摘要:
Disclosed are basic azo dyes, free from sulphonic acid groups, and of formula, ##STR1## in which Q signifies an unsubstituted or substituted phenyl or naphthyl radical,R.sub.1 signifies hydrogen, unsubstituted or substituted C.sub.1-4 alkyl, phenyl or cyclohexyl,Z signifies a ring forming residue,R.sub.4 signifies optionally substituted alkyl, alkenyl, alkoxy or cycloalkyl,K signifies a coupling component,A.crclbar. signifies an anion, andx signifies 1, 2 or 3.The dyes are useful for dyeing and printing textiles of polymers and copolymers of acrylonitrile and dicyanoethylene as well as synthetic polyamides and polyesters that have been modified to contain acid groups. The dyeings are level and exhibit good fastness to light, wet treatments, perspiration, sublimation, pressing and dry cleaning.
摘要:
Disclosed are basic dyes free from sulphonic acid groups of the formula ##STR1## in which F.sup.+ signifies a cationic group-containing residue of a dye such as an azo, styryl, azomethine, methine, anthraquinone, nitro or triphenylmethyl dye,x signifies 1, 2 or 3,y signifies 1, 2, 3 or 4,A.sup.+ signifies an anion, andQ signifies an optionally substituted biphenylyl, dibenzofuranyl, carbazolyl, dibenzothiophenyl, dibenzothiophendioxydyl, dibenzothiophenmonoxydyl, fluorenyl or fluorenonyl radical, andR.sub.1 signifies hydrogen, phenyl, cycloalkyl, unsubstituted C.sub.1-4 alkyl or C.sub.1-4 alkyl substituted by halogen, C.sub.1-4 alkoxy or phenoxy.These dyes are useful for dyeing and printing polyacrylonitrile and poly-asymmetrical dicyanoethylene and copolymers thereof as well as modified polyesters and polyamides containing acid groups. The dyes build-up well and exhibit good pH stability and stability to boiling. The obtained dyeings are level and possess good fastness to light, wet treatments, solvents, heat treatments and cross-dyeing.
摘要:
Cyan azo dye-providing compounds having the formula ##STR1## wherein Car represents a carrier moiety which, as a function of oxidation under alkaline conditions, releases a diffusible dye from said compound;X represents a bivalent linking group;R represents hydrogen or alkyl;J represents sulfonyl or carbonyl;M and q each represent an integer having a value of 0 or 1;Q represents hydroxy or acylamino;G represents a hydroxy radical, a salt thereof, or a hydrolyzable acyloxy group;D represents halogen, cyano, nitro, trifluoromethyl, alkyl, alkoxy, carboxy, a carboxylic acid ester, fluorosulfonyl, trifluoromethylsulfonyl, --SO.sub.3 --phenyl radical, sulfo, a sulfamoyl radical, a carbamoyl radical, an alkyl- or alkylsulfonyl radical, or a phenylsulfonyl radical;E represents hydrogen, halogen, nitro, cyano, or trifluoromethyl; andM represents sulfo, cyano, fluorosulfonyl, halogen, a -SO.sub.3 -phenyl radical, an alkylsulfinyl radical, a phenylsulfinyl radical; a sulfamoyl radical, a carbamoyl radical, an alkylsulfonyl radical, or a phenylsulfonyl radical;With the proviso that there be no more than one sulfo radical and no more than one carboxy radical present in said compound.
摘要:
A nondiffusible sulfonamide compound which is alkali-cleavable upon oxidation to release a diffusible magenta color-providing moiety from a benzene nucleus thereof, said compound having a formula as follows: ##SPC1##WhereinBall represents an organic ballasting group.Y represents the carbon atoms necessary to complete a benzene or naphthalene nucleus;X represents a bivalent linking group;R represents hydrogen or alkyl;J represents sulfonyl or carbonyl;M and q each represent an integer having a value of 0 or 1;R.sup.1 represents hydrogen, halogen, alkyl or alkoxy;Q is in the 5- or 8-position relative to the hydroxy radical and represents hydrogen, hydroxy or an acylamino radical;G represents hydroxy, a salt thereof, or a hydrolyzable acyloxy group;E represents hydrogen, sulfo, a sulfamoyl radical; or E can represent a radical of the formula ##SPC2##WhereinEach member is as described previously;R is an integer having a value of 1 or 2;Z represents halogen, carboxy; a carboxylic acid ester; a sulfamoyl radical; as well as hydrogen, alkoxy, an alkyl radical, or a carbamoyl radical;X.sup.1 represents an alkylene, phenylene radical or substituted phenylene as described for R.sup.2 ;X.sup.2 represents an alkylene radical as described for R.sup.2 ;with the proviso that there be only one sulfo or carboxy radical present in said compound and that only one of R.sup.1 and Z be hydrogen.