Polyazole-based polymer films
    14.
    发明授权
    Polyazole-based polymer films 失效
    聚唑类聚合物膜

    公开(公告)号:US07485227B2

    公开(公告)日:2009-02-03

    申请号:US11512803

    申请日:2006-08-30

    摘要: The present invention relates to polymer films and a polymer membrane having an improved mechanical property profile produced therefrom, to a process for producing them and to their use.The polymer films, polymer membranes and separation membranes of the invention are produced from selected polymer raw materials and have excellent chemical, thermal. and mechanical properties as are required for use as polymer electrolyte membranes (PEMs) in PEM fuel cells or in apparatuses for the filtration and/or separation of gases and/or liquids or for reverse osmosis.

    摘要翻译: 本发明涉及聚合物膜和具有改进的机械性能特性曲线的聚合物膜,制造方法及其用途。 本发明的聚合物膜,聚合物膜和分离膜由选择的聚合物原料生产并且具有优异的化学,热学性质。 以及用作PEM燃料电池中的聚合物电解质膜(PEM)或用于气体和/或液体的过滤和/或分离或用于反渗透的装置中所需的机械性能。

    Proton-conducting polymer membrane comprising a polymer with sulphonic acid groups and use thereof in fuel cells
    16.
    发明授权
    Proton-conducting polymer membrane comprising a polymer with sulphonic acid groups and use thereof in fuel cells 失效
    导电聚合物膜,其包含具有磺酸基团的聚合物并且其在燃料电池中的用途

    公开(公告)号:US07332530B2

    公开(公告)日:2008-02-19

    申请号:US10523373

    申请日:2003-07-31

    IPC分类号: C08J5/22 H01M8/10

    摘要: The present invention relates to a proton-conducting polymer membrane comprising polymers containing sulfonic acid groups, obtainable by a process comprising the steps of A) mixing vinyl-containing sulfonic acid with one or more aromatic tetraamino compounds with one or more aromatic carboxylic acids, their esters, their acid halides or their acid anhydrides, containing at least two acid groups per carboxylic acid monomer, and/or mixing vinyl-containing sulfonic acid with one or more aromatic and/or heteroaromatic diaminocarboxylic acids, their esters, their acid halides or their acid anhydrides, B) heating the mixture obtainable according to step A) under inert gas to temperatures of up to 350° C., to form polyazole polymers, C) applying a layer to a support, using the mixture according to step A) and/or B), D) polymerizing the vinyl-containing sulfonic acid present in the sheetlike structure obtainable according to step C).

    摘要翻译: 本发明涉及包含含有磺酸基团的聚合物的质子传导性聚合物膜,该方法包括以下步骤:A)将含乙烯基的磺酸与一种或多种芳族四氨基化合物与一种或多种芳族羧酸混合, 酯,它们的酰卤或其酸酐,每个羧酸单体含有至少两个酸基,和/或将含乙烯基的磺酸与一种或多种芳族和/或杂芳族二氨基羧酸,它们的酯,它们的酰卤或它们的酰卤混合 酸酐,B)将惰性气体中可获得的混合物加热至高达350℃的温度,以形成聚唑聚合物,C)使用根据步骤A)和 /或B),D)聚合存在于根据步骤C)获得的片状结构中的含乙烯基磺酸。

    POLYMER MEMBRANE, METHOD FOR THE PRODUCTION AND USE THEREOF
    20.
    发明申请
    POLYMER MEMBRANE, METHOD FOR THE PRODUCTION AND USE THEREOF 失效
    聚合物膜,其生产和使用方法

    公开(公告)号:US20100164148A1

    公开(公告)日:2010-07-01

    申请号:US12720026

    申请日:2010-03-09

    IPC分类号: B29C39/14

    摘要: The present invention relates to an acid-doped polymer membrane based on polyazoles. The acid-doped polymer membrane can be used in a variety of applications because of its excellent mechanical properties and is useful as polymer electrolyte membrane (PEM) in PEM fuel cells. A doped polymer membrane based on polyazoles is obtained by a process comprising the steps of: A) casting a film using a solution of polymers based on polyazoles in a polar, aprotic organic solvent; B) drying the film formed in step A) until it is self-supporting; C) treating the film obtained in step B) with a treatment liquid at a temperature in the range from room temperature to the boiling point of the treatment liquid; D) drying and/or dabbing the film treated according to step C) to remove the treatment liquid from step C); and E) doping the film treated according to step D) with a doping agent.

    摘要翻译: 本发明涉及基于聚唑的酸掺杂聚合物膜。 酸掺杂聚合物膜由于其优异的机械性能可用于各种应用,并且可用作PEM燃料电池中的聚合物电解质膜(PEM)。 通过包括以下步骤的方法获得基于多唑的掺杂聚合物膜:A)使用在极性非质子有机溶剂中基于聚唑的聚合物溶液浇铸膜; B)干燥步骤A)中形成的膜,直到其自支撑; C)在处理液的室温至沸点范围内的温度下用处理液处理步骤B)中得到的膜; D)干燥和/或吸收根据步骤C)处理的膜以从步骤C)中除去处理液; 和E)用掺杂剂掺杂根据步骤D)处理的膜。