Abstract:
The present invention relates to N-methylol amide-containing resinous compositions and the methods of preparing them. Aqueous dispersions of the instant resinous composition containing N-methylol amides in amounts sufficient to impart self-curing at comparatively low temperatures are disclosed. The aqueous dispersions of the instant resinous compositions are useful as coating compositions; they are particularly suited to electrodeposition.
Abstract:
A thermosetting binder composition for coating, comprising:(1) A non-acidic resinous saturated compound having a molecular weight of at least 900, and an alcoholic hydroxyl content of at least 0.2 eq./100 g;(2) A non-acidic polyester of a polycarboxylic acid cross-linking agent having more than one .beta.-hydroxyl ester group per molecule, and at least one of components (1) and (2) having an alcoholic hydroxyl functionality of more than 2, and(II) A transesterification-promoting metal salt or complex curing catalyst which is soluble in liquid hydrocarbons.For aqueous compositions, component (I) (1) is preferably a neutralized epoxy resin/amine adduct and component (II) should be insoluble in water; they can be used for cathodic electrodeposition.
Abstract:
Thermosetting compositions comprising a film forming component bearing or capable of generating hydroxyl functionality, amine-aldehyde crosslinking agent, and a latent reactive catalyst comprising the reaction product of (i) a copolymer bearing pendent epoxy functionality, and (ii) a sulfonic acid having the formula ##STR1## wherein R is selected from linear or branched alkyl groups and aryl groups.Preferred compositions within the scope of the invention include high solids, thermosetting coating compositions suitable for automotive applications.
Abstract:
An alcoholic varnish comprising an alcoholic solution of a hydroxyl group-containing copolymer resin of cyclopentadiene, dicyclopentadiene or an alkyl-substituted derivative thereof and a compound, such as allyl alcohol, having at least one double bond and at least one hydroxyl group in the molecule. In one embodiment, this invention relates to an alcoholic varnish comprising an alcoholic solution of said hydroxyl group-containing resin and at least one known alcohol soluble resin such as maleinated rosin or alkyd resin.
Abstract:
Novel thermosetting resinous compositions are disclosed. The compositions comprise the reaction product of a polymeric polyol having a cured glass transition temperature less than 20.degree. C. with a substantial stoichiometric excess of an aminoplast curative. The cured compositions are hard with good durability and surprising flexibility for such high aminoplast loadings.These compositions are particularly useful as coatings for resilient and rubbery substrates such as foam rubber, polyurethane foam and vinyl foam and on soft metal surfaces such as mild steel and aluminum.
Abstract:
Aqueous emulsion thermosetting coating compositions possessing superior flexibility and room temperature coalescence are provided by combining certain aqueous emulsion copolymers including hydroxy and carboxy functionality, aminoplast resin and water dispersible high boiling polyhydric adduct of an aliphatic polyhydric alcohol containing from 2-4 hydroxyl groups with a monoepoxide or a lactone.
Abstract:
Thermosetting resins containing hydroxyl groups which can be cured with aminoplast resins are stabilized by the addition of 1,4-diazo[2,2,2]-bicyclooctane. This method is particularly useful in stabilizing the gloss retention of extensible coatings formed by curing a hydroxyl-containing urethane product with an aminoplast resin. Such coatings can be applied to virtually any solid substrate and are especially useful on rubbery, resilient substrates such as polyurethane or polyethylene foam, natural or synthetic rubber or rubber foam, and various elastomeric plastic materials. They are also particularly useful on other substrates such as mild steel or aluminum.
Abstract:
Powdered thermosetting compositions, comprising I a resinous constituent selected from the group consisting of (1) a mixture of a saturated linear or branched chain resin (A) containing free reactive groups selected from hydroxyl and carboxyl groups and an aminoplast resin (B) selected from the group consisting of polyamide-aldehyde resins, polyamide-aldehyde resins, etherified polyamine-aldehyde resins and etherified polyamide-aldehyde resins, and (2) a self-thermo-cross-linking resin containing Nmethylolamide or alkoxylated N-methylolamide groups; II a polycondensation catalyst (C) consisting of an alkyl monoester of a halogenated aromatic polycarboxylic acid; and III auxiliary agents (D) for coating compositions; processes for the preparation of these powdered compositions and the use thereof as protective and/or decorative coatings on articles which are conductors of electricity.
Abstract:
An un-reacted substantially formaldehyde free curable binder solution for binding loose mutter consists essentially of a solution obtainable by dissolving a reducing sugar, an ammonium salt acid precursor, optionally a carboxylic acid or a precursor thereof and optionally ammonia in water.