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    Process for the production of compounds containing isocyanurate groups and olefinic double bonds and their use as binders
    12.
    发明授权
    Process for the production of compounds containing isocyanurate groups and olefinic double bonds and their use as binders 失效
    用于生产含有异氰脲酸酯基和烯属双键的化合物的方法及其作为粘合剂的用途

    公开(公告)号：US4870152A

    公开(公告)日：1989-09-26

    申请号：US262623

    申请日：1988-10-26

    申请人： Jurgen Meixner ,  Manfred Bock ,  Josef Pedain ,  Manfred Schonfelder

    发明人： Jurgen Meixner ,  Manfred Bock ,  Josef Pedain ,  Manfred Schonfelder

    IPC分类号： C07D251/34 ,  C08G18/42 ,  C08G18/67 ,  C08G18/72 ,  C08G18/79 ,  C08G18/81 ,  C09D175/00 ,  C09D175/14

    CPC分类号： C08G18/672 ,  C07D251/34 ,  C08G18/4216 ,  C08G18/4238 ,  C08G18/792 ,  C08G18/8175

    摘要： Binders which are hardenable by radiation or peroxides and are useful in coating compositions are compounds containing isocyanurate groups and olefinic double bonds produced by the reaction of components (a), (b) and (c) wherein(a) is a polyisocyanate component containing isocyanurate polyisocyanates which is(i) N,N',N"-tris-(isocyanatohexyl)-isocyanurate alone or in admixture with its higher homologs containing more than one isocyanurate ring or(ii) mixtures of the polyisocyanates (i) with up to 40 NCO-equivalent-%, based on the total component (a), of other polyisocyanates containing aliphatically or cycloaliphatically bound isocyanate groups;(b) is an olefinically unsaturated alcohol component comprising at least one hydroxyalkyl ester of acrylic acid or methacrylic acid; and(c) is a polyol component consisting essentially of a polyester polyol having an OH value of 80 to 350 based on (i) an acid component, of which at least 80 carboxyl equivalent-% is adipic acid, isophthalic acid or a mixture of both and (ii) a polyhydroxy component of which at least 70 hydroxyl equivalent-% is hexane-1, 6-diol;wherein component (c) amounts to 20 to 150% by weight, based on the weight of component (b), and the reaction is carried out at with an NCO:OH equivalent ratio maintained at 0.9:1 to 1.1:1, and wherein components (b) and (c) are reacted with the polyisocyanate component in any order or in admixture.

    摘要翻译： 通过辐射或过氧化物可硬化并且可用于涂料组合物的粘合剂是含有通过组分（a），（b）和（c）反应生成的异氰脲酸酯基团和烯属双键的化合物，其中（a）是含有异氰脲酸酯的多异氰酸酯组分 多异氰酸酯，其是单独的或与其含有多于一个异氰脲酸酯环的较高同系物混合的（i）N，N'，N“ - 三 - （异氰酸根合己基） - 异氰脲酸酯的多异氰酸酯，或（ii）多异氰酸酯（i） 基于总组分（a），含有脂族或环脂族结合的异氰酸酯基团的其它多异氰酸酯的40NCO当量％; （b）是包含至少一种丙烯酸或甲基丙烯酸的羟烷基酯的烯属不饱和醇组分; 和（c）是基于（i）酸组分的羟值为80至350的聚酯多元醇组成的多元醇组分，其中至少80羧基当量 - ％是己二酸，间苯二甲酸或 两者和（ii）多羟基组分，其中至少70个羟基当量 - ％是己烷-1,6-二醇; 其中组分（c）基于组分（b）的重量计为20至150重量％，并且以保持在0.9:1至1.1:1的NCO:OH当量比进行反应，其中 组分（b）和（c）以多异氰酸酯组分的任何顺序或混合物反应。

    Process for the preparation of polyisocyanates containing isocyanurate groups
    13.
    发明授权
    Process for the preparation of polyisocyanates containing isocyanurate groups 失效
    制备含有异氰脲酸酯基团的多异氰酸酯的方法

    公开(公告)号：US4288586A

    公开(公告)日：1981-09-08

    申请号：US11465

    申请日：1979-02-12

    申请人： Manfred Bock ,  Josef Pedain ,  Wilhelm Slawyk

    发明人： Manfred Bock ,  Josef Pedain ,  Wilhelm Slawyk

    IPC分类号： B01J31/02 ,  C07B61/00 ,  C07D251/34 ,  C08G18/00 ,  C08G18/78 ,  C08G18/79 ,  C08G18/80 ,  C08G18/16

    CPC分类号： C07D251/34 ,  C08G18/792 ,  C08G18/8061 ,  C08G2150/20

    摘要： The present invention relates to a new process for the preparation of polyisocyanates containing isocyanurate groups by the partial trimerization of the isocyanate groups of 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethyl-cyclohexane (also known as isophorone diisocyanate and abbreviated IPDI), using catalysts which accelerate the trimerization of isocyanate groups, characterized in that the catalysts used are quaternary hydroxyalkyl ammonium hydroxides containing at least one hydroxyalkyl group. The present invention also relates to the polyisocyanates containing isocyanurate groups produced according to this process and to their use, optionally in the form of products which are blocked with blocking agents for isocyanate groups, as isocyanate components for polyurethane lacquers.

    摘要翻译： 本发明涉及通过1-异氰酸酯基-3,3,5-三甲基-5-异氰酸甲酯基环己烷（也称为异佛尔酮二异氰酸酯）和缩写的异氰酸酯二异氰酸酯的异氰酸酯基部分三聚制备含有异氰脲酸酯基团的多异氰酸酯的新方法 IPDI），使用加速异氰酸酯基团三聚的催化剂，其特征在于所用的催化剂是含有至少一个羟烷基的季羟基烷基氢氧化铵。 本发明还涉及根据该方法制备的含有异氰脲酸酯基团的多异氰酸酯基团及其用途，任选地以用于异氰酸酯基团的封闭剂封闭的产品形式，作为聚氨酯漆的异氰酸酯组分。

    Process for the production of polyisocyanates containing isocyanurate groups and their use
    15.
    发明授权
    Process for the production of polyisocyanates containing isocyanurate groups and their use 失效
    用于生产含有异氰脲酸酯基团的多异氰酸酯的方法及其用途

    公开(公告)号：US06765111B1

    公开(公告)日：2004-07-20

    申请号：US08784875

    申请日：1997-01-16

    申请人： Josef Pedain ,  Manfred Bock ,  Carl-Gerd Dieris

    发明人： Josef Pedain ,  Manfred Bock ,  Carl-Gerd Dieris

    IPC分类号： C08G1820

    CPC分类号： C08G18/792 ,  C07D251/34

    摘要： The present invention is directed to a process for the production of polyisocyanates containing isocyanurate groups by trimerizing a portion of the isocyanate groups of hexamethylene diisocyanate using N,N,N-trialkyl-N-benzyl-quaternary ammonium hydroxides as the trimerization catalyst, terminating the trimerization reaction at the desired degree of trimerization by adding a catalyst poison and/or by thermally deactivating the catalyst and removing unreacted hexamethylene diisocyanate to a residual content of at most 0.2% by weight, characterized in that a) the hexamethylene diisocyanate used as starting material is freed from carbon dioxide to a residual content of less than 20 ppm (weight) and b) the catalyst is used in a quantity of less than about 0.03% by weight, based on the weight of the hexamethylene diisocyanate used. The present invention is also directed to the polyisocyanates containing isocyanurate groups obtained by this process and to their use, optionally blocked by blocking agents for isocyanate groups, as the isocyanate component for the production of polyisocyanate polyaddition products.

    摘要翻译： 本发明涉及通过使用N，N，N-三烷基-N-苄基季铵氢氧化物作为三聚催化剂使六亚甲基二异氰酸酯的一部分异氰酸酯基团三聚而制备含有异氰脲酸酯基团的多异氰酸酯的方法， 通过加入催化剂毒物和/或通过使催化剂热失活并除去未反应的六亚甲基二异氰酸酯至残留含量至多为0.2重量％的三聚反应，其特征在于a）用作原料的六亚甲基二异氰酸酯是 从二氧化碳释放到残留含量小于20ppm（重量），和b）催化剂的用量小于约0.03重量％，基于所用的六亚甲基二异氰酸酯的重量。本发明还涉及 涉及通过该方法获得的含有异氰脲酸酯基团的多异氰酸酯及其用途，任选地被嵌段封端 作为异氰酸酯基团的异氰酸酯组分，用于生产多异氰酸酯加聚产物。

    Process for the production of compounds containing isocyanurate groups and olefinic double bonds, the compounds obtainable by this process and their use as binders or binder component in coating compositions
    16.
    发明授权
    Process for the production of compounds containing isocyanurate groups and olefinic double bonds, the compounds obtainable by this process and their use as binders or binder component in coating compositions 失效
    用于生产含有异氰脲酸酯基和烯属双键的化合物的方法，可通过该方法获得的化合物及其作为涂料组合物中的粘合剂或粘合剂组分的用途

    公开(公告)号：US4485226A

    公开(公告)日：1984-11-27

    申请号：US606308

    申请日：1984-05-02

    申请人： Klaus Noll ,  Josef Pedain ,  Manfred Bock

    发明人： Klaus Noll ,  Josef Pedain ,  Manfred Bock

    IPC分类号： C07D251/34 ,  C08F299/06 ,  C08G18/79 ,  C08G18/81 ,  C09D4/00 ,  C09D175/00 ,  C09D175/14 ,  C08G18/32 ,  C08G18/67 ,  C08G18/80

    CPC分类号： C08G18/8175 ,  C08F299/06 ,  C08G18/792 ,  C09D4/00

    摘要： A process for the production of compounds which crosslink under the effect of high-energy radiation containing isocyanurate groups, olefinic double bonds, and, optionally, blocked or free isocyanate groups by reacting(i) isocyanurate-group-containing polyisocyanates which are based on aliphatic and/or cycloaliphatic diisocyanates with(ii) compounds containing at least one isocyanate-reactive group and at least one olefinic double bond, such as hydroxyl-containing esters of acrylic acid and methacrylic acid with at least dihydric aliphatic alcohols having a molecular weight of from 62 to about 300,to form urethanes, the quantitative ratios between the reactants being selected so that for every free isocyanate group in component (i), the reaction mixture contains from about 0.9 to 1.5 hydroxyl groups of component (ii).The present invention also relates to the compounds prepared by this process and to the use of these compounds as the binder or a binder component in coating compositions crosslinkable by high-energy radiation.

    摘要翻译： 通过使（i）含有异氰脲酸酯基的多异氰酸酯（基于脂肪族）的异氰脲酸酯基团，烯属双键和任选的封闭或游离的异氰酸酯基团，在高能量辐射的作用下交联的化合物的方法 和/或脂环族二异氰酸酯与（ii）含有至少一个异氰酸酯反应性基团和至少一个烯属双键的化合物，例如丙烯酸和甲基丙烯酸的含羟基酯与至少二元脂族醇的分子量为 62至约300，为了形成氨基甲酸酯，选择反应物之间的定量比例，使得对于组分（i）中的每个游离异氰酸酯基团，反应混合物含有组分（ii）的约0.9至1.5个羟基。 本发明还涉及通过该方法制备的化合物以及这些化合物在通过高能量辐射可交联的涂料组合物中作为粘合剂或粘合剂组分的用途。

    Process for the preparation of polyisocyanates containing urethane and biuret groups
    19.
    发明授权
    Process for the preparation of polyisocyanates containing urethane and biuret groups 失效
    制备含氨基甲酸酯和缩二脲基团的多异氰酸酯的方法

    公开(公告)号：US4124569A

    公开(公告)日：1978-11-07

    申请号：US832318

    申请日：1977-09-12

    申请人： Manfred Bock ,  Josef Pedain ,  Walter Uerdingen ,  Manfred Schonfelder

    发明人： Manfred Bock ,  Josef Pedain ,  Walter Uerdingen ,  Manfred Schonfelder

    IPC分类号： C08G18/00 ,  C07C67/00 ,  C07C239/00 ,  C07C269/02 ,  C07C273/18 ,  C07C275/48 ,  C07C275/62 ,  C08G18/78 ,  C08G18/80 ,  C08G18/79

    CPC分类号： C07C273/1863 ,  C07C273/1872 ,  C08G18/7831 ,  C08G18/8041 ,  C08G18/8058

    摘要： The present invention is concerned with a process for producing biuret polyisocyanates and the polyisocyanates so produced. These isocyanates are produced by the reaction of at least about a four fold molar excess of a diisocyanate having aliphatically bound isocyanate groups with amino alcohols having a particular structure at a temperature between about 90 and 200.degree. C. The amino alcohols contain at least three carbon atoms, have their hydroxyl and amino groups separated by at least two carbon atoms, and may contain urea, urethane, ether or amino bonds. The present invention is also concerned with a process for producing two component and one component moisture curing lacquers using the biuret polyisocyanates of the present invention and the lacquers so produced.

    摘要翻译： 本发明涉及制备缩二脲多异氰酸酯的方法和如此制备的多异氰酸酯。 这些异氰酸酯是通过至少约四倍摩尔过量的具有脂肪族结合的异氰酸酯基团的二异氰酸酯与具有特定结构的氨基醇在约90-200℃之间的温度下进行的反应来制备的。氨基醇含有至少三个碳 原子，其羟基和氨基被至少两个碳原子分开，并且可以含有脲，氨基甲酸酯，醚或氨基键。 本发明还涉及使用本发明的缩二脲多异氰酸酯和如此制备的漆制备两组分和一种组分的湿固化漆的方法。

    Colloidal metal oxides having blocked isocyanate groups
    20.
    发明授权
    Colloidal metal oxides having blocked isocyanate groups 失效
    具有封端异氰酸酯基团的胶体金属氧化物

    公开(公告)号：US5998504A

    公开(公告)日：1999-12-07

    申请号：US54590

    申请日：1998-04-03

    申请人： Stefan Groth ,  Claus Kobusch ,  Lutz Schmalstieg ,  Lothar Puppe ,  Theodor Engbert ,  Manfred Bock ,  Gerhard Jonschker

    发明人： Stefan Groth ,  Claus Kobusch ,  Lutz Schmalstieg ,  Lothar Puppe ,  Theodor Engbert ,  Manfred Bock ,  Gerhard Jonschker

    IPC分类号： C07F7/10 ,  C08G18/38 ,  C08G18/80 ,  C08J7/04 ,  C08K5/54 ,  C07B37/02

    CPC分类号： C08G18/3895 ,  C08G18/3897 ,  C08G18/8054 ,  C08G18/809 ,  C08G18/8096

    摘要： The present invention relates to colloidal metal oxides having blocked isocyanate groups, which are based on the reaction product ofA) blocked isocyanate group-containing silanes corresponding to formula (I) ##STR1## wherein R represents hydrogen or an organic group having 1 to 40 carbon atoms,X, Y and Z represent identical or different organic groups having 1 to 30 carbon atoms which are inert to isocyanate groups below 100.degree. C., provided that at least one of these groups is a C.sub.1 -C.sub.4 -alkoxy group,Q represents an organic group which contains at least one isocyanate group reacted with a blocking agent andn is 2, 3 or 4 withB) colloidal metal oxides selected from Al, Si, Ti, Ta, W, Hf, Zr, Sn and Y.The present invention also relates to the use of modified metal oxides, either alone or in combination with compounds containing at least two isocyanate-reactive groups, for the preparation of optionally expanded polyurethane plastics, lacquers or coating agents.

    摘要翻译： 本发明涉及具有封端异氰酸酯基团的胶态金属氧化物，其基于A）封端异氰酸酯基硅烷对应于其中R表示氢或具有1至40个碳原子的有机基团的式（I）的反应产物， X，Y和Z表示相同或不同的具有1至30个碳原子的有机基团，其对于低于100℃的异氰酸酯基团是惰性的，条件是这些基团中的至少一个是C 1 -C 4 - 烷氧基，Q表示有机 含有至少一个与封闭剂反应的异氰酸酯基团的基团，n为2,3或4，B）选自Al，Si，Ti，Ta，W，Hf，Zr，Sn和Y的胶态金属氧化物。本发明 还涉及使用改性金属氧化物，单独或与含有至少两个异氰酸酯反应性基团的化合物组合，用于制备任选发泡的聚氨酯塑料，漆或涂层剂。