公开(公告)号：US20090246561A1

公开(公告)日：2009-10-01

申请号：US12409866

申请日：2009-03-24

申请人： Arden P. Johnson ,  Konstantin Tikhonov ,  Douglas Woodnorth ,  Jon J. Carroll

发明人： Arden P. Johnson ,  Konstantin Tikhonov ,  Douglas Woodnorth ,  Jon J. Carroll

IPC分类号： H01M12/00

CPC分类号： H01M10/0525 ,  H01M4/382 ,  H01M4/388 ,  H01M4/5825 ,  H01M4/587 ,  H01M6/162 ,  H01M6/164 ,  H01M6/5033 ,  H01M10/425 ,  H01M16/00 ,  H01M2300/0031

摘要： A lithium oxyhalide cell electrically connected in parallel with a lithium ion cell is described. Importantly, the open circuit voltage of the freshly built primary lithium oxyhalide cell is equal to or less that the open circuit voltage of the lithium ion cell in a fully charged state. This provides a power system that combines the high capacity of the primary cell with the high pulse power of the secondary cell. This hybrid power system exhibits increased rate capability, higher capacity and improved safety in addition to elimination of voltage delay in comparison to a comparable lithium oxyhalide cell discharge alone.

摘要翻译： 描述与锂离子电池并联电连接的卤氧化锂电池。 重要的是，新建的卤代锂离子电池的开路电压等于或小于完全充电状态下的锂离子电池的开路电压。 这提供了将主电池的高容量与二次电池的高脉冲功率组合的电力系统。 与可比较的单独的卤氧化锂电池放电相比，除了消除电压延迟之外，该混合动力系统显示出增加的速率能力，更高的容量和更高的安全性。

公开(公告)号：US6083647A

公开(公告)日：2000-07-04

申请号：US103792

申请日：1993-08-10

申请人： Kazuhiro Noda ,  Kenichi Takahashi ,  Koichi Tanaka ,  Haruo Watanabe

发明人： Kazuhiro Noda ,  Kenichi Takahashi ,  Koichi Tanaka ,  Haruo Watanabe

IPC分类号： C25D3/44 ,  H01M4/46 ,  H01M6/16 ,  H01M10/054 ,  H01M10/0566 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/36 ,  H01M4/02

CPC分类号： H01M6/164 ,  C25D3/44 ,  H01M10/054 ,  H01M10/0566 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0031 ,  H01M4/463 ,  H01M6/166

摘要： A non-aqueous electrolyte comprises an aluminium halide and a quaternary ammonium halide dissolved in a non-aqueous solvent. A non-aqueous electrolytic cell is also described, which comprises an anode made of Al or its alloy, an cathode and the non-aqueous electrolyte provided between the anode and the cathode. The non-aqueous electrolyte is suitable for electrodeposition of aluminium from the electrolyte. Because aluminium is reversibly electrodeposited from and dissolved in the electrolyte, the electrolyte is usable for making secondary cells having good charge and discharge characteristics and a high energy density.

摘要翻译： 非水电解质包括溶解在非水溶剂中的卤化铝和季铵盐。 还描述了一种非水电解池，其包括由Al或其合金制成的阳极，阴极和设置在阳极和阴极之间的非水电解质。 非水电解质适用于从电解质中电沉积铝。 由于铝可电解沉积并溶解在电解质中，电解质可用于制造具有良好充放电特性和高能量密度的二次电池。

公开(公告)号：US20170244132A1

公开(公告)日：2017-08-24

申请号：US15584097

申请日：2017-05-02

申请人： Bayerische Motoren Werke Aktiengesellschaft

发明人： Ralf WAGNER ,  Dennis GALLUS ,  Benjamin STREIPERT ,  Martin WINTER ,  Johannes KASNATSCHEEW ,  Marius AMERELLER

IPC分类号： H01M10/0568 ,  H01M4/134 ,  H01M4/131 ,  H01M4/133 ,  H01M10/0525 ,  H01M10/0569

CPC分类号： H01M10/0568 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M10/0525 ,  H01M10/0569 ,  H01M2220/20 ,  H01M2300/0031 ,  H01M2300/0034 ,  H01M2300/0037 ,  Y02E60/122

摘要： An electrolyte for a lithium-ion battery which includes lithium hexafluorophosphate and lithium 2-pentafluoroethoxy-1,1,2,2-tetrafluoroethanesulfonate. A lithium-ion battery which includes an electrolyte containing lithium hexafluorophosphate and lithium 2-pentafluoroethoxy-1,1,2,2-tetrafluoroethanesulfonate. A motor vehicle which uses a lithium-ion battery having electrolytes containing lithium hexafluorophosphate and lithium 2-pentafluoroethoxy-1,1,2,2-tetrafluoroethanesulfonate. The electrolyte can increase the service life of the lithium-ion battery.

公开(公告)号：US20160261005A1

公开(公告)日：2016-09-08

申请号：US15036763

申请日：2014-11-17

申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA

发明人： Cyrus Rustomji ,  Sungho Jin ,  Taekyoung Kim ,  Jungmin You ,  Joseph Wang ,  Duyoung Choi

IPC分类号： H01M10/0569 ,  H01M10/0525 ,  H01G11/46 ,  H01G11/22 ,  H01G11/78 ,  H01G11/86 ,  C25D5/00 ,  H01G11/60

CPC分类号： H01M10/0569 ,  C25D3/42 ,  C25D3/44 ,  C25D3/50 ,  C25D3/54 ,  C25D5/003 ,  C25D9/08 ,  C25D17/02 ,  C25D21/00 ,  H01G11/22 ,  H01G11/46 ,  H01G11/60 ,  H01G11/62 ,  H01G11/78 ,  H01G11/86 ,  H01M4/382 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0564 ,  H01M2300/0028 ,  H01M2300/0031 ,  H01M2300/0034 ,  Y02E60/13

摘要： Disclosed are novel electrolytes, and techniques for making and devices using such electrolytes, which are based on compressed gas solvents. Unlike conventional electrolytes, disclosed electrolytes are based on “compressed gas solvents” mixed with various salts, referred to as “compressed gas electrolytes.” Various embodiments of a compressed gas solvent includes a material that is in a gas phase and has a vapor pressure above an atmospheric pressure at a room temperature. The disclosed compressed gas electrolytes can have wide electrochemical potential windows, high conductivity, low temperature capability and/or high pressure solvent properties.

摘要翻译： 本发明公开了基于压缩气体溶剂的新型电解质以及使用这种电解质的制造方法和装置。 与常规电解质不同，所公开的电解质基于与称为“压缩气体电解质”的各种盐混合的“压缩气体溶剂”。压缩气体溶剂的各种实施方案包括处于气相并且具有高于 在室温下的大气压。 所公开的压缩气体电解质可以具有宽的电化学电位窗口，高导电性，低温能力和/或高压溶剂性质。

公开(公告)号：US09425455B1

公开(公告)日：2016-08-23

申请号：US14167654

申请日：2014-01-29

申请人： HRL Laboratories, LLC

发明人： John J. Vajo ,  Adam F. Gross ,  Ping Liu ,  Jocelyn Hicks-Garner ,  Elena Sherman ,  Sky Van Atta

IPC分类号： H01M4/36 ,  H01M4/04 ,  H01M4/48 ,  H01M4/58

CPC分类号： H01M4/044 ,  H01M4/0402 ,  H01M4/0404 ,  H01M4/131 ,  H01M4/136 ,  H01M4/36 ,  H01M4/463 ,  H01M4/48 ,  H01M4/483 ,  H01M4/5815 ,  H01M4/582 ,  H01M4/625 ,  H01M4/80 ,  H01M10/054 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/399 ,  H01M2300/0031

摘要： Variations of the invention provide an improved aluminum battery consisting of an aluminum anode, a non-aqueous electrolyte, and a cathode comprising a metal oxide, a metal fluoride, a metal sulfide, or sulfur. The cathode can be fully reduced upon battery discharge via a multiple-electron reduction reaction. In some embodiments, the cathode materials are contained within the pore volume of a porous conductive carbon scaffold. Batteries provided by the invention have high active material specific energy densities and good cycling stabilities at a variety of operating temperatures.

摘要翻译： 本发明的变化提供了由铝阳极，非水电解质和包含金属氧化物，金属氟化物，金属硫化物或硫的阴极组成的改进的铝电池。 通过多电子还原反应，电池放电时阴极可以完全降低。 在一些实施方案中，阴极材料包含在多孔导电碳支架的孔体积内。 本发明提供的电池在各种操作温度下具有高的活性材料比能量密度和良好的循环稳定性。

公开(公告)号：US08715853B1

公开(公告)日：2014-05-06

申请号：US12868479

申请日：2010-08-25

申请人： John J. Vajo ,  Adam F. Gross ,  Ping Liu ,  Jocelyn Hicks-Garner ,  Elena Sherman ,  Sky Van Atta

发明人： John J. Vajo ,  Adam F. Gross ,  Ping Liu ,  Jocelyn Hicks-Garner ,  Elena Sherman ,  Sky Van Atta

IPC分类号： H01M4/02

CPC分类号： H01M4/044 ,  H01M4/0402 ,  H01M4/0404 ,  H01M4/131 ,  H01M4/136 ,  H01M4/36 ,  H01M4/463 ,  H01M4/48 ,  H01M4/483 ,  H01M4/5815 ,  H01M4/582 ,  H01M4/625 ,  H01M4/80 ,  H01M10/054 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/399 ,  H01M2300/0031

摘要： Variations of the invention provide an improved aluminum battery consisting of an aluminum anode, a non-aqueous electrolyte, and a cathode comprising a metal oxide, a metal fluoride, a metal sulfide, or sulfur. The cathode can be fully reduced upon battery discharge via a multiple-electron reduction reaction. In some embodiments, the cathode materials are contained within the pore volume of a porous conductive carbon scaffold. Batteries provided by the invention have high active material specific energy densities and good cycling stabilities at a variety of operating temperatures.

摘要翻译： 本发明的变化提供了由铝阳极，非水电解质和包含金属氧化物，金属氟化物，金属硫化物或硫的阴极组成的改进的铝电池。 通过多电子还原反应，电池放电时阴极可以完全降低。 在一些实施方案中，阴极材料包含在多孔导电碳支架的孔体积内。 本发明提供的电池在各种操作温度下具有高的活性材料比能量密度和良好的循环稳定性。

公开(公告)号：US08691449B2

公开(公告)日：2014-04-08

申请号：US13105066

申请日：2011-05-11

申请人： Toshiyuki Kobayashi ,  Kazushige Kohno

发明人： Toshiyuki Kobayashi ,  Kazushige Kohno

IPC分类号： H01M6/16

CPC分类号： H01M10/0525 ,  H01M10/0567 ,  H01M10/0569 ,  H01M10/4235 ,  H01M2300/0028 ,  H01M2300/0031 ,  H01M2300/0042

摘要： A nonaqueous electrolyte and a lithium-ion secondary battery using the same, wherein a mixture of a cyclic carbonate, a chain carbonate, a first phosphoric acid ester wherein bonding between carbons is a single bond, and a second phosphoric acid ester wherein bonding between carbons contains a double bond is used as the nonaqueous electrolyte. It is desirable that the first phosphoric acid ester is a trimethyl phosphate. In addition, it is desirable that the second phosphoric acid ester is a dimethylisopropenyl phosphate.

摘要翻译： 一种非水电解质和使用该非水电解质的锂离子二次电池，其中环状碳酸酯，链状碳酸酯，碳键合为单键的第一磷酸酯和碳键之间的第二磷酸酯的混合物 含有双键作为非水电解质。 第一磷酸酯是磷酸三甲酯是理想的。 此外，优选第二磷酸酯是二甲基异丙烯基磷酸酯。

公开(公告)号：US20120058401A1

公开(公告)日：2012-03-08

申请号：US13210046

申请日：2011-08-15

申请人： Masayuki Ihara ,  Takehiko Tanaka ,  Tadahiko Kubota

发明人： Masayuki Ihara ,  Takehiko Tanaka ,  Tadahiko Kubota

IPC分类号： H01M10/056 ,  H01M4/134 ,  H01M4/133

CPC分类号： H01M10/0567 ,  H01M4/386 ,  H01M4/387 ,  H01M4/525 ,  H01M10/052 ,  H01M2300/0031 ,  H01M2300/0034 ,  H01M2300/0037 ,  Y02E60/122 ,  Y02T10/7011

摘要： A secondary battery includes a cathode, an anode, and an electrolytic solution. The electrolytic solution contains chlorine ions together with a nonaqueous solvent and an electrolyte salt. The nonaqueous solvent contains sulfonic acid anhydrides (disulfonic acid anhydride or sulfonic acid carboxylic acid anhydride). A content of the chlorine ions is 5000 wt ppm or less.

摘要翻译： 二次电池包括阴极，阳极和电解液。 电解液与非水溶剂和电解质盐一起含有氯离子。 非水溶剂含有磺酸酐（二磺酸酐或磺酸羧酸酐）。 氯离子的含量为5000重量ppm以下。

公开(公告)号：US06558838B1

公开(公告)日：2003-05-06

申请号：US09502327

申请日：2000-02-11

申请人： Kazuhiro Noda ,  Kenichi Takahashi ,  Koichi Tanaka ,  Haruo Watanabe

发明人： Kazuhiro Noda ,  Kenichi Takahashi ,  Koichi Tanaka ,  Haruo Watanabe

IPC分类号： H01M604

CPC分类号： H01M6/164 ,  C25D3/44 ,  H01M4/463 ,  H01M6/166 ,  H01M10/054 ,  H01M10/0566 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0031

摘要： A non-aqueous electrolyte comprises an aluminum halide and a quaternary ammonium halide dissolved in a non-aqueous solvent. A non-aqueous electrolytic cell is also described, which comprises an anode made od Al or its alloy, an cathode and the non-aqueous electrolyte provided between the anode and the cathode. The non-aqueous electrolyte is suitable for electrodeposition of aluminum from the electrolyte. Because aluminum is reversibly electrodeposited from and dissolved in the electrolyte, the electrolyte is usable for making secondary cells having good charge and discharge characteristics and a high energy density.

摘要翻译： 非水电解质包括溶解在非水溶剂中的卤化铝和季铵盐。 还描述了一种非水电解池，其包括阳极制成的铝或其合金，阴极和设置在阳极和阴极之间的非水电解质。 非水电解质适用于从电解质中电沉积铝。 由于铝可电解沉积并溶解在电解质中，电解质可用于制造具有良好充放电特性和高能量密度的二次电池。

公开(公告)号：US20180026263A1

公开(公告)日：2018-01-25

申请号：US15548162

申请日：2016-02-10

申请人： COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES

发明人： Eric Mayousse ,  Lionel Blanc ,  Benoit Chavillon ,  Philippe Chenebault

IPC分类号： H01M4/36 ,  H01M10/054 ,  H01M4/66 ,  H01M10/0567 ,  H01M10/0569 ,  H01M10/0568 ,  H01M10/058 ,  H01M4/38 ,  H01M4/70

CPC分类号： H01M4/368 ,  H01M4/381 ,  H01M4/58 ,  H01M4/582 ,  H01M4/625 ,  H01M4/663 ,  H01M4/70 ,  H01M6/14 ,  H01M6/20 ,  H01M10/054 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/058 ,  H01M2004/021 ,  H01M2300/002 ,  H01M2300/0031

摘要： The invention relates to a liquid cathode cell including: a calcium anode; an electrolyte containing a sulphurous or phosphorous oxidising solvent and at least one salt; and a cathode containing, as an active material, a compound that is identical to the aforementioned oxidising solvent. The invention is characterised in that the salt is a strontium salt which is present in a concentration of from 1.15 mol·L−1 to 3 mol·L−1.