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    Silver halide elements that produce sharp images without fixing and processes for their use
    12.
    发明授权
    Silver halide elements that produce sharp images without fixing and processes for their use 失效
    产生清晰图像的卤化银元件，无需固定和使用

    公开(公告)号：US06255044B1

    公开(公告)日：2001-07-03

    申请号：US09010055

    申请日：1998-01-21

    申请人： David H. Levy ,  John Gasper

    发明人： David H. Levy ,  John Gasper

    IPC分类号： G03C1735

    CPC分类号： G03C7/39204 ,  G03C1/95 ,  G03C5/16 ,  G03C5/38 ,  Y10S430/148

    摘要： A silver halide imaging element is disclosed that is capable of providing a sharp image with silver halide grains still present following imagewise exposure and development. This is achieved by choosing a dispersing medium for the silver halide grains comprised of an organic vehicle and, dispersed therein, titanium dioxide particles having an average size of less than 0.1 micrometer accounting for at least 10 percent by weight of the dispersing medium. The elements are useful for optical printing or scan image retrieval without fixing. The elements can be used for providing black-and-white photographic images, radiographic images or dye images.

    摘要翻译： 公开了一种卤化银成像元件，其能够在图像曝光和显影之后提供仍然存在的卤化银颗粒的清晰图像。 这通过选择用于由有机载体组成的卤化银颗粒的分散介质来实现，并且其中分散有平均尺寸小于0.1微米的二氧化钛颗粒，占分散介质的至少10重量％。 这些元件可用于光学打印或扫描图像检索而无需固定。 这些元件可用于提供黑白照相图像，放射照相图像或染料图像。

    Electrically-conductive layer for imaging element containing composite metal-containing particles
    13.
    发明授权
    Electrically-conductive layer for imaging element containing composite metal-containing particles 失效
    用于含复合金属颗粒的成像元件的导电层

    公开(公告)号：US6114079A

    公开(公告)日：2000-09-05

    申请号：US053563

    申请日：1998-04-01

    申请人： Paul A. Christian ,  Debasis Majumdar ,  Ibrahim M. Shalhoub ,  Dennis J. Eichorst

    发明人： Paul A. Christian ,  Debasis Majumdar ,  Ibrahim M. Shalhoub ,  Dennis J. Eichorst

    IPC分类号： G03C1/85 ,  G03C1/89 ,  G03C1/95 ,  B41J3/407 ,  G03C8/52 ,  G03C11/22

    CPC分类号： G03C1/95 ,  G03C1/85 ,  G03C1/853 ,  G03C1/89

    摘要： The present invention is an imaging element including a support having a frontside and a backside, an imaging layer superposed on the frontside of said support, and a print-retaining, electrically-conductive layer superposed on the backside of the support. The electrically-conductive layer includes a film-forming binder comprising the latex polymeric addition product of from 20 to 65 mol % of styrene, from 30 to 78 mol % of n-butyl methacrylate, and from 2 to 10 mol % of the sodium salt of 2-sulfoethyl methacrylate. and at least about 60 weight percent composite electrically conductive particles. The composite electrically-conductive particles have a layer of electrically-conductive metal-containing crystallites overlying a nonconductive substrate particle. The electrically-conductive layer is formed by dispersing the composite electrically-conductive particles using polymeric milling media having a mean particle size less than 350 .mu.m to form a colloidal dispersion, combining the colloidal dispersion with the film forming binder to form a mixture, coating the mixture onto the support and drying the mixture to form the electrically-conductive layer.

    摘要翻译： 本发明是一种成像元件，其包括具有前侧和后侧的支撑体，叠置在所述支撑体的前侧上的成像层和叠置在支撑体的背面上的印刷保持导电层。 导电层包括成膜粘合剂，其包含20至65mol％的苯乙烯，30至78mol％的甲基丙烯酸正丁酯和2至10mol％的钠盐的胶乳聚合加成产物 的甲基丙烯酸2-磺乙酯。 和至少约60重量％的复合导电颗粒。 复合导电颗粒具有覆盖在非导电性基材颗粒上的导电性含金属微晶层。 通过使用平均粒度小于350μm的聚合物研磨介质分散复合导电颗粒来形成导电层，以形成胶体分散体，将胶体分散体与成膜粘合剂组合以形成混合物，涂层 将混合物加载到载体上并干燥混合物以形成导电层。

    Fine polymer particles having heterogeneous phase structure
    14.
    发明授权
    Fine polymer particles having heterogeneous phase structure 失效
    具有异质相结构的聚合物微粒

    公开(公告)号：US6027805A

    公开(公告)日：2000-02-22

    申请号：US103936

    申请日：1998-06-25

    申请人： Junichi Yamanouchi ,  Hidetoshi Watanabe ,  Kunio Ishigaki ,  Seiichi Yamamoto ,  Kouta Fukui

    发明人： Junichi Yamanouchi ,  Hidetoshi Watanabe ,  Kunio Ishigaki ,  Seiichi Yamamoto ,  Kouta Fukui

    IPC分类号： C08F279/02 ,  C08L51/00 ,  C08L51/04 ,  C08L51/06 ,  C08L53/00 ,  C08L53/02 ,  G03C1/053 ,  G03C1/95 ,  G03C5/26 ,  G03C5/30 ,  G03C5/305 ,  G03C5/31 ,  C08F279/00

    CPC分类号： G03C5/30 ,  C08F279/02 ,  C08L51/00 ,  C08L51/04 ,  C08L51/06 ,  C08L53/00 ,  C08L53/02 ,  G03C1/053 ,  G03C1/95 ,  G03C5/26 ,  G03C5/265 ,  G03C5/3021 ,  G03C5/3035 ,  G03C5/305 ,  G03C5/31 ,  Y10T428/2984 ,  Y10T428/2987 ,  Y10T428/2989

    摘要： Latex polymer of fine particles having a heterogeneous phase structure which comprises a core of a polymer having repeating units derived from a conjugated diene monomer and a shell of a polymer having repeating units derived from at least one ethylenically unsaturated monomer carrying an active methylene group; a silver halide photographic light-sensitive material comprises a core/shell latex polymer whose shell consists of a polymer having repeating units of an ethylenically unsaturated monomer represented by the formula: CH.sub.2 .dbd.C(R.sup.1)--L--X (wherein R.sup.1 represents H, alkyl or halogen, L represents a single bond or a bivalent coupling group, X represents an active methylene group, provided that L is bonded to X in the form of alkylene; and a method for forming images on a silver halide light-sensitive material which comprises exposing the material which comprises at least one light-sensitive silver halide emulsion layer and at least one hydrophilic colloidal layer either of which comprises a latex polymer having active methylene groups and developing the exposed material with a developer which comprises a dihydroxybenzene developing agent and an auxiliary developing agent showing superadditivity, the pH increase observed when adding 0.1 mole/l developer of NaOH to the developer .ltoreq.0.25; 9.5.ltoreq. initial pH of the developer .ltoreq.11.0; the amount of the developer supplemented .ltoreq.225 ml/ml.sup.2.

    摘要翻译： 具有非均相结构的细颗粒的乳胶聚合物，其包含具有衍生自共轭二烯单体的重复单元的聚合物芯和具有衍生自至少一种带有活性亚甲基的烯属不饱和单体的重复单元的聚合物的壳; 卤化银照相感光材料包括核/壳胶乳聚合物，其壳由具有由式：CH 2 = C（R 1）-LX（其中R 1表示H的烷基或烷基）的烯属不饱和单体的重复单元的聚合物组成， 卤素，L表示单键或二价偶联基团，X表示活性亚甲基，条件是L以亚烷基的形式键合到X;以及在卤化银感光材料上形成图像的方法，其包括曝光 所述材料包含至少一种感光卤化银乳剂层和至少一种亲水性胶体层，其中任一种包含具有活性亚甲基的胶乳聚合物，并用显影剂显影所述外露材料，所述显影剂包含二羟基苯显影剂和辅助显影剂 显示超加性剂，当向显影剂添加0.1mol / l NaOH显影剂时观察到的pH增加

    Silver halide photographic light-sensitive material
    15.
    发明授权
    Silver halide photographic light-sensitive material 失效
    卤化银照相感光材料

    公开(公告)号：US6013410A

    公开(公告)日：2000-01-11

    申请号：US42133

    申请日：1998-03-13

    申请人： Takeo Arai

    发明人： Takeo Arai

    IPC分类号： G03C1/053 ,  G03C1/06 ,  G03C1/93 ,  G03C1/95 ,  G03C1/795 ,  G03C1/295 ,  G03C1/89

    CPC分类号： G03C1/95 ,  G03C1/053 ,  G03C1/93 ,  G03C1/061 ,  Y10S430/162

    摘要： A silver halide photographic light-sensitive material is disclosed. The light-sensitive material comprises a support having thereon a subbing layer having a glass transition point Tg of 40.degree. C. to 200.degree. C. which comprises a hydrophobic resin, and a silver halide emulsion layer and optionally a non-light-sensitive hydrophilic colloid layer provided on the subbing layer, and at least one of the silver halide emulsion layer and the non-light-sensitive hydrophilic colloid layer contains an inorganic colloidal particle or a composite latex comprising an inorganic particle and a hydrophobic resin in an amount of 0.1 g/m.sup.2 to 2.0 g/m.sup.2 of in total.

    摘要翻译： 公开了一种卤化银照相感光材料。 感光材料包括其上具有玻璃化转变点Tg为40℃至200℃的底层的载体，其包含疏水性树脂，以及卤化银乳剂层和任选的非光敏亲水性 提供在底层上的胶体层，并且卤化银乳剂层和非感光亲水胶体层中的至少一个含有无机胶体颗粒或包含0.1重量％的无机颗粒和疏水性树脂的复合胶乳 g / m2〜2.0g / m2。

    Silver halide elements that produce sharp images without fixing and processes for their use
    16.
    发明授权
    Silver halide elements that produce sharp images without fixing and processes for their use 失效
    产生清晰图像的卤化银元件，无需固定和使用

    公开(公告)号：US6007976A

    公开(公告)日：1999-12-28

    申请号：US10055

    申请日：1998-01-21

    申请人： David H. Levy ,  John Gasper

    发明人： David H. Levy ,  John Gasper

    IPC分类号： G03C1/32 ,  G03C1/95 ,  G03C5/16 ,  G03C5/38 ,  G03C7/392 ,  G03C1/735

    CPC分类号： G03C7/39204 ,  G03C1/95 ,  G03C5/16 ,  G03C5/38 ,  Y10S430/148

    摘要： A silver halide imaging element is disclosed that is capable of providing a sharp image with silver halide grains still present following imagewise exposure and development. This is achieved by choosing a dispersing medium for the silver halide grains comprised of an organic vehicle and, dispersed therein, titanium dioxide particles having an average size of less than 0.1 micrometer accounting for at least 10 percent by weight of the dispersing medium. The elements are useful for optical printing or scan image retrieval without fixing. The elements can be used for providing black-and-white photographic images, radiographic images or dye images.

    摘要翻译： 公开了一种卤化银成像元件，其能够在图像曝光和显影之后提供仍然存在的卤化银颗粒的清晰图像。 这通过选择用于由有机载体组成的卤化银颗粒的分散介质来实现，并且其中分散有平均尺寸小于0.1微米的二氧化钛颗粒，占分散介质的至少10重量％。 这些元件可用于光学打印或扫描图像检索而无需固定。 这些元件可用于提供黑白照相图像，放射照相图像或染料图像。

    Photographic elements containing elastomeric matting agent
    17.
    发明授权
    Photographic elements containing elastomeric matting agent 失效
    含有弹性体消光剂的摄影元件

    公开(公告)号：US5916741A

    公开(公告)日：1999-06-29

    申请号：US920144

    申请日：1997-05-26

    申请人： Dennis E. Smith ,  Yongcai Wang ,  Patrick M. Jeffries ,  James R. Bennett

    发明人： Dennis E. Smith ,  Yongcai Wang ,  Patrick M. Jeffries ,  James R. Bennett

    IPC分类号： G03C1/95 ,  G03C1/76

    CPC分类号： G03C1/95 ,  Y10S430/151 ,  Y10S430/162

    摘要： The present invention provides a photographic element comprises a support, at least one hydrophilic light-sensitive layer, and a light-insensitive layer containing a binder and polymer matte particles having the formula:(A).sub.x (B).sub.y (C).sub.z (I)where A is a monofunctional ethylenically unsaturated monomer which forms a homopolymer with a Tg less than 20.degree. C., B is a monofunctional ethylenically unsaturated monomer which forms a homopolymer with a Tg greater than 60.degree. C., C is a monomer with two or more ethylenically unsaturated groups, x is about 10 to 95 mole %, y is less than 85 mole %, and z is about 5 to 90 mole %.

    摘要翻译： 本发明提供了一种照相元件，其包括载体，至少一个亲水感光层和含有粘合剂的光不敏感层和具有下式的聚合物哑光颗粒：（A）x（B）y（C）z（ I）其中A是形成Tg小于20℃的均聚物的单官能烯属不饱和单体，B是形成Tg大于60℃的均聚物的单官能烯属不饱和单体，C是具有 两个或更多个烯键式不饱和基团，x为约10至95摩尔％，y小于85摩尔％，z为约5至90摩尔％。

    Photographic element having surface protective layer
    18.
    发明授权
    Photographic element having surface protective layer 失效
    具有表面保护层的摄影元件

    公开(公告)号：US5866312A

    公开(公告)日：1999-02-02

    申请号：US878791

    申请日：1997-06-19

    申请人： Yongcai Wang ,  Dennis E. Smith ,  Alfred B. Fant

    发明人： Yongcai Wang ,  Dennis E. Smith ,  Alfred B. Fant

    IPC分类号： G03C1/005 ,  G03C1/04 ,  G03C1/76 ,  G03C1/95 ,  G03C1/89

    CPC分类号： G03C1/95 ,  G03C1/7614 ,  G03C1/005 ,  G03C1/04 ,  Y10S430/162

    摘要： The present invention is a photographic element which includes a support, at least one silver halide emulsion layer, and a light-insensitive protective overcoat. The light insensitive protective overcoat includes a hydrophilic binder and polymer particles having a glass transition temperature of at least 70.degree. C. The polymer particles prepared by the process of mechanically forming oil-in-water droplets having a size less than 400 nm of an ethylenically unsaturated monomer having hydrophobic groups, the hydrophobic groups having a logP.sub.(calc) greater than a logP.sub.(calc) of the ethylenically unsaturated monomer by at least 1 unit in an aqueous medium. A hydrophilic colloid is added to the aqueous medium in an amount sufficient to render the polymer partice compatible with the hydrophilic binder. The droplets are polymerized to a size of less than 400 nm. The present invention is also a photographic element which includes a support, at least one silver halide emulsion layer, and a light-insensitive protective overcoat. The light insensitive protective overcoat includes a hydrophilic binder and polymer particles having a glass transition temperature of at least 70.degree. C. The polymer particles prepared by the process of mechanically forming oil-in-water droplets having a size less than 400 nm of an ethylenically unsaturated monomer having a logP.sub.(calc) greater than 4, preferably greater than 6 in an aqueous medium. A hydrophilic colloid is added to the aqueous medium in an amount sufficient to render the polymer partice compatible with the hydrophilic binder. The droplets are polymerized to a size of less than 400 nm.

    摘要翻译： 本发明是一种照相材料，它包括一种载体，至少一种卤化银乳剂层和一种不透光的保护性外涂层。 光不敏感的保护性外涂层包括亲水性粘合剂和玻璃化转变温度至少为70℃的聚合物颗粒。通过机械地形成尺寸小于400nm的水包油液滴制备的聚合物颗粒为烯属 具有疏水基团的不饱和单体，所述疏水基团在水性介质中具有大于所述烯键式不饱和单体的logP（calc））至少1单位的logP（calc）。 将亲水胶体以足以使聚合物部分与亲水性粘合剂相容的量加入到水性介质中。 液滴聚合成小于400nm的尺寸。 本发明还是一种照相元件，它包括一种载体，至少一种卤化银乳剂层和一种不透光的保护性外涂层。 光不敏感的保护性外涂层包括亲水性粘合剂和玻璃化转变温度至少为70℃的聚合物颗粒。通过机械地形成尺寸小于400nm的水包油液滴制备的聚合物颗粒为烯属 在水性介质中logP（calc）大于4，优选大于6的不饱和单体。 将亲水胶体以足以使聚合物部分与亲水性粘合剂相容的量加入到水性介质中。 液滴聚合成小于400nm的尺寸。