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公开(公告)号：US5439661A
公开(公告)日：1995-08-08
申请号：US330202
申请日：1994-10-27
IPC分类号： C01C3/02
CPC分类号： C01C3/0204
摘要： There is disclosed a process for efficiently producing hydrogen cyanide at a reaction temperature of preferably 250.degree. to 550.degree. C. by a catalytic dehydrative reaction of formamide which comprises employing as a catalyst, a manganese oxide (MnO) and/or a magnesium oxide (MgO) each modified with an alkali metal (Na, K, Rb, Cs, etc. ). The above process is capable of producing hydrogen cyanide at an enhanced conversion efficiency of formamide and at a high selectivity while minimizing the by-production of ammonia. The use of the catalyst comprising as a principal component, MnO modified with an alkali metal is particularly effective in prolonging its service life and enables a long-term stable operation.
摘要翻译： 公开了通过甲酰胺的催化脱氢反应在优选250-550℃的反应温度下有效地生产氰化氢的方法，该方法包括使用氧化锰（MnO）和/或氧化镁（MnO） MgO），其用碱金属（Na，K，Rb，Cs等）修饰。 上述方法能够以提高甲酰胺的转化效率并以高选择性产生氰化氢，同时最小化氨的副产物。 使用以碱金属为主成分的催化剂MnO特别有效延长其使用寿命，能够长期稳定运行。
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公开(公告)号：US5391813A
公开(公告)日：1995-02-21
申请号：US135247
申请日：1993-10-12
申请人： Nobuyuki Muro , Takafumi Abe , Hirofumi Higuchi
发明人： Nobuyuki Muro , Takafumi Abe , Hirofumi Higuchi
IPC分类号： C07B61/00 , C07C67/20 , C07C69/675
CPC分类号： C07C67/20
摘要： There is disclosed a process for efficiently producing methyl .alpha.-hydroxyisobutyrate from .alpha.-hydroxyisobutyramide and methyl formate by means of reaction distillation which comprises feeding .alpha.-hydroxyisobutyramide and an alkali metal hydroxide in a continuous distillation column to prepare therein the dehydrated condensate of .alpha.-hydroxyisobutyramide with the alkali metal hydroxide as the catalyst and reacting remaining .alpha.-hydroxyisobutyramide with methyl formate in the presence of the dehydrated condensate as the catalyst.According to the above process, the objective methyl .alpha.-hydroxyisobutyrate is continuously obtained in high yield and high selectivity without any operational trouble.
摘要翻译： 公开了一种通过反应蒸馏从α-羟基异丁酰胺和甲酸甲酯有效生产α-羟基异丁酸甲酯的方法，其中包括在连续蒸馏塔中加入α-羟基异丁酰胺和碱金属氢氧化物，以制备α-羟基异丁酰胺的脱水缩合物 与碱金属氢氧化物作为催化剂，并在脱水缩合物作为催化剂存在下使残余的α-羟基异丁酰胺与甲酸甲酯反应。 根据上述方法，以高产率和高选择性连续获得目标α-羟基异丁酸甲酯，没有任何操作故障。
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公开(公告)号：US5312966A
公开(公告)日：1994-05-17
申请号：US944359
申请日：1992-09-14
IPC分类号： B01J31/08 , C07B61/00 , C07C67/20 , C07C67/36 , C07C69/14 , C07C69/54 , C07C69/675 , C07C231/08 , C07C233/03 , C07C69/34 , C07C69/68
CPC分类号： C07C67/20
摘要： There is disclosed a process for efficiently producing a carboxylic acid ester and formamide by reacting a carboxylic acid amide with a formic acid ester or with an alcohol and carbon monoxide in the presence of a strongly basic anion-exchange resin. By the use of the strongly basic anion-exchange resin as the catalyst, the process of the present invention enables the efficient production of the carboxylic acid ester as well as formamide from the Carboxylic acid amide and Formic acid ester, etc. with a high selectivity under mild reaction conditions and facilitates the separation of the catalyst from the reaction product, thereby greatly enhancing the industrial significance of itself.
摘要翻译： 公开了在强碱性阴离子交换树脂存在下，使羧酸酰胺与甲酸酯或与醇和一氧化碳反应，有效地制备羧酸酯和甲酰胺的方法。 通过使用强碱性阴离子交换树脂作为催化剂，本发明的方法能够以高选择性从羧酸酰胺和甲酸酯等有效地制备羧酸酯以及甲酰胺 在温和的反应条件下，促进了催化剂与反应产物的分离，从而大大增强了其自身的工业意义。
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公开(公告)号：US5703272A
公开(公告)日：1997-12-30
申请号：US707135
申请日：1996-09-03
申请人： Mariko Abe , Shuji Ebata , Takafumi Abe , Hirofumi Higuchi
发明人： Mariko Abe , Shuji Ebata , Takafumi Abe , Hirofumi Higuchi
CPC分类号： B01J21/063 , B01J21/08 , B01J37/03 , C07C67/08
摘要： A process for preparing a carboxylic acid ester which includes subjecting a carboxylic acid and an alcohol or a phenol to an esterification reaction in the presence of a silica-titania catalyst. The silica-titania catalyst is prepared by adding an acidic solution containing a silicon compound and a titanium compound dissolved therein to a solution of a basic compound to bring about co-precipitation, in which the acidic solution is a nitric acid-acidic solution or a sulfuric acid-acidic solution, a ratio of the amount (gram equivalent) of nitric acid or sulfuric acid to the amount (mol) of the silicon compound in the acidic solution is 0.5 to 50 and the amount of the titanium compound in the acidic solution is such that a ratio of titania (TiO.sub.2) in the silica-titania catalyst is 1 to 50% by weight.
摘要翻译： 一种制备羧酸酯的方法，包括在二氧化硅 - 二氧化钛催化剂的存在下使羧酸和醇或酚进行酯化反应。 二氧化硅 - 二氧化钛催化剂通过将含有硅化合物和溶解在其中的钛化合物的酸性溶液加入到碱性化合物的溶液中来进行共沉淀，其中酸性溶液是硝酸 - 酸性溶液或 硫酸 - 酸性溶液，酸性溶液中的硝酸或硫酸的量（克当量）与硅化合物的量（摩尔）的比例为0.5〜50，酸性溶液中钛化合物的量 使得二氧化硅 - 二氧化钛催化剂中的二氧化钛（TiO 2）的比例为1〜50重量％。
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公开(公告)号：US20070043242A1
公开(公告)日：2007-02-22
申请号：US10569643
申请日：2004-09-01
申请人： Yuichi Sugano , Takafumi Abe , Toshifumi Abe
发明人： Yuichi Sugano , Takafumi Abe , Toshifumi Abe
IPC分类号： C07C233/02
CPC分类号： C07B59/001 , C07B2200/05 , C07C67/20 , C07C69/54
摘要： A method for producing MMA-d8 which includes a step of exchanging D in hydroxyl group of methanol-d4 represented by the formula: CD3OD with H to prepare the methanol-d3 represented by the formula CD3OH and simultaneously recovering a deuterium-containing compound, and a step of reacting methanol-d3 with sulfuric acid salt of methacrylic acid amide represented by the formula CD2═(CD3)CO(NH2·H2SO4) to prepare MMA-d8 represented by the formula: CD2═(CD3)COOCD3.
摘要翻译： 一种制备MMA-d 8 N的方法，该方法包括在由下式表示的甲醇-d 4的羟基中交换D的步骤：＆lt; 3＆lt; 3＆gt; > OD以制备由式CD 3 OH表示的甲醇-d 3并同时回收含氘化合物，并且使甲醇-d 3反应， 由式CD 2 - （CD 3 N）CO（NH 2）2表示的甲基丙烯酸酰胺的硫酸盐与（3-N） > H 2 SO 4），以制备由下式表示的MMA-d 8：（Ⅳ）（（（（（（（：：：：：：：：：：：：：：：：：：：：：：：：：：：：：：： CD 3）COOCD 3 3。
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公开(公告)号：US5646603A
公开(公告)日：1997-07-08
申请号：US565274
申请日：1995-11-30
申请人： Atsushi Nagata , Haruo Iwasaki , Kazuhiko Shimizu , Yoshinori Tanba , Takafumi Abe , Tatsuo Imai , Akihiro Kikuchi , Teruyuki Miyakawa
发明人： Atsushi Nagata , Haruo Iwasaki , Kazuhiko Shimizu , Yoshinori Tanba , Takafumi Abe , Tatsuo Imai , Akihiro Kikuchi , Teruyuki Miyakawa
CPC分类号： G11B15/023 , H04N5/44 , H04N5/765 , H04N5/9206
摘要： A remote control apparatus for recording/playback equipment capable of remotely controlling complicated recording playback equipment while placing little burden on the control side. Schedule data is transmitted from an uplink system 100 to a downlink system 200 via a communications satellite. The schedule data includes operation data for recording and playback operations and their related operations, start data which displays at least the operation start time, and position data which indicates the recording/playback position on the recording medium. The received schedule data is stored in a non-volatile RAM in the control area of the VCR 203. The VCR then uses this schedule data as a basis for automatically carrying out recording or playback operations and their related operations. As is no longer necessary to control the operation by providing appropriate commands to the VCR 203 in real time, the burden on the control side is greatly eased with regards to the control of complicated operations in addition to recording and playback, such as rewind and pre-roll operation modes.
摘要翻译： 一种用于记录/重放设备的远程控制装置，其能够远程控制复杂的记录重放设备，同时在控制侧施加很小的负担。 调度数据经由通信卫星从上行链路系统100发送到下行链路系统200。 调度数据包括用于记录和重放操作及其相关操作的操作数据，至少显示操作开始时间的起始数据和指示记录介质上的记录/重放位置的位置数据。 所接收的时间表数据被存储在VCR203的控制区域中的非易失性RAM中。然后，VCR将该调度数据用作自动执行记录或重放操作及其相关操作的基础。 由于不再需要通过向VCR 203实时提供适当的命令来控制操作，所以除了记录和回放之外的复杂操作的控制（例如倒带和预取），控制侧的负担被大大减轻 滚动操作模式。
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公开(公告)号：US5618953A
公开(公告)日：1997-04-08
申请号：US595271
申请日：1996-02-01
申请人： Takafumi Abe , Fumio Tanaka , Hiroyuki Nitobe , Masaki Takemoto
发明人： Takafumi Abe , Fumio Tanaka , Hiroyuki Nitobe , Masaki Takemoto
IPC分类号： C07D307/06 , C07D307/02
CPC分类号： C07D307/06
摘要： A process for producing 3-methyltetrahydrofuran, wherein in a first step, prussic acid is reacted with methyl methacrylate to produce methyl 3-cyanoisobutyrate. The methyl 3-cyanoisobutyrate is then reacted with water and sulfuric acid to produce a resultant product which is reacted with a C.sub.1 -C.sub.8 aliphatic alcohol to produce a methylsuccinic acid ester. The methylsuccinic acid ester is catalytically hydrogenated to prepare the 3-methyltetrahydrofuran. Alternatively, the methyl 3-cyanoisobutyrate is hydrated to produce methyl 3-carbamoylisobutyrate, which is then reacted with a formic acid ester to form a methylsuccinic acid ester and formamide and the resultant methylsuccinic acid ester is catalytically hydrogenated. The 3-methyltetrahydrofuran is produced in high selectivity and in a commercially advantageous manner from inexpensive reactants. The 3-methyltetrahydrofuran is useful as a commoner for producing polyether glycol, which is utilized as starting raw material for preparing spandex fiber.
摘要翻译： 一种生产3-甲基四氢呋喃的方法，其中在第一步中，使二异丁酸与甲基丙烯酸甲酯反应产生3-氰基异丁酸甲酯。 然后使3-氰基异丁酸甲酯与水和硫酸反应，生成与C1-C8脂族醇反应生成甲基琥珀酸酯的产物。 将甲基琥珀酸酯催化氢化以制备3-甲基四氢呋喃。 或者，将3-氰基异丁酸甲酯水合，得到3-氨基甲酰基异丁酸甲酯，然后与甲酸酯反应形成甲基琥珀酸酯和甲酰胺，得到的甲基琥珀酸酯被催化氢化。 3-甲基四氢呋喃以廉价的反应物以高选择性和商业上有利的方式生产。 3-甲基四氢呋喃可用作制备聚醚二醇的通用剂，其用作制备氨纶纤维的起始原料。
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18.发明申请公开(公告)号：US20130303775A1
公开(公告)日：2013-11-14
申请号：US13996759
申请日：2011-12-22
申请人： Yutaka Kanbara , Takafumi Abe , Norio Fushimi
发明人： Yutaka Kanbara , Takafumi Abe , Norio Fushimi
IPC分类号： C07B41/02 , C07D213/30 , C07C29/00
CPC分类号： C07B41/02 , B01J23/04 , C07C29/00 , C07C29/09 , C07C29/128 , C07C41/26 , C07C213/00 , C07D213/30 , C07C33/18 , C07C33/22 , C07C33/26 , C07C33/20 , C07C43/23 , C07C33/46 , C07C215/68
摘要： A process of production of an aromatic alcohol or a heterocyclic aromatic alcohol, containing a step of reacting an aromatic amine or a heterocyclic aromatic amine having an aromatic ring or a heterocyclic aromatic ring having thereon at least one substituent —CHR1NR2R3 (wherein R1, R2 and R3 each independently represent hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a benzyl group), with an alcohol, in the presence of a basic catalyst.
摘要翻译： 一种制备芳族醇或杂环芳族醇的方法，其包括使芳族胺或具有芳环的杂环芳族胺或其上具有至少一个取代基的杂环芳族环的芳基胺反应的步骤，其中R1，R2和 R 3各自独立地表示氢，具有1至4个碳原子的烷基或苄基）与醇在碱性催化剂的存在下反应。
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公开(公告)号：US07375247B2
公开(公告)日：2008-05-20
申请号：US10569643
申请日：2004-09-01
申请人： Yuichi Sugano , Takafumi Abe , Toshifumi Abe
发明人： Yuichi Sugano , Takafumi Abe , Toshifumi Abe
IPC分类号： C07C67/20
CPC分类号： C07B59/001 , C07B2200/05 , C07C67/20 , C07C69/54
摘要： A method for producing MMA-d8 which includes a step of exchanging D in hydroxyl group of methanol-d4 represented by the formula: CD3OD with H to prepare the methanol-d3 represented by the formula CD3OH and simultaneously recovering a deuterium-containing compound, and a step of reacting methanol-d3 with sulfuric acid salt of methacrylic acid amide represented by the formula CD2=(CD3)CO(NH2.H2SO4) to prepare MMA-d8 represented by the formula: CD2=(CD3)COOCD3.
摘要翻译： 一种制备MMA-d 8 N的方法，该方法包括在由下式表示的甲醇-d 4的羟基中交换D的步骤：＆lt; 3＆lt; 3＆gt; > OD以制备由式CD 3 OH表示的甲醇-d 3并同时回收含氘化合物，并且使甲醇-d 3反应， 由式CD 2代表的甲基丙烯酸酰胺的硫酸盐（NH 3 CO 2（CO 3 NH 3）） 以制备由下列化学式表示的MMA-d 8：（2）式（Ⅳ） CD 3）COOCD 3 3。
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公开(公告)号：US06532124B1
公开(公告)日：2003-03-11
申请号：US09484351
申请日：2000-01-18
申请人： Takafumi Abe
发明人： Takafumi Abe
IPC分类号： G11B509
CPC分类号： G11B27/328 , G11B7/00 , G11B20/10 , G11B20/1202 , G11B27/107 , G11B27/11 , G11B27/3027 , G11B2020/1062 , G11B2220/65 , G11B2220/90
摘要： The present invention relates to an information recording apparatus and a method thereof that allow all data on a magnetic tape to be easily obtained and instrumental data and header information supplied from respective systems to be combined when instrumental data is recorded. According to the present invention, an additional information area is formed at the top of the magnetic tape. The additional information area is followed by a data area. Instrumental data is stored in a buffer memory through a data connector. The header information is stored in a local memory through a header information control connector in addition to a control command. Instrumental data is swept out from the buffer memory and recorded to a data area of the magnetic tape. After the instrumental data is recorded, header information is read from the local memory and stored in the buffer memory. The header information is swept out from the buffer memory and recorded to the additional information area of the magnetic tape. When data is read from the additional information area, all contents of the magnetic tape are obtained. Since header information is temporarily stored to the local memory and then recorded, a processing portion that combines header information and instrumental data can be omitted.
摘要翻译： 信息记录装置及其方法技术领域本发明涉及一种信息记录装置及其方法，其能够容易地获得磁带上的所有数据，并且当记录工具数据时，组合从相应系统提供的工具数据和标题信息。 根据本发明，在磁带的顶部形成附加的信息区域。 附加信息区域后面是数据区域。 乐器数据通过数据连接器存储在缓冲存储器中。 标题信息除了控制命令之外还通过头信息控制连接器存储在本地存储器中。 工具数据从缓冲存储器扫出并记录到磁带的数据区。 在记录工具数据之后，从本地存储器中读取标题信息并将其存储在缓冲存储器中。 标题信息从缓冲存储器扫出并记录到磁带的附加信息区。 当从附加信息区读取数据时，获得磁带的所有内容。 由于标题信息被临时存储到本地存储器中然后被记录，所以可以省略组合标题信息和工具数据的处理部分。
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