Abstract:
Thermosetting resins containing hydroxyl groups which can be cured with aminoplast resins are stabilized by the addition of 1,4-diazo[2,2,2]-bicyclooctane. This method is particularly useful in stabilizing the gloss retention of extensible coatings formed by curing a hydroxyl-containing urethane product with an aminoplast resin. Such coatings can be applied to virtually any solid substrate and are especially useful on rubbery, resilient substrates such as polyurethane or polyethylene foam, natural or synthetic rubber or rubber foam, and various elastomeric plastic materials. They are also particularly useful on other substrates such as mild steel or aluminum.
Abstract:
Resinous compositions useful as coating compositions comprise blends of hydroxyfunctional polymers; organoalkoxy silane crosslinking agents represented by the formula: R.sub.n Si(OR').sub.4-n wherein R is an aryl, alkaryl, aralkyl, alkyl having 1 to 8 carbon atoms, XR .sub.4 -- or ##STR1## RADICAL, WHEREIN R.sub.1 is hydrogen or an alkyl radical of 1 to 6 carbon atoms, R.sub.2 is a member selected from the group consisting of alkylene radicals of 1 to 7 carbon atoms and carbonyloxy radicals represented by the formula: ##STR2## wherein R.sub.3 is an alkylene radical of 1 to 6 carbon atoms, wherein R.sub.4 is an alkylene radical of 1 to 6 carbon atoms, a cycloalkylene radical, or an arylene radical and X is a functional group selected from the group consisting of --OH, --SH, ##STR3## halogen, NH.sub.2 --, ##STR4## and NH.sub.2 --CH.sub.2 --CH.sub.2 --NH--, and wherein R' is methyl, ethyl, 2-methoxyethoxy, 2-ethoxyethoxy, m is 0 or 1 and n is 0, 1 or 2; and cure accelerating catalysts. Hydroxyfunctional polymers such as hydroxyfunctional acrylic polymers, polyesters and polyurethanes are particularly useful. Organic acids, metallic salts of organic acids and organic bases are useful cure accelerating catalysts.
Abstract:
Thermosetting elastomeric coating compositions are disclosed. The resinous binder of the coating compositions is based on a hard polyester polyol containing cycloaliphatic moieties plasticized with a soft polyurethane polyol and cured with a curing agent capable of reacting with active hydrogens, for example, an aminoplast curing agent. The coating compositions are particularly useful on elastomeric substrates such as high density polyurethane foams, as well as on metal substrates such as steel and aluminum.
Abstract:
Cured coatings having a high degree of extensibility, gloss retention, good sprayability and other desirable properties are obtained from compositions comprising (A) an interpolymer of a hydroxyalkyl ester of an ethylenically-unsaturated carboxylic acid and a copolymerizable material; (B) an organic polyisocyanate; (C) a polymeric polyol of low glass transition temperature; and (D) a curing agent, present either externally and/or as a part of the interpolymer. These compositions, when used as coatings, are durable, adherent and highly extensible. The coatings are particularly useful on resilient and rubbery substrates such as EPDM rubber, foam rubber, polyurethane foam and vinyl foam and on soft metal surfaces such as steel and aluminum.
Abstract:
New organic silanes are claimed carrying at least one water-solubilizing moiety and at least one hydrophobic group suitable for preparing stable solutions or dispersions containing in excess of about five weight percent of such silanes.
Abstract:
Disclosed herein are organosilane resins which are derived from an aminoalkoxysilane and hydroxy- and amine-functional compound; said resins are useful in curable compositions containing epoxy materials.
Abstract:
An abrasion and solvent resistant polyurethane protective coating for bilayer windshields is formulated by the reaction of a polyester or polyether diol with an aliphatic isocyanate-terminated prepolymer.
Abstract:
A coating composition contains at least 15 percent by weight of an ungelled reaction product of:(i) at least 2 percent by weight of an amine having in a molecule thereof at least one amino hydrogen atom, and at least one silicon atom directly bonded to a hydrolyzable group;(ii) at least 4 percent by weight of a material containing at least one epoxide group, at least 30 percent of said material being essentially free of hydroxyl groups; and(iii) a material selected from vinyl alkoxysilanes; nonfunctional organosilanes; organosilicates; and partial hydrolysis products thereof; the percentages by weight being based on the total weight of the resin solids of the coating composition including (i), (ii) and (iii).
Abstract:
There are disclosed herein polyurethane polyols and coating compositions formulated therewith. The polyurethane polyols are prepared by typically reacting low molecular weight polyols in amounts sufficient to produce reaction products containing a significant amount of unreacted starting polyols which can be subsequently removed by means such as vacuum distillation.
Abstract:
A high solids, organic solvent based, sprayable coating composition which is capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent present externally and/or internally as a part of the active hydrogen-containing resin, and a catalytic amount of a non-ionic ester of a sulfonic acid. The sulfonic acid ester is represented by the following structural formula: ##STR1## wherein: Z is a radical selected from the group consisting of amino and an organic radical, said organic radical being connected to the sulfur atom by a carbon atom; ##STR2## C.sub.3 -C.sub.20 cycloalkyl; and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 are independently hydrogen or an organic radical. These groups can be particularly described as follows:R.sub.1 is hydrogen, carboalkoxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.2 is hydrogen, carboalkoxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.3 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.4 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl, andR.sub.5 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl.