中M至少为Fe或Mn。 所述材料通过包括以下步骤的方法制备：包括提供起始微米尺寸的颗粒和开始至少一种锂金属磷酸盐或锂金属磷酸盐前体的亚微米尺寸的颗粒; 通过机械装置混合所述起始颗粒; 在混合步骤之前或之后在锂金属磷酸盐起始颗粒上制备热解碳沉积物，以及在混合颗粒之前或之后对其金属前体; 在机械混合之前，任选地将碳黑，石墨粉或纤维加入到所述锂金属磷酸盐颗粒中。