摘要:
A non-aqueous electrolyte secondary cell provided with: a positive electrode that has a positive electrode active material; a negative electrode; and a non-aqueous electrolyte. The positive electrode active material contains a lithium composite oxide containing Ni, and the non-aqueous electrolyte contains a non-aqueous solvent containing a fluorinated chain carboxylic acid ester and an organochlorine compound. The organochlorine compound is represented by general formula CF3CH2CO—CClR1R2 (where in the formula, R1 and R2 are respectively independent, and are selected from a hydrogen, a halogen, a C1-2 alkyl group, or a C1-2 halogenated alkyl group).
摘要:
An object, of the present invention is to provide a new liquid-repellent coating film. This object can be achieved by a coating film that has a fluorine content of less than 1 wt %, a water contact angle (droplet: 2 μL) of 115° or more, and a water contact angle of 300° or more after surface friction with a PET film (under a load of 100 gf/cm2; 1500 reciprocations); and that satisfies at least one of the following regarding surface roughness indices: (a) an average surface roughness Ra of 1.6 μm or more; and (b) a Wenzel roughness factor of 1.2 or more.
摘要:
A method for producing one or more hydrocarbon compounds from at least one of 2,3-butanediol, acetoin, and ethanol, the method comprising contacting said at least one of 2,3-butanediol, acetoin, and ethanol with a catalyst at a temperature of at least 100° C. and up to 500° C. to result in said 2,3-butanediol, acetoin, and/or ethanol being converted to said one or more hydrocarbon compounds, wherein said catalyst is either: (i) a catalyst comprising nanoparticles composed of (a) a first metal oxide selected from the group consisting of zirconium oxide, cerium oxide, titanium oxide, and lanthanum oxide, and (b) a main group metal oxide; or (ii) a catalyst comprising a zeolite loaded with at least one metal selected from the group consisting of copper, silver, nickel, palladium, platinum, rhodium, and ruthenium in an amount of 1-30 wt % by weight of the zeolite.
摘要:
The present invention relates to compounds capable of acting as androgen receptor antagonists, pharmaceutical formulations containing the same, and methods of use thereof. Such uses include, but are not limited to, use as antitumor agents, particularly for the treatment of cancers such as colon, skin and prostate cancer and to induce androgen receptor antagonist activity in a subject afflicted with an androgen-related affliction. Examples of androgen-related afflictions include, but are not limited to, baldness, hirsutism, behavioral disorders, acne, and uninhibited spermatogenesis wherein inhibition of spermatogenesis is so desired.
摘要:
A catalyst for the production of an oxygen-containing compound, comprising palladium, tungsten and zirconium, a production process thereof, and a production process of an oxygen-containing compound using the catalyst. The catalyst can provide an oxygen-containing compound from a lower olefin and oxygen with high productivity and high selectivity.
摘要:
A process for hydrolysing allylethers of the general formula:R.sub.6 CH.dbd.CR.sub.5 --CR.sub.4 --O--CR.sub.1 R.sub.2 R.sub.3wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6, which may be the same or different, represent a hydrogen atom or an alkyl group of from 1 to 8 carbon atoms or one of R.sub.1, R.sub.2 or R.sub.3 and R.sub.6 together represent a covalent bond, with water in the presence of a supported Group VIII metal catalyst. Methyl sec-butenyl ether can be hydrolysed in high yield to methyl ethyl ketone.
摘要:
Alcohols are dehydrogenated to form ketones, using a catalyst containing liquid indium dispersed and retained in the pore structure of a porous carrier. The catalyst is prepared by mixing powdered In.sub.2 O.sub.3 and MgO, firing the mixture at 900.degree.-1150.degree. C. for 5-20 hours, and activating the catalyst by passing through a reducing gas.
摘要:
Preparation of carbonyl compounds from unsaturated olefin hydrocarbons is conducted in the presence of a catalyst system such as palladium chloride in an aqueous medium, a redox system such as cupric chloride using an oxidant such as oxygen or air in which the rate of reaction or throughput may be increased by use of a wetproofed Contacogen. Typical materials for use as a Contacogen include granular carbon wetproofed with a fluorocarbon resin such as PTFE. By use of a Contacogen it is possible to increase the rate and/or throughput over that obtained without the use of a Contacogen even when the reactions are conducted at relatively low temperatures and pressures, e.g., below about 150*C and below about 5 atmospheres. Various catalyst and redox systems may be used and process parameters may be varied to produce various products, e.g., acetaldehyde from ethylene at low temperatures and pressure.
摘要:
1. A PROCESS FOR UPGRADING A BYPRODUCT CARBONYL STREAM PRODUCED IN THE PREPARATION OF BUTADIENE BY THE CATALYTIC DEHYDROGENATION OF BUTYLENE, THE STREAM CONTAINONG A MIXTURE OF SUBSTANCES INCLUDING WATER, ACETONE, METHLYL VINYL KETONE, ABD METHYL ETHYL KETONE, COMPRISING THE STEPS OF ADDING CALCIUM CHLORIDE TO THE MIXTURE TO FORM A HEAVIER WATER PHASE AND A LIGHTER CARBONYL PHASE, THE MIXTURE BEING TREATED WITH AT LEAST 0.5 PART BY WEIGHT OF CALCIUM CHLORIDE FOR EACH PART BY WEIGHT OF WATER, SEPARATING THE HEAVIER WATER PHASE FROM THE THE LIGHTER CARBONYL PHASE, DISTILLING THE ACETONE FROM THE MIXTURE BEFORE SEPARATION OF THE WATER PHASE OR FROM THE CARBONYL PHASE AFTER SEPARATION TO THE WATER PHASE, REACTING THE METHYL VINYL KETONE CONTAINED IN THE RESIDUAL LIQUID IN ADMIXTURE WITH THE METHYL ETHYL KETONE WITH AT LEAST ONE ETHYLENICALLY UNSATURATED COMPOUND SELECTED FROM THE GROUP CONSISTING OF STYRENE, VINYL NAPHTHALENE, ALPHA-OLEFINS CONTAINING 2 TO 20 CARBON ATOMS VINYL CHLORIDE AND VINYLIDENE CHLORIDE, ACRYLIC ACID, METHYL ACRYLATE, ETHYL ACRYLATE, METHACRYLIC ACID, METHAYLMETHACRYLATE, ETHYLMETHACRYLATE, VINYL ACETATE, VINYL PYRIDINE AND ACRYLAMIDE IN THE PRESENCE OF A FREE RADICAL CATALYST AND THEN SEPARATING THE METHYL ETHYL KETONE FROM THE PRODUCT OF THE REACTION OF THE METHYL VINYL KETONE AND THE ETHYLENICALLY UNSATURATED COMPOUND.
摘要:
The present invention relates to a thermo-responsive solution and in particular, a solution for use in an osmosis process that is suitable for separating or purifying solutes and or water from an aqueous solution on a large scale and under energy efficient conditions.