公开(公告)号：US10927315B2

公开(公告)日：2021-02-23

申请号：US16323710

申请日：2017-10-04

Applicant: SABIC Global Technologies B.V.

Inventor： Krishna Kumar Ramamurthy ,  Nicolas Goyheneix ,  Ravichander Narayanaswamy ,  Lara Galan-Sanchez

IPC: C10G69/06 ,  C07C4/22 ,  C10G1/00 ,  C10G1/10 ,  C10G9/36 ,  C10G45/00 ,  C10G51/06 ,  C10G69/00

Abstract: A process for producing olefins and aromatics comprising converting plastics to a hydrocarbon product comprising a gas phase and a liquid phase in a pyrolysis unit; separating the hydrocarbon product into a hydrocarbon gas stream comprising the gas phase and a hydrocarbon liquid stream comprising the liquid phase; feeding the hydrocarbon gas stream to a gas steam cracker to produce a gas steam cracker product comprising olefins, wherein an olefins amount in the gas steam cracker product is greater than in the hydrocarbon gas stream; separating the hydrocarbon liquid stream into a first fraction (b.p. 300° C.); feeding the first fraction to a liquid steam cracker to produce a liquid steam cracker product comprising olefins and aromatics, wherein an olefins amount in the liquid steam cracker product is greater than in the first fraction; and recycling the second fraction to the pyrolysis unit.

公开(公告)号：US10513661B2

公开(公告)日：2019-12-24

申请号：US16323191

申请日：2017-09-21

Applicant: SABIC Global Technologies B.V.

Inventor： Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  Abrar A. Hakeem ,  Lara Galan-Sanchez ,  Nicolas Goyheneix ,  Santosh Ganji

IPC: C10G1/10 ,  C10G1/06 ,  C07C4/02 ,  C07C4/12 ,  C07C4/14 ,  B01D3/14 ,  B01D53/40 ,  B01D53/78 ,  C10B47/24 ,  C10B53/07 ,  C10B57/06 ,  C10G69/14

Abstract: A process for processing plastic waste comprising converting plastic waste to hydrocarbon liquid and a first C1-4 gas; contacting hydrocarbon liquid with a first hydroprocessing catalyst in hydroprocessing unit to yield a second C1-4 gas and a first hydrocarbon product comprising C5+ liquid hydrocarbons; introducing the first hydrocarbon product to a first separating unit to produce treated hydrocarbon stream comprising C5-8 hydrocarbons and a first heavies stream comprising C9+ hydrocarbons; contacting the first heavies stream with a second hydroprocessing catalyst in hydrodealkylating unit to yield a second hydrocarbon product comprising C5+ liquid hydrocarbons and a third C1-4 gas; conveying the second hydrocarbon product to the first separating unit; feeding treated hydrocarbon stream to steam cracker to produce steam cracker product; separating steam cracker product into olefin gas, saturated hydrocarbons gas, aromatics, and a second heavies stream; and conveying the second heavies stream to hydroprocessing unit.

公开(公告)号：US10442997B2

公开(公告)日：2019-10-15

申请号：US15636785

申请日：2017-06-29

Applicant: SABIC Global Technologies B.V.

Inventor： Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  Nicolas Goyheneix ,  Lara Galan-Sanchez

IPC: C10G1/10 ,  C10G1/02 ,  C10G9/00 ,  C10G11/00 ,  C10G1/00 ,  C10G11/18 ,  C10G47/12

Abstract: Disclosed are methods of reduction of chlorine in pyrolysis products derived from a mixed plastics stream. Methods may comprise: (a) causing pyrolysis of a plastic feedstock to produce a first stream of C1-C4 gaseous hydrocarbons and light gas olefins and a second stream comprising the remaining pyrolysis components. The second stream and hydrogen gas may be fed into a hydrocracker to produce a third stream of gaseous C1-C4 hydrocarbon gases and a fourth stream comprising the remaining hydrocracker components. The fourth stream may be fed to either (i) a steam cracker to produce a fifth stream comprising C1-C4 gaseous hydrocarbons and light gas olefins, a sixth stream comprising C6-C8 hydrocarbons and a seventh stream comprising hydrocarbons heavier than C8; or (ii) a fluidized catalytic cracker to produce an eighth stream comprising C1-C4 gases and light gas olefins and a ninth stream comprising hydrocarbons that are C5 or greater.

公开(公告)号：US20230272286A1

公开(公告)日：2023-08-31

申请号：US18017010

申请日：2021-07-15

Applicant: SABIC Global Technologies B.V.

Inventor： Anthoni Wouter Zijl Van ,  Nicolas Goyheneix ,  Lara Maria Galan-Sanchez ,  Christoph Roosen ,  Johan Pastwa ,  Safa Farajzadeh Bibalan

IPC: C10G1/10 ,  C10G47/02 ,  C10G47/36

CPC classification number: C10G1/10 ,  C10G47/02 ,  C10G47/36 ,  C10G2400/30 ,  C10G2300/1003 ,  C10G2300/4006 ,  C10G2300/807

Abstract: The present invention relates to a process for the production of aromatics from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to one or more separation units; (f) performing a separation operation to obtain different streams comprising benzene, toluene, styrene, ethylbenzene and xylenes; wherein in step (d): ⋅ the coil outlet temperature is ≥800 and ≤80° C., preferably ≥830 and ≤870° C.; 7 and ⋅ the weight ratio of steam to feed C is >0.3 and 0.3 and

公开(公告)号：US20230257323A1

公开(公告)日：2023-08-17

申请号：US18017325

申请日：2021-07-15

Applicant: SABIC Global Technologies B.V.

Inventor： Anthoni Wouter Zijl Van ,  Nicolas Goyheneix ,  Lara Maria Galan-Sanchez ,  Christoph Roosen ,  Johan Pastwa ,  Safa Farajzadeh Bibalan

IPC: C07C4/04 ,  C07C7/00

CPC classification number: C07C4/04 ,  C07C7/00

Abstract: Process for the production of butenes and butadienes from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to one or more separation units; and (f) performing a separation operation to obtain different streams comprising isobutene, 1-butene, 2-butene, 1,2-butediene and 1,3-butadiene; wherein in step (d): • the coil outlet temperature is ≥ 800 and ≤ 850° C. and • the weight ratio of steam to feed C is > 0.3 and

公开(公告)号：US11685867B2

公开(公告)日：2023-06-27

申请号：US17425466

申请日：2020-01-24

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Anthoni Van Zijl ,  Nicolas Goyheneix ,  Lara Galan-Sanchez ,  Christoph Roosen ,  Johan Pastwa ,  Safa Farajzadeh Bibalan

IPC: C10G57/02 ,  B29B17/04 ,  C08J11/00 ,  C10G9/14 ,  C10G50/00 ,  C10G69/12 ,  C10G1/10 ,  C10G47/00 ,  B29C48/275 ,  B29B17/02 ,  C08J11/06 ,  C10G51/02 ,  C08J11/12 ,  C08J11/14 ,  C08L23/06 ,  B29B17/00

CPC classification number: C10G57/02 ,  B29B17/02 ,  B29B17/04 ,  B29C48/277 ,  C08J11/00 ,  C08J11/06 ,  C08J11/12 ,  C08J11/14 ,  C08L23/06 ,  C10G1/10 ,  C10G9/14 ,  C10G47/00 ,  C10G50/00 ,  C10G51/023 ,  C10G69/12 ,  B29B2017/0089 ,  B29B2017/0203 ,  B29B2017/0496 ,  C08J2300/30 ,  C08L2207/20 ,  C10G2300/1003 ,  C10G2300/1085 ,  C10G2300/1096 ,  C10G2300/201 ,  C10G2400/20

Abstract: The present invention relates to a process for the production of polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising a monomer; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an polymer. The process of the present invention allows for optimisation of the quantity of waste plastic material that finds its way back into a polymer that is produced as outcome of the process.

公开(公告)号：US20230183579A1

公开(公告)日：2023-06-15

申请号：US18017345

申请日：2021-07-15

Applicant: SABIC Global Technologies B.V.

Inventor： Anthoni Wouter Zijl Van ,  Nicolas Goyheneix ,  Lara Maria Galan-Sanchez ,  Christoph Roosen ,  Johan Pastwa ,  Safa Farajzadeh Bibalan

IPC: C10B53/07 ,  C10G1/10 ,  C10G9/14

CPC classification number: C10B53/07 ,  C10G1/10 ,  C10G9/14 ,  C10G2400/20

Abstract: The present invention relates to a process for the production of butenes and butadienes from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by hydrotreatment of pyrolysis oil produced from a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and optionally a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to one or more separation units; (f) performing a separation operation to obtain different streams of chemical products comprising ethylene, propylene, isobutene, 1-butene, 2-butene, 1,2-butadiene, 1,3-butadiene, benzene, styrene, toluene, ethylbenzene and xylenes; wherein in step (d): the coil outlet temperature is >800 and 805 and 0.3 and 0.3 and

公开(公告)号：US11667854B2

公开(公告)日：2023-06-06

申请号：US17425173

申请日：2020-01-24

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Anthoni Van Zijl ,  Nicolas Goyheneix ,  Lara Galan-Sanchez ,  Christoph Roosen ,  Johan Pastwa ,  Safa Farajzadeh Bibalan

IPC: C10G50/00 ,  C10G55/04 ,  B29B17/04 ,  C08J11/00 ,  C10G9/14 ,  C10G57/02 ,  C10G69/12 ,  C10G1/10 ,  C10G47/00 ,  B29C48/275 ,  B29B17/02 ,  C08J11/06 ,  C10G51/02 ,  C08J11/12 ,  C08J11/14 ,  C08L23/06 ,  B29B17/00

CPC classification number: C10G50/00 ,  B29B17/02 ,  B29B17/04 ,  B29C48/277 ,  C08J11/00 ,  C08J11/06 ,  C08J11/12 ,  C08J11/14 ,  C08L23/06 ,  C10G1/10 ,  C10G9/14 ,  C10G47/00 ,  C10G51/023 ,  C10G57/02 ,  C10G69/12 ,  B29B2017/0089 ,  B29B2017/0203 ,  B29B2017/0496 ,  C08J2300/30 ,  C08L2207/20 ,  C10G2300/1003 ,  C10G2300/1085 ,  C10G2300/1096 ,  C10G2300/201 ,  C10G2400/20

Abstract: The present invention relates to a process for the production of propylene-based polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising propylene; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an propylene-based polymer; wherein in step (d): •⋅ the coil outlet temperature is 2:: 800 and:::; 850° C., preferably 2:: 805 and:::; 835° C.; and •⋅ the weight ratio of steam to feed C is >0.3 and

公开(公告)号：US20180002609A1

公开(公告)日：2018-01-04

申请号：US15636785

申请日：2017-06-29

Applicant: SABIC Global Technologies B.V.

Inventor： Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  Nicolas Goyheneix ,  Lara Galan-Sanchez

IPC: C10G1/10 ,  C10G1/02 ,  C10G1/00 ,  C10G9/00 ,  C10G11/18 ,  C10G47/12

CPC classification number: C10G1/10 ,  C10G1/002 ,  C10G1/02 ,  C10G9/00 ,  C10G11/18 ,  C10G47/12 ,  C10G2400/20

Abstract: Disclosed are methods of reduction of chlorine in pyrolysis products derived from a mixed plastics stream. Methods may comprise: (a) causing pyrolysis of a plastic feedstock to produce a first stream of C1-C4 gaseous hydrocarbons and light gas olefins and a second stream comprising the remaining pyrolysis components. The second stream and hydrogen gas may be fed into a hydrocracker to produce a third stream of gaseous C1-C4 hydrocarbon gases and a fourth stream comprising the remaining hydrocracker components. The fourth stream may be fed to either (i) a steam cracker to produce a fifth stream comprising C1-C4 gaseous hydrocarbons and light gas olefins, a sixth stream comprising C6-C8 hydrocarbons and a seventh stream comprising hydrocarbons heavier than C8; or (ii) a fluidized catalytic cracker to produce an eighth stream comprising C1-C4 gases and light gas olefins and a ninth stream comprising hydrocarbons that are C5 or greater.