公开(公告)号：US20110219677A1

公开(公告)日：2011-09-15

申请号：US13130172

申请日：2009-11-19

申请人： Akira Koyama ,  Tatsuo Hamamatsu ,  Yasutoshi Iguchi ,  Hideshi Iki

发明人： Akira Koyama ,  Tatsuo Hamamatsu ,  Yasutoshi Iguchi ,  Hideshi Iki

IPC分类号： C10L1/00

CPC分类号： C10L1/04 ,  C10G3/00 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2300/30 ,  C10G2400/08 ,  Y02P30/20

摘要： The present invention provides a process of producing an aviation fuel base oil having excellent combustibility, oxidation stability and life cycle characteristics, hydrotreating in the presence of hydrogen a feedstock comprising an oxygen-containing hydrocarbon compound originating from an animal or vegetable fat (preferably an animal or vegetable fat that contains fatty acids each having 10 to 14 carbon atoms in the fatty acid carbon chain in the total amount of 60 percent by mass or more) and a sulfur-containing hydrocarbon compound. The present invention also provides a process for producing an aviation fuel base oil by blending such an aviation fuel base oil and an aviation fuel base oil produced by refining crude oil.

摘要翻译： 本发明提供一种生产具有优异的燃烧性，氧化稳定性和寿命特性的航空燃料基础油的方法，在氢气存在下加氢处理包含源自动物或植物脂肪（优选动物）的含氧烃化合物 或含有脂肪酸碳链中各自具有10〜14个碳原子的脂肪酸的植物油，总量为60质量％以上）和含硫烃化合物。 本发明还提供了一种通过混合这种航空燃料基础油和通过精炼原油生产的航空燃料基础油来生产航空燃料基础油的方法。

公开(公告)号：US08551325B2

公开(公告)日：2013-10-08

申请号：US13119310

申请日：2009-09-16

申请人： Tatsuo Hamamatsu ,  Hideki Ono ,  Yasutoshi Iguchi ,  Hideshi Iki ,  Yoshihiko Kinoshita

发明人： Tatsuo Hamamatsu ,  Hideki Ono ,  Yasutoshi Iguchi ,  Hideshi Iki ,  Yoshihiko Kinoshita

IPC分类号： C10G45/02 ,  C07C1/20

CPC分类号： C10G45/02 ,  C10G3/46 ,  C10G3/49 ,  C10G3/50 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2300/4018 ,  Y02P30/20

摘要： A method for manufacturing a hydrocarbon oil, comprising: a first step wherein a feedstock oil containing an oxygen-containing organic compound and a water-insoluble chlorine-containing compound is brought into contact with a hydrogenation catalyst comprising a support containing a porous inorganic oxide and one or more metals selected from Group VIA and Group VIII of the periodic table supported on the support in the presence of hydrogen to generate a hydrocarbon oil and water in a vapor state by the hydrodeoxygenation of an oxygen-containing organic compound and convert the water-insoluble chlorine-containing compound into a water-soluble chlorine-containing compound; a second step wherein the water in the reaction product of the first step is maintained in a vapor state and the reaction product of the first step is brought into contact with a nitrogen-containing Brønsted base compound which has a boiling point at normal pressure of 100° C. or less and is water-soluble to obtain a product to be treated; and a third step wherein the product to be treated is cooled to a temperature not higher than the temperature at which water in a vapor state is liquefied to form an aqueous phase containing a water-soluble chlorine-containing compound and a nitrogen-containing Brønsted base compound and then separate the aqueous phase from an oil to be treated to obtain a product oil containing a hydrocarbon oil.

摘要翻译： 一种烃油的制造方法，包括：第一工序，其中含有含氧有机化合物的原料油和不溶于水的含氯化合物与含有多孔无机氧化物的载体的氢化催化剂接触， 选自元素周期表第VIA族和第VIII族的一种或多种金属在氢气存在下负载在载体上以通过含氧有机化合物的加氢脱氧产生烃油和蒸气状态的水， 不溶性含氯化合物变成水溶性含氯化合物; 第二步骤，其中第一步骤的反应产物中的水保持蒸气状态，并使第一步的反应产物与常压下的沸点为100的含氮布朗斯台德碱化合物接触 ℃或更低，并且是水溶性的，以获得待处理的产品; 以及第三步骤，其中待处理的产品被冷却到不高于蒸汽状态的水液化的温度的温度，以形成含有水溶性含氯化合物和含氮布朗斯台德碱 化合物，然后将水相与待处理的油分离，得到含有烃油的产物油。

公开(公告)号：US20110219676A1

公开(公告)日：2011-09-15

申请号：US13130155

申请日：2009-11-19

申请人： Akira Koyama ,  Tatsuo Hamamatsu ,  Yasutoshi Iguchi ,  Hideshi Iki

发明人： Akira Koyama ,  Tatsuo Hamamatsu ,  Yasutoshi Iguchi ,  Hideshi Iki

IPC分类号： C10L1/10 ,  C10L1/00

CPC分类号： C10G3/44 ,  C10G3/50 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2400/08 ,  C10L1/04 ,  Y02P30/20

摘要： The present invention provides an environment friendly aviation fuel base oil having combustibility, oxidation stability and excellent life cycle characteristics and contributing to diversification of primary energy, which is produced by hydrotreating a feedstock comprising a mixed oil of an oxygen-containing hydrocarbon compound originating from an animal or vegetable fat and a sulfur-containing hydrocarbon compound or a feedstock comprising said mixed oil and a petroleum base oil produced by refining crude oil and an aviation fuel composition comprising the aviation fuel base oil, and an aviation fuel composition containing such an aviation fuel base oil.

摘要翻译： 本发明提供一种具有可燃性，氧化稳定性和优异的寿命周期特性的环境友好的航空燃料基础油，并且有助于一次能量的多样化，其通过加氢处理包含源自 动物或植物脂肪和含硫烃化合物或包含所述混合油的原料和通过精炼原油生产的石油基础油和包含航空燃料基础油的航空燃料组合物，以及含有这种航空燃料的航空燃料组合物 基础油

公开(公告)号：US09464250B2

公开(公告)日：2016-10-11

申请号：US13130172

申请日：2009-11-19

申请人： Akira Koyama ,  Tatsuo Hamamatsu ,  Yasutoshi Iguchi ,  Hideshi Iki

发明人： Akira Koyama ,  Tatsuo Hamamatsu ,  Yasutoshi Iguchi ,  Hideshi Iki

IPC分类号： C10L1/00 ,  C10L1/04 ,  C10G3/00

CPC分类号： C10L1/04 ,  C10G3/00 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2300/30 ,  C10G2400/08 ,  Y02P30/20

摘要： The present invention provides a process of producing an aviation fuel base oil having excellent combustibility, oxidation stability and life cycle characteristics, hydrotreating in the presence of hydrogen a feedstock comprising an oxygen-containing hydrocarbon compound originating from an animal or vegetable fat (preferably an animal or vegetable fat that contains fatty acids each having 10 to 14 carbon atoms in the fatty acid carbon chain in the total amount of 60 percent by mass or more) and a sulfur-containing hydrocarbon compound. The present invention also provides a process for producing an aviation fuel base oil by blending such an aviation fuel base oil and an aviation fuel base oil produced by refining crude oil.

摘要翻译： 本发明提供一种生产具有优异的燃烧性，氧化稳定性和寿命特性的航空燃料基础油的方法，在氢气存在下加氢处理包含源自动物或植物脂肪（优选动物）的含氧烃化合物 或含有脂肪酸碳链中各自具有10〜14个碳原子的脂肪酸的植物油，总量为60质量％以上）和含硫烃化合物。 本发明还提供了一种通过混合这种航空燃料基础油和通过精炼原油生产的航空燃料基础油来生产航空燃料基础油的方法。

公开(公告)号：US20060260983A1

公开(公告)日：2006-11-23

申请号：US10548315

申请日：2004-03-05

申请人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka

发明人： Hideshi Iki ,  Yukihiro Sugiura ,  Yuichi Tanaka

IPC分类号： C07C37/00 ,  C10G45/04 ,  C10G25/00 ,  C10G45/60

CPC分类号： C10G45/44 ,  B01J29/126 ,  C10G2300/1059 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/06

摘要： The gas oil fraction hydrotreatment process of the invention is characterized by using a hydrorefined petroleum-based hydrocarbon oil with a sulfur content of 5-15 ppm by mass, a total aromatic content of 10-25% by volume and a boiling point range of 150-380° C. as the feed oil and subjecting the feed oil to hydrotreatment in the presence of a hydrogenation catalyst to obtain an ultralow sulfur and low aromatic gas oil fraction having a sulfur content of not greater than 1 ppm by mass and a total aromatic content of not greater than 1% by volume. This hydrotreatment process allows production of a “zero sulfur” and “zero aromatic” gas oil fraction in an efficient and reliable manner without provision of special operating conditions or equipment investment.

摘要翻译： 本发明的粗柴油馏分加氢处理方法的特征在于使用硫含量为5〜15质量ppm的加氢精制石油基烃油，总芳族化合物含量为10〜25体积％，沸点范围为150 -380℃作为原料油，并在进料油在氢化催化剂存在下进行加氢处理，得到硫含量不大于1质量ppm的超低硫和低芳烃馏分，总芳烃 含量不超过1％（体积）。 该加氢处理方法允许以有效和可靠的方式生产“零硫”和“零芳烃”瓦斯油馏分，而不需要特殊的操作条件或设备投资。

公开(公告)号：US06251262B1

公开(公告)日：2001-06-26

申请号：US09377087

申请日：1999-08-19

申请人： Shigeto Hatanaka ,  Osamu Sadakane ,  Hideshi Iki

发明人： Shigeto Hatanaka ,  Osamu Sadakane ,  Hideshi Iki

IPC分类号： C10G6504

CPC分类号： C10G65/04 ,  C10G2400/04

摘要： Diesel gas oil feedstock with 1-3 wt % sulfur can be hydrodesulfurized to a diesel gas oil with 0.05 wt % or less sulfur and a Saybolt color of +20 or higher, by defining a hydrogenation region in a fixed bed reactor with a first hydrogenation zone for dibenzothiophene, 1-, 2- and 3-methyldibenzothiophenes, a second hydrogenation zone for 4-methyldibenzothiophene and 4,6-dimethyldibenzothiophene and a third hydrogenation zone for thiols, sulfides and other sulfur-containing substances.

摘要翻译： 通过在具有第一氢化的固定床反应器中限定氢化区域，可以将具有1-3重量％硫的柴油瓦斯油原料加氢脱硫至具有0.05重量％或更少硫并且Saybolt颜色为+ 20以上的柴油瓦斯油 二苯并噻吩，1-，2-和3-甲基二苯并噻吩的区域，4-甲基二苯并噻吩和4,6-二甲基二苯并噻吩的第二氢化区和用于硫醇，硫化物和其它含硫物质的第三氢化区。

公开(公告)号：US07914593B2

公开(公告)日：2011-03-29

申请号：US12294110

申请日：2007-02-22

申请人： Masanori Hirose ,  Hideshi Iki

发明人： Masanori Hirose ,  Hideshi Iki

IPC分类号： C10L1/10

CPC分类号： C10G47/16 ,  C10G2/00 ,  C10G45/08 ,  C10G65/14 ,  C10G69/04 ,  C10G2300/1022 ,  C10G2300/1096 ,  C10G2300/301 ,  C10L1/04

摘要： The present invention provides a fuel composition capable of suppressing reduction of fuel consumption, maintaining the excellent exhaust gas properties of a Fischer-Tropsch synthetic oil. The fuel composition comprises a Fischer-Tropsch synthetic oil and a petroleum-based hydrocarbon mixture A having the following properties (1) to (5) in an amount of 10 to 30 percent by volume on the basis of the total mass of the composition: (1) 15° C. density: 800 Kg/cm3 or greater and 900 Kg/m3 or less; (2) 10 volume % distillation temperature (T10): 150° C. or higher and 200° C. or lower; (3) 97 volume % distillation temperature (T97): 270° C. or lower; (4) aromatic content: 40 percent by volume or more and 70 percent by volume or less; and (5) sulfur content: 30 ppm by mass or less.

摘要翻译： 本发明提供能够抑制燃料消耗的降低，维持费 - 托合成油优异的废气性能的燃料组合物。 燃料组合物包含基于组合物的总质量的10至30体积％的具有以下性质（1）至（5）的费 - 托合成油和石油基烃混合物A： （1）15℃密度：800Kg / cm 3以上900kg / m 3以下; （2）10体积％蒸馏温度（T10）：150℃以上且200℃以下; （3）97体积％蒸馏温度（T97）：270℃以下; （4）芳香族含量：40体积％以上且70体积％以下; 和（5）硫含量：30质量ppm以下。

公开(公告)号：US20100219102A1

公开(公告)日：2010-09-02

申请号：US12681787

申请日：2008-10-06

申请人： Shigeto Hatanaka ,  Koji Shimada ,  Hideshi Iki

发明人： Shigeto Hatanaka ,  Koji Shimada ,  Hideshi Iki

IPC分类号： C10G69/02

CPC分类号： C10G11/00 ,  C10G45/02 ,  C10G45/04 ,  C10G65/04 ,  C10G69/04 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/02 ,  C10L1/06

摘要： The production process of the invention comprises a first step of hydrodesulfurizing of catalytically-cracked gasoline so as to result in an olefin hydrogenation rate of no greater than 25 mol % in the catalytically-cracked gasoline, a total sulfur content of no greater than 20 ppm by weight based on the product oil weight, a sulfur content derived from thiophenes and benzothiophenes of no greater than 5 ppm by weight and a sulfur content derived from thiacyclopentanes of no greater than 0.1 ppm by weight, and a second step of further hydrodesulfurizing of the product oil obtained by the first step so as to result in a total of no greater than 30 mol % for the olefin hydrogenation rate in the first step and the olefin hydrogenation rate in the second step, a total sulfur content of no greater than 10 ppm by weight based on the product oil weight, and a sulfur content derived from thiols of no greater than 5 ppm by weight.

摘要翻译： 本发明的制造方法包括催化裂化汽油的加氢脱硫的第一步骤，使催化裂化汽油中的烯烃氢化率不大于25mol％，总硫含量不大于20ppm 基于产品油重量，来自噻吩和苯并噻吩的硫含量不大于5ppm重量，硫代环戊烷的硫含量不大于0.1ppm重量，第二步是进一步加氢脱硫 通过第一步获得的产物油，以使第一步中的烯烃氢化速率和第二步中的烯烃氢化速率总共不大于30mol％，总硫含量不大于10ppm 基于产品油重量，和硫醇的硫含量不大于5重量ppm。

公开(公告)号：US20090126264A1

公开(公告)日：2009-05-21

申请号：US12294110

申请日：2007-02-22

申请人： Masanori Hirose ,  Hideshi Iki

发明人： Masanori Hirose ,  Hideshi Iki

IPC分类号： C10L1/18

CPC分类号： C10G47/16 ,  C10G2/00 ,  C10G45/08 ,  C10G65/14 ,  C10G69/04 ,  C10G2300/1022 ,  C10G2300/1096 ,  C10G2300/301 ,  C10L1/04

摘要： The present invention provides a fuel composition capable of suppressing reduction of fuel consumption, maintaining the excellent exhaust gas properties of a Fischer-Tropsch synthetic oil. The fuel composition comprises a Fischer-Tropsch synthetic oil and a petroleum-based hydrocarbon mixture A having the following properties (1) to (5) in an amount of 10 to 30 percent by volume on the basis of the total mass of the composition: (1) 15° C. density: 800 Kg/cm3 or greater and 900 Kg/m3 or less; (2) 10 volume % distillation temperature (T10): 150° C. or higher and 200° C. or lower; (3) 97 volume % distillation temperature (T97): 270° C. or lower; (4) aromatic content: 40 percent by volume or more and 70 percent by volume or less; and (5) sulfur content: 30 ppm by mass or less.

摘要翻译： 本发明提供能够抑制燃料消耗的降低，维持费 - 托合成油优异的废气性能的燃料组合物。 燃料组合物包含基于组合物的总质量的10至30体积％的具有以下性质（1）至（5）的费 - 托合成油和石油基烃混合物A： （1）15℃密度：800Kg / cm 3以上900kg / m 3以下; （2）10体积％蒸馏温度（T10）：150℃以上且200℃以下; （3）97体积％蒸馏温度（T97）：270℃以下; （4）芳香族含量：40体积％以上且70体积％以下; 和（5）硫含量：30质量ppm以下。

公开(公告)号：US07776784B2

公开(公告)日：2010-08-17

申请号：US10888972

申请日：2004-07-13

申请人： Hideshi Iki ,  Shigeto Hatanaka ,  Eitaro Morita ,  Shinya Takahashi

发明人： Hideshi Iki ,  Shigeto Hatanaka ,  Eitaro Morita ,  Shinya Takahashi

IPC分类号： B01J23/00 ,  B01J21/00 ,  B01J20/00 ,  B01J29/00

CPC分类号： B01J37/0009 ,  B01J23/88 ,  B01J23/885 ,  B01J23/8871 ,  B01J23/8873 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0207 ,  B01J37/20 ,  C10G45/08

摘要： A hydrodesulfurization catalyst used for hydrodesulfurization of catalytically cracked gasoline comprises a support composed mainly of alumina modified with an oxide of at least one metal selected from the group consisting of iron, chromium, cobalt, nickel, copper, zinc, yttrium, scandium and lanthanoid-based metals, with at least one metal selected from the group consisting of Group 6A and Group 8 metals loaded as an active metal on the support. Hydrogenation of olefins generated as by-products during hydrodesulfurization of the catalytically cracked gasoline fraction, as an important constituent base of gasoline, can be adequately inhibited to maintain the octane number, while sufficiently reducing the sulfur content of the hydrodesulfurized catalytically cracked gasoline fraction.

摘要翻译： 用于催化裂化汽油加氢脱硫的加氢脱硫催化剂包括主要由氧化物组成的载体，该氧化铝用选自铁，铬，钴，镍，铜，锌，钇，钪和镧系元素中的至少一种金属的氧化物， 具有至少一种选自负载作为活性金属的6A族和第8族金属的金属在载体上。 作为汽油的重要成分基的催化裂化汽油馏分的加氢脱硫期间作为副产物生成的烯烃的氢化可以充分地抑制维持辛烷值，同时充分降低加氢脱硫催化裂化汽油馏分的硫含量。