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11.发明授权Process for production of acrylic acid or its derivatives from hydroxypropionic acid or its derivatives 有权由羟基丙酸或其衍生物生产丙烯酸或其衍生物的方法公开(公告)号：US08884050B2
公开(公告)日：2014-11-11
申请号：US13760483
申请日：2013-02-06
Applicant: The Proctor & Gamble Company
Inventor： Jane Ellen Godlewski , Janette Villalobos , Dimitris Ioannis Collias , Juan Estaban Velasquez
IPC: C07B35/00 , C07C67/30 , B01J37/00 , B01J35/02 , B01J27/188 , C07C57/04 , B01J27/25 , B01J27/186 , B01J27/195 , B01J27/16 , C07C51/48 , B01J27/18 , C07C51/09 , B01J27/198 , B01J27/187 , B01J27/185 , A61F13/534 , C08F2/10 , C07C51/377
CPC classification number: C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
Abstract: Processes for the catalytic dehydration of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity and without significant conversion to undesired side products, such as, acetaldehyde, propanoic acid, and acetic acid, are provided.
Abstract translation: 将羟基丙酸，羟基丙酸衍生物或其混合物催化脱水至丙烯酸，丙烯酸衍生物或其混合物的方法，具有高产率和选择性，并且不显着转化为不期望的副产物，例如乙醛，丙酸和 乙酸。
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12.发明申请Catalysts Conversion Of Hydroxypropionic Acid Or Its Derivatives To Acrylic Acid Or Its Derivatives 有权催化剂将羟基丙酸或其衍生物转化为丙烯酸或其衍生物公开(公告)号：US20130274512A1
公开(公告)日：2013-10-17
申请号：US13760472
申请日：2013-02-06
Applicant: THE PROCTER & GAMBLE COMPANY
Inventor： Janette Villalobos , Juan Estaban Velasquez , Jane Ellen Godlewski , Dimitris Ioannis Collias
IPC: C07C51/377
CPC classification number: C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
Abstract: Methods for catalytically dehydrating hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity and without significant conversion to undesired side products, such as, acetaldehyde, propionic acid, and acetic acid, are provided. The catalysts are mixed condensed phosphates.
Abstract translation: 以高产率和选择性将羟基丙酸，羟基丙酸衍生物或其混合物催化脱水成丙烯酸，丙烯酸衍生物或其混合物的方法，并且不显着转化为不期望的副产物，例如乙醛，丙酸和乙酸 ，提供。 催化剂是混合的缩合磷酸盐。
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13.发明申请Catalysts For The Conversion Of Hydroxypropionic Acid Or Its Derivatives To Acrylic Acid Or Its Derivatives 审中-公开用于将羟基丙酸或其衍生物转化为丙烯酸或其衍生物的催化剂公开(公告)号：US20130274094A1
公开(公告)日：2013-10-17
申请号：US13760444
申请日：2013-02-06
Applicant: THE PROCTER & GAMBLE COMPANY
Inventor： Juan Estaban Velasquez , Janette Villalobos Lingoes , Jane Ellen Godlewski , Dimitris Ioannis Collias , Fred C. Wireko , Marc Andrew Mamak , Nancy Lee Redman-Furey
IPC: B01J27/25 , B01J27/18 , B01J27/187
CPC classification number: C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
Abstract: Catalysts for dehydrating hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity, short residence time, and without significant conversion to undesired side products, such as, for example, acetaldehyde, propionic acid, and acetic acid, are provided. The catalysts are mixed condensed phosphates. Methods of preparing the catalysts are also provided.
Abstract translation: 用于将羟基丙酸，羟基丙酸衍生物或其混合物脱氢至丙烯酸，丙烯酸衍生物或其混合物的高产率和选择性，短停留时间并且不显着转化为不需要的副产物例如乙醛的催化剂 ，丙酸和乙酸。 催化剂是混合的缩合磷酸盐。 还提供了制备催化剂的方法。
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14.发明申请NITRIDED MIXED OXIDE CATALYST SYSTEM AND A PROCESS FOR THE PRODUCTION OF ETHYLENICALLY UNSATURATED CARBOXYLIC ACIDS OR ESTERS 有权硝化混合氧化物催化剂体系及一种生产乙烯不饱和羧酸或酯的方法公开(公告)号：US20130158287A1
公开(公告)日：2013-06-20
申请号：US13805413
申请日：2011-06-24
Applicant: Ian Andrew York , Sabina Ziemian
Inventor： Ian Andrew York , Sabina Ziemian
IPC: B01J27/24
CPC classification number: C07C67/343 , B01J23/18 , B01J23/20 , B01J27/16 , B01J27/1811 , B01J27/1813 , B01J27/24 , B01J37/036 , C01B21/0821 , C01B21/097 , C07C51/353 , C07C57/04 , C07C69/54
Abstract: The invention relates to a method of producing an ethylenically unsaturated carboxylic acid or ester, preferably an α, β ethylenically unsaturated carboxylic acid or ester. The method includes contacting formaldehyde or a suitable source thereof with a carboxylic acid or ester in the presence of a catalyst and optionally in the presence of an alcohol. The catalyst comprises a nitrided metal oxide having at least two types of metal cations, M1 and M2, wherein M1 is selected from the metals of group 2, 3, 4, 13 (called also IIIA) or 14 (called also IVA) of the periodic table and M2 is selected from the metals of groups 5 or 15 (called also VA) of the periodic table. The invention extends to a catalyst system.
Abstract translation: 本发明涉及一种制备烯属不饱和羧酸或酯，优选α，β-烯属不饱和羧酸或酯的方法。 该方法包括在催化剂存在下和任选在醇存在下使甲醛或其合适的来源与羧酸或酯接触。 催化剂包括具有至少两种金属阳离子M1和M2的氮化金属氧化物，其中M1选自第2,3,4,13族（也称为IIIA）或14（也称为IVA）的金属， 周期表和M2选自元素周期表第5或15族（也称为VA）的金属。 本发明延伸到催化剂体系。
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公开(公告)号：US20020010359A1
公开(公告)日：2002-01-24
申请号：US09885962
申请日：2001-06-22
Applicant: Kao Corporation
Inventor： Jun Kaita , Taku Mimura , Noriaki Fukuoka , Yasuyuki Hattori
IPC: C07C067/02 , C07C067/03
CPC classification number: C11C3/003 , B01J27/16 , B01J27/1811 , B01J27/1853
Abstract: The present invention provides a heterogeneous catalyst which is highly active, excellent in selectivity and free from elution of its catalyst-components during reaction and which has long lifetime. That is, a phosphate of a metal selected from the group consisting of aluminum, gallium and iron is used as the catalyst for transesterification of the present invention.
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Patent Agency Ranking
公开(公告)号：US3067272A
公开(公告)日：1962-12-04
申请号：US7952760
申请日：1960-12-30
Applicant: SHELL OIL CO
Inventor： VOGE HERVEY H
CPC classification number: C07C5/48 , B01J23/28 , B01J23/30 , B01J27/1811
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17.发明授权公开(公告)号：US09809527B2
公开(公告)日：2017-11-07
申请号：US14511195
申请日：2014-10-10
Applicant: The Procter & Gamble Company
Inventor： Jane Ellen Godlewski , Janette Villalobos , Dimitris Ioannis Collias , Juan Estaban Velasquez
IPC: C07C51/377 , C07C51/48 , B01J27/18 , B01J27/187 , B01J27/25 , C07C51/09 , C07C57/04 , A61F13/534 , C08F2/10 , B01J27/16 , B01J27/185 , B01J27/186 , B01J27/188 , B01J27/195 , B01J27/198 , B01J35/02 , B01J37/00 , B01J37/04 , B01J37/08 , C07C51/44 , A61F13/53
CPC classification number: C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
Abstract: Processes for the catalytic dehydration of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity and without significant conversion to undesired side products, such as, acetaldehyde, propanoic acid, and acetic acid, are provided.
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18.发明申请公开(公告)号：US20170022238A1
公开(公告)日：2017-01-26
申请号：US15124939
申请日：2015-03-10
Applicant: JAPAN SCIENCE AND TECHNOLOGY AGENCY
Inventor： Michikazu HARA , Kiyotaka NAKAJIMA , Daiki TAKEDA
CPC classification number: C07H3/02 , B01J21/04 , B01J23/08 , B01J27/16 , B01J27/1811 , B01J35/002 , B01J35/1014 , B01J35/1019 , B01J37/28 , C07H1/00
Abstract: A novel catalyst capable of selectively catalyzing conversion from glucose to fructose in water or in an aqueous solution is provided. The catalyst is a solid catalyst for a hydride isomerization reaction from glucose to fructose performed in water or in an aqueous solution, comprising a group 13 element oxide whose surface has been subjected to a phosphoric acid treatment.
Abstract translation: 提供了能够选择性催化从水中或水溶液中的葡萄糖转化为果糖的新型催化剂。 该催化剂是在水中或在水溶液中进行的从葡萄糖到果糖的氢化物异构化反应的固体催化剂，其包含其表面进行了磷酸处理的13族元素氧化物。
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公开(公告)号：US09505697B2
公开(公告)日：2016-11-29
申请号：US13839986
申请日：2013-03-15
Applicant: The Procter & Gamble Company
Inventor： Juan Esteban Velasquez , Janette Villalobos Lingoes , Dimitris Ioannis Collias , Jane Ellen Godlewski
IPC: C07C51/02 , C07C51/48 , B01J27/18 , B01J27/187 , B01J27/25 , C07C51/377 , C07C51/09 , C07C57/04 , A61F13/534 , C08F2/10 , B01J27/16 , B01J27/185 , B01J27/186 , B01J27/188 , B01J27/195 , B01J27/198 , B01J35/02 , B01J37/00 , B01J37/04 , B01J37/08 , C07C51/44
CPC classification number: C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
Abstract: Methods for catalytically dehydrating hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity and without significant conversion to undesired side products, such as, acetaldehyde, propionic acid, and acetic acid, are provided. The catalysts are mixed monophosphates.
Abstract translation: 以高产率和选择性将羟基丙酸，羟基丙酸衍生物或其混合物催化脱水成丙烯酸，丙烯酸衍生物或其混合物的方法，并且不显着转化为不期望的副产物，例如乙醛，丙酸和乙酸 ，提供。 催化剂是混合的单磷酸盐。
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20.发明申请NITRIDED MIXED OXIDE CATALYST SYSTEM AND A PROCESS FOR THE PRODUCTION OF ETHYLENICALLY UNSATURATED CARBOXYLIC ACIDS OR ESTERS 审中-公开硝化混合氧化物催化剂体系及一种生产乙烯不饱和羧酸或酯的方法公开(公告)号：US20160297739A1
公开(公告)日：2016-10-13
申请号：US15188349
申请日：2016-06-21
Applicant: Lucite International UK Limited
Inventor： Ian Andrew York , Sabina Zieman
IPC: C07C67/343 , C07C51/353 , B01J27/24 , C01B21/097 , C01B21/082
CPC classification number: C07C67/343 , B01J23/18 , B01J23/20 , B01J27/16 , B01J27/1811 , B01J27/1813 , B01J27/24 , B01J37/036 , C01B21/0821 , C01B21/097 , C07C51/353 , C07C57/04 , C07C69/54
Abstract: The invention relates to a method of producing an ethylenically unsaturated carboxylic acid or ester, preferably an α, β ethylenically unsaturated carboxylic acid or ester. The method includes contacting formaldehyde or a suitable source thereof with a carboxylic acid or ester in the presence of a catalyst and optionally in the presence of an alcohol. The catalyst comprises a nitrided metal oxide having at least two types of metal cations, M1 and M2, wherein M1 is selected from the metals of group 2, 3, 4, 13 (called also IIIA) or 14 (called also IVA) of the periodic table and M2 is selected from the metals of groups 5 or 15 (called also VA) of the periodic table. The invention extends to a catalyst system.
Abstract translation: 本发明涉及一种制备烯属不饱和羧酸或酯，优选α，β-烯属不饱和羧酸或酯的方法。 该方法包括在催化剂存在下和任选在醇存在下使甲醛或其合适的来源与羧酸或酯接触。 催化剂包括具有至少两种金属阳离子M1和M2的氮化金属氧化物，其中M1选自第2,3,4,13族（也称为IIIA）或14（也称为IVA）的金属， 周期表和M2选自元素周期表第5或15族（也称为VA）的金属。 本发明延伸到催化剂体系。
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