公开(公告)号：US09850352B2

公开(公告)日：2017-12-26

申请号：US15342510

申请日：2016-11-03

Applicant: TOPPAN PRINTING CO., LTD.

Inventor： Akiko Saiki ,  Yumiko Oomori

IPC: C08J3/03 ,  C08J3/05 ,  C08J3/11 ,  C08J5/18 ,  C08B15/04 ,  C09D101/04 ,  C08L1/04 ,  C08B15/02 ,  C08J3/09

CPC classification number: C08J3/03 ,  C08B15/02 ,  C08B15/04 ,  C08J3/05 ,  C08J3/095 ,  C08J3/11 ,  C08J5/18 ,  C08J2301/04 ,  C08L1/04 ,  C09D101/04

Abstract: A method of manufacturing a fine cellulose fiber dispersion liquid includes: an oxidation process in which a cellulose is subjected to an oxidation treatment to obtain an oxidized cellulose; and a dispersion process in which the oxidized cellulose obtained in the oxidation process is subjected to a dispersion treatment in a water-based medium in which a pH thereof is adjusted to 4 to 12 using either an ammonia water or an organic alkali to obtain the fine cellulose fiber dispersion liquid.

公开(公告)号：US09718969B2

公开(公告)日：2017-08-01

申请号：US15285236

申请日：2016-10-04

Applicant: TOPPAN PRINTING CO., LTD.

Inventor： Yumiko Oomori ,  Kosuke Shimizu ,  Nao Nishijima ,  Mitsuharu Kimura

IPC: C09D7/12 ,  C08B15/04 ,  C08J3/03 ,  C08J7/04 ,  C09D101/04 ,  C08L1/04 ,  C09D101/02 ,  C09J175/04 ,  C08L29/04

CPC classification number: C09D7/1291 ,  C08B15/04 ,  C08J3/03 ,  C08J7/047 ,  C08J2301/04 ,  C08J2401/02 ,  C08J2401/04 ,  C08J2403/02 ,  C08J2405/08 ,  C08J2429/04 ,  C08J2475/00 ,  C08J2475/04 ,  C08K3/34 ,  C08K2201/008 ,  C08L1/04 ,  C08L3/02 ,  C08L5/08 ,  C08L29/04 ,  C08L75/00 ,  C09D7/68 ,  C09D7/70 ,  C09D101/02 ,  C09D101/04 ,  C09J175/04

Abstract: A method for preparing a cellulose dispersion includes oxidizing cellulose; preparing cellulose nanofibers by defibrating the oxidized cellulose; and adding a water-soluble polymer and inorganic particles to the dispersion containing the cellulose nanofibers.

公开(公告)号：US09404016B2

公开(公告)日：2016-08-02

申请号：US13901503

申请日：2013-05-23

Applicant: Toppan Printing Co., Ltd.

Inventor： Yumiko Oomori ,  Kazuko Imai ,  Mitsuharu Kimura ,  Kosuke Shimizu

IPC: B32B5/02 ,  B32B7/10 ,  C08B15/02 ,  C09D167/00 ,  C09D123/26 ,  C09D175/04 ,  C09D105/08 ,  C09D133/00 ,  C09D101/02 ,  C09D101/04 ,  C09D133/06 ,  C09D151/06

CPC classification number: C09D167/00 ,  B32B5/02 ,  B32B7/10 ,  C08B15/02 ,  C08J7/047 ,  C08J2323/12 ,  C08J2367/02 ,  C08J2367/04 ,  C08J2423/16 ,  C08J2467/02 ,  C08J2467/04 ,  C08J2475/04 ,  C09D101/02 ,  C09D101/04 ,  C09D101/286 ,  C09D105/08 ,  C09D123/26 ,  C09D133/00 ,  C09D133/06 ,  C09D151/06 ,  C09D175/04 ,  Y10T428/265 ,  Y10T428/31515 ,  Y10T428/31591 ,  Y10T428/31779 ,  Y10T428/3179 ,  Y10T428/3188 ,  Y10T428/31971 ,  C08L1/00 ,  C08L2205/16

Abstract: The invention makes it possible to use a coating liquid of a fine cellulose fiber (a natural material) and to form a coated layer which can be used as a various-functions layer such as a gas barrier layer and water vapor barrier layer etc. by achieving good adhesiveness and coatability of the coating liquid, and as a result, provides a laminated material in which temporal degradation of a substrate and the fine cellulose fiber layer is prevented. The laminated body includes a substrate, an anchor layer arranged on a surface the substrate, and a fine cellulose fiber layer containing a fine cellulose fiber having a carboxy group, wherein the anchor layer contains at least one resin having a carboxy group, sulfonate group, amino group or hydroxyl group.

Abstract translation: 本发明使得可以使用细纤维素纤维（天然材料）的涂布液，并形成可以用作各种功能层如阻气层和水蒸气阻隔层等的涂层，通过 实现涂布液的良好的粘附性和涂布性，结果提供了防止基材和细纤维素纤维层的颞下降的层压材料。 层叠体包括基板，布置在基板的表面上的锚定层和含有具有羧基的细纤维素纤维的细纤维素纤维层，其中，所述锚层包含至少一种具有羧基的树脂，磺酸盐基， 氨基或羟基。

公开(公告)号：US20140228487A1

公开(公告)日：2014-08-14

申请号：US14257842

申请日：2014-04-21

Applicant: Toppan Printing Co., Ltd.

Inventor： Kosuke Shimizu ,  Yumiko Oomori ,  Mizuhiro Tani ,  Akiko Saiki

IPC: C08L1/10

CPC classification number: C08L1/10 ,  C08B15/02 ,  C08J5/18 ,  C08J2301/04 ,  C08K5/005 ,  C08K5/523 ,  G02B1/105 ,  G02B1/14 ,  G02B1/18 ,  G02B5/3033 ,  C08L1/04 ,  C08L51/06

Abstract: The present invention provides a formed article, or more specifically a transparent substrate, which effectively utilizes a natural stuff and which has a low linear expansion coefficient, a high light transmittance and an appropriate level of moisture permeability. The transparent substrate includes at least an oxidized polysaccharide and has a linear expansion coefficient of 50 ppm/° C. or less at 30-150° C. and a light transmittance of 70% or more at 660 nm. Its manufacturing method includes an oxidation process in which cellulose reacts with TEMPO or its derivatives as a catalyst to be oxidized in water under the presence of a co-oxidant, along with a fiberizing process in which the oxidized cellulose is fiberized in water to form a cellulose fiber, and a substrate-forming process in which a transparent substrate is formed from a cellulose dispersion liquid containing the cellulose fiber.

Abstract translation: 本发明提供了一种有效利用天然材料并且具有低线性膨胀系数，高透光率和适当水分渗透性水平的成形制品，或更具体地说是透明基材。 透明基材至少含有氧化多糖，在30〜150℃下的线膨胀系数为50ppm /℃以下，660nm下的透光率为70％以上。 其制造方法包括氧化方法，其中纤维素与TEMPO或其衍生物作为催化剂与助氧化剂存在下在水中氧化的催化剂一起，以及纤维化方法，其中氧化纤维素在水中纤维化形成 纤维素纤维和由含有纤维素纤维的纤维素分散液形成透明基材的基板形成方法。

公开(公告)号：US20140206798A1

公开(公告)日：2014-07-24

申请号：US14222212

申请日：2014-03-21

Applicant: TOPPAN PRINTING CO., LTD.

Inventor： Yumiko Oomori ,  Kosuke Shimizu ,  Nao Nishijima ,  Mitsuharu Kimura

IPC: C09D101/02

CPC classification number: C09D7/1291 ,  C08B15/04 ,  C08J3/03 ,  C08J7/047 ,  C08J2301/04 ,  C08J2401/02 ,  C08J2401/04 ,  C08J2403/02 ,  C08J2405/08 ,  C08J2429/04 ,  C08J2475/00 ,  C08J2475/04 ,  C08K3/34 ,  C08K2201/008 ,  C08L1/04 ,  C08L3/02 ,  C08L5/08 ,  C08L29/04 ,  C08L75/00 ,  C09D7/68 ,  C09D7/70 ,  C09D101/02 ,  C09D101/04 ,  C09J175/04

Abstract: [Problem] To provide a composition for film formation comprising cellulose fibers, a layered inorganic compound, and a water-soluble polymer, which are each dispersed on nano level, a method for preparing a cellulose dispersion capable of forming a moisture-resistant film containing cellulose nanofibers, a gas-barrier laminate obtained by use of the dispersion, and a packaging material using the laminate. [Solution] A film-forming composition comprising at least cellulose fibers and a swollen inorganic compound is prepared. The method of preparing a cellulose dispersion comprises the steps of oxidizing cellulose, fibrillating the thus oxidized cellulose to prepare cellulose nanofibers, and adding a water-soluble polymer and inorganic particles to the dispersion containing the cellulose nanofibers.

Abstract translation: [问题]提供一种包含各自分散在纳米级的纤维素纤维，层状无机化合物和水溶性聚合物的成膜用组合物，制备能够形成含有 纤维素纳米纤维，使用该分散体得到的阻气性叠层体，以及使用该层叠体的包装材料。 [溶液]制备至少包含纤维素纤维和溶胀无机化合物的成膜组合物。 制备纤维素分散体的方法包括氧化纤维素，将如此氧化的纤维素原纤化以制备纤维素纳米纤维，并将水溶性聚合物和无机颗粒加入到含有纤维素纳米纤维的分散体中的步骤。