公开(公告)号：US08003013B2

公开(公告)日：2011-08-23

申请号：US12233103

申请日：2008-09-18

申请人： Ronald J. Lewarchik ,  Scott Rier

发明人： Ronald J. Lewarchik ,  Scott Rier

IPC分类号： C09K3/00 ,  C23F11/00 ,  B60C1/00 ,  C08K5/06 ,  C08F283/00 ,  C08G59/14 ,  C08L63/00

CPC分类号： C09D5/084 ,  C08G2650/56 ,  C08K3/32 ,  C08L63/00 ,  C08L71/00 ,  C09D5/10 ,  C09D7/70 ,  Y02P20/582 ,  C08L2666/22

摘要： A waterborne thermoset cured anticorrosion formulation includes a water dispersed or emulsified phosphonated or water dispersed or emulsified sulfonated epoxy resin that is cured with a phenoxy resin having a polyhydroxyl ether backbone and terminal alpha glycol moieties. Water is present as a predominant volatile in which the epoxy resin and phenoxy resin are present in a weight ratio of epoxy resin to phenoxy resin of between 0.1 and 3:1. An aqueous curative is provided to induce cure between the epoxy resin and phenoxy resin, A corrosion inhibiting metal salt is also present having a salt anion of phosphate, biphosphate or tetraborate and a metal cation with the proviso that the metal cation formulation as a whole is devoid of chromium, lead, cobalt, and cadmium. Ideal curatives include aqueous aminoplast crosslinkers, aqueous unblocked isocyanates, aqueous blocked isocyanates, and a mixture thereof. With the inclusion of electrically conductive aluminum or zinc particulate the formulation is rendered corrosion resistant as well as electrically conductive to make an inventive coating amenable to powder coating.

摘要翻译： 水性热固性固化防腐制剂包括用具有多羟基醚骨架和末端α二醇部分的苯氧基树脂固化的水分散或乳化的膦酸化或水分散或乳化的磺化环氧树脂。 以环氧树脂与苯氧树脂的重量比为0.1〜3:1，存在环氧树脂和苯氧基树脂为主要挥发性物质。 提供水性固化剂以引发环氧树脂和苯氧树脂之间的固化。 还存在具有磷酸盐，二磷酸盐或四硼酸盐的盐阴离子和金属阳离子的腐蚀抑制金属盐，条件是金属阳离子配方作为一个整体没有铬，铅，钴和镉。 理想的固化剂包括水性氨基塑料交联剂，未封闭的水溶液异氰酸酯，水封闭的异氰酸酯及其混合物。 通过包含导电铝或锌颗粒，该制剂具有耐腐蚀性以及导电性，从而制成适合于粉末涂层的本发明的涂层。

公开(公告)号：US06485781B2

公开(公告)日：2002-11-26

申请号：US10087634

申请日：2002-03-01

申请人： Jack C. Allman ,  Ronald J. Lewarchik ,  Victor J. Scaricamazza

发明人： Jack C. Allman ,  Ronald J. Lewarchik ,  Victor J. Scaricamazza

IPC分类号： B05D112

CPC分类号： E04D3/30 ,  E04D1/18 ,  E04D1/22 ,  E04D3/34 ,  E04D5/04 ,  E04D2001/005

摘要： This invention relates to a method for embedding a multiplicity of discrete masses of material in a resinous coating on a sheet of metal in a coil coating system. The sheet is coated, the masses are embedded in the wet resinous coating, and the coating is dried in a one-pass system. The resinous coating and the embedded masses are preferably resistant to ultra-violet radiation. The wet resinous coating, therefore, is preferably a liquid fluorocarbon resin. The discrete masses comprise pigmented particulate minerals and resins in the form of granules, beads, vesiculated beads, pellets, flakes, platelets, cylinders, coating powders, and coating powder precursor chips. The minerals include glass, quartz, mica, pebbles, and ceramics. The particulate resins include polyesters, acrylics, nylons, polyurethanes, polycarbonates, solid fluorocarbon resins, and solid mixtures of a fluorocarbon resin and an acrylate or methacrylate polymer or copolymer. Sheet metal decorated in such a manner is useful as stock in the manufacture of metal roofing shingles simulating the appearance of traditional asphalt shingles.

摘要翻译： 本发明涉及一种用于在线圈涂覆系统中将多个离散质量的材料嵌入树脂涂层的金属片上的方法。 将该片材进行涂布，将质量嵌入湿树脂涂层中，并且涂层在一次通过系统中干燥。 树脂涂层和嵌入块优选耐紫外线辐射。 因此，湿树脂涂料优选为液体氟碳树脂。 离散的质量包括着色颗粒矿物和颗粒形式的颗粒，珠粒，泡状珠粒，颗粒，薄片，血小板，圆柱体，涂层粉末和涂层粉末前体碎片。 矿物包括玻璃，石英，云母，鹅卵石和陶瓷。 颗粒状树脂包括聚酯，丙烯酸树脂，尼龙，聚氨酯，聚碳酸酯，固体氟碳树脂，以及氟碳树脂和丙烯酸酯或甲基丙烯酸酯聚合物或共聚物的固体混合物。 以这种方式装饰的钣金在用于模拟传统沥青瓦的外观的金属屋顶瓦的制造中是有用的。

公开(公告)号：US5516549A

公开(公告)日：1996-05-14

申请号：US332283

申请日：1994-10-31

申请人： Kenneth E. Jasenof ,  Ronald J. Lewarchik ,  Douglas A. Stumpfl ,  David K. Black

发明人： Kenneth E. Jasenof ,  Ronald J. Lewarchik ,  Douglas A. Stumpfl ,  David K. Black

IPC分类号： B05D1/28 ,  B05D5/06 ,  B05D7/14 ,  B21C47/26 ,  C08G18/40 ,  C08G18/42 ,  C09D167/00 ,  C09D175/06 ,  B05D3/12 ,  B21C47/00

CPC分类号： C09D167/00 ,  B05D1/28 ,  B05D5/061 ,  B05D7/14 ,  B21C47/26 ,  C08G18/4045 ,  C08G18/4202 ,  C09D175/06 ,  Y10T428/24355 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31786

摘要： A polyester-based coating composition capable of forming a striated pattern on a metal surface at a film thickness less than half of that of PVC plastisol films is provided by a thixotropic composition having a thix index of from about 1.5 to about 3 and comprising a hydroxy-functional polyester, a thixotropy-inducing rheologic agent and curing agent. The striated coating is applied to sheet metal in a coil coating operation by introducing the composition into a paint pan of a coil coater, transferring said composition from said paint pan to an applicator roll by rotating a pick-up roll in contact with the composition and with said applicator roll; continuously withdrawing a sheet of metal from a coil thereof and coating said sheet by contacting it with the applicator roll; curing the coating on said sheet by passing the sheet through an oven at an elevated temperature; and continuously rewinding said sheet into a coil.

摘要翻译： 能够以薄膜厚度小于PVC增塑溶胶膜的一半的方式在金属表面上形成条纹图案的聚酯基涂料组合物由具有约1.5至约3的thix指数的触变组合物提供，并且包含羟基 功能性聚酯，触变性流变剂和固化剂。 通过将组合物引入线圈涂布机的油漆盘中将条纹涂层施加到金属板上，通过旋转与组合物接触的拾取辊将所述组合物从所述油漆盘转移到涂布辊，并且 与所述涂布辊; 从其线圈连续地取出金属片，并通过与涂布辊接触来涂覆所述片; 通过使片材在高温下通过烘箱来固化所述片材上的涂层; 并将所述片材连续地卷绕成线圈。

公开(公告)号：US5211989A

公开(公告)日：1993-05-18

申请号：US867585

申请日：1992-04-13

申请人： David D. Clinnin ,  Ronald J. Lewarchik ,  Dexter F. Sunderman

发明人： David D. Clinnin ,  Ronald J. Lewarchik ,  Dexter F. Sunderman

IPC分类号： B05D5/04 ,  B05D7/14 ,  C09D123/08

CPC分类号： B05D7/14 ,  B05D5/04 ,  C09D123/0876 ,  B05D2202/25 ,  B05D2401/20 ,  Y10T428/31699

摘要： The combination of an ethylene/acrylic acid copolymer and a water soluble amine salt of a fatty acid is useful as a hydrophilic coating for the surfaces of fins in a heat exchanger. The exchanger is more efficient because the coating prevents the blockage of air flow by beads of condensed water which would otherwise build up in the narrow spaces between the fins.

公开(公告)号：US4532021A

公开(公告)日：1985-07-30

申请号：US606527

申请日：1984-05-07

申请人： Edward J. Murphy ,  Ronald J. Lewarchik ,  Jeffrey W. Thompson

发明人： Edward J. Murphy ,  Ronald J. Lewarchik ,  Jeffrey W. Thompson

IPC分类号： C09D4/06 ,  C08J3/28 ,  C08L31/08

CPC分类号： C09D4/06

摘要： Ultraviolet-curable liquid coating compositions are disclosed in which improved adhesion to metal and plastic surfaces is obtained. This improvement is obtained by using, in admixture: (1) from 10% to about 60% of total resin solids of an organic solvent-soluble solution copolymer of monoethylenically unsaturated monomers including from 2.5% to 10% of tertiary amine monomer which is an aminoalkyl ester or amide of an alpha, beta-monoethylenic monocarboxylic acid in which the alkyl group contains 2-4 carbon atoms; and (2) from 40% to 90% of total resin solids of radiation-curable ethylenically unsaturated liquid. The coating composition includes photoinitiators and/or photosensitizers rendering the composition sensitive to ultraviolet light, and the components are present in solution in at least about 10% of inert volatile organic solvent.

摘要翻译： 公开了可获得改善的对金属和塑料表面的粘附性的紫外线固化液体涂料组合物。 这种改进通过以下方式获得：（1）总树脂固体的10％至约60％的单烯属不饱和单体的有机溶剂可溶性溶液共聚物，包括2.5％至10％的叔胺单体，其为 其中烷基含有2-4个碳原子的α，β-单烯基单羧酸的氨基烷基酯或酰胺; 和（2）可辐射固化的烯属不饱和液体的总树脂固体的40％至90％。 涂料组合物包括光引发剂和/或光敏剂，使组合物对紫外光敏感，并且组分在溶液中存在于至少约10％的惰性挥发性有机溶剂中。

公开(公告)号：US4252935A

公开(公告)日：1981-02-24

申请号：US62589

申请日：1979-07-31

申请人： Carl C. Anderson ,  William J. Birkmeyer ,  Roger M. Christenson ,  Rostyslaw Dowbenko ,  Ronald J. Lewarchik

发明人： Carl C. Anderson ,  William J. Birkmeyer ,  Roger M. Christenson ,  Rostyslaw Dowbenko ,  Ronald J. Lewarchik

IPC分类号： C08G59/00 ,  C08G18/48 ,  C08G18/58 ,  C08G18/64 ,  C08G59/06 ,  C08G59/16 ,  C08G59/24 ,  C08G59/62 ,  C09D163/00 ,  C09D175/00

CPC分类号： C08G59/625 ,  C08G18/4875 ,  C08G18/58 ,  C08G18/581 ,  C08G18/6407 ,  C08G59/1455 ,  C08G59/24 ,  C09D163/00

摘要： Esters of glycidyl polyethers of saturated phenols are especially useful in coating compositions having a low organic solvent content. The esters are the reaction products of from about 0.5 to about 1.5 equivalents of a saturated monocarboxylic acid with each epoxy group in a diglycidyl polyether of phenols where the aromatic rings of the phenols are saturated.

摘要翻译： 饱和酚的缩水甘油聚醚的酯特别可用于具有低有机溶剂含量的涂料组合物。 酯是在酚的二环氧甘油基聚醚中酚基饱和的约0.5至约1.5当量的饱和一元羧酸与每个环氧基的反应产物。

公开(公告)号：US4228294A

公开(公告)日：1980-10-14

申请号：US950105

申请日：1978-10-10

申请人： Ronald J. Lewarchik ,  J. Alden Erikson ,  William J. Birkmeyer

发明人： Ronald J. Lewarchik ,  J. Alden Erikson ,  William J. Birkmeyer

IPC分类号： C07D233/72 ,  C07D233/74 ,  C07D233/78 ,  C08G18/38 ,  C08G59/16 ,  C09D163/00

CPC分类号： C08G59/1455 ,  C07D233/72 ,  C07D233/78 ,  C08G18/3848 ,  C09D163/00

摘要： Esters of imidazolidinedione-based diepoxides are especially useful in coating compositions having a low organic solvent content. The esters have the structure ##STR1## wherein R and R' are independently hydrogen or hydrocarbon groups having from 1 to 8 carbon atoms, one X is hydrogen and the other X is ##STR2## one Y is hydrogen and the other Y is ##STR3## where the R" groups are independently saturated hydrocarbon groups having from 1 to 17 carbon atoms or unsaturated hydrocarbon groups having from 4 to 17 carbon atoms and n is 0 or 1.

摘要翻译： 基于咪唑烷二酮的二环氧化物的酯特别可用于具有低有机溶剂含量的涂料组合物。 所述酯具有结构单元，其中R和R'独立地是氢或具有1至8个碳原子的烃基，一个X是氢，另一个X是一个Y是氢， 其它Y是，其中R“基团是具有1至17个碳原子的饱和烃基或具有4至17个碳原子的不饱和烃基，n是0或1。

公开(公告)号：US4218355A

公开(公告)日：1980-08-19

申请号：US926690

申请日：1978-07-21

申请人： Wen-Hsuan Chang ,  John R. Peffer ,  Ronald J. Lewarchik

发明人： Wen-Hsuan Chang ,  John R. Peffer ,  Ronald J. Lewarchik

IPC分类号： C09D161/20 ,  C09D167/00 ,  C08L61/28

CPC分类号： C09D167/00 ,  C09D161/20

摘要： Low organic solvent-containing coating compositions are prepared by blending (i) an ester-containing polyol, having a number average molecular weight of from about 140 to about 700, a hydroxyl value of from about 160 to about 1100 and a viscosity of less than about 1200 poises, which is derived from an aromatic or alicyclic monobasic acid and, optionally, a minor proportion of a polybasic acid and a polyol having an average hydroxyl functionality of from about 2.1 to about 5.0 with (ii) an aminealdehyde crosslinking agent. Particularly valuable coating compositions which can be cured at relatively low temperatures are obtained by incorporating a cure accelerating catalyst into the composition. The compositions aid in environmental pollution control and form films having good adhesion, flexibility, hardness, stain resistance, detergent resistance, solvent resistance and durability.

摘要翻译： 低含有机溶剂的涂料组合物通过将（i）数均分子量为约140至约700的含酯多元醇，约160至约1100的羟值和低于 约1200泊，其衍生自芳族或脂环族一元酸，以及任选地少量的多元酸和具有约2.1至约5.0的平均羟基官能度的多元醇与（ⅱ）胺醛交联剂。 可以在相对低的温度下固化的特别有价值的涂料组合物通过将固化促进催化剂加入到组合物中来获得。 该组合物有助于环境污染控制，并形成具有良好粘附性，柔韧性，硬度，耐污染性，耐洗涤性，耐溶剂性和耐久性的膜。

公开(公告)号：US20100092664A1

公开(公告)日：2010-04-15

申请号：US12249406

申请日：2008-10-10

申请人： Simon Palushaj ,  Ronald J. Lewarchik

发明人： Simon Palushaj ,  Ronald J. Lewarchik

IPC分类号： B05D5/00 ,  B05D3/02 ,  C08L33/02

CPC分类号： C04B41/71 ,  B05D5/00 ,  B05D7/14 ,  B05D7/52 ,  B05D2203/30 ,  C04B41/009 ,  C04B41/52 ,  C04B2111/27 ,  C08F222/1006 ,  C09D133/14 ,  C04B41/483 ,  C04B41/524 ,  C04B28/02

摘要： A self curing, two component penetrating densifying sealant and coating composition that imparts protection and reinforcement to porous substrates, such as wood and concrete, as well as non porous substrates, such a metal surfaces, whether or not corroded, and concrete surfaces.

摘要翻译： 自固化，双组分渗透致密化密封剂和涂料组合物，对多孔基材（如木材和混凝土）以及非多孔基材（无论是否腐蚀的金属表面）和混凝土表面都给予保护和加固。

公开(公告)号：US06602552B1

公开(公告)日：2003-08-05

申请号：US09712496

申请日：2000-11-14

申请人： Edward J. Daraskevich ,  Ronald J. Lewarchik ,  Mark P. Slawikowski ,  Sebastian E. McCann

发明人： Edward J. Daraskevich ,  Ronald J. Lewarchik ,  Mark P. Slawikowski ,  Sebastian E. McCann

IPC分类号： B05D302

CPC分类号： C09D175/04 ,  C08G18/222 ,  C09D167/00 ,  C08L2666/08

摘要： A method for a low temperature cure for a coating composition comprising: applying to a substrate a low temperature curing coating composition consisting essentially of a film forming component consisting essentially of a non-carbamate functional polymeric component selected from the group consisting of polyester, silicone modified polyester, polyurethane, acrylic, alkyd, epoxy, polyamide, phenolic and polysilane polymers and mixtures thereof; a crosslinking component to crosslink the non-carbamate functional polymeric component; a catalyst selected from the group consisting of Lewis acids, perflouracetic acid, methane sulfonic acid catalyst and mixtures thereof; and additives selected from the group consisting of solvents, flow control agents, pigments, flexibilizing resins, surfactants, waxes, wetting agents, plasticizers, anti-oxidants, UV light absorbers, and a mixture thereof, and subjecting the coated substrate to a cure temperature of between 280° F. and 450° F., for a time sufficient to cure the coating.

摘要翻译： 一种用于涂料组合物的低温固化的方法，包括：向基材施加低温固化涂料组合物，所述低温固化涂料组合物基本上由主要由非氨基甲酸酯官能聚合物组分组成的成膜组分组成，所述非氨基甲酸酯官能聚合物组分选自聚酯，硅氧烷改性 聚酯，聚氨酯，丙烯酸，醇酸树脂，环氧树脂，聚酰胺，酚醛和聚硅烷聚合物及其混合物; 用于交联非氨基甲酸酯官能聚合物组分的交联组分; 选自路易斯酸，全氟乙酸，甲磺酸催化剂及其混合物的催化剂; 和选自溶剂，流动控制剂，颜料，柔性树脂，表面活性剂，蜡，润湿剂，增塑剂，抗氧化剂，UV光吸收剂及其混合物的添加剂的组合物，以及将涂覆的基材经受固化温度 在280°F和450°F之间，足以固化涂层的时间。