公开(公告)号：US09388301B2

公开(公告)日：2016-07-12

申请号：US14257842

申请日：2014-04-21

Applicant: Toppan Printing Co., Ltd.

Inventor： Kosuke Shimizu ,  Yumiko Oomori ,  Mizuhiro Tani ,  Akiko Saiki

IPC: C08L1/00 ,  C08L1/10 ,  C08L1/04 ,  G02B1/10 ,  C09D101/08 ,  C08B15/02 ,  C08J5/18 ,  G02B5/30

CPC classification number: C08L1/10 ,  C08B15/02 ,  C08J5/18 ,  C08J2301/04 ,  C08K5/005 ,  C08K5/523 ,  G02B1/105 ,  G02B1/14 ,  G02B1/18 ,  G02B5/3033 ,  C08L1/04 ,  C08L51/06

Abstract: The present invention provides a formed article, or more specifically a transparent substrate, which effectively utilizes a natural stuff and which has a low linear expansion coefficient, a high light transmittance and an appropriate level of moisture permeability. The transparent substrate includes at least an oxidized polysaccharide and has a linear expansion coefficient of 50 ppm/° C. or less at 30-150° C. and a light transmittance of 70% or more at 660 nm. Its manufacturing method includes an oxidation process in which cellulose reacts with TEMPO or its derivatives as a catalyst to be oxidized in water under the presence of a co-oxidant, along with a fiberizing process in which the oxidized cellulose is fiberized in water to form a cellulose fiber, and a substrate-forming process in which a transparent substrate is formed from a cellulose dispersion liquid containing the cellulose fiber.

Abstract translation: 本发明提供了一种有效利用天然材料并且具有低线性膨胀系数，高透光率和适当水分渗透性水平的成形制品，或更具体地说是透明基材。 透明基材至少含有氧化多糖，在30〜150℃下的线膨胀系数为50ppm /℃以下，660nm下的透光率为70％以上。 其制造方法包括氧化方法，其中纤维素与TEMPO或其衍生物作为催化剂与助氧化剂存在下在水中氧化的催化剂一起，以及纤维化方法，其中氧化纤维素在水中纤维化形成 纤维素纤维和由含有纤维素纤维的纤维素分散液形成透明基材的基板形成方法。

公开(公告)号：US11136164B2

公开(公告)日：2021-10-05

申请号：US16157686

申请日：2018-10-11

Applicant: TOPPAN PRINTING CO., LTD. ,  Nippon Paper Industries Co., Ltd.

Inventor： Kosuke Shimizu ,  Akiko Saiki ,  Kaori Yamabe

IPC: B65D5/56 ,  D21H19/34 ,  D21H19/84 ,  D21H11/18 ,  B32B27/00 ,  B32B23/06 ,  B65D65/40

Abstract: A barrier paper includes a paper base material and a barrier layer containing cellulose fibers formed on the paper base material, in which an integrated value from 10.0 μm to 500.0 μm, obtained from a volume-based particle size distribution diagram when a dispersion containing the cellulose fibers is measured by laser diffraction, is 30% or more.

公开(公告)号：US20190077541A1

公开(公告)日：2019-03-14

申请号：US16157686

申请日：2018-10-11

Applicant: TOPPAN PRINTING CO., LTD. ,  Nippon Paper Industries Co. Ltd.

Inventor： Kosuke Shimizu ,  Akiko Saiki ,  Kaori Yamabe

IPC: B65D5/56 ,  D21H19/34 ,  D21H19/84

Abstract: A barrier paper includes a paper base material and a barrier layer containing cellulose fibers formed on the paper base material, in which an integrated value from 10.0 μm to 500.0 μm, obtained from a volume-based particle size distribution diagram when a dispersion containing the cellulose fibers is measured by laser diffraction, is 30% or more.

公开(公告)号：US20140199541A1

公开(公告)日：2014-07-17

申请号：US14218089

申请日：2014-03-18

Applicant: TOPPAN PRINTING CO., LTD.

Inventor： Mitsuharu KIMURA ,  Yumiko Oomori ,  Nao Nishijima ,  Kosuke Shimizu

IPC: C09D101/02 ,  B32B23/04

CPC classification number: C09D101/02 ,  B32B23/04 ,  B32B2255/10 ,  B32B2255/12 ,  B32B2307/7242 ,  C08J7/047 ,  C08J2301/02 ,  C08J2377/00 ,  C08J2401/02 ,  D21H11/20 ,  D21H19/34 ,  D21H27/30 ,  Y10T428/253 ,  Y10T428/31739 ,  Y10T428/31978 ,  Y10T428/31982

Abstract: A laminate having high adhesion between a fine cellulose layer and a base material, a method for producing the same, and a gas barrier material. The laminate is such that a fine cellulose layer containing fine cellulose having a carboxyl group is laminated on the base material, and a mixed layer in which the fine cellulose is mixed in the base material is further interposed between the base material and the fine cellulose layer. This laminate can be produced by coating the base material with a dispersion containing fine cellulose having a carboxyl group, swelling the base material with the thus coated dispersion, and drying the swollen base material and the coated dispersion. The laminate may also be produced by providing a swollen base material, coating the swollen base material with a dispersion containing fine cellulose having a carboxyl group, and drying the base material and the coated dispersion.

Abstract translation: 在纤维素纤维素层和基材之间具有高粘附性的层压体，其制造方法和阻气材料。 层压体是这样的，在基材上层压含有具有羧基的微细纤维素的微细纤维素层，并且在基材和细纤维素层之间进一步插入其中在基材中混合微细纤维素的混合层 。 该层压体可以通过用含有具有羧基的微细纤维素的分散体涂布基材，利用如此涂布的分散体使基材膨胀，并干燥溶胀的基材和涂布分散体来制造。 层压体也可以通过提供膨胀的基体材料，用包含具有羧基的细纤维素的分散体涂覆溶胀的基材，并干燥基材和涂布的分散体来制备。

公开(公告)号：US10358253B2

公开(公告)日：2019-07-23

申请号：US16156211

申请日：2018-10-10

Applicant: TOPPAN PRINTING CO., LTD.

Inventor： Akiko Saiki ,  Kosuke Shimizu

IPC: B32B1/02 ,  B65D3/06 ,  B32B27/10 ,  B32B29/00 ,  B65D3/22 ,  B32B5/02 ,  B65D3/04 ,  B65D3/10 ,  B65D65/40

Abstract: A paper cup includes barrier paper, the barrier paper including at least a paper base material, a reinforcing layer containing cellulose nanofibers which is formed on the paper base material, and a sealant layer formed on the reinforcing layer, in which after the paper cup is caused to free-fall 5 times towards a concrete floor surface from a height of 1 m with the bottom portion being disposed downward, the paper cup has a buckling strength of 350 N or more in a case of being sandwiched between two parallel plate surfaces and compressed in a height direction of the body portion, and has a lateral pressing strength of 4 N or more in a case where the body portion is pressed by 10 mm at a ⅔ height, from a bottom, of the entire height of the paper cup.

公开(公告)号：US09994726B2

公开(公告)日：2018-06-12

申请号：US14218089

申请日：2014-03-18

Applicant: TOPPAN PRINTING CO., LTD.

Inventor： Mitsuharu Kimura ,  Yumiko Oomori ,  Nao Nishijima ,  Kosuke Shimizu

IPC: B23B23/04 ,  C09D101/02 ,  B32B23/04 ,  C08J7/04 ,  D21H27/30 ,  D21H11/20 ,  D21H19/34

CPC classification number: C09D101/02 ,  B32B23/04 ,  B32B2255/10 ,  B32B2255/12 ,  B32B2307/7242 ,  C08J7/047 ,  C08J2301/02 ,  C08J2377/00 ,  C08J2401/02 ,  D21H11/20 ,  D21H19/34 ,  D21H27/30 ,  Y10T428/253 ,  Y10T428/31739 ,  Y10T428/31978 ,  Y10T428/31982

Abstract: A laminate having high adhesion between a fine cellulose layer and a base material, a method for producing the same, and a gas barrier material. The laminate is such that a fine cellulose layer containing fine cellulose having a carboxyl group is laminated on the base material, and a mixed layer in which the fine cellulose is mixed in the base material is further interposed between the base material and the fine cellulose layer. This laminate can be produced by coating the base material with a dispersion containing fine cellulose having a carboxyl group, swelling the base material with the thus coated dispersion, and drying the swollen base material and the coated dispersion. The laminate may also be produced by providing a swollen base material, coating the swollen base material with a dispersion containing fine cellulose having a carboxyl group, and drying the base material and the coated dispersion.

公开(公告)号：US09718969B2

公开(公告)日：2017-08-01

申请号：US15285236

申请日：2016-10-04

Applicant: TOPPAN PRINTING CO., LTD.

Inventor： Yumiko Oomori ,  Kosuke Shimizu ,  Nao Nishijima ,  Mitsuharu Kimura

IPC: C09D7/12 ,  C08B15/04 ,  C08J3/03 ,  C08J7/04 ,  C09D101/04 ,  C08L1/04 ,  C09D101/02 ,  C09J175/04 ,  C08L29/04

CPC classification number: C09D7/1291 ,  C08B15/04 ,  C08J3/03 ,  C08J7/047 ,  C08J2301/04 ,  C08J2401/02 ,  C08J2401/04 ,  C08J2403/02 ,  C08J2405/08 ,  C08J2429/04 ,  C08J2475/00 ,  C08J2475/04 ,  C08K3/34 ,  C08K2201/008 ,  C08L1/04 ,  C08L3/02 ,  C08L5/08 ,  C08L29/04 ,  C08L75/00 ,  C09D7/68 ,  C09D7/70 ,  C09D101/02 ,  C09D101/04 ,  C09J175/04

Abstract: A method for preparing a cellulose dispersion includes oxidizing cellulose; preparing cellulose nanofibers by defibrating the oxidized cellulose; and adding a water-soluble polymer and inorganic particles to the dispersion containing the cellulose nanofibers.

公开(公告)号：US09404016B2

公开(公告)日：2016-08-02

申请号：US13901503

申请日：2013-05-23

Applicant: Toppan Printing Co., Ltd.

Inventor： Yumiko Oomori ,  Kazuko Imai ,  Mitsuharu Kimura ,  Kosuke Shimizu

IPC: B32B5/02 ,  B32B7/10 ,  C08B15/02 ,  C09D167/00 ,  C09D123/26 ,  C09D175/04 ,  C09D105/08 ,  C09D133/00 ,  C09D101/02 ,  C09D101/04 ,  C09D133/06 ,  C09D151/06

CPC classification number: C09D167/00 ,  B32B5/02 ,  B32B7/10 ,  C08B15/02 ,  C08J7/047 ,  C08J2323/12 ,  C08J2367/02 ,  C08J2367/04 ,  C08J2423/16 ,  C08J2467/02 ,  C08J2467/04 ,  C08J2475/04 ,  C09D101/02 ,  C09D101/04 ,  C09D101/286 ,  C09D105/08 ,  C09D123/26 ,  C09D133/00 ,  C09D133/06 ,  C09D151/06 ,  C09D175/04 ,  Y10T428/265 ,  Y10T428/31515 ,  Y10T428/31591 ,  Y10T428/31779 ,  Y10T428/3179 ,  Y10T428/3188 ,  Y10T428/31971 ,  C08L1/00 ,  C08L2205/16

Abstract: The invention makes it possible to use a coating liquid of a fine cellulose fiber (a natural material) and to form a coated layer which can be used as a various-functions layer such as a gas barrier layer and water vapor barrier layer etc. by achieving good adhesiveness and coatability of the coating liquid, and as a result, provides a laminated material in which temporal degradation of a substrate and the fine cellulose fiber layer is prevented. The laminated body includes a substrate, an anchor layer arranged on a surface the substrate, and a fine cellulose fiber layer containing a fine cellulose fiber having a carboxy group, wherein the anchor layer contains at least one resin having a carboxy group, sulfonate group, amino group or hydroxyl group.

Abstract translation: 本发明使得可以使用细纤维素纤维（天然材料）的涂布液，并形成可以用作各种功能层如阻气层和水蒸气阻隔层等的涂层，通过 实现涂布液的良好的粘附性和涂布性，结果提供了防止基材和细纤维素纤维层的颞下降的层压材料。 层叠体包括基板，布置在基板的表面上的锚定层和含有具有羧基的细纤维素纤维的细纤维素纤维层，其中，所述锚层包含至少一种具有羧基的树脂，磺酸盐基， 氨基或羟基。

公开(公告)号：US20140228487A1

公开(公告)日：2014-08-14

申请号：US14257842

申请日：2014-04-21

Applicant: Toppan Printing Co., Ltd.

Inventor： Kosuke Shimizu ,  Yumiko Oomori ,  Mizuhiro Tani ,  Akiko Saiki

IPC: C08L1/10

CPC classification number: C08L1/10 ,  C08B15/02 ,  C08J5/18 ,  C08J2301/04 ,  C08K5/005 ,  C08K5/523 ,  G02B1/105 ,  G02B1/14 ,  G02B1/18 ,  G02B5/3033 ,  C08L1/04 ,  C08L51/06

Abstract: The present invention provides a formed article, or more specifically a transparent substrate, which effectively utilizes a natural stuff and which has a low linear expansion coefficient, a high light transmittance and an appropriate level of moisture permeability. The transparent substrate includes at least an oxidized polysaccharide and has a linear expansion coefficient of 50 ppm/° C. or less at 30-150° C. and a light transmittance of 70% or more at 660 nm. Its manufacturing method includes an oxidation process in which cellulose reacts with TEMPO or its derivatives as a catalyst to be oxidized in water under the presence of a co-oxidant, along with a fiberizing process in which the oxidized cellulose is fiberized in water to form a cellulose fiber, and a substrate-forming process in which a transparent substrate is formed from a cellulose dispersion liquid containing the cellulose fiber.

Abstract translation: 本发明提供了一种有效利用天然材料并且具有低线性膨胀系数，高透光率和适当水分渗透性水平的成形制品，或更具体地说是透明基材。 透明基材至少含有氧化多糖，在30〜150℃下的线膨胀系数为50ppm /℃以下，660nm下的透光率为70％以上。 其制造方法包括氧化方法，其中纤维素与TEMPO或其衍生物作为催化剂与助氧化剂存在下在水中氧化的催化剂一起，以及纤维化方法，其中氧化纤维素在水中纤维化形成 纤维素纤维和由含有纤维素纤维的纤维素分散液形成透明基材的基板形成方法。

公开(公告)号：US20140206798A1

公开(公告)日：2014-07-24

申请号：US14222212

申请日：2014-03-21

Applicant: TOPPAN PRINTING CO., LTD.

Inventor： Yumiko Oomori ,  Kosuke Shimizu ,  Nao Nishijima ,  Mitsuharu Kimura

IPC: C09D101/02

CPC classification number: C09D7/1291 ,  C08B15/04 ,  C08J3/03 ,  C08J7/047 ,  C08J2301/04 ,  C08J2401/02 ,  C08J2401/04 ,  C08J2403/02 ,  C08J2405/08 ,  C08J2429/04 ,  C08J2475/00 ,  C08J2475/04 ,  C08K3/34 ,  C08K2201/008 ,  C08L1/04 ,  C08L3/02 ,  C08L5/08 ,  C08L29/04 ,  C08L75/00 ,  C09D7/68 ,  C09D7/70 ,  C09D101/02 ,  C09D101/04 ,  C09J175/04

Abstract: [Problem] To provide a composition for film formation comprising cellulose fibers, a layered inorganic compound, and a water-soluble polymer, which are each dispersed on nano level, a method for preparing a cellulose dispersion capable of forming a moisture-resistant film containing cellulose nanofibers, a gas-barrier laminate obtained by use of the dispersion, and a packaging material using the laminate. [Solution] A film-forming composition comprising at least cellulose fibers and a swollen inorganic compound is prepared. The method of preparing a cellulose dispersion comprises the steps of oxidizing cellulose, fibrillating the thus oxidized cellulose to prepare cellulose nanofibers, and adding a water-soluble polymer and inorganic particles to the dispersion containing the cellulose nanofibers.

Abstract translation: [问题]提供一种包含各自分散在纳米级的纤维素纤维，层状无机化合物和水溶性聚合物的成膜用组合物，制备能够形成含有 纤维素纳米纤维，使用该分散体得到的阻气性叠层体，以及使用该层叠体的包装材料。 [溶液]制备至少包含纤维素纤维和溶胀无机化合物的成膜组合物。 制备纤维素分散体的方法包括氧化纤维素，将如此氧化的纤维素原纤化以制备纤维素纳米纤维，并将水溶性聚合物和无机颗粒加入到含有纤维素纳米纤维的分散体中的步骤。