公开(公告)号：US06936670B2

公开(公告)日：2005-08-30

申请号：US10482546

申请日：2002-06-27

Applicant: Andreas Kramer ,  Andreas Mühlebach ,  Peter Nesvadba ,  Marie-Odile Zink ,  Tobias Hintermann

Inventor： Andreas Kramer ,  Andreas Mühlebach ,  Peter Nesvadba ,  Marie-Odile Zink ,  Tobias Hintermann

IPC: C07D295/22 ,  C07D211/94 ,  C08F2/00 ,  C08F2/38 ,  C08F4/00 ,  C08F10/00 ,  C08F12/00 ,  C08F12/08 ,  C08F20/18 ,  C08F118/00 ,  C08F122/00 ,  C08F136/00 ,  C08F126/06

CPC classification number: C08F4/00 ,  C07D211/94

Abstract: The instant invention relates to multifunctional alkoxyamines based on polyalkylpiperidines, polyalkylpiperazinones and polyalkylmorpholinones and their use as polymerization regulatros/initiators. Further subjects of the invention are a polymerizable composition comprising an ethylenically unsaturated monomer or oligomer and the alkoxyamine compound as well as a process for polymerization and a process for preparation of the compounds.

Abstract translation: 本发明涉及基于聚烷基哌啶，聚烷基哌嗪酮和聚烷基吗啉酮的多官能烷氧基胺及其作为聚合调节剂/引发剂的用途。 本发明的其它主题是包含烯键式不饱和单体或低聚物和烷氧基胺化​​合物的可聚合组合物以及聚合方法和化合物的制备方法。

公开(公告)号：US06235856B1

公开(公告)日：2001-05-22

申请号：US08860268

申请日：1997-06-19

Applicant: Andreas Hafner ,  Paul Adriaan Van Der Schaaf ,  Andreas Mühlebach

Inventor： Andreas Hafner ,  Paul Adriaan Van Der Schaaf ,  Andreas Mühlebach

IPC: C08F480

CPC classification number: C08G61/08 ,  B33Y70/00

Abstract: Composition of (a) dicyclopentadiene, by itself or in a mixture with a strained cycloolefin, and (b) a catalytic amount of at least one carbene-free, divalent-cationic ruthenium or osmium compound as a single-component catalyst, which contains at least one phosphine group and a total of 2 to 5 ligands bonded to the metal atom, and which contains acid anions for charge balancing. The compositions can be polymerized by means of heat (metathesis polymerization) and are suitable for the production of shaped articles and coatings.

Abstract translation: （a）二环戊二烯本身或与应变环烯烃的混合物的组成，和（b）催化量的至少一种不含有无碳原子的二价阳离子钌或锇化合物作为单组分催化剂，其含有 至少一个膦基和总共2至5个与金属原子键合的配体，并且其含有用于电荷平衡的酸阴离子。 组合物可以通过热（易位聚合）聚合，并且适用于成型制品和涂料的生产。

公开(公告)号：US08623459B2

公开(公告)日：2014-01-07

申请号：US12595969

申请日：2008-04-11

Applicant: Andreas Mühlebach ,  Erich Nyfeler ,  Stephan Ilg ,  Pascal Hayoz ,  Jens Möller

Inventor： Andreas Mühlebach ,  Erich Nyfeler ,  Stephan Ilg ,  Pascal Hayoz ,  Jens Möller

IPC: B05D3/00 ,  B05D3/02 ,  B32B27/08

CPC classification number: C08J7/18 ,  C08F255/00 ,  C08F291/00 ,  C08J7/047 ,  C08J7/16 ,  C08J2433/00 ,  C08J2471/00 ,  C08L51/003 ,  C08L51/06 ,  C09D151/003 ,  C09D151/06 ,  Y10T428/31913 ,  C08L2666/02

Abstract: The present invention provides a process for imparting decreased adhesion of biological material to the surface of a substrate comprises the following steps (i) oxidizing the surface of the substrate (ii) applying a composition comprising one or more ethylenically unsaturated compounds to the oxidized surface of the substrate and (iii) curing the composition in order to form a coating layer.

Abstract translation: 本发明提供了一种赋予生物材料对基材表面附着力降低的方法，其包括以下步骤：（i）将基材表面氧化（ⅱ）将包含一种或多种烯属不饱和化合物的组合物施加到氧化表面 基材和（iii）固化组合物以形成涂层。

公开(公告)号：US08456733B2

公开(公告)日：2013-06-04

申请号：US12083884

申请日：2006-10-16

Applicant: Margherita Fontana ,  Gabriele Baisch ,  Thomas Giesenberg ,  Laurent Michau ,  Reinhold Öhrlein ,  Andreas Mühlebach

Inventor： Margherita Fontana ,  Gabriele Baisch ,  Thomas Giesenberg ,  Laurent Michau ,  Reinhold Öhrlein ,  Andreas Mühlebach

IPC: G02B26/00

CPC classification number: G02F1/167 ,  B82Y30/00 ,  C01P2002/88 ,  C01P2004/62 ,  C01P2004/64 ,  C09C1/3081 ,  C09C1/407 ,  C09C3/12

Abstract: The present invention discloses the use of functionalized particles as electrophoretic displaying particles, wherein the functionalized particles are SiO2, Al2O3 or mixed SiO2 and Al2O3 particles comprising, covalently bound to an oxygen atom on the surface, a radical of formula (1), wherein R1 and R2 are independently of each other hydrogen, particle surface-O—, or a substituent, n is 1, 2, 3, 4, 5, 6, 7 or 8, B is the direct bond or a bridge member, and D is the residue of an organic chromophore.

Abstract translation: 本发明公开了使用官能化颗粒作为电泳显示颗粒，其中官能化颗粒是SiO 2，Al 2 O 3或混合SiO 2和Al 2 O 3颗粒，其包含与表面上的氧原子共价结合的式（1）基团，其中R 1 和R2彼此独立地为氢，颗粒表面-O-或取代基，n为1,2,3,4,5,6,7或8，B为直接键或桥构件，D为 有机发色团的残留物。

公开(公告)号：US20090306382A1

公开(公告)日：2009-12-10

申请号：US12535747

申请日：2009-08-05

Applicant: ANDREAS Mühlebach ,  Peter Nesvadba ,  Andreas Kramer

Inventor： ANDREAS Mühlebach ,  Peter Nesvadba ,  Andreas Kramer

IPC: C07D241/08 ,  C07D401/12 ,  C07D211/68 ,  C07F9/28 ,  C07D211/98 ,  C07D211/00 ,  C07D221/20

CPC classification number: C08F4/00 ,  C07D211/94 ,  C07D241/08 ,  C07F9/4006 ,  C07F9/59

Abstract: The instant invention relates to cationic alkoxyamines, which are useful as polymerization initiators/regulators in a controlled stable free radical polymerization process to produce intercalated and/or exfoliated nanoparticles from natural or synthetic clays, The invention also relates to improved nanocomposites produced by this process and to the use of these nanocomposite compositions as, for example, coatings, sealants, caulks, adhesives and as plastic additives.

Abstract translation: 本发明涉及阳离子烷氧基胺，其可用作控制稳定的自由基聚合方法中的聚合引发剂/调节剂，以从天然或合成粘土生产嵌入和/或剥离的纳米颗粒。本发明还涉及通过该方法制备的改进的纳米复合材料， 涉及使用这些纳米复合组合物作为例如涂料，密封剂，填缝剂，粘合剂和作为塑料添加剂。

公开(公告)号：US07615522B2

公开(公告)日：2009-11-10

申请号：US10513837

申请日：2003-04-29

Applicant: Hugo Camenzind ,  Paul Dubs ,  Peter Hänggi ,  Roger Martin ,  Andreas Mühlebach ,  François Rime

Inventor： Hugo Camenzind ,  Paul Dubs ,  Peter Hänggi ,  Roger Martin ,  Andreas Mühlebach ,  François Rime

IPC: C08F8/00 ,  C08F293/00 ,  C08K5/00 ,  C10M145/00

CPC classification number: C08F293/005 ,  C08F8/26 ,  C08F8/30 ,  C08F8/34 ,  C08F8/40 ,  C08F2438/01 ,  C08K5/005 ,  C08F120/18

Abstract: The present invention relates to a block copolymer prepared by ATRP, wherein the polymer chain terminal group is structurally modified with the functionally effective group of a lubricant or polymer additive selected from the group consisting of antioxidants, metal deactivators, antiwear and extreme pressure additives and corrosion inhibitors. The invention also relates to a composition comprising the structurally modified block copolymer and a composition of matter subject to oxidative, thermal or light induced degradation, such as lubricants or polymers.

Abstract translation: 本发明涉及由ATRP制备的嵌段共聚物，其中聚合物链末端基团用功能有效的润滑剂或聚合物添加剂基团进行结构改性，所述润滑剂或聚合物添加剂选自抗氧化剂，金属钝化剂，抗磨和极压添加剂以及腐蚀 抑制剂。 本发明还涉及包含结构改性的嵌段共聚物和经受氧化，热或光诱导降解的物质组合物如润滑剂或聚合物的组合物。

公开(公告)号：US07595359B2

公开(公告)日：2009-09-29

申请号：US10519030

申请日：2003-06-17

Applicant: Andreas Mühlebach ,  Peter Nesvadba ,  Andreas Kramer

Inventor： Andreas Mühlebach ,  Peter Nesvadba ,  Andreas Kramer

IPC: C08K3/34

CPC classification number: C08F4/00 ,  C07D211/94 ,  C07D241/08 ,  C07F9/4006 ,  C07F9/59

Abstract: The instant invention relates to cationic alkoxyamines, which are useful as polymerization initiators/regulators in a controlled stable free radical polymerization process to produce intercalated and/or exfoliated nanoparticles from natural or synthetic clays. The invention also relates to improved nanocomposites produced by this process and to the use of these nanocomposite compositions as, for example, coatings, sealants, caulks, adhesives and as plastic additives.

Abstract translation: 本发明涉及阳离子烷氧基胺，其可用作控制稳定的自由基聚合方法中的聚合引发剂/调节剂，以从天然或合成粘土生产插层和/或剥离的纳米颗粒。 本发明还涉及通过该方法生产的改进的纳米复合材料以及这些纳米复合材料组合物作为例如涂料，密封剂，填缝剂，粘合剂和塑料添加剂的用途。

公开(公告)号：US20090217465A1

公开(公告)日：2009-09-03

申请号：US12084023

申请日：2006-10-16

Applicant: Christian Cremer ,  Andreas Mühlebach ,  Olof Wallquist ,  Thomas Giesenberg ,  Beate Fröhling ,  Richard Lewis Riggs

Inventor： Christian Cremer ,  Andreas Mühlebach ,  Olof Wallquist ,  Thomas Giesenberg ,  Beate Fröhling ,  Richard Lewis Riggs

IPC: A61K8/58 ,  A61K8/02

CPC classification number: C09C1/407 ,  A61K8/25 ,  A61K8/355 ,  A61Q5/065 ,  A61Q5/10 ,  B82Y30/00 ,  C01P2002/88 ,  C01P2004/62 ,  C01P2004/64 ,  C09C1/3063 ,  C09C1/3081 ,  C09C1/309 ,  C09C3/12

Abstract: Disclosed is a process for dyeing of keratin-containing fibers comprising treating the fibers with at least one functionalized particle comprising on the surface an organic chromophore which is bound via a bridge member, wherein the particles are based on SiO2, Al2O3 or mixtures thereof, and the functionalized particles carry a positive charge.

Abstract translation: 公开了一种用于染色含角蛋白纤维的方法，包括用至少一种官能化颗粒处理纤维，所述官能化颗粒在表面上包含通过桥构件结合的有机发色团，其中所述颗粒基于SiO 2，Al 2 O 3或其混合物，以及 官能化颗粒携带正电荷。

公开(公告)号：US07199177B2

公开(公告)日：2007-04-03

申请号：US10690652

申请日：2003-10-22

Applicant: Clemens Auschra ,  Andreas Mühlebach ,  Ernst Eckstein

Inventor： Clemens Auschra ,  Andreas Mühlebach ,  Ernst Eckstein

IPC: C08L53/00

CPC classification number: C08F293/005 ,  C08F2438/01 ,  C08K3/013 ,  C08L53/00 ,  C09B67/009 ,  C09D11/03 ,  C09D17/00 ,  C09D153/00 ,  C08L2666/02

Abstract: The present invention relates to a composition containing ATRP polymers and dispersible inorganic or organic pigment particles. The pigment composition is useful for preparing coating compositions, prints, images, inks or lacquers and other disperse systems.

Abstract translation: 本发明涉及含有ATRP聚合物和可分散的无机或有机颜料颗粒的组合物。 颜料组合物可用于制备涂料组合物，印刷品，图像，油墨或漆和其它分散体系。

公开(公告)号：US06465554B1

公开(公告)日：2002-10-15

申请号：US09647031

申请日：2000-09-25

Applicant: Paul Adriaan Van Der Schaaf ,  Roman Kolly ,  Andreas Mühlebach ,  Andreas Hafner

Inventor： Paul Adriaan Van Der Schaaf ,  Roman Kolly ,  Andreas Mühlebach ,  Andreas Hafner

IPC: C08K318

CPC classification number: C07F15/002 ,  C07F15/0046 ,  C08G61/06 ,  C08G61/08

Abstract: The invention relates to compositions of hexacoordinated ruthenium and osmium carbenes with a carbonyl group as ligand and a vinyl group as substituent on the carbene group as catalysts for the photoinduced ring-opening metathesis of strained cycloolefins. It also relates to novel hexacoordinated ruthenium and osmium carbenes having a carbonyl group as ligand and a vinyl group as substituent on the carbene group, to compositions of the catalyst with cycloolefins, and to the polymerization process.

Abstract translation: 本发明涉及六配位的钌和咔唑碳组合物，其中羰基作为配体，乙烯基作为卡宾的取代基，作为应变环烯烃的光诱导开环复分解的催化剂。 它还涉及具有羰基作为配体和乙烯基作为卡宾基团上的取代基的新型六配位钌和咔啉，催化剂与环烯烃的组成以及聚合方法。