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11.发明授权Copper oxide-aluminum oxide-magnesium oxide catalysts for conversion of carbon monoxide 失效用于转化一氧化碳的氧化铜 - 氧化铝 - 氧化镁催化剂
公开(公告)号：US5387408A
公开(公告)日：1995-02-07
申请号：US992496
申请日：1992-12-17
申请人： Michael Schneider , Karl Kochloefl , Gerd Maletz
发明人： Michael Schneider , Karl Kochloefl , Gerd Maletz
摘要： A catalyst for the conversion of carbon monoxide which before reductive activation, has the chemical composition which corresponds to the formulaCu.sub.0.04-6 AlMg.sub.0.1-10.sup.O.sub.X,wherein x denotes the number of oxygen atoms required to maintain electroneutrality per formula unit; and wherein the intensity ratio between the x-ray diffraction lines of the spinels CuAl.sub.2 O.sub.4 and MgAl.sub.2 O.sub.4 at d=0.244 nm and copper oxide at d=0.232 nm, determined as the ratio of reflex heights is about 0.05 to 0.5.
摘要翻译： 用于转化一氧化碳的催化剂，其在还原活化之前具有对应于式Cu0.04-6AlMg0.1-10OX的化学组成，其中x表示维持每个式单元的电中性所需的氧原子数; 并且其中d = 0.244nm处的尖晶石CuAl 2 O 4和MgAl 2 O 4的x射线衍射线与d = 0.232nm处的氧化铜之间的强度比确定为反射高度的比率为约0.05至0.5。
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12.发明授权Catalyst for the selective hydrogenation of polyunsaturated hydrocarbons and process for preparing the catalyst 失效用于多不饱和烃的选择性氢化的催化剂和制备催化剂的方法
公开(公告)号：US4906602A
公开(公告)日：1990-03-06
申请号：US261674
申请日：1988-10-24
CPC分类号： B01J23/66 , B01J23/8926
摘要： A catalyst for the selective hydrogenation of polyunsaturated hydrocarbons which contain entirely or predominantly more than five carbon atoms, containing palladium with a promotor on a metal oxide support. The promotor is a metal from the subgroup IB of the periodic system (preferably silver) and the metal oxide support (TiO.sub.2 optionally mixed with CeO.sub.2 and/or ZrO.sub.2) is macroporous, the pore volume being about 0.2 to 0.4, preferably about 0.25 to 0.30 ml per g of carrier and the proportion of the macropores having a diameter of more than 14 nm being at least 65%.
摘要翻译： 用于选择氢化多不饱和烃的催化剂，其含有完全或主要多于五个碳原子，在金属氧化物载体上含有启动子的钯。 促进剂是来自周期系统（优选为银）的亚组IB的金属，并且金属氧化物载体（任选与CeO 2和/或ZrO 2混合的TiO 2）是大孔的，孔体积为约0.2至0.4，优选约0.25至0.30 ml，并且直径大于14nm的大孔的比例为至少65％。
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公开(公告)号：US4720476A
公开(公告)日：1988-01-19
申请号：US895405
申请日：1986-08-11
IPC分类号： B01J21/16 , B01D53/56 , B01D53/86 , B01D53/94 , B01J8/00 , B01J20/12 , B01J21/12 , B01J23/10 , B01J23/16 , B01J23/22 , B01J23/24 , B01J37/00 , C01B21/20
CPC分类号： B01J21/16 , B01D53/8628 , B01J23/22 , B01J23/28 , B01J23/30 , B01J35/1066
摘要： A catalyst for decreasing the content of nitrogen oxides in flue gases. The catalyst contains at least one of the metals titanium, zirconium, vanadium, tungsten, molybdenum, or cerium in the form of one or more of their oxides combined with a silicate with a three-layer structure (three-layer silicate) comprising acid-activated pyrophyllite. The crystalline layer structure of the acid-activated pyrophyllite is essentially retained, while being not yet X-ray amorphous. The acid activation increases the BET surface area at least 15% and preferably at least 50% in terms of the BET surface area of the pyrophyllite before acid activation. The atomic ratio of the silicon in the acid-activated pyrophyllite to the metal in the oxide is from 0.2 and 50 and preferably from 0.4 to 25.
摘要翻译： 用于降低烟道气中氮氧化物含量的催化剂。 催化剂含有至少一种金属钛，锆，钒，钨，钼或铈中的一种或多种氧化物与具有三层结构（三层硅酸盐）的硅酸盐形式， 活性叶蜡石。 酸活化的叶蜡石的结晶层结构基本上保持不变，而尚未成为X射线无定形。 在酸活化之前，酸活化使得BET表面积在叶蜡石的BET表面积方面增加至少15％，优选至少50％。 酸活化的叶蜡石中的硅与氧化物中的金属的原子比为0.2〜50，优选为0.4〜25。
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公开(公告)号：US07229941B2
公开(公告)日：2007-06-12
申请号：US10725313
申请日：2003-12-01
申请人： Götz Burgfels , Karl Kochloefl , Jürgen Ladebeck , Michael Schneider , Friedrich Schmidt , Hans-Jürgen Wernicke , Josef Schönlinner
发明人： Götz Burgfels , Karl Kochloefl , Jürgen Ladebeck , Michael Schneider , Friedrich Schmidt , Hans-Jürgen Wernicke , Josef Schönlinner
IPC分类号： B01J29/06
CPC分类号： B01J29/40 , B01J35/023 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/1066 , B01J35/108 , B01J37/0009 , C10G3/49 , C10G2400/20
摘要： A catalyst is described based on crystalline aluminosilicates of the pentasil type, characterized in that it is constructed from primary crystallites with an average diameter of at least 0.01 μm and less than 0.1 μm, that are combined to at least 20% to agglomerates of 5 to 500 μm, in which the primary crystallites or agglomerates are bonded together by finely divided aluminum oxide, that its BET surface is 300 to 600 m2/g and its pore volume (determined according to mercury porosimetry) is 0.3 to 0.8 cm3/g, that it is present in H form and that the amount of finely divided aluminum oxide binder is 10 to 40 wt. %, referred to the total weight of the aluminosilicate, in which the finely divided aluminum oxide binder is used in the reaction charge as peptizable aluminum oxide hydrate, sodium aluminate being used as aluminum and alkali source, and primary synthesis of the crystalline aluminosilicate occurs without addition of acid. A method is also described for production of such a catalyst and its preferred applications.
摘要翻译： 基于pentasil类型的结晶硅铝酸盐描述催化剂，其特征在于其由平均直径为至少0.01μm和小于0.1μm的初级微晶构成，其与至少20％的附聚物组合为5至 500微米，其中初级微晶或团聚体通过细碎的氧化铝结合在一起，其BET表面积为300-600m 2 / g，其孔体积（根据水银孔率法测定）为 0.3〜0.8cm 3 / g，以H形式存在，细分的氧化铝粘合剂的量为10〜40wt。 ％，以铝硅酸盐的总重量计，其中细分的氧化铝粘合剂用作反应电荷，作为可溶解的氧化铝水合物，铝酸钠用作铝和碱源，并且结晶硅铝酸盐的初步合成发生在没有 加酸。 还描述了用于生产这种催化剂及其优选应用的方法。
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公开(公告)号：US5403962A
公开(公告)日：1995-04-04
申请号：US251625
申请日：1994-05-31
申请人： Michael Schneider , Karl Kochloefl , Gerd Maletz
发明人： Michael Schneider , Karl Kochloefl , Gerd Maletz
IPC分类号： B01J23/889 , C07B61/00 , C07C29/149 , C07C31/02 , C07C31/125 , C07C29/141 , C07C29/145
CPC分类号： B01J23/8892 , C07C29/149
摘要： The invention describes a chromium-free catalyst for hydrogenation of organic compounds, especially organic compounds containing the carbonyl function, such as aldehydes, ketones, or carboxylic acids or their esters, to the corresponding alcohols wherein the catalysts is characterized by the following features:its oxide form corresponds to the compositionCu.sub.a Al.sub.b Zr.sub.c Mn.sub.d O.sub.xwherein the following relations apply:for the first embodiment:a>O; b>O; c.gtoreq.O; d>O; a>b/2; b>a/4; a>c; a>d;and for the second embodiment:a>O; b=a/40 to a/4; c.gtoreq.O; d>O; a>c; a=0.5 d to 0.95 dand x is the number of oxygen ions needed per formula unit for electrical neutrality.
摘要翻译： 本发明描述了一种无铬催化剂，用于将有机化合物，特别是含有羰基官能团的有机化合物如醛，酮或羧酸或其酯氢化成相应的醇，其中催化剂的特征在于以下特征：其 氧化物形式对应于组成CuaAlbZrcMndOx，其中以下关系适用：对于第一实施方案：a> O; b> O; c> / = O; d> O; a> b / 2; b> a / 4; a> c a> d 并且对于第二实施例：a> O; b = a / 40到a / 4; c> / = O; d> O; a> c a = 0.5 d至0.95 d，x为电中性所需的每个配方单位所需的氧离子数。
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公开(公告)号：US5063187A
公开(公告)日：1991-11-05
申请号：US436477
申请日：1989-11-14
申请人： Gotz Burgfels , Karl Kochloefl , Jurgen Ladebeck , Friedrich Schmidt , Michael Schneider , Hans J. Wernicke
发明人： Gotz Burgfels , Karl Kochloefl , Jurgen Ladebeck , Friedrich Schmidt , Michael Schneider , Hans J. Wernicke
CPC分类号： B01J29/40 , B01J35/023 , C07C1/20 , C07C2529/40 , Y02P30/20
摘要： A catalyst based on crystalline aluminosilicates of the pentasil type, having an Si/Al atomic ratio of at least 10, has the structure of primary crystallites of a mean diameter of at least 0.1 micron and at most 0.9 micron, which crystallites are partially combined into agglomerates the primary crystallites and/or agglomerates being mutually joined by finely disperse alumina obtainable by hydrolysis of aluminum-organic compounds, the BET surface area of the catalyst being 300 to 600 m.sup.2 /g and its pore volume (determined by mercury porosimetry) being 0.3 to 0.8 cm.sup.3 /g.
摘要翻译： 具有Si / Al原子比至少为10的pentasil型结晶硅铝酸盐的催化剂具有平均直径为至少0.1微米且至多0.9微米的初级微晶的结构，该微晶部分组合成 通过铝 - 有机化合物的水解得到的细分散氧化铝相互连接的初级微晶和/或附聚物，催化剂的BET表面积为300〜600m 2 / g，孔体积（通过水银孔率法测定）为0.3 至0.8cm 3 / g。
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公开(公告)号：US4792439A
公开(公告)日：1988-12-20
申请号：US47797
申请日：1987-05-07
IPC分类号： B01J21/16 , B01D53/56 , B01D53/86 , B01D53/94 , B01J8/00 , B01J20/12 , B01J21/12 , B01J23/10 , B01J23/16 , B01J23/22 , B01J23/24 , B01J37/00 , C01B21/20 , C01B21/00
CPC分类号： B01J21/16 , B01D53/8628 , B01J23/22 , B01J23/28 , B01J23/30 , B01J35/1066
摘要： A process for decreasing the content of nitrogen oxides in flue gases. The process comprising contacting the flue gases with a catalyst. The catalyst contains at least one of the metals titanium, zirconium, vanadium, tungsten, molybdenum, or cerium in the form of one or more of their oxides combined with a silicate with a layer structure (layer silicate) comprising acid-activated kaolin. The crystalline layer structure of the acid-activated kaolin is essentially retained, while being not yet X-ray amorphous. The acid activation increases the BET surface area at least 15% and preferably at least 50% in terms of the BET surface area of the kaolin before acid activation. The atomic ratio of the silicon in the acid-activated kaolin to the metal in the oxide is from 0.2 and 50 and preferably from 0.4 to 25.
摘要翻译： 降低烟道气中氮氧化物含量的方法。 该方法包括使烟道气与催化剂接触。 催化剂含有至少一种金属钛，锆，钒，钨，钼或铈，其中一种或多种氧化物与具有含酸活化高岭土的层结构（层状硅酸盐）的硅酸盐结合。 酸活化的高岭土的结晶层结构基本上保持不变，同时还没有X射线无定形。 在酸活化之前，酸活化使得BET表面积以高岭土的BET表面积计增加至少15％，优选至少50％。 酸活化高岭土中的硅与氧化物中的金属的原子比为0.2〜50，优选为0.4〜25。
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公开(公告)号：US4692425A
公开(公告)日：1987-09-08
申请号：US880168
申请日：1986-06-30
CPC分类号： B01J37/0009 , B01D53/8628 , B01J21/16
摘要： A catalyst for lowering the nitrogen oxide content of flue gases contains as the active component an acid-activated layer silicate, in particular of the smectite type, whose layered structure is to a large extent intact after the acid treatment.
摘要翻译： 用于降低烟道气的氮氧化物含量的催化剂含有作为活性组分的酸活化层硅酸盐，特别是绿土类型的硅酸盐，其层状结构在酸处理后在很大程度上是完整的。
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19.发明授权公开(公告)号：US09491266B2
公开(公告)日：2016-11-08
申请号：US13692646
申请日：2012-12-03
申请人： Karsten Bohlmann , Steffen Huester , Sven Kobler-Morris , Holger Koser , Michael Schneider , Thomas Alexander Ritter , Eric Westenberger
发明人： Karsten Bohlmann , Steffen Huester , Sven Kobler-Morris , Holger Koser , Michael Schneider , Thomas Alexander Ritter , Eric Westenberger
摘要： A business application backend system, such as an Advanced Business Application Programming backend can receive and respond to representational state transfer (RESTful) service requests via both HTTP and Remote Function Call (RFC) protocols. In particular, the backend system extracts the RESTful service requests and fulfills the extracted requests using a protocol-independent resource controller. Related apparatus, systems, techniques and articles are also described.
摘要翻译： 业务应用后端系统（如高级业务应用程序编程后端）可以通过HTTP和远程函数调用（RFC）协议接收和响应表示状态转移（RESTful）服务请求。 特别地，后端系统提取RESTful服务请求，并使用与协议无关的资源控制器来实现提取的请求。 还描述了相关设备，系统，技术和物品。
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公开(公告)号：US20160087999A1
公开(公告)日：2016-03-24
申请号：US14494723
申请日：2014-09-24
申请人： Michael Schneider , Paul Gartside , David Oxley , Ramon Peypoch
发明人： Michael Schneider , Paul Gartside , David Oxley , Ramon Peypoch
IPC分类号： H04L29/06
CPC分类号： H04L63/1408 , G06F21/562
摘要： Particular embodiments described herein provide for an electronic device that can be configured to receive data in a data flow, extract a data visa from the data flow, wherein the data visa is related to the data, and determine a reputation of the data from the data visa. The data visa can include reputation determination information obtained by previous network elements in the data flow. In addition, the electronic device can update the data visa, and communicate the updated data visa and data to a next network element in the data flow.
摘要翻译： 本文描述的特定实施例提供了一种电子设备，其可以被配置为在数据流中接收数据，从数据流提取数据签证，其中数据签证与数据相关，并且从数据中确定数据的信誉 签证。 数据签证可以包括由数据流中的先前网络元素获得的信誉确定信息。 此外，电子设备可以更新数据签证，并将更新的数据签证和数据传送到数据流中的下一个网络元素。
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