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    Membranes for fuel cells, method for producing said membranes and production of fuel cells using membranes of this type
    11.
    发明申请
    Membranes for fuel cells, method for producing said membranes and production of fuel cells using membranes of this type 失效
    用于燃料电池的膜，用于制造所述膜的方法和使用这种膜的燃料电池的生产

    公开(公告)号：US20070003808A1

    公开(公告)日：2007-01-04

    申请号：US11498730

    申请日：2006-08-04

    申请人： Dieter Melzner ,  Annette Reiche ,  Ulrich Maehr ,  Suzana Kiel ,  Stefan Haufe

    发明人： Dieter Melzner ,  Annette Reiche ,  Ulrich Maehr ,  Suzana Kiel ,  Stefan Haufe

    IPC分类号： H01M8/10 ,  C08J5/22

    CPC分类号： B01D71/58 ,  C08J5/22 ,  H01M8/02 ,  H01M8/10 ,  Y02P70/56

    摘要： A membrane for fuel cells, which is characterized by a homogeneous absorption and good retention of doping agents, and which guarantees a high mechanical stability at high temperatures when doped. Such membranes consist of at least one polymer, whose nitrogen atoms are chemically bonded to a central atom of a derivative of a polybasic inorganic oxo acid. The membranes are produced from polymer solutions that are devoid of water and oxo acid derivatives, by heating the solution that has been introduced into a membrane mold until a self-supporting membrane has been formed and then by thermally regulating the latter. Inventive fuel cells having a membrane electrode assembly (MEA) that comprises a membrane of the invention and phosphoric acid as the doping agent have, for example, an impedance of 0.5-1 Ωcm2 at a measuring frequency of 1000 Hz and at an operating temperature of 160° C. and a gas flow for hydrogen of 170 mL/min and for air of 570 mL/min. They can be used as high-temperature polyelectrolyte membrane fuel cells for a working temperature of up to at least 250° C.

    摘要翻译： 用于燃料电池的膜，其特征在于掺杂剂具有均匀的吸收和良好的保留性，并且当掺杂时，其在高温下保证高的机械稳定性。 这样的膜由至少一种聚合物组成，其中氮原子与多元无机含氧酸的衍生物的中心原子化学键合。 通过加热已经引入到膜模具中的溶液直到形成自支撑膜，然后通过热调节后者，由不含水和含氧酸衍生物的聚合物溶液制备膜。 具有包含本发明的膜和作为掺杂剂的磷酸的膜电极组件（MEA）的本发明的燃料电池在测量频率为例如0.5-1Ωm2 / 1000Hz，工作温度为160℃，氢气流量为170mL / min，空气为570mL / min。 它们可以用作高温聚电解质膜燃料电池，工作温度高达至少250°C。

    Membrane electrode assembly for a fuel cell
    13.
    发明申请
    Membrane electrode assembly for a fuel cell 有权
    用于燃料电池的膜电极组件

    公开(公告)号：US20070072045A1

    公开(公告)日：2007-03-29

    申请号：US11605464

    申请日：2006-11-29

    申请人： Stefan Haufe ,  Annette Reiche ,  Suzana Kiel ,  Ulrich Maehr ,  Dieter Melzner

    发明人： Stefan Haufe ,  Annette Reiche ,  Suzana Kiel ,  Ulrich Maehr ,  Dieter Melzner

    IPC分类号： H01M2/08 ,  H01M8/10 ,  H01M8/24

    CPC分类号： H01M8/0273 ,  H01M8/1004 ,  H01M8/103 ,  H01M8/1048 ,  H01M8/242

    摘要： A membrane electrode assembly (MEA) for a fuel cell, which has a planar polymer membrane. This membrane, in a tangentially inner area, is coated on both sides with electrode structure, and, in a tangentially outer area projecting at least on one side beyond the electrode structure coating, is connected to a sealing member. A marginal zone of the polymer membrane is embedded in the elastomer sealing member. The sealing member extends tangentially inward to a transition area that lies tangentially between the outer area and the inner area, where it overlaps the electrode structures on outer faces of the electrode structures, on both of the sides of the polymer membrane.

    摘要翻译： 一种用于燃料电池的膜电极组件（MEA），其具有平面聚合物膜。 该膜在切向内部的区域中用电极结构涂覆在两侧，并且在至少在电极结构涂层之上的至少一侧突出的切向外部区域中连接到密封构件。 聚合物膜的边缘区域嵌入弹性体密封构件中。 密封构件向内切向延伸到在外部区域和内部区域之间切向位于聚合物膜的两侧上的与电极结构的外表面上的电极结构重叠的过渡区域。

    Proton-conducting electrolyte membrane method for production and use thereof in a fuel cell
    14.
    发明申请
    Proton-conducting electrolyte membrane method for production and use thereof in a fuel cell 失效
    用于在燃料电池中制造和使用的质子传导电解质膜方法

    公开(公告)号：US20050118476A1

    公开(公告)日：2005-06-02

    申请号：US10495222

    申请日：2002-11-07

    申请人： Dieter Melzner ,  Suzana Kiel ,  Ulrich Mahr ,  Annette Reiche

    发明人： Dieter Melzner ,  Suzana Kiel ,  Ulrich Mahr ,  Annette Reiche

    IPC分类号： C08J5/22 ,  H01M8/10

    CPC分类号： C08J5/2256 ,  C08J2379/06

    摘要： A proton-conducting electrolyte membrane is disclosed, comprising at least one base material and at least one dopant, which is the reaction product of an at least dibasic inorganic acid with an organic compound, comprising one acidic hydroxyl group, or the condensation product of said compound with a polybasic acid. The membrane may be produced by a single step method, which avoids the use of dangerous materials and environmental pollutants. Subsequent doping of the membrane, e.g., in conjunction with assembly of the membrane electrode assembly (MEA) is not excluded. The electrolyte membrane has a high and constant mechanical stability and flexibility, excellent chemical and thermal stability and a high and constant conductivity. The membrane may be used in a fuel cell in a wide temperature range from 50° C. to more than 200° C., for example, whereby the fuel cell has a high and constant power level over the entire temperature range.

    摘要翻译： 公开了一种质子传导电解质膜，其包括至少一种基材和至少一种掺杂剂，其是至少二元无机酸与有机化合物的反应产物，其包含一个酸性羟基或所述 与多元酸的化合物。 膜可以通过单步法制造，避免使用危险物质和环境污染物。 后续的膜的掺杂，例如与膜电极组件（MEA）的组装结合不排除。 电解质膜具有高且恒定的机械稳定性和柔韧性，优异的化学和热稳定性以及高且恒定的导电性。 该膜可以在例如50℃至200℃以上的宽温度范围的燃料电池中使用，由此燃料电池在整个温度范围内具有高且恒定的功率水平。

    Membranes for fuel cells, method for producing said membranes and production of fuel cells using membranes of this type
    16.
    发明授权
    Membranes for fuel cells, method for producing said membranes and production of fuel cells using membranes of this type 失效
    用于燃料电池的膜，用于制造所述膜的方法和使用这种膜的燃料电池的生产

    公开(公告)号：US07682723B2

    公开(公告)日：2010-03-23

    申请号：US11498730

    申请日：2006-08-04

    申请人： Dieter Melzner ,  Annette Reiche ,  Ulrich Maehr ,  Suzana Kiel ,  Stefan Haufe

    发明人： Dieter Melzner ,  Annette Reiche ,  Ulrich Maehr ,  Suzana Kiel ,  Stefan Haufe

    IPC分类号： H01M8/10 ,  C08J5/20

    CPC分类号： B01D71/58 ,  C08J5/22 ,  H01M8/02 ,  H01M8/10 ,  Y02P70/56

    摘要： A membrane for fuel cells, which is characterized by a homogeneous absorption and good retention of doping agents, and which guarantees a high mechanical stability at high temperatures when doped. Such membranes consist of at least one polymer, whose nitrogen atoms are chemically bonded to a central atom of a derivative of a polybasic inorganic oxo acid. The membranes are produced from polymer solutions that are devoid of water and oxo acid derivatives, by heating the solution that has been introduced into a membrane mold until a self-supporting membrane has been formed and then by thermally regulating the latter. Inventive fuel cells having a membrane electrode assembly (MEA) that comprises a membrane of the invention and phosphoric acid as the doping agent have, for example, an impedance of 0.5-1 Ωcm2 at a measuring frequency of 1000 Hz and at an operating temperature of 160° C. and a gas flow for hydrogen of 170 mL/min and for air of 570 mL/min. They can be used as high-temperature polyelectrolyte membrane fuel cells for a working temperature of up to at least 250° C.

    摘要翻译： 用于燃料电池的膜，其特征在于掺杂剂具有均匀的吸收和良好的保留性，并且当掺杂时，其在高温下保证高的机械稳定性。 这样的膜由至少一种聚合物组成，其中氮原子与多元无机含氧酸的衍生物的中心原子化学键合。 通过加热已经引入到膜模具中的溶液直到形成自支撑膜，然后通过热调节后者，由不含水和含氧酸衍生物的聚合物溶液制备膜。 具有包含本发明的膜和磷酸作为掺杂剂的膜电极组件（MEA）的本发明的燃料电池例如在1000Hz的测量频率和操作时具有例如0.5-1＆OHgr; cm 2的阻抗 温度为160℃，氢气流量为170mL / min，空气为570mL / min。 它们可以用作高温聚电解质膜燃料电池，工作温度高达至少250°C。

    Proton-conducting electrolyte membrane method for production and use thereof in a fuel cell
    17.
    发明授权
    Proton-conducting electrolyte membrane method for production and use thereof in a fuel cell 失效
    用于在燃料电池中制造和使用的质子传导电解质膜方法

    公开(公告)号：US07655334B2

    公开(公告)日：2010-02-02

    申请号：US10495222

    申请日：2002-11-07

    申请人： Dieter Melzner ,  Suzana Kiel ,  Ulrich Mahr ,  Annette Reiche

    发明人： Dieter Melzner ,  Suzana Kiel ,  Ulrich Mahr ,  Annette Reiche

    IPC分类号： H01M8/10

    CPC分类号： C08J5/2256 ,  C08J2379/06

    摘要： A proton-conducting electrolyte membrane is disclosed, comprising at least one base material and at least one dopant, which is the reaction product of an at least dibasic inorganic acid with an organic compound, comprising one acidic hydroxyl group, or the condensation product of said compound with a polybasic acid. The membrane may be produced by a single step method, which avoids the use of dangerous materials and environmental pollutants. Subsequent doping of the membrane, e.g., in conjunction with assembly of the membrane electrode assembly (MEA) is not excluded. The electrolyte membrane has a high and constant mechanical stability and flexibility, excellent chemical and thermal stability and a high and constant conductivity. The membrane may be used in a fuel cell in a wide temperature range from 50° C. to more than 200° C., for example, whereby the fuel cell has a high and constant power level over the entire temperature range.

    摘要翻译： 公开了一种质子传导电解质膜，其包括至少一种基材和至少一种掺杂剂，其是至少二元无机酸与有机化合物的反应产物，其包含一个酸性羟基或所述 与多元酸的化合物。 膜可以通过单步法制造，避免使用危险物质和环境污染物。 后续的膜的掺杂，例如与膜电极组件（MEA）的组装结合不排除。 电解质膜具有高且恒定的机械稳定性和柔韧性，优异的化学和热稳定性以及高且恒定的导电性。 该膜可以在例如50℃至200℃以上的宽温度范围的燃料电池中使用，由此燃料电池在整个温度范围内具有高且恒定的功率水平。

    Fuel cell with insulating element
    18.
    发明申请
    Fuel cell with insulating element 审中-公开
    带绝缘元件的燃料电池

    公开(公告)号：US20070231651A1

    公开(公告)日：2007-10-04

    申请号：US11716506

    申请日：2007-03-09

    申请人： Stefan Haufe ,  Annette Reiche ,  Dieter Melzner ,  Fabian Walter

    发明人： Stefan Haufe ,  Annette Reiche ,  Dieter Melzner ,  Fabian Walter

    IPC分类号： H01M8/10 ,  H01M2/08

    CPC分类号： H01M8/0273 ,  H01M8/0284 ,  H01M8/04007 ,  H01M8/04089 ,  H01M2008/1095

    摘要： The invention relates to an insulating element for a fuel cell stack, which is composed of a thermally insulating plastic or plastic composite material. The insulating element is connected to the end plate and the bipolar end plate of the stack and achieves virtually uniform distribution of temperature and flow density along the fuel cell stack in the cell operating mode. As a result, the condensation of product water is prevented. The efficiency of the fuel cell stack is increased since it is possible to dispense with external heating of the stack by a cell current and costly measuring and control technology,

    摘要翻译： 本发明涉及一种用绝热塑料或塑料复合材料制成的燃料电池堆绝缘元件。 绝缘元件连接到堆叠的端板和双极端板，并且在电池工作模式下实现沿着燃料电池堆的温度和流量密度的实质上均匀的分布。 结果，防止了产品水的冷凝。 燃料电池堆的效率增加，因为可以通过电池电流和昂贵的测量和控制技术免除堆叠的外部加热，