Method of stabilizing the gloss retention of thermosetting resins
containing hydroxyl groups
    11.
    发明授权
    Method of stabilizing the gloss retention of thermosetting resins containing hydroxyl groups 失效
    稳定含有羟基的热固性树脂的光泽保留性的方法

    公开(公告)号:US4125570A

    公开(公告)日:1978-11-14

    申请号:US774296

    申请日:1977-03-04

    CPC classification number: C09D175/04 C09D167/00 C09D201/06

    Abstract: Thermosetting resins containing hydroxyl groups which can be cured with aminoplast resins are stabilized by the addition of 1,4-diazo[2,2,2]-bicyclooctane. This method is particularly useful in stabilizing the gloss retention of extensible coatings formed by curing a hydroxyl-containing urethane product with an aminoplast resin. Such coatings can be applied to virtually any solid substrate and are especially useful on rubbery, resilient substrates such as polyurethane or polyethylene foam, natural or synthetic rubber or rubber foam, and various elastomeric plastic materials. They are also particularly useful on other substrates such as mild steel or aluminum.

    Abstract translation: 含有可用氨基塑料树脂固化的羟基的热固性树脂通过加入1,4-二偶氮[2,2,2] - 双环辛烷来稳定。 该方法特别可用于稳定通过用氨基塑料树脂固化含羟基的聚氨酯产物形成的可延展涂层的光泽保留性。 这种涂层可以应用于几乎任何固体基质,并且特别适用于橡胶状弹性基材如聚氨酯或聚乙烯泡沫,天然或合成橡胶或橡胶泡沫,以及各种弹性塑料材料。 它们在其他基材如低碳钢或铝上也特别有用。

    Coating compositions composed of hydroxyfunctional polymers or
copolymers and alkoxysilanes
    12.
    发明授权
    Coating compositions composed of hydroxyfunctional polymers or copolymers and alkoxysilanes 失效
    由羟基官能聚合物或共聚物和烷氧基硅烷组成的涂料组合物

    公开(公告)号:US4093673A

    公开(公告)日:1978-06-06

    申请号:US523781

    申请日:1974-11-14

    CPC classification number: C08G18/837 C08K5/54 C09D133/14

    Abstract: Resinous compositions useful as coating compositions comprise blends of hydroxyfunctional polymers; organoalkoxy silane crosslinking agents represented by the formula: R.sub.n Si(OR').sub.4-n wherein R is an aryl, alkaryl, aralkyl, alkyl having 1 to 8 carbon atoms, XR .sub.4 -- or ##STR1## RADICAL, WHEREIN R.sub.1 is hydrogen or an alkyl radical of 1 to 6 carbon atoms, R.sub.2 is a member selected from the group consisting of alkylene radicals of 1 to 7 carbon atoms and carbonyloxy radicals represented by the formula: ##STR2## wherein R.sub.3 is an alkylene radical of 1 to 6 carbon atoms, wherein R.sub.4 is an alkylene radical of 1 to 6 carbon atoms, a cycloalkylene radical, or an arylene radical and X is a functional group selected from the group consisting of --OH, --SH, ##STR3## halogen, NH.sub.2 --, ##STR4## and NH.sub.2 --CH.sub.2 --CH.sub.2 --NH--, and wherein R' is methyl, ethyl, 2-methoxyethoxy, 2-ethoxyethoxy, m is 0 or 1 and n is 0, 1 or 2; and cure accelerating catalysts. Hydroxyfunctional polymers such as hydroxyfunctional acrylic polymers, polyesters and polyurethanes are particularly useful. Organic acids, metallic salts of organic acids and organic bases are useful cure accelerating catalysts.

    Abstract translation: 可用作涂料组合物的树脂组合物包含羟基官能聚合物的共混物; 由下式表示的有机烷氧基硅烷交联剂:

    Composition useful in making extensible films
    14.
    发明授权
    Composition useful in making extensible films 失效
    用于制作可扩展膜的组合物

    公开(公告)号:US4208495A

    公开(公告)日:1980-06-17

    申请号:US964557

    申请日:1978-11-29

    Abstract: Cured coatings having a high degree of extensibility, gloss retention, good sprayability and other desirable properties are obtained from compositions comprising (A) an interpolymer of a hydroxyalkyl ester of an ethylenically-unsaturated carboxylic acid and a copolymerizable material; (B) an organic polyisocyanate; (C) a polymeric polyol of low glass transition temperature; and (D) a curing agent, present either externally and/or as a part of the interpolymer. These compositions, when used as coatings, are durable, adherent and highly extensible. The coatings are particularly useful on resilient and rubbery substrates such as EPDM rubber, foam rubber, polyurethane foam and vinyl foam and on soft metal surfaces such as steel and aluminum.

    Abstract translation: 包含(A)烯键式不饱和羧酸的羟烷基酯和可共聚材料的互聚物的组合物获得具有高延展性,光泽保持性,良好喷涂性和其它所需性能的固化涂料。 (B)有机多异氰酸酯; (C)玻璃化转变温度低的聚合多元醇; 和(D)固化剂,其存在于互聚物的外部和/或作为共聚体的一部分。 当这些组合物用作涂料时,其耐久性,粘附性和高度可延展性。 这些涂料在弹性和橡胶基质如EPDM橡胶,泡沫橡胶,聚氨酯泡沫和乙烯基泡沫以及软质金属表面如钢和铝上特别有用。

    Coating composition containing an ungelled reaction product as a curative
    18.
    发明授权
    Coating composition containing an ungelled reaction product as a curative 失效
    含有未凝胶化反应产物作为治疗剂的涂料组合物

    公开(公告)号:US4678835A

    公开(公告)日:1987-07-07

    申请号:US824040

    申请日:1986-01-30

    CPC classification number: C08G77/54 C09D183/14

    Abstract: A coating composition contains at least 15 percent by weight of an ungelled reaction product of:(i) at least 2 percent by weight of an amine having in a molecule thereof at least one amino hydrogen atom, and at least one silicon atom directly bonded to a hydrolyzable group;(ii) at least 4 percent by weight of a material containing at least one epoxide group, at least 30 percent of said material being essentially free of hydroxyl groups; and(iii) a material selected from vinyl alkoxysilanes; nonfunctional organosilanes; organosilicates; and partial hydrolysis products thereof; the percentages by weight being based on the total weight of the resin solids of the coating composition including (i), (ii) and (iii).

    Abstract translation: 涂料组合物含有至少15重量%的未凝胶化反应产物:(i)至少2重量%的分子中至少有一个氨基氢原子的胺和至少一个直接连接到 可水解基团; (ii)至少4重量%的含有至少一个环氧基团的材料,至少30%的所述材料基本上不含羟基; 和(iii)选自乙烯基烷氧基硅烷的材料; 非功能性有机硅烷; 有机硅酸盐 及其部分水解产物; 重量百分比基于包括(i),(ii)和(iii)的涂料组合物的树脂固体的总重量。

    Aminoplast curable coating compositions containing sulfonic acid esters
as latent acid catalysts
    20.
    发明授权
    Aminoplast curable coating compositions containing sulfonic acid esters as latent acid catalysts 失效
    含有磺酸酯作为潜酸催化剂的氨基塑料可固化涂料组合物

    公开(公告)号:US4477618A

    公开(公告)日:1984-10-16

    申请号:US427402

    申请日:1982-09-29

    CPC classification number: C07C309/00 C08K5/42 C09D161/20

    Abstract: A high solids, organic solvent based, sprayable coating composition which is capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent present externally and/or internally as a part of the active hydrogen-containing resin, and a catalytic amount of a non-ionic ester of a sulfonic acid. The sulfonic acid ester is represented by the following structural formula: ##STR1## wherein: Z is a radical selected from the group consisting of amino and an organic radical, said organic radical being connected to the sulfur atom by a carbon atom; ##STR2## C.sub.3 -C.sub.20 cycloalkyl; and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 are independently hydrogen or an organic radical. These groups can be particularly described as follows:R.sub.1 is hydrogen, carboalkoxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.2 is hydrogen, carboalkoxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.3 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.4 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl, andR.sub.5 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl.

    Abstract translation: 能够进行酸催化交联的高固体,有机溶剂型可喷涂涂料组合物由含活性氢的树脂,在外部和/或内部作为含活性氢树脂的一部分存在的固化剂组成,以及 催化量的磺酸的非离子酯。 磺酸酯由以下结构式表示:其中:Z是选自氨基和有机基团的基团,所述有机基团通过碳原子连接到硫原子上; C3-C20环烷基; 并且R 1,R 2,R 3,R 4,R 5独立地为氢或有机基团。 这些基团可以特别描述如下:R 1是氢,烷氧羰基,C 3 -C 20烷基,C 6 -C 18芳基或C 3 -C 20环烷基; R2是氢,烷氧羰基,C3-C20烷基,C6-C18芳基或C3-C20环烷基; R3是氢,烷氧羰基,酰氧基,N-烷基氨基甲酰氧基,N-芳基氨基甲酰氧基,C3-C20烷基,C6-C18芳基或C3-C20环烷基; R4是氢,烷氧羰基,酰氧基,N-烷基氨基甲酰氧基,N-芳基氨基甲酰氧基,C3-C20烷基,C6-C18芳基或C3-C20环烷基,R5是氢,烷氧羰基,酰氧基,N-烷基氨基甲酰氧基,N-芳基氨基甲酰氧基,C3 -C 20烷基,C 6 -C 18芳基或C 3 -C 20环烷基。

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