Abstract:
The invention relates to a process for preparing water-absorbing polymers by polymerizing a monomer solution, wherein the oxygen content of the monomer solution has been reduced by addition of at least one reducing agent before the polymerization.
Abstract:
The invention relates to processes for preparing water absorbing polymers by polymerization of a monomer solution comprising allyl acrylate and/or allyl alcohol, the solution comprising not more than 0.002% by weight of allyl acrylate and/or allyl alcohol, based on acrylic acid, to aqueous monomer solutions for producing water absorbing polymers, to water absorbing polymers, to processes for producing hygiene articles and also to hygiene articles.
Abstract:
The present invention relates to novel (meth)acrylic esters of polyalkoxylated glycols of the formula where AO is independently at each instance is —O—CHR3-CHR4- or —CHR3-CHR4-O— where R3 and R4 are independently H, linear or branched C1-C8-alkyl, p1 is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, or 35, p2 is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, or 35, n is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 447, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90, 91, 92, 93, 94, 95, 96, 97, 98, 99, 100, R1 and R2 are independently H or CH3, wherein there is at least one AO in (AO)p1 and also at least one AO in (AO)p2 where R3 and R4 are not both H at one and the same time, a simplified process for preparing these esters and use of reaction mixtures thus obtainable.
Abstract:
The present invention relates to novel (meth)acrylic esters of polyalkoxylated trimethylolpropane of the formula where AO is for each AO independently at each instance EO, PO or BO where EO is O—CH2-CH2- PO is independently at each instance O—CH2-CH(CH3)- or O—CH(CH3)-CH2- BO is independently at each instance O—CH2-CH(CH2-CH3)- or O—CH(CH2-CH3)-CH2- p1+p2+p3 is 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74 or 75, R1, R2 and R3 are independently H or CH3, a simplified process for preparing these esters and the use of reaction mixtures thus obtainable.
Abstract:
The present invention relates to polymer mixtures including hydrogel-forming polymers capable of absorbing aqueous fluids and prepared by polymerization of olefinically unsaturated carboxylic acids or derivatives thereof together with copolymers of C2-C8 olefins or styrenes with anhydrides and also their preparation, use and hygiene articles which include same.
Abstract:
Stable peroxycarboxylic acid granules composed essentially of (1) an imidoperoxycarboxylic acid or its salts of the formula ##STR1## in which A is a group of the formula ##STR2## n is the number 0, 1 or 2, R.sup.1 is hydrogen, chlorine, bromine, C.sub.1 -C.sub.20 -alkyl, C.sub.1 -C.sub.20 -alkenyl, aryl or alkylaryl,R.sup.2 is hydrogen, chlorine, bromine or a group of the formula --SO.sub.3 M, --CO.sub.2 M or --OSO.sub.3 M,M is hydrogen, an alkali metal or ammonium ion or the equivalent of an alkaline earth metal ion, andX is C.sub.1 -C.sub.19 -alkylene or arylene,(2) an inorganic sulfate and/or phosphate salt and/or a non-oxidizable surfactant as granulating auxiliaries and (3) a homo- or copolymer of (meth)acrylic acid or its salts or a copolymer of (meth)acrylic acid or its salts and other carboxylic acids polymerizable therewith as a film-forming coating substance.
Abstract:
A process for producing water-absorbing polymer particles by neutralizing the monomer and cooling it by means of an indirect heat exchanger, wherein the specific cooling performance of the heat exchanger is less than 10 W/m2.
Abstract translation:通过中和单体并通过间接热交换器进行冷却来制造吸水性聚合物颗粒的方法,其中热交换器的比冷却性能小于10W / m 2。
Abstract:
A process for continuously producing water-absorbing polymer particles, comprising polymerization, drying, grinding, classification and at least partial recycling of the undersize obtained in the classification, wherein the polymer gel obtained by the polymerization is withdrawn from the polymerization reactor and mixed with the recycled undersize.
Abstract:
A process for pneumatic delivery of water-absorbing polymer particles using curved pipelines, the ratio of radius of curvature to tube diameter being at least 5.
Abstract:
The invention relates to a neutralization process in which at least one ethylenically unsaturated carboxylic acid is neutralized at least partly with a base and at least one stream of the neutralization is determined continuously, and also to an apparatus for carrying out the process.