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    Inorganic-organic plastic
    21.
    发明授权
    Inorganic-organic plastic 失效
    无机 - 有机塑料

    公开(公告)号：US4142030A

    公开(公告)日：1979-02-27

    申请号：US795834

    申请日：1977-05-11

    Applicant: Dieter Dieterich ,  Peter Markusch ,  Helmut Reiff

    Inventor： Dieter Dieterich ,  Peter Markusch ,  Helmut Reiff

    IPC: C04B28/00 ,  C04B28/24 ,  C08G18/08 ,  C08G18/30 ,  C08G18/38 ,  C08K3/34 ,  C08G18/32

    CPC classification number: C08G18/3895 ,  C04B28/003 ,  C04B28/24 ,  C08G18/0804 ,  C08G18/302 ,  C08K3/34

    Abstract: An inorganic-organic plastic having improved strength, elasticity, dimensional stability with increase in temperature and flame resistace and adapted for use in filling cracks and cavities and for making materials useful in the building industry is prepared by (1) premixing (c) an organic compound having at least two reactive hydrogen and at least one non-ionic hydrophilic group with (b) an aqueous silicate and then mixing the resulting mixture with (a) an organic polyisocyanate or (2) mixing (a), (b) and (c) simultaneously and reacting the mixture thus obtained to form a colloidal xerosol.

    Abstract translation: 具有改善的强度，弹性，尺寸稳定性，温度升高和阻燃性并适用于填充裂纹和空腔以及用于制造建筑工业中有用的材料的无机 - 有机塑料是通过（1）预混合（c）有机 具有至少两个反应性氢和至少一个非离子亲水基团的化合物与（b）硅酸水溶液混合，然后将所得混合物与（a）有机多异氰酸酯或（2）混合（a），（b）和（ c）同时并使由此获得的混合物反应以形成胶态干燥剂。

    Leather tanning with oligourethanes
    22.
    发明授权
    Leather tanning with oligourethanes 失效
    皮革鞣制与低聚氨酯

    公开(公告)号：US4106897A

    公开(公告)日：1978-08-15

    申请号：US718489

    申请日：1976-08-30

    Applicant: Harro Traubel ,  Helmut Reiff ,  Dieter Dieterich

    Inventor： Harro Traubel ,  Helmut Reiff ,  Dieter Dieterich

    IPC: C14C3/18

    CPC classification number: C14C3/18

    Abstract: This invention is concerned with a method of tanning or retanning leather or pelts by treating them with an aqueous liquor containing water-soluble oligourethanes having ionic groups. The oligourethanes have a molecular weight of from 300 to 20,000 and they may be methylolated. The oligourethanes may be water-soluble owing to their ionic groups or they may contain hydrophilic segments to aid in their solubility in the aqueous liquor. The liquor may also contain up to an equal amount of formaldehyde or compounds which split off formaldehyde.

    Abstract translation: 本发明涉及通过用含有具有离子基团的水溶性低聚氨酯的含水液体处理皮革或毛皮来鞣制或复鞣的方法。 低聚氨酯的分子量为300至20,000，它们可以是羟甲基化的。 寡聚氨酯由于其离子基团而可能是水溶性的，或者它们可以含有亲水链段以帮助其在含水液体中的溶解度。 该液体还可含有相等量的甲醛或分解甲醛的化合物。

    Colored poly (urethane) urea powders
    25.
    发明授权
    Colored poly (urethane) urea powders 失效
    彩色聚氨酯脲粉

    公开(公告)号：US3970601A

    公开(公告)日：1976-07-20

    申请号：US573491

    申请日：1975-05-01

    Applicant: Karl-Arnold Weber ,  Helmut Reiff ,  Dieter Dieterich

    Inventor： Karl-Arnold Weber ,  Helmut Reiff ,  Dieter Dieterich

    IPC: C08G18/08 ,  C09B69/10 ,  C08G18/00

    CPC classification number: C09B69/10 ,  C08G18/0804 ,  Y10T428/2998

    Abstract: The instant invention relates to thermoplastic polyurea powders, optionally containing urethane groups, characterized byA. a smooth, substantially spherical or lenticular surface,B. an average particle diameter of 5 to 1,000.mu., preferably 10 to 200.mu.,C. a urea group content, and, optionally, a urethane group content, of 8 to 30% by weight,D. an ionic group content of 0.01-0.15 milliequivalents per gram of solids, preferably 0.02-0.1 milliequivalent per gram andE. 0.1 to 10% by weight, preferably 0.2 to 5% by weight, of an organic dye incorporated in the polymer molecule by way of at least one urethane and/or urea group,And the process of manufacture thereof.

    Abstract translation: 本发明涉及任选地含有氨基甲酸酯基团的热塑性聚脲粉末，其特征在于A.A SMOOTH，主要的球形或透明表面，B.平均颗粒直径为5至1,000μm，优选10至200μm，尿素组 内容和可选择的URETHANE集团内容，按重量计，8至30％，D.固体含量为0.01-0.15百万分之一的离子组含量，优选0.02-0.1百万分之一百克，E. 0.1至10％ 重量，优选0.2至5％重量，有机染料以聚合物分子的方式通过至少一个URURHANE和/或UREA集团的方式及其制造过程。

    Liquid organic polyisocyanates containing carboxyl and/or carboxylate groups
    26.
    发明授权
    Liquid organic polyisocyanates containing carboxyl and/or carboxylate groups 失效
    含羧基和/或羧酸酯基的液体有机多异氰酸酯

    公开(公告)号：US3959348A

    公开(公告)日：1976-05-25

    申请号：US527389

    申请日：1974-11-26

    Applicant: Helmut Reiff ,  Peter Markusch ,  Dieter Dieterich

    Inventor： Helmut Reiff ,  Peter Markusch ,  Dieter Dieterich

    IPC: C09K17/00 ,  C04B38/02 ,  C07C67/00 ,  C07C239/00 ,  C07C269/02 ,  C08G18/08 ,  C08G18/34 ,  C08G18/38 ,  C08G18/42 ,  C08G18/80 ,  C09K17/30 ,  C07C119/048 ,  C07C155/02

    CPC classification number: C08G18/0823 ,  C08G18/348 ,  C08G18/3876 ,  C08G18/3895 ,  C08G18/4263 ,  C08G18/8003 ,  C08G18/8048

    Abstract: Liquid organic polyisocyanates containing carboxyl and/or carboxylate groups are prepared by reacting liquid multicomponent mixtures of aromatic polyisocyanates having an isocyanato content of about 10 to about 20% by weight and a viscosity of about 8 cP to about 10,000 cP at 25.degree.C withA. a compound which contains carboxylate groups and hydrogen atoms which are reactive with isocyanate groups; orB. a hydroxycarboxylic or mercaptocarboxylic acid, wherebyBa. at least partial conversion of the carboxyl group into the corresponding carboxylate group by neutralization with a base is carried out simultaneously with or after the isocyanate addition reaction orBb. the hydroxycarboxylic acid or mercaptocarboxylic acid is of the kind in which the carboxyl groups are much less reactive with the isocyanate groups than are the hydroxyl or mercapto groups, the quantitative proportion of the reactants being so chosen that the products of the process have an isocyanate content of 10 to 40% by weight and a carboxyl or carboxylate group content of 0.1 to 10% by weight. The polyisocyanates can be used to make inorganic-organic plastics.

    Abstract translation: 含有羧基和/或羧酸酯基团的液体有机多异氰酸酯是通过使具有约10至约20重量％的异氰酸酯基含量的芳族多异氰酸酯的液体多组分混合物与25℃下的约8cP至约10,000cP的粘度与A 含有与异氰酸酯基团反应的羧酸酯基团和氢原子的化合物; 或B.羟基羧基或邻甲氧基苯甲酸，其中BA。 通过与基质中和的羧基相对于羧酸酯基团的至少部分转化与异氰酸酯添加反应或BB同时进行。 羟基羧基酸或羧甲氧基酸是这样的种类，其中羧酸基团与异羟基化合物没有反应，而不是羟基或甘油聚糖组，反应物的定量比例表明该方法的产物具有异氰酸酯的含量 10-40重量％，羧基或羧酸酯基含量为0.1〜10重量％。 多异氰酸酯可用于制备无机 - 有机塑料。

    Bisulfite-blocked polyisocyanates as tanning agents
    30.
    发明授权
    Bisulfite-blocked polyisocyanates as tanning agents 失效
    亚硫酸氢盐封端的多异氰酸酯作为鞣剂

    公开(公告)号：US5618317A

    公开(公告)日：1997-04-08

    申请号：US456972

    申请日：1995-06-01

    Applicant: Harro Traubel ,  Helmut Reiff

    Inventor： Harro Traubel ,  Helmut Reiff

    IPC: C08G18/30 ,  C08G18/80 ,  C14C3/18 ,  C14C3/22 ,  A61K7/42 ,  C08G18/52

    CPC classification number: C14C3/18

    Abstract: The present invention relates to tanning agents containing carbamoyl sulfonate groups that are prepared by the reaction of(A) organic polyisocyanates,(B) 0.01 to 0.4 equivalents, relative to the isocyanate groups of polyisocyanate (A), of polyether alcohols having incorporated polyalkylene oxide units (the equivalents of the polyether alcohol being based on the hydroxyl groups), wherein 40 to 100 mole-% of the polyalkylene oxide units consist of polyethylene oxide units having a sequence length of 5 to 70,(C) optionally, NCO-reactive components other than polyether polyol (B), and(D) ammonium or alkali bisulfites or disulfites.

    Abstract translation: 本发明涉及含有氨基甲酰磺酸盐基团的鞣剂，其通过（A）有机多异氰酸酯反应制备，（B）相对于多异氰酸酯（A）的异氰酸酯基为0.01〜0.4当量，具有掺合聚环氧烷的聚醚醇 单元（聚醚醇基于羟基的当量），其中40-100摩尔％的聚环氧烷单元由序列长度为5-70的聚环氧乙烷单元组成，（C）任选的NCO-反应性 除聚醚多元醇（B）以外的成分，（D）铵或碱式亚硫酸氢盐或亚硫酸氢盐。

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