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    Colloidal metal oxides having blocked isocyanate groups
    1.
    发明授权
    Colloidal metal oxides having blocked isocyanate groups 失效
    具有封端异氰酸酯基团的胶体金属氧化物

    公开(公告)号：US5998504A

    公开(公告)日：1999-12-07

    申请号：US54590

    申请日：1998-04-03

    申请人： Stefan Groth ,  Claus Kobusch ,  Lutz Schmalstieg ,  Lothar Puppe ,  Theodor Engbert ,  Manfred Bock ,  Gerhard Jonschker

    发明人： Stefan Groth ,  Claus Kobusch ,  Lutz Schmalstieg ,  Lothar Puppe ,  Theodor Engbert ,  Manfred Bock ,  Gerhard Jonschker

    IPC分类号： C07F7/10 ,  C08G18/38 ,  C08G18/80 ,  C08J7/04 ,  C08K5/54 ,  C07B37/02

    CPC分类号： C08G18/3895 ,  C08G18/3897 ,  C08G18/8054 ,  C08G18/809 ,  C08G18/8096

    摘要： The present invention relates to colloidal metal oxides having blocked isocyanate groups, which are based on the reaction product ofA) blocked isocyanate group-containing silanes corresponding to formula (I) ##STR1## wherein R represents hydrogen or an organic group having 1 to 40 carbon atoms,X, Y and Z represent identical or different organic groups having 1 to 30 carbon atoms which are inert to isocyanate groups below 100.degree. C., provided that at least one of these groups is a C.sub.1 -C.sub.4 -alkoxy group,Q represents an organic group which contains at least one isocyanate group reacted with a blocking agent andn is 2, 3 or 4 withB) colloidal metal oxides selected from Al, Si, Ti, Ta, W, Hf, Zr, Sn and Y.The present invention also relates to the use of modified metal oxides, either alone or in combination with compounds containing at least two isocyanate-reactive groups, for the preparation of optionally expanded polyurethane plastics, lacquers or coating agents.

    摘要翻译： 本发明涉及具有封端异氰酸酯基团的胶态金属氧化物，其基于A）封端异氰酸酯基硅烷对应于其中R表示氢或具有1至40个碳原子的有机基团的式（I）的反应产物， X，Y和Z表示相同或不同的具有1至30个碳原子的有机基团，其对于低于100℃的异氰酸酯基团是惰性的，条件是这些基团中的至少一个是C 1 -C 4 - 烷氧基，Q表示有机 含有至少一个与封闭剂反应的异氰酸酯基团的基团，n为2,3或4，B）选自Al，Si，Ti，Ta，W，Hf，Zr，Sn和Y的胶态金属氧化物。本发明 还涉及使用改性金属氧化物，单独或与含有至少两个异氰酸酯反应性基团的化合物组合，用于制备任选发泡的聚氨酯塑料，漆或涂层剂。

    Coating compositions and process for the production of polyurethane coatings
    5.
    发明授权
    Coating compositions and process for the production of polyurethane coatings 失效
    涂料组合物和生产聚氨酯涂料的方法

    公开(公告)号：US4373081A

    公开(公告)日：1983-02-08

    申请号：US325242

    申请日：1981-11-27

    申请人： Klaus Nachtkamp ,  Manfred Bock ,  Gerhard Mennicken ,  Josef Pedain

    发明人： Klaus Nachtkamp ,  Manfred Bock ,  Gerhard Mennicken ,  Josef Pedain

    IPC分类号： C08G18/00 ,  C08G18/10 ,  C08G18/42 ,  C08G18/80 ,  C09D175/00 ,  C09D175/06

    CPC分类号： C08G18/8093 ,  C08G18/10 ,  Y10T428/31551 ,  Y10T428/31605

    摘要： The present invention relates to thermally cross-linkable coating compositions which are liquid and stable in storage at room temperature and which contain combinations of dialkyl-malonate-blocked polyisocyanates and organic polyhydroxyl compounds as binders and, optionally, auxiliaries and additives, being characterized in that the binder comprises:(a) a polyisocyanate component containing dialkyl-malonate-blocked isocyanate groups and a content of blocked isocyanate groups, expressed as NCO, based on the weight of the polyisocyanate component excluding the weight of the blocking agent, of from about 3 to 33.6% by weight, comprising(aa) at least one dialkyl-malonate-blocked, optionally alkyl-substituted diisocyanato-diphenyl methane and/or(ab) at least one dialkyl-malonate-blocked NCO-prepolymer based on excess quantities of optionally alkyl-substituted diisocyanatodiphenyl methane and organic compounds containing at least two hydroxyl groups and(b) a polyol component having an average hydroxyl functionality of greater than 2 and a content of alcoholic hydroxyl groups of from about 1.5 to 8% by weight, comprising at least one polyester polyol in quantities corresponding to an equivalent ratio of blocked isocyanate groups to hydroxyl groups of from about 0.6:1 to 2:1.The present invention also relates to a process for the production of coatings by coating heat-resistant substrates of any type with these coating compositions and subsequently hardening the coating at about 90.degree. to 220.degree. C.

    摘要翻译： 本发明涉及在室温下储存的液体和稳定的可热交联的涂料组合物，其含有二烷基 - 丙二酸酯封端的多异氰酸酯和有机多羟基化合物作为粘合剂和任选的助剂和添加剂的组合，其特征在于 粘合剂包括：（a）含有二烷基 - 丙二酸酯封端的异氰酸酯基团的多异氰酸酯组分和封端异氰酸酯基团的含量，基于除了封闭剂重量以外的多异氰酸酯组分的重量，表示为NCO，为约3 包含（aa）至少一种二烷基 - 丙二酸酯封端的，任选的烷基取代的二异氰酸根合二苯基甲烷和/或（ab）至少一种二烷基 - 丙二酸酯封闭的NCO-预聚物， 烷基取代的二异氰酸二苯二甲烷和含有至少两个羟基的有机化合物和（b）具有av的多元醇组分 包括至少一种聚酯多元醇，其数量对应于封端异氰酸酯基与羟基的当量比为约0.6:1，其中羟基官能度大于2，醇羟基含量为约1.5至8重量％ 至2：1。 本发明还涉及通过用这些涂料组合物涂覆任何类型的耐热基材并随后在约90℃至220℃硬化涂层来生产涂料的方法。

    Cosolvent-free, aqueous, anionic polyurethane dispersions and their use as peelable coatings
    7.
    发明授权
    Cosolvent-free, aqueous, anionic polyurethane dispersions and their use as peelable coatings 失效
    无溶剂，水性，阴离子聚氨酯分散体及其作为可剥离涂料的用途

    公开(公告)号：US06172126B2

    公开(公告)日：2001-01-09

    申请号：US09339458

    申请日：1999-06-24

    申请人： Hanns-Peter M{umlaut over (u)}ller ,  Horst Gruttmann ,  Holger Casselmann ,  Heino M{umlaut over (u)}ller ,  Joachim Petzoldt ,  Manfred Bock

    发明人： Hanns-Peter M{umlaut over (u)}ller ,  Horst Gruttmann ,  Holger Casselmann ,  Heino M{umlaut over (u)}ller ,  Joachim Petzoldt ,  Manfred Bock

    IPC分类号： C08J1104

    CPC分类号： C09D5/20 ,  C08G18/0823 ,  C08G18/12 ,  C08G18/6625 ,  C09D175/12 ,  C09J175/12 ,  C08G18/3228 ,  C08G18/3234 ,  C08G18/3225 ,  C08G18/2865 ,  C08G18/3271

    摘要： The present invention relates to coating composition, which is suitable for preparing light fast coatings and contains a cosolvent-free, aqueous, anionic dispersion of polyurethane-ureas, the solids content of which contains the reaction product, present at least partially in salt form, of a) an NCO prepolymer prepared from i) an aliphatic and/or cycloaliphatic diisocyanate, ii) a macrodiol having a number average molecular weight of 500 to 10,000 iii) a 2,2-bis-(hydroxymethyl)alkane monocarboxylic acid and iv) a diol having a molecular weight of 62 to 400, with b) optionally a diamine, c) a monofunctional chain terminating agent, d) water and e) a neutralizing agent, provided that the NCO content of the prepolymer is up to 25% lower than the theoretical value, the entire polyurethane-urea synthesis reaction is performed in the homogeneous phase and no cosolvent having a boiling range of greater than 100° C. is used during the preparation of the dispersion of polyurethane-ureas. The present invention also relates to light fast coatings prepared from these coating compositions and to a process for preparing these coating compositions. Finally, the present invention relates to peelable coatings and to a method for recycling these coatings.

    摘要翻译： 本发明涉及涂料组合物，其适用于制备防光涂料，并且含有无溶剂的聚氨酯 - 脲的阴离子水性分散体，其中固体含量含有至少部分为盐形式的反应产物， 的a）由i）脂族和/或脂环族二异氰酸酯制备的NCO预聚物，ii）数均分子量为500至10,000的大型二醇），2,2-双 - （羟甲基）烷烃单羧酸和ii）具有 分子量为62至400，带有b）任选的二胺，c）单官能链终止剂，d）水和）中和剂，条件是预聚物的NCO含量低于理论值的25％ 整个聚氨酯 - 尿素合成反应在均相中进行，并且在制备聚氨酯 - 脲的分散体期间不使用沸点范围大于100℃的共溶剂。目前在 还涉及由这些涂料组合物制备的耐光性涂料和制备这些涂料组合物的方法。 最后，本发明涉及可剥离涂层以及这些涂层的回收方法。

    Coating compound, a process for its preparation and its use for the production of coatings
    9.
    发明授权
    Coating compound, a process for its preparation and its use for the production of coatings 失效
    涂料化合物，其制备方法及其在涂料生产中的应用

    公开(公告)号：US5552477A

    公开(公告)日：1996-09-03

    申请号：US204183

    申请日：1994-03-04

    申请人： Rolf Dhein ,  Knud Reuter ,  Lothar B acker ,  Manfred Bock ,  Werner Kubitza ,  Joachim Probst

    发明人： Rolf Dhein ,  Knud Reuter ,  Lothar B acker ,  Manfred Bock ,  Werner Kubitza ,  Joachim Probst

    IPC分类号： C08G18/66 ,  C08G18/08 ,  C08G18/42 ,  C08G18/62 ,  C08G18/65 ,  C08G18/70 ,  C09D175/04 ,  C08L75/04 ,  C08L75/06

    CPC分类号： C08G18/6511 ,  C08G18/0819 ,  C08G18/4288 ,  C08G18/6254 ,  C08G18/706

    摘要： An aqueous two-component coating agent whose binder consists essentially of a combination of a) a polyol component present dissolved and/or dispersed in water comprising a1) at least one water-dilutable polymerisation resin or polycondensation resin with a molecular weight Mn of over 500 possessing hydroxyl groups and a2) a reactive diluent consisting of at least one water-soluble compound with a molecular weight Mn of under 500 capable of reacting with isocyanate groups and b) a polyisocyanate component with a viscosity at 23.degree. C. of from 50 to 10 000 mPa present emulsified in the aqueous solution or dispersion, a method for producing such coating agents wherein the said polyisocyanate component is emulsified in the said aqueous solution or dispersion with the optional incorporation of auxiliary substances and additives in the system prior to adding the polyisocyanate, and the use of the coating agents for the production of air-drying and/or heat-drying coatings.

    摘要翻译： PCT No.PCT / EP92 / 01983 Sec。 371日期1994年3月4日 102（e）1994年3月4日PCT PCT 1992年8月28日PCT公布。 公开号WO93 / 05087 日期1993年3月18日一种水性双组分涂布剂，其粘合剂基本上由以下组合组成：a）溶解和/或分散在水中的多元醇组分，其包含a1）至少一种水可稀释聚合树脂或缩聚树脂与分子 重量Mn超过500具有羟基，和a2）由至少一种分子量为500以下的可与异氰酸酯基反应的水溶性化合物组成的反应性稀释剂，和b）在23℃下的粘度的多异氰酸酯组分 在水溶液或分散体中乳化的50至10000立方厘米的方法，制备这种涂料的方法，其中所述多异氰酸酯组分在所述水溶液或分散体中乳化，并且可选地将辅助物质和添加剂并入系统中 在加入多异氰酸酯之前，以及使用涂布剂来生产空气干燥和/或加热干燥涂层。