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公开(公告)号:US5494882A
公开(公告)日:1996-02-27
申请号:US233759
申请日:1994-04-26
CPC分类号: B41M5/3333
摘要: It is provided with a thermal recording material having a support coated with a coating solution as a color developing layer. The color developing layer has a colorless dye precursor which is normally colorless or light-colored, and a developer which reacts with the dye precursor to cause color development thereof upon heating. The developer is a bisthiourea compound represented by, for example, a formula (A-2): ##STR1## and the thermal color developing layer contains no sensitizer. In the thermal recording materials of the present invention, substantially no color is developed at a temperature of 120.degree. C. while color development can be caused in response to heating with a thermal head or a laser beam. The developed color on the material can be erased upon contacting with alcoholic solvents, depending on the thiourea compound contained in the color developing layer. After erasure of the image, the material can be used again for recording with a thermal head or a laser beam.
摘要翻译: 其具有热敏记录材料,其具有涂覆有作为彩色显影层的涂布溶液的载体。 彩色显影层具有通常无色或浅色的无色染料前体,以及与染料前体反应以在加热时使其显色的显影剂。 显色剂是例如由式(A-2)表示的二硫脲化合物:(IMA)(A-2),热显色层不含敏化剂。 在本发明的热敏记录材料中,在120℃的温度下基本上没有显色,同时可以利用热敏头或激光束加热而引起显色。 取决于包含在彩色显影层中的硫脲化合物,材料上显影的颜色可以在与醇溶剂接触时被擦除。 在擦除图像之后,可以再次使用材料用热敏头或激光束进行记录。
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公开(公告)号:US5482913A
公开(公告)日:1996-01-09
申请号:US166815
申请日:1993-12-15
申请人: Toshimi Satake , Tomoaki Nagai , Toshiyuki Takano , Akio Sekine
发明人: Toshimi Satake , Tomoaki Nagai , Toshiyuki Takano , Akio Sekine
CPC分类号: B41M5/32 , B41M5/3335
摘要: A dispersion of a carbonate type blocked color developer having a hydroxyl group having a color developing function which is blocked by an O-substituted oxycarbonyl group (--(C.dbd.O)OR.sub.1), and a metal salt of an organic acid or inorganic acid or a leuco dye are mixed to obtain an opaque undeveloped coating color, and the coating color is coated on paper or the like to obtain a recording sheet. Also, the coating color is further mixed with a light absorbent to obtain an opaque undeveloped coating color, which is coated on paper or the like to obtain an optical recording sheet.
摘要翻译: 具有由O-取代的氧羰基( - (C = O)OR 1)封端的具有显色功能的羟基的碳酸酯型阻挡显色剂的分散体和有机酸或无机酸的金属盐或 将无色染料混合以获得不透明的未显影涂料颜色,并将涂料涂布在纸等上以获得记录片材。 此外,涂料颜色进一步与光吸收剂混合以获得不透明的未显影涂料颜色,其涂布在纸等上以获得光学记录片材。
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公开(公告)号:US5434119A
公开(公告)日:1995-07-18
申请号:US903566
申请日:1992-06-24
申请人: Toshimi Satake , Tomoaki Nagai , Toshiyuki Takano , Akio Sekine
发明人: Toshimi Satake , Tomoaki Nagai , Toshiyuki Takano , Akio Sekine
IPC分类号: B41M5/155 , B41M5/30 , B41M5/32 , B41M5/333 , C07C69/96 , C07C271/44 , C07C271/46 , C07C271/56 , C07C271/58 , C07C315/04 , C07C317/22 , B41M5/40
CPC分类号: C07C315/04 , B41M5/155 , B41M5/32 , B41M5/3333 , B41M5/3335 , C07C271/44 , C07C271/46 , C07C271/56 , C07C271/58 , C07C69/96 , B41M5/3336 , C07C2101/14 , Y10S430/146
摘要: A transparent recording medium is disclosed which can directly record a fine, precise image. With the recording medium, a compact, fine image occupying a small storage space can be easily enlarged and confirmed by an enlarged projection. It is prepared by applying a coating liquid for recording comprising a developer in which a hydroxyl group with a developing function is blocked by an N-substituted carbamoyl group or an O-substituted oxycarbonyl group, an iron salt of an organic acid or a leuco dye, a near-infrared absorbing agent, and a binder, uniformly dissolved in an organic solvent such as MEK, to a transparent plastic substrate, and drying to obtain a transparent recording layer with a thickness of 3 .mu.m to 8 .mu.m. A visible, precise, fine direct image can then be recorded using a semiconductor laser beam.
摘要翻译: 公开了可直接记录精细图像的透明记录介质。 利用记录介质,可以容易地放大占据小存储空间的紧凑而精细的图像,并通过放大的投影来确认。 通过涂布包含显影功能的显影剂的显影剂用N-取代氨基甲酰基或O-取代氧羰基封闭的显影剂,有机酸的铁盐或无色染料 ,近红外吸收剂和粘合剂,均匀地溶解在有机溶剂如MEK中,并且干燥,得到厚度为3μm至8μm的透明记录层。 然后可以使用半导体激光束来记录可见,精确,精细的直接图像。
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公开(公告)号:US5707778A
公开(公告)日:1998-01-13
申请号:US613720
申请日:1996-03-12
申请人: Toshiaki Minami , Tomoaki Nagai , Kaoru Hamada , Akio Sekine , Toshimi Satake , Toshiyuki Takano , Hideki Hayasaka
发明人: Toshiaki Minami , Tomoaki Nagai , Kaoru Hamada , Akio Sekine , Toshimi Satake , Toshiyuki Takano , Hideki Hayasaka
CPC分类号: B41M5/3333 , B41M5/26 , B41M5/46 , B41M5/465 , Y10S430/145 , Y10S430/146 , Y10S430/165
摘要: An optical recording medium including a substrate having thereon a recording layer containing a dye precursor, a color developer reactable with the dye precursor to develop a color, and a light absorbent for converting light to heat, characterized in that the color developer is at least one compound of Formula (1): (R--NH (C.dbd.S) NH)n--Z (1) (wherein R denotes a substituted or unsubstituted alkyl, cycloalkyl, aryl, aralkyl, or alkenyl. n is an integer of 2 or more, and Z denotes a group having a valence of 2 or more.). The optical recording medium is superior in heat resistance and plasticizer resistance of the recorded image, heat resistance of background, water resistance, and moisture resistance.).
摘要翻译: 一种光记录介质,包括其上具有含有染料前体的记录层的基底,可与染料前体反应以显色的彩色显影剂和用于将光转换成热的光吸收剂,其特征在于,彩色显影剂是至少一种 式(1)的化合物:( R-NH(C = S)NH)nZ(1)(其中R表示取代或未取代的烷基,环烷基,芳基,芳烷基或烯基,n为2以上的整数, Z表示2价以上的基团。 光记录介质的记录图像的耐热性和耐增塑剂性,背景耐热性,耐水性和耐湿性优异。
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公开(公告)号:US4853362A
公开(公告)日:1989-08-01
申请号:US234463
申请日:1988-08-19
申请人: Toshimi Satake , Tadakazu Fukuchi , Toshiaki Minami , Tomoaki Nagai , Toshio Kaneko , Fumio Fujimura
发明人: Toshimi Satake , Tadakazu Fukuchi , Toshiaki Minami , Tomoaki Nagai , Toshio Kaneko , Fumio Fujimura
CPC分类号: B41M5/327 , B41M5/3377 , B41M5/3275 , Y10S428/913 , Y10S428/914
摘要: A heat-sensitive recording material has a support and a color-developing layer which comprises both as a colorless basic chromogenic dye at least one of a particular fluorane-type leuco dye and a particular divinyl compound and as a stabilizer a particular halogen-substituted zinc benzoate derivative.This heat-sensitive recording material is superior in light resistance, weather resistance, oil resistance and optical readability in the near infrared region.
摘要翻译: 热敏记录材料具有支撑体和显色层,其包含特定的氟烷型无色染料和特定二乙烯基化合物中的至少一种作为无色碱性显色染料,作为稳定剂,特定的卤素取代的锌 苯甲酸酯衍生物。 该热敏记录材料在近红外区域的耐光性,耐气候性,耐油性和光学可读性方面优异。
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公开(公告)号:US4849396A
公开(公告)日:1989-07-18
申请号:US53961
申请日:1987-05-22
申请人: Toshimi Satake , Toshiaki Minami , Tomoaki Nagai , Fumio Fujimura
发明人: Toshimi Satake , Toshiaki Minami , Tomoaki Nagai , Fumio Fujimura
CPC分类号: G03C1/4989 , B41M5/32 , B41M5/3335 , B41M5/3336
摘要: A heat-sensitive recording material including a support and a color-developing layer having both an electron donor and a metal double salt or higher fatty acid having 16-35 carbon atoms as an electron acceptor. The heat-sensitive recording material is superior is dispersibility, image contrast, oil resistance, solvent resistance and optical readability in the near infrared region.
摘要翻译: 一种热敏记录材料,包括支持体和具有电子给体和具有16-35个碳原子的金属双盐或高级脂肪酸作为电子受体的显色层。 热敏记录材料在近红外区域具有优异的分散性,图像对比度,耐油性,耐溶剂性和光学可读性。
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公开(公告)号:US4721701A
公开(公告)日:1988-01-26
申请号:US814921
申请日:1985-12-30
申请人: Toshimi Satake , Toshiaki Minami , Tomoaki Nagai , Fumio Fujimura
发明人: Toshimi Satake , Toshiaki Minami , Tomoaki Nagai , Fumio Fujimura
CPC分类号: B41M5/3335
摘要: A thermosensitive recording sheet having a thermosensitive color developing layer containing a basic leuco dye and an organic color developer, said organic color developer consisting of at least partly of a halogen-substituted benzoic acid zinc salt represented by the following general formula ##STR1## wherein X.sub.1 represents a halogen atom, X.sub.2 represents a hydrogen or halogen atom, and R.sub.1, R.sub.2 and R.sub.3, independently from each other, represent a hydrogen atom or an alkyl, alkoxy, cycloalkyl, nitro, cyano or hydroxyl group.
摘要翻译: 一种热敏记录片材,其具有含有碱性无色染料和有机显色剂的热敏彩色显影层,所述有机彩色显影剂由至少部分由以下通式表示的卤素取代的苯甲酸锌盐组成(I )其中X1表示卤原子,X2表示氢或卤素原子,R1,R2和R3彼此独立地表示氢原子或烷基,烷氧基,环烷基,硝基,氰基或羟基。
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公开(公告)号:US4853361A
公开(公告)日:1989-08-01
申请号:US181711
申请日:1988-04-14
申请人: Toshimi Satake , Toshiaki Minami , Tomoaki Nagai , Fumio Fujimura
发明人: Toshimi Satake , Toshiaki Minami , Tomoaki Nagai , Fumio Fujimura
CPC分类号: G03C1/73 , B41M5/3275 , Y10S428/913 , Y10S428/914 , Y10S430/146
摘要: A heat- and light-sensitive recording material has a substrate and a color-forming layer which comprises a particular fluoran-type leuco dye.This heat- and light-sensitive recording material provides a clear image a superior contamination-resistance and an excellent readability in visible and near infrared range.
摘要翻译: 热敏和感光记录材料具有基材和包含特定的荧烷型无色染料的成色层。 这种热敏和感光记录材料提供了清晰的图像,具有优异的抗污染性和在可见光和近红外范围内极好的可读性。
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公开(公告)号:US5236633A
公开(公告)日:1993-08-17
申请号:US932730
申请日:1992-08-24
申请人: Toshimi Satake , Tomoaki Nagai , Miyuki Yokoyama
发明人: Toshimi Satake , Tomoaki Nagai , Miyuki Yokoyama
CPC分类号: G11B7/245 , C08K5/0091 , C08K5/098 , C08K5/405 , G11B7/249 , G11B7/244 , G11B7/253 , G11B7/2532 , G11B7/2533
摘要: A plate or a sheet being capable of absorbing near IR-rays, which is prepared by heating both at least a raw material of a transparent polymer and a mixture of a thiourea compound and a copper compound. This invention provides superior optical materials for shielding sunlight thermic rays, better information recording materials and the like.
摘要翻译: 通过加热至少透明聚合物的原料和硫脲化合物和铜化合物的混合物而制备的能够吸收近红外线的板或片。 本发明提供了用于遮蔽太阳热光的优良光学材料,更好的信息记录材料等。
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公开(公告)号:US5612279A
公开(公告)日:1997-03-18
申请号:US456806
申请日:1995-06-01
IPC分类号: B41M5/30 , B41M5/333 , B41M5/337 , B41M5/46 , B41M7/00 , C07C275/28 , C07C275/30 , C07C275/32 , C07C275/42 , C07C317/42 , C07C323/44 , C07D295/13 , C07D295/28 , G03G7/00 , G03C1/725
CPC分类号: C07D295/32 , B41M5/305 , B41M5/3333 , B41M5/46 , B41M7/0027 , C07C275/28 , C07C275/30 , C07C275/32 , C07C275/42 , C07C317/42 , C07C323/44 , C07D295/13 , C07C2101/14 , G03G7/00
摘要: In an optical recording sheet having a thermal recording layer containing a colorless or pale colored dye precursor and a color developer reactable with the dye precursor upon heating to develop a color, a dimerized or trimerized urea compound is used as the color developer to obtain an optical recording sheet which is superior in ground color stability and an optical recording sheet having a reversible recordability.
摘要翻译: 在具有含有无色或浅色染料前体的热敏记录层的光学记录片材和在加热产生颜色时可与染料前体反应的彩色显影剂,使用二聚或三聚化尿素化合物作为显色剂以获得光学 具有优异的地面颜色稳定性的记录纸和具有可逆记录性的光学记录纸。
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