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21.发明授权
公开(公告)号：US4758250A
公开(公告)日：1988-07-19
申请号：US57135
申请日：1987-06-01
Applicant: Daniel V. Laciak , Guido P. Pez
Inventor： Daniel V. Laciak , Guido P. Pez
IPC: B01D15/04 , B01D53/22 , B01D53/58 , B01D61/00 , B01D71/26 , B01D71/44 , B01D71/82 , B01J47/12 , C01C1/02 , C01C1/10 , C01C1/12 , C08F8/34 , C08J5/22 , D01F6/26 , B01D53/04
CPC classification number: C08J5/2231 , B01D71/44 , B01D71/82 , B01J47/12 , C08J2339/02 , Y10S95/90
Abstract: The present invention is a process for separating ammonia from mixtures of other gases or from aqueous streams. The ammonia containing mixture is contacted with an anion exchange polymer cast into membrane form, which selectively permeates NH.sub.3 thereby providing a separation from the other components in the mixture. Alternatively, ammonia recovery may be achieved by employing the said anion exchange polymer as a selective, reversible NH.sub.3 sorbent.
Abstract translation: 本发明是从其它气体或与水的混合物中分离氨的方法。 将含氨混合物与阴离子交换聚合物接触，所述阴离子交换聚合物浇铸成膜形式，其选择性渗透NH 3，从而提供与混合物中其它组分的分离。 或者，可以通过使用所述阴离子交换聚合物作为选择性可逆的NH 3吸附剂来实现氨回收。
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公开(公告)号：US4558157A
公开(公告)日：1985-12-10
申请号：US617305
申请日：1984-06-05
Applicant: John A. Marsella , Guido P. Pez
Inventor： John A. Marsella , Guido P. Pez
IPC: C07C231/00 , C07C233/00 , C07C102/00
CPC classification number: C07C231/00 , C07C233/00
Abstract: In the catalytic reaction of ammonia or formamide with CO and H.sub.2, exceptionally high yields of mono- and di-methyl formamide are obtained among the reaction products when the reaction is carried out in the presence of a platinum group catalyst soluble in the reaction medium, particularly a compound or complex of ruthenium or rhodium, employing a relatively non-volatile polar solvent which does not contain an active methyl function and which does not enter into the reaction producing formamide compounds. The pressure employed is in the range of 3000-8000 psi with a hydrogen partial pressure of at least 1500 psi, the preferred solvent being sulfolane.
Abstract translation: 在氨或甲酰胺与CO和H 2的催化反应中，当在可溶于反应介质的铂族催化剂存在下进行反应时，在反应产物中获得了特别高的单 - 和二 - 甲基甲酰胺的产率， 特别是钌或铑的化合物或络合物，其使用不含活性甲基官能团并且不进入生成甲酰胺化合物的反应的相对非挥发性极性溶剂。 所用的压力在3000-8000psi的范围内，氢分压至少为1500psi，优选的溶剂是环丁砜。
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公开(公告)号：US4356337A
公开(公告)日：1982-10-26
申请号：US317626
申请日：1981-11-02
Applicant: Guido P. Pez , Irving L. Mador
Inventor： Guido P. Pez , Irving L. Mador
CPC classification number: C07C5/11 , C07C2101/16
Abstract: Benzene or an alkylbenzene is reacted with hydrogen and an alkali metal such as potassium in the presence of a polyamine to produce cyclohexene or alkylcyclohexene and alkali metal hydride. The polyamine contains only C, N and H and has at least three nitrogens. Each nitrogen is linked to three carbons and each carbon bridge is at least two methylenes long. Representative polyamines are hexamethyl hexacyclen, hexamethyl triethylene tetraamine, tris(2-dimethylamino ethyl)amine and octamethyl pentaethylene hexamine. Cyclohexene is produced at high ratios with respect to cyclohexane.
Abstract translation: 在多胺的存在下，使苯或烷基苯与氢和碱金属如钾反应生成环己烯或烷基环己烯和碱金属氢化物。 多胺仅含有C，N和H，并且具有至少三个氮。 每个氮与三个碳相连，每个碳桥至少有两个亚甲基长。 代表性的多胺是六甲基六环，六甲基三亚乙基四胺，三（2-二甲基氨基乙基）胺和八甲基五亚乙基六胺。 相对于环己烷，环己烯的产率高。
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24.发明授权
公开(公告)号：US5141725A
公开(公告)日：1992-08-25
申请号：US669811
申请日：1991-03-15
Applicant: Dorai Ramprasad , Guido P. Pez , Ronald M. Pearlstein , Ingrid K. Meier
Inventor： Dorai Ramprasad , Guido P. Pez , Ronald M. Pearlstein , Ingrid K. Meier
CPC classification number: B01D53/02 , B01J20/0225 , B01J20/024 , B01J20/04 , B01J20/22 , B01J20/223 , B01J20/3071 , B01J20/3425 , B01J20/3483 , B01J20/3491
Abstract: A process is provided for selectively separating oxygen from an oxygen-containing fluid stream by bringing said fluid stream into contact with a high capacity solid state cyanocobaltate complex in a non-aluminosilicate environment represented by the chemical formula:A.sub.x/z.sup.z+ [Co(CN).sub.n ].sup.x- .multidot.pSwhere:A is an alkali, alkaline earth, transition, or Group 12 metal atom;z is 1, 2 or 3;n is any number from 3 to 5;x is n-2;p is any number from greater than zero to 6; andS is a ligand which is capable of coordinating with A.sup.z+, Co or both.These complexes chemically bind oxygen to form novel oxygen adducts, thereby selectively removing oxygen from the fluid stream. The bound oxygen may be recovered by increasing the temperature or by reducing the partial pressure of O.sub.2 above the adduct.
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公开(公告)号：US5026929A
公开(公告)日：1991-06-25
申请号：US477289
申请日：1990-02-08
Applicant: John A. Marsella , Guido P. Pez , Anne M. Coughlin
Inventor： John A. Marsella , Guido P. Pez , Anne M. Coughlin
IPC: C07C17/00
CPC classification number: C07C17/00
Abstract: A process is disclosed for making a highly fluorinated aromatic compound by contacting a perfluorocycloalkane, such as perfluorodecahydronaphthalene, with a complex of a metal from Groups IA and IIA of the Periodic Table and an organic electron acceptor. The reaction is carried out in an organic solvent and under reducing conditions which are relatively moderate. Best results are obtained using a perfluorocycloalkane having 2-4 condensed rings and a complex of either sodium or lithium and benzophenone thereby making a perfluorinated condensed ring aromatic compound such as perfluoronaphthalene or perfluorophenanthrene.
Abstract translation: 公开了通过使全氟环烷烃如全氟代十氢萘与元素周期表IA和IIA族金属络合物和有机电子受体接触来制备高度氟化的芳族化合物的方法。 该反应在有机溶剂中并在相对温和的还原条件下进行。 使用具有2-4个稠环的全氟环烷烃和钠或锂和二苯甲酮的络合物得到最佳结果，由此制得全氟化稠环芳族化合物如全氟萘或全氟菲。
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Patent Agency Ranking
公开(公告)号：US4973456A
公开(公告)日：1990-11-27
申请号：US261653
申请日：1988-10-24
Applicant: Robert Quinn , Guido P. Pez
Inventor： Robert Quinn , Guido P. Pez
CPC classification number: C10K1/14 , B01D53/1493 , C10K1/10 , C10K1/12
Abstract: The present invention is a process for reversibly absorbing acid gases, such as CO.sub.2, H.sub.2 S, SO.sub.2, HCN and the like from gas mixtures. The gas mixture containing one or more of these acid gases is contacted with a hydrated salt of the compositionA.sub.x.sup.m+ B.sub.y.sup.n-.rH.sub.2 Owherein A.sup.m+ is a cation, B.sup.n- is the conjugate base of a weak acid having a pKa corresponding to an ionization constant of the acid greater than 3 as measured in dilute aqueous solution, m and n are independently integers from 1-4, x and y are integers such that the ratio of x to y provides a neutral salt and r is any number greater than zero up to the maximum number of moles of water which can be bound to the salt. The salt hydrate reversibly absorbs the acid gas from the gas mixture.
Abstract translation: 本发明是从气体混合物中可逆地吸收诸如CO 2，H 2 S，SO 2，HCN等酸性气体的方法。 含有一种或多种这些酸性气体的气体混合物与组合物Axm + Byn-.H 2 O的水合盐接触，其中Am +是阳离子，Bn-是具有对应于电离常数的pKa的弱酸的共轭碱 的酸大于3，在稀水溶液中测定，m和n独立地为1-4的整数，x和y为整数，使得x与y的比例提供中性盐，r为大于零的任何数 达到可以与盐结合的水的最大摩尔数。 盐水合物从气体混合物中可逆地吸收酸性气体。
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公开(公告)号：US4762535A
公开(公告)日：1988-08-09
申请号：US57403
申请日：1987-06-02
Applicant: Guido P. Pez , Daniel V. Laciak
Inventor： Guido P. Pez , Daniel V. Laciak
IPC: B01D53/22 , B01D19/00 , B01D53/58 , B01D61/38 , B01D69/00 , B01D69/14 , C01C1/04 , C01C1/10 , C01C1/12 , C01C3/02 , C02F1/20
CPC classification number: B01D61/38 , B01D69/141 , C01C1/0458 , C01C1/12 , C01C3/0212 , Y02P20/52
Abstract: The present invention is a process for separating ammonia from mixtures of other gases or from aqueous streams. The ammonia-containing mixture is contacted with a membrane containing, as the active component, a salt having the structural formula: NR.sub.4.sup.+ X.sup.-, wherein each R is independently H or a straight chain or branched alkyl group and X.sup.- is an organic or inorganic anion. The membrane is useful for the selective permeation of ammonia from mixtures of gases containing ammonia, nitrogen and hydrogen.
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公开(公告)号：US4617029A
公开(公告)日：1986-10-14
申请号：US707298
申请日：1985-03-01
Applicant: Guido P. Pez , Richard T. Carlin
Inventor： Guido P. Pez , Richard T. Carlin
CPC classification number: B01D53/228 , B01D61/38 , Y10S423/12
Abstract: A process for separating a gas from a mixture of gases comprises passing the gas mixture over a membrane, selectively permeable by the gas being separated, owing to the occurrence of one or more reversible oxidation-reduction reactions between a continuous layer of active molten material, immobilized in a rigid, porous, inert support therefor, and the gas being separated.
Abstract translation: 一种从气体混合物中分离气体的方法包括使气体混合物通过可选择地被待分离气体渗透的膜，由于在连续的活性熔融材料层之间发生一次或多次可逆的氧化还原反应， 固定在刚性，多孔的惰性载体中，并且气体被分离。
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公开(公告)号：US4514337A
公开(公告)日：1985-04-30
申请号：US509528
申请日：1983-06-30
Applicant: Guido P. Pez
Inventor： Guido P. Pez
CPC classification number: C01B6/02 , B01J31/121 , C07C5/11 , B01J2231/646 , C07C2101/16 , C07C2531/12
Abstract: Benzene, or an alkylbenzene, is hydrogenated by reaction with hydrogen in the presence of a Group IVa or Va metal hydride catalyst. The catalyst may be a simple hydride such as ZrH.sub.2 or a hydride of an alloy such as Cu.sub.3 Zr or may be a complex material. One complex material is the reaction product of a Group IVa or Va metal halide, such as ZrCl.sub.4 with an alkyllithium or aryllithium, such as n-butyllithium, in a hydrocarbon solvent.
Abstract translation: 苯或烷基苯通过在IVa或Va族金属氢化物催化剂存在下与氢反应而氢化。 催化剂可以是简单的氢化物，例如ZrH 2或合金如Cu 3 Zr的氢化物，或者可以是复合材料。 一种复合材料是在烃溶剂中的IVa或Va族金属卤化物如ZrCl 4与烷基锂或芳基锂如正丁基锂的反应产物。
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30.发明授权Hydrogenation of esters using alkali doped heterogeneous Group VIII transition metal catalysts 失效使用碱掺杂的异构的第VIII族过渡金属催化剂氢化酯
公开(公告)号：US4359404A
公开(公告)日：1982-11-16
申请号：US306834
申请日：1981-09-29
Applicant: Roger A. Grey , Guido P. Pez
Inventor： Roger A. Grey , Guido P. Pez
CPC classification number: B01J31/1616 , B01J23/40 , B01J23/58 , B01J31/2226 , B01J31/2295 , B01J31/28 , C07C29/149 , C07C29/19 , B01J21/18 , B01J2231/643 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828 , Y02P20/52
Abstract: A novel class of heterogeneous catalysts, containing Group VIII transition metals in combination with alkali organic compounds is prepared, such as potassium naphthalene on ruthenium on carbon. The catalysts are useful as heterogeneous catalysts in the hydrogenation of carboxylic acid esters. A process for producing the materials is described. The catalysts permit the process of the hydrogenation of carboxylic acid esters to primary alcohols to be conducted with the ester in the liquid phase at a temperature not exceeding about 150.degree. C. with high selectivity. Catalysts of Group VIII transition metals and alkali metal on carbon are also useful in such processes.
Abstract translation: 制备了一类新颖的非均相催化剂，其中含有与碱性有机化合物组合的第VIII族过渡金属，例如萘上钌碳上的萘。 催化剂可用作羧酸酯氢化中的非均相催化剂。 对材料的制造方法进行说明。 催化剂允许羧酸酯与伯醇的氢化在液相中以不超过约150℃的温度以高选择性进行。 第VIII族过渡金属和碱金属碳的催化剂在这些方法中也是有用的。
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