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公开(公告)号：US5304693A
公开(公告)日：1994-04-19
申请号：US751008
申请日：1991-08-28
CPC分类号： B01D53/02 , B01D53/8665
摘要： A process for the elimination of mercury from an overall steam cracking installation, characterized in that regeneration is terminated by the injection of regeneration gas onto an active demercurizing mass, such that there is substantially no trace of mercury in the air or liquids leaving the installation. The process involves the use of three demercurizing masses, namely two upstream of the installation which are in series and one downstream, which latter is demercurized by at least one of the upstream masses. The use more particularly applies to the depollution of steam cracking installations which are already polluted by mercury.
摘要翻译： 一种从整体蒸汽裂解装置中消除汞的方法，其特征在于再生通过将再生气体注入到活性脱水剂块而终止，使得离开设备的空气或液体基本上没有痕量的汞。 该过程涉及使用三个脱水质量块，即串联的两个上游设备和一个下游管道，后者由至少一个上游质量块排出。 这种用途更特别适用于已经被汞污染的蒸汽裂解装置的污染。
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12.发明授权Selective hydrogenation of diolefins in steam cracking petrol on catalysts based on a support metal in which an organic compound has been incorporated prior to loading into the reactor 失效在蒸汽裂解汽油中的二烯烃选择性加氢在催化剂基础上的载体金属中，其中有机化合物在装入反应器之前被引入
公开(公告)号：US5417844A
公开(公告)日：1995-05-23
申请号：US978074
申请日：1992-11-18
CPC分类号： B01J37/20 , B01J23/755 , C10G45/36
摘要： The invention relates to a process for the selective hydrogenation of diolefins in steam cracking petrol in the presence of a nickel catalyst and is characterized in that prior to the use of the catalyst, a suphur-containing organic compound is incorporated into the catalyst outside of the reactor.
摘要翻译： 本发明涉及一种在镍催化剂存在下在蒸汽裂解汽油中选择性氢化二烯烃的方法，其特征在于在使用催化剂之前，将含Suprur的有机化合物引入催化剂外 反应堆。
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13.发明授权Process for the production of an olefin-free tert, amyl alkyl ether-rich fraction and a n-pentane rich paraffin fraction 失效生产无烯烃的富含叔戊基烷基醚的馏分和富含正戊烷的石蜡馏分的方法
公开(公告)号：US5352846A
公开(公告)日：1994-10-04
申请号：US142107
申请日：1993-10-28
IPC分类号： B01J23/40 , C07B61/00 , C07C20060101 , C07C5/03 , C07C7/148 , C07C9/15 , C07C41/05 , C07C41/20 , C07C41/42 , C07C43/04 , C10G20060101 , C10G69/02 , C07C41/06
CPC分类号： C10G69/02
摘要： The simultaneous production of an olefin-free, tert.amyl alkyl, ether-rich fraction an n-pentane-rich paraffin fraction, wherein a charge based on isopentenes is hydrogenated (1) under appropriate conditions to bring about a distribution of the methyl butenes close to thermodynamic equilibrium and then the hydrogenation effluent is treated in an etherification zone (2).
摘要翻译： 同时生产无烯烃，富烷基的富醚馏分，富含正戊烷的石蜡馏分，其中基于异戊烯的电荷在适当的条件下氢化（1）以产生甲基丁烯的分布 接近热力学平衡，然后氢化流出物在醚化区（2）中处理。
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14.发明授权Method for removing arsenic and phosphorus contained in liquid hydrocarbon cuts, nickel based retaining material 失效用于除去液体烃馏分中所含的砷和磷的方法，镍基保持材料
公开(公告)号：US5268091A
公开(公告)日：1993-12-07
申请号：US700120
申请日：1991-05-10
CPC分类号： C10G25/00
摘要： A method for removing arsenic and/or phosphorus from a petroleum charge with a retaining material comprising:(a) from 60 to 97% of a carrier containing, by weight, from 1.5 to 60% of oxide of at least one metal A selected from the group consisting of Mg, Ca, Sr, Ba, Mn, Fe, Co, Ni, Cu and Zn, dissolved in alumina in the form of aluminate, and from 40 to 98.5% of at least one alumina,(b) from 3 to 40% of nickel oxide, with which the carrier is impregnated by exchange or depositing, and(c) possibly from 0 to 1% of platinum and/or palladium oxide with which the carrier is impregnated.
摘要翻译： 一种从具有保留材料的石油装料中除去砷和/或磷的方法，包括：（a）60至97％的载体，其含有至少一种选自以下的金属的氧化物的1.5至60重量％ 以铝酸盐形式溶解在氧化铝中的Mg，Ca，Sr，Ba，Mn，Fe，Co，Ni，Cu和Zn组成的组和40至98.5％的至少一种氧化铝，（b）3 至40％的氧化镍，载体通过其交换或沉积而浸渍，和（c）可能含有0至1％的载体浸渍的铂和/或氧化钯。
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公开(公告)号：US5534658A
公开(公告)日：1996-07-09
申请号：US477588
申请日：1995-06-07
IPC分类号： B01J27/128 , B01J23/40 , B01J23/74 , B01J27/13 , C07C5/22 , C10G35/06 , C10G35/085 , C10G45/60 , C07C5/13
摘要： The invention concerns a process for reducing the benzene content of petrol fractions and isomerizing paraffins in the presence of an isomerization catalyst comprising 4 to 15% of at least one halogen and at least one metal from group VIII deposited on a support composed of a mixture of specific proportions of eta alumina and gamma alumina, in which isomerization is carried out on a mixture of a) a feed with the following composition by weight: 40% to 80% of paraffins, 0.5% to 7% of cyclic hydrocarbons and 6% to 45% of aromatics, and with a maximum distillation temperature of between 70.degree. C. and 90.degree. C., b) a C.sub.5 -C.sub.6 cut which is generally a straight run cut, and c) a chlorine-containing compound providing a concentration of 50-5000 ppm of chlorine in the mixture.
摘要翻译： 本发明涉及一种在含有4至15％的至少一种卤素和至少一种VIII族金属的异构化催化剂存在下降低汽油馏分的苯含量并沉积在载体上的方法，所述载体由 特殊比例的ηa氧化铝和γ氧化铝，其中异构化在a）具有以下重量组成的进料的混合物上进行：40％至80％的链烷烃，0.5％至7％的环状烃和6％ 45％的芳族化合物，最高蒸馏温度在70℃至90℃之间，b）一般为直线切割的C5-C6馏分，和c）提供浓度为 混合物中为50-5000ppm的氯。
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公开(公告)号：US5578196A
公开(公告)日：1996-11-26
申请号：US365927
申请日：1994-12-29
IPC分类号： B01J21/04 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/755 , B01J23/78 , B01J27/128 , B01J27/13 , C07B61/00 , C07C5/13 , C07C9/00 , C10G35/04 , C10G45/60 , C10G65/08 , C10G69/02 , C10G69/08 , C10G45/00
摘要： The invention concerns a process for reducing the benzene content of petrol fractions, in which hydrogenation is carried out on a feed with the following composition by weight: 40% to 80% of paraffins, 0.5% to 7% of cyclic hydrocarbons and 6% to 45% of aromatics, and with a maximum distillation temperature of between 70.degree. C. and 90.degree. C., followed by isomerisation of the effluent from the hydrogenation step, mixing said feed and/or said effluent with a C.sub.5 -C.sub.6 cut; said process being characterised in that an isomerisation catalyst is used which contains chlorine and at least one group VIII metal deposited on a support composed of a mixture of specific proportions of eta alumina and gamma alumina.
摘要翻译： 本发明涉及一种降低汽油馏分苯含量的方法，其中对具有以下重量组成的进料进行氢化：40％至80％的链烷烃，0.5％至7％的环状烃和6％ 45％的芳族化合物，并且最高蒸馏温度在70℃至90℃之间，随后将来自氢化步骤的流出物异构化，将所述进料和/或所述流出物与C5-C6馏分混合; 所述方法的特征在于使用异构化催化剂，其含有氯和沉积在由特定比例的氧化铝和γ氧化铝的混合物组成的载体上的至少一种第Ⅷ族金属。
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公开(公告)号：US5607891A
公开(公告)日：1997-03-04
申请号：US638313
申请日：1996-04-26
IPC分类号： B01J27/128 , B01J23/40 , B01J23/74 , B01J27/13 , C07C5/22 , C10G35/06 , C10G35/085 , C10G45/60 , B01J27/06
摘要： The invention concerns an isomerization catalyst comprising 4 to 15% of at least one halogen and at least one metal from group VIII deposited on a support composed of a mixture of specific proportions of eta alumina and gamma alumina. The invention also concerns a process for reducing the benzene content of gasoline fractions and isomerizing paraffins in the presence of this catalyst, in which isomerization is carried out on a mixture of a) a feed with the following composition by weight: 40% to 80% of paraffins, 0.5% to 7% of cyclic hydrocarbons and 6% to 45% of aromatics, and with a maximum distillation temperature of between 70.degree. C. and 90.degree. C., and b) a C.sub.5 -C.sub.6 cut which is generally a straight run cut.
摘要翻译： 本发明涉及一种异构化催化剂，其包含4至15％的至少一种卤素和至少一种沉积在由特定比例的氧化铝和γ氧化铝的混合物构成的载体上的来自第VIII族的金属。 本发明还涉及在该催化剂存在下降低汽油馏分的苯含量和异构化烷烃的方法，其中异构化在a）以下重量组成的进料的混合物中进行：40％至80％ 的链烷烃，0.5％至7％的环烃和6％至45％的芳族化合物，最高蒸馏温度在70℃至90℃之间，和b）C5-C6馏分，通常为 直跑
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公开(公告)号：US5648576A
公开(公告)日：1997-07-15
申请号：US466685
申请日：1995-06-06
IPC分类号： B01J23/44 , B01J23/48 , B01J23/50 , B01J23/58 , B01J23/66 , B01J35/00 , B01J35/02 , B01J35/08 , C07B61/00 , C07C5/09 , C07C7/167 , C07C11/04 , C07C11/06 , B01J21/04
CPC分类号： C07C5/09 , B01J23/44 , B01J23/48 , B01J23/50 , B01J23/58 , B01J23/66 , B01J35/0006 , C07C7/167 , B01J35/008 , C07C2521/04 , C07C2523/02 , C07C2523/04 , C07C2523/44 , C07C2523/50 , C07C2523/66 , Y02P20/52
摘要： A process for the selective hydrogenation in the gas phase of acetylene compounds containing 2 or 3 carbon atoms to the corresponding ethylene compounds in the presence of a catalyst in the form of spherules or extradates containing an alumina support, 0.01-0.5% by weight palladium, 0.001 to 0.5% by weight of at least one group IB metal, preferably silver, and optionally at least one alkaline or alkaline-earth metal, the weight ratio of the group IB metal to palladium being 0.05:1 to 0.25:1, in which catalyst at least 80% of the palladium and at least 80% of the group IB element are present in a volume at a periphery of the catalyst defined between a spherical or cylindrical surface of radius r.sub.1 corresponding to the average spherule or extradate diameter and a spherical or cylindrical surface of radius r.sub.2 at least equal to 0.8r.sub.1.
摘要翻译： 含有2或3个碳原子的乙炔化合物的气相中的选择性氢化到相应的乙烯化合物在催化剂存在下的催化剂的方法，所述催化剂是包含0.01-0.5重量％钯的氧化铝载体， 0.001至0.5重量％的至少一种IB族金属，优选银，以及任选的至少一种碱金属或碱土金属，IB族金属与钯的重量比为0.05:1至0.25:1，其中 催化剂至少80％的钯和至少80％的IB族元素以体积计存在催化剂的外围，该体积定义在对应于平均球粒或引导体直径的半径r1的球形或圆柱形表面之间， 或半径r2的圆柱形表面至少等于0.8r1。
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公开(公告)号：US6054409A
公开(公告)日：2000-04-25
申请号：US770426
申请日：1996-12-20
CPC分类号： B01J23/44 , B01J23/50 , B01J23/58 , C07C5/09 , B01J35/008 , C07C2521/04 , C07C2523/02 , C07C2523/04 , C07C2523/44 , C07C2523/50
摘要： A catalyst is described for selective gas phase hydrogenation of acetylenic compounds containing 2 or 3 carbon atoms to the corresponding ethylenic compounds. The catalyst, in the form of spherules or extrudates, comprises palladium, at least one metal from group IB, optionally at least one alkali or alkaline-earth metal, and alumina, in which at least 80% of the palladium and at least 80% of the element from group IB are present in a volume at the periphery of the catalyst defined between a spherical or cylindrical surface with radius r.sub.1 corresponding to the average radius of the spherules or extrudates of the catalyst and a spherical or cylindrical surface with radius r.sub.2 at least equal to 0.8 r.sub.1, the catalyst having a group IB metal/palladium ratio of 0.4 to 3 by weight. Further, it is advantageous for this catalyst that at least 30% of the metal particles contain both palladium and silver.
摘要翻译： 描述了一种催化剂，用于将含有2或3个碳原子的炔属化合物选择性气相氢化成相应的烯属化合物。 小球或挤出物形式的催化剂包含钯，至少一种来自IB组分的金属，任选至少一种碱金属或碱土金属和氧化铝，其中至少80％的钯和至少80％ 来自IB组分的元素存在于催化剂周边的体积中，该体积在球形或圆柱形表面之间，其半径r1对应于催化剂的球体或挤出物的平均半径，并且具有半径r 2的球形或圆柱形表面 至少等于0.8r1，IB族金属/钯比例为0.4-3的催化剂。 此外，该催化剂有利的是，至少30％的金属颗粒含有钯和银。
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20.发明授权Olefin isomerisation process using metallic catalysts impregnated with organic sulphur-containing compounds before loading into the reactor 失效在装入反应器之前，使用浸渍有机含硫化合物的金属催化剂进行烯烃异构化处理
公开(公告)号：US5569806A
公开(公告)日：1996-10-29
申请号：US282470
申请日：1994-07-29
IPC分类号： C07B61/00 , B01J37/20 , C07C5/13 , C07C5/22 , C07C5/25 , C07C5/27 , C07C9/15 , C07C11/02 , C07C11/107 , C10G45/60 , C10G45/62 , C07C5/23
摘要： The invention concerns a process for the isomerisation of less substituted olefins to more substituted external olefins and/or internal olefins in the absence of diolefins, in the presence of a palladium based catalyst deposited on a support. Before loading it into the reactor, said catalyst is treated with at least one sulphur-containing compound which is dissolved in a solvent then activated in a neutral or reducing atmosphere between 20.degree. C. and 300.degree. C., 1 and 50 bars and with a VVH of 50 to 600 h.sup.-1. The catalyst, containing 0.05% to 10% by weight of sulphur, is brought into contact with the feedstock and hydrogen between 20.degree. C. and 200.degree. C., 1 and 50 bars, a VVH of 0.5 to 10 h.sup.-1 and a H.sub.2 /olefin molar ratio of 0.01 to 1.
摘要翻译： 本发明涉及在沉积在载体上的钯基催化剂存在下，在不存在二烯烃的情况下将较少取代的烯烃异构化为更多取代的外部烯烃和/或内部烯烃的方法。 在将其装入反应器之前，所述催化剂用至少一种含硫化合物处理，该化合物溶解在溶剂中，然后在中性或还原性气氛中在20℃至300℃，1和50巴之间并在 50至600 h-1的VVH。 将含有0.05重量％至10重量％硫的催化剂与原料接触，在20℃至200℃，1和50巴之间的氢气，0.5至10小时-1的VVH和 H2 /烯烃摩尔比为0.01〜1。
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